Chem 7 Organic Chem Principles

Physical World, Units and Measurements P-1
Organic Chemistry - Some Basic

Principles & Techniques
Numerical
Q.1. The total number of chiral compound/s from the following is

______________.
JEE Main 2023 (Online) 1st February Morning Shift

Answer Key & Explanation
1. Ans. Correct answer is 2

Explanation
MCQ (Single Correct Answer)
Q.1. Decreasing order of reactivity towards electrophilic

substitution for the following compounds is :
JEE Main 2023 (Online) 15th April Morning Shift
Q.2. Given below are two statements :
Statement I : Tropolone is an aromatic compound and

has 8π electrons.
Statement II : π electrons of >C=O group in tropolone is involved
in aromaticity.
In the light of the above statements, choose the correct answer

from the options given below:
JEE Main 2023 (Online) 13th April Evening Shift
Q.3. Given below are two statements, one is labelled as Assertion

A and the other is labelled as Reason R.
Assertion A : Order of acidic nature of the following compounds is

A > B > C.
Reason R : Fluoro is a stronger electron withdrawing group than
Chloro group.

Q.4. Among the following compounds, the one which shows

highest dipole moment is

A and the other is labelled as Reason R.
Assertion A : A solution of the product obtained by heating a mole

of glycine with a mole of chlorine in presence of red phosphorous
generates chiral carbon atom.
Reason R : A molecule with 2 chiral carbons is always optically

active.
Q.6. The decreasing order of hydride affinity for following

carbocations is:
Choose the correct answer from the options given below:
Q.7. The correct order for acidity of the following hydroxyl

compound is :
A. CH3OH
B.
Q.8. The pair from the following pairs having both compounds
with net non-zero dipole moment is
Q.9. The correct IUPAC nomenclature for the following compound

is:
Q.10. The descending order of acidity for the following carboxylic

acid is-
A. CH3COOH
B. F3C−COOH
C. ClCH2−COOH
D. FCH2−COOH
E. BrCH2−COOH

Q.11. The strongest acid from the following is

Q.12. Resonance in carbonate ion is
Which of the following is true?
JEE Main 2023 (Online) 1st February Morning Shift

Q.13. The most stable carbocation for the following is:
JEE Main 2023 (Online) 30th January Evening Shift
Q.14. The correct order of pKa values for the following compounds
is:
Q.15. The increasing order of pKa for the following phenols is
(A) 2, 4 - Dinitrophenol
(B) 4 - Nitrophenol
(C) 2, 4, 5 - Trimethylphenol
(D) Phenol
(E) 3-Chlorophenol
Choose the correct answer from the option given below :

JEE Main 2023 (Online) 29th January Morning Shift
Q.16. Match List I with List II
List I List II
Isomeric pairs Type of isomers
A. Propanamine and N- I. Metamers

Methylethanamine
B. Hexan-2-one and Hexan-3-one II. Positional

isomers
C. Ethanamide and III. Functional

Hydroxyethanimine isomers
D. o-nitrophenol and p-nitrophenol IV. Tautomers
Choose the correct answer from the options given below :

Q.17. Which of the following conformations will be the most
stable?
Q.18. The correct order in aqueous medium of basic strength in

case of methyl substituted amines is :

A and the other is labelled as Reason R
Assertion A : Benzene is more stable than hypothetical

cyclohexatriene
Reason R : The delocalised π electron cloud is attracted more

strongly by nuclei of carbon atoms.
Q.20. Which will undergo deprotonation most readily in the basic

medium?
Q.21. Increasing order of stability of the resonance structures is :

Answer key & Explanation
1. Ans. (D)
Explanation
Higher the electron density on Benzene Ring, Higher its Reactivity
towards electrophilic substitution Reaction
2. Ans. (C)
Explanation
Tropolone is an aromatic compound, and it contains a seven-
membered ring with six carbon atoms and one oxygen atom. The
oxygen atom is doubly bonded to one of the carbon atoms,
forming a carbonyl group (C=O). The remaining carbon atoms
form a conjugated ring system. The oxygen atom's lone pair of
electrons also participates in the conjugation, making the
molecule aromatic.
Let's analyze the given statements:
Statement I: Tropolone is an aromatic compound and has 8 π

electrons. This statement is true. Tropolone is aromatic and has 6
π electrons from the carbon atoms in the ring and 2 π electrons
from the oxygen atom's lone pair, resulting in a total of 8 π
electrons.
Statement II: π electrons of >C=O group in tropolone are involved
in aromaticity. This statement is false. In tropolone, the oxygen
atom's lone pair participates in the conjugation and contributes to
the aromaticity, not the π electrons of the C=O bond.
Based on the analysis, the correct answer is:
Statement I is true, but Statement II is false.

