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    Coordination Compounds - Short Notes - Prayas JEE 2.0 2024

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    aryasushama2611
    1. Coordination compounds consist of a central metal ion bonded to surrounding ligand atoms or molecules. The coordination number refers to the number of ligands bonded to the central metal ion. 2. Coordination compounds form when the metal ion provides hybridized orbitals to accept lone pairs from ligands. The ligand strength, hybridization state of the metal ion, and geometry of the complex determine its magnetic behavior. 3. Organometallic compounds contain direct bonds between carbon atoms in ligands and the central metal ion. These include s-bonded and p-bonded organometallic compounds like metal carbonyls.

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    Coordination Compounds - Short Notes - Prayas JEE 2.0 2024

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    aryasushama2611
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    1. Coordination compounds consist of a central metal ion bonded to surrounding ligand atoms or molecules. The coordination number refers to the number of ligands bonded to the central metal ion. 2. Coordination compounds form when the metal ion provides hybridized orbitals to accept lone pairs from ligands. The ligand strength, hybridization state of the metal ion, and geometry of the complex determine its magnetic behavior. 3. Organometallic compounds contain direct bonds between carbon atoms in ligands and the central metal ion. These include s-bonded and p-bonded organometallic compounds like metal carbonyls.

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    Coordination Compounds _ Short Notes __ Prayas JEE 2.0 2024

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    1. Coordination compounds consist of a central metal ion bonded to surrounding ligand atoms or molecules. The coordination number refers to the number of ligands bonded to the central metal ion. 2. Coordination compounds form when the metal ion provides hybridized orbitals to accept lone pairs from ligands. The ligand strength, hybridization state of the metal ion, and geometry of the complex determine its magnetic behavior. 3. Organometallic compounds contain direct bonds between carbon atoms in ligands and the central metal ion. These include s-bonded and p-bonded organometallic compounds like metal carbonyls.

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    64 views1 page

    Coordination Compounds - Short Notes - Prayas JEE 2.0 2024

    Uploaded by

    aryasushama2611
    1. Coordination compounds consist of a central metal ion bonded to surrounding ligand atoms or molecules. The coordination number refers to the number of ligands bonded to the central metal ion. 2. Coordination compounds form when the metal ion provides hybridized orbitals to accept lone pairs from ligands. The ligand strength, hybridization state of the metal ion, and geometry of the complex determine its magnetic behavior. 3. Organometallic compounds contain direct bonds between carbon atoms in ligands and the central metal ion. These include s-bonded and p-bonded organometallic compounds like metal carbonyls.

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    of 1

    CHAPTER

    11 Coordination Compounds

    Representation of Complex Compound Exception


    ligand
    ™ d3s hybridisation, Td, diamagnetic, inner orbital complex eg.
    co-ordination n± charge on
    MLX coordination sphere MnO 4– , CrO 2– 2– 3–
    sphere 4 , Cr2 O 7 , CrO 2 Cl 2 , CrO 2 F2 , VO 4
    central metal ion number of ligand ™ Transference of electron
    Co-ordination number = Number of atoms surrounded to eg. Cu+2 in C.N. → 4 with L
    central metal ion. -
    Notes: (where L = NO 2 / CN– / NH3 etc.)
    Bidentate and Polydentate are also called chelating ligand. Organometallic Compounds
    Bonding in Coordination Compound Compounds in which the less E.N. (Ge, Sb, B, Si, P, As) central
    Effective Atomic Number & Sidgwick Rule metal atoms are bonded directly to carbon atoms are called
    Total number of electron present on central metal atom or ion organometallic compounds.
    after accepting the electron pair from ligand.
    ™ s-bonded compounds formed by nontransition elements.
    VBT R-Mg-X, (CH3–CH2)2 Zn, Ziegler natta catalyst, etc.
    ™ Metal provoide hybridised vacant orbital for the acceptance
    of lone pair from ligand. ™ p-bonded organometallic compounds are generally formed
    ™ Hybridisation, shape and magnetic behaviour of complex by transition elements e.g. Zeise’s salt, ferrocene, dibenzene
    depends upon the nature of ligand. chromium, etc.
    ™ Strong field ligand pair up the unpaired e– of central metal ™ s-and p-bonded organometallic compounds: Metal carbonyls
    atom where as weak field ligand does not.
    ™ If unpaired e– present in complex then complex is compounds formed between metal and carbon monoxide
    paramagnetic. If unpaired e– is absent then diamagnatic. belong to this class. Ni(CO)4, Fe(CO)5 etc.
    eg. C.N. = 4; [NiCl4]2–
    Stereo Isomerism
    Series which shows the Relative Strength of Ligands
    I– (weakest) < Br– < SCN– < Cl– < S2– < F– < OH– < C2O42– < H2O Stereo Isomerism in Co-ordination Compound
    < NCS– < edta4– < NH3 < en < CN– < CO(strongest) CN-4
    Exception ™ Square planar complex does not show optical isomerism.

    [Co(OX)3]3– d2sp3 diamagnetic ™ Square planar complex show optical activity if the co-ordinated
    ligand having chiral center.
    [Co(H2O)6]3+ d2sp3 diamagnetic
    ™ Square planar complex
    [NiF6]2– d2sp3 diamagnetic ™ [Ma2b2]n± , [Ma2bc]n± , [Mabcd]n± , [M(AB)cd]n±
    [Cr(NH3)6 ]2+ sp3d2 paramagnetic ™ [M(AB)(CD)]n± show geometrical isomerism
    [Mn(NH3)6]2+ sp3d2 paramagnetic ™ [Mabcd]n± form two cis and one trans.

    [Fe(NH3)6]2+ sp3d2 paramagnetic ™ Tetrahedral complex [Mabcd]n±, [M(AB)cd]n± [M(AB)(CD)] n±


    show optical isomerism
    [CoL6]4– (L = NO2– /CN–) d2sp3 paramagnatic
    ™ Tetrahdral complex does not show geometrical isomerism.

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