3. Ans. (A)
Explanation
Among A and B; since inductive effect is distance dependent,

Extent of −I effect is higher in A followed by B even though F is
stronger electron withdrawing group than Cl. Thus, A is more
acidic than B.
4. Ans. (D)
Explanation
Among the given compounds, the following compound has the
highest dipole moment because both the +ve and -ve ends
acquire aromaticity.
5. Ans. (C)
Explanation
As for Reason R, it is false. A molecule with 2 chiral carbons is not

necessarily optically active. It may be if the molecule is not
superimposable on its mirror image (i.e., it's chiral). But if the
molecule is superimposable on its mirror image (i.e., it's achiral),
then it will not be optically active. This can occur if the molecule
has a plane of symmetry, in which case it is a meso compound.
6. Ans. (B)
Explanation
Least stable carbocation will have highest hydride affinity.
Stability of carbocation:
7. Ans. (A)
Explanation
8. Ans. (B)
Explanation
The correct option from the pairs having both compounds with a
net non-zero dipole moment is:
Option A: cis-butene, trans-butenecis-butene, trans-butene cis-

butene has a net dipole moment because the two alkyl groups are
on the same side of the molecule, causing an imbalance in the
distribution of electrons. However, trans-butene is symmetric, so
the dipole moments of the two alkyl groups cancel each other out,
giving it a net dipole moment of zero. Therefore, this pair does not
have both compounds with a net non-zero dipole moment.
Option
B: CHClCHClCH2Cl2,CHCl3 Both CHClCH2Cl2 (dichloromethane)
and CHClCHCl3 (chloroform) have a net non-zero dipole moment
due to the difference in electronegativity between the hydrogen
and chlorine atoms. Hence, this pair has both compounds with a
net non-zero dipole moment.
Option C: Benzene, AnisidineBenzene, Anisidine Benzene has a

symmetrical structure, leading to a net zero dipole moment.
Anisidine, however, does have a net dipole moment due to the
asymmetry in its structure. Therefore, this pair does not have
both compounds with a net non-zero dipole moment.
Option D: 1,4-Dichlorobenzene, 1,3-Dichlorobenzene1,4-

Dichlorobenzene, 1,3-Dichlorobenzene 1,4-Dichlorobenzene1,4-
Dichlorobenzene has a symmetrical structure, leading to a net
zero dipole moment. However, 1,3-Dichlorobenzene1,3-
Dichlorobenzene has a non-zero dipole moment due to the
asymmetry in its structure. Therefore, this pair does not have
both compounds with a net non-zero dipole moment.
9. Ans. (D)
Explanation
IUPAC name of the following compound is
2-Methyl-5-oxohexanoic acid
10. Ans. (C)
Explanation
The acidity of carboxylic acids is influenced by the electron-
withdrawing ability of the groups attached to the carboxylic acid.
The stronger the electron-withdrawing ability of the group, the
more it stabilizes the carboxylate anion (formed after losing the
acidic proton), and hence the stronger the acid.
Let's look at the groups attached to the carboxylic acid in each

option:
A. CH3−: Methyl group. It's electron-donating due to the

hyperconjugation effect.
B. F3C−: Trifluoromethyl group. Strong electron-withdrawing

group due to the electronegativity of fluorine atoms and inductive
effect.
C. ClCH2−: Chloromethyl group. It has some electron-withdrawing
ability due to the electronegativity of the chlorine atom, but it's
less than that of fluorine.
D. FCH2−: Fluoromethyl group. It has electron-withdrawing

ability due to the electronegativity of the fluorine atom, but less
than that of the trifluoromethyl group.
E. BrCH2−: Bromomethyl group. It has some electron-

withdrawing ability due to the electronegativity of the bromine
atom, but it's less than that of chlorine and fluorine.
So the order of acidity will be: B > D > C > E > A
11. Ans. (B)

12. Ans. (D)
Explanation
Resonating structure are hypothetical and resonance hybrid is
real structure which is weighted average of all the resonating
structures.
13. Ans. (C)
Explanation
The +M effect of NH2 is stabilizing the carbocation.

14. Ans. (C)
Explanation
Higher the value of Ka or lower the value pKa, stronger will be the
acid.
Presence of electron donating groups destabilises the phonoxide

ion, thus, reduces acidic nature of phenol. Presence of electron
withdrawing group stabilises the phenoxide ion thus increase the
acidic strength of phenol.
Thus, order of acidic strength is:
- Order of pKa will be = b > d > a > c

Acid Strength : -
Acids : Acids are those molecules which donates H+ ion in

aqueous solution (water) and increases concentration of H + ion
in water.
Dissociation constant of this reaction is K a. It is called ionisation

constant.
→ So we can say if a acid form more H+ ion after adding it in H2O

then that acid is called strong acid. If acid produce less H + ion in
H2O then that acid is weak acid.
15. Ans. (D)

Explanation
Order of acidity for following phenol is A > B > E > D > C.
- M and – I increases acidity.
+ M and + I decreases acidity.
∴ Their pKa value is A < B < E < D < C.

16. Ans. (A)
Explanation
A. Propanamine N–Methylethanamine
B. Hexan–2–one Hexan–3–one
C. Ethanamide Hydroxyethanimine
D. o–Nitrophenol p–nitrophenol
17. Ans. (A)
Explanation
18. Ans. (C)

Explanation
In aqueous medium basic strength is dependent on electron
density on nitrogen as well as solvation of cation formed after
accepting H+. After considering all these factors overall basic
strength order is
19. Ans. (B)

Explanation
Benzene is more stable than hypothetical cyclohexatriene due to
the delocalization of electrons in the π electron cloud of the
aromatic ring. This delocalization of electrons leads to a more
stable electronic configuration in benzene, as the electrons are
shared more evenly between all six carbon atoms in the ring. This
is in agreement with Assertion A.
Reason R is also correct, as the delocalized π electron cloud in the

aromatic ring is attracted more strongly by the nuclei of the
carbon atoms. This is due to the fact that the π electrons in the
ring are more spread out and are not localized to a single atom,
which makes them more attracted to the positively charged nuclei
of the carbon atoms. This explanation supports Assertion A.
20. Ans. (A)

Explanation
Most easily deprotonation
21. Ans. (C)

Explanation
2022
Numerical
Q.1. Optical activity of an enantiomeric mixture is +12.6∘ and the specific

rotation of (+) isomer is +30∘. The optical purity is __________%.
JEE Main 2022 (Online) 27th July Morning Shift
Q.2. Total number of isomers (including stereoisomers) obtained on

monochlorination of methylcyclohexane is ___________.
JEE Main 2022 (Online) 26th July Evening Shift
Q.3. The total number of monobromo derivatives formed by he alkanes

with molecular formula C5H12 is (excluding stereo isomers) __________.
Q.4. The number of sp3 hybridised carbons in an acyclic neutral compound

with molecular formula C4H5N is ___________.
Q.5. Observe structures of the following compounds
The total number of structures/compounds which possess asymmetric

carbon atoms is ______________.
JEE Main 2022 (Online) 29th June Morning Shift
Q.6. Total number of possible stereoisomers of dimethyl cyclopentane is

____________.
Q.7. Number of electrophilic centres in the given compound is
_______________.

Explanation

Explanation
Compounds formed on mono-chlorination of methylcyclohexane are :
Total mono-chlorinated products formed = 12

Explanation
Total mono bromo derivatives = 8

Explanation
3 double bond equivalent are present in compound
Only 1 sp3 hybridised carbon is there
(Keeping compound as acyclic)

Explanation
The number of compounds containing asymmetric carbons is three.

Explanation
Dimethyl cyclopentane
will show stereo isomerism, Its stereo isomers are
will show stereo isomerism, Its stereo isomers are

7 Ans. Correct answer is 3
Explanation
Given compounds :
Number of electrophilic centres = 3

Q.1. Given below are two statements.
Statement I : The compound is optically active.
Statement II : is mirror image of above compound A.
In the light of the above statement, choose the most appropriate answer
from the options given below.
In the light of the above statement, choose the most appropriate answer
Q.2. Which among the following is the strongest Bronsted base?

Q.3. Match List - I with List - II.

Q.4. Among the following marked proton of which compound shows

lowest pKa value?
Q.5. Given below are two statements: one is labelled as Assertion A and,
the other is labelled as Reason R.
Assertion A: [6] Annulene, [8] Annulene and cis-[10] Annulene, are

respectively aromatic, not-aromatic and aromatic.
Reason R: Planarity is one of the requirements of aromatic systems.
In the light of the above statements, choose the most appropriate answer
Q.6. The correct decreasing order of priority of functional groups in

naming an organic Question: compound as per IUPAC system of
nomenclature is
Q.7. Which of the following compounds is not aromatic?

Q.8. Arrange the following in decreasing acidic strength.

Q.9. Which of the following carbocations is most stable?
JEE Main 2022 (Online) 29th June Evening Shift

Q.10. The correct IUPAC name of the following compound is :
Q.11. Which of the following structure are aromatic in nature?

Q.12. Which of the following is most stable?

Q.13. The correct order of nucleophilicity is
Q.14. In the following structures, which on is having staggered

conformation with maximum dihedral angle?
Q.15. The IUPAC name of ethylidene chloride is :
Q.16. Arrange the following carbocations in decreasing order of stability.

Q.17. Which of the following is an example of conjugated diketone

1. Ans. (C)
Explanation
Compound (A) in Statement-I and compound in Statement-II is not the

mirror image of (I).
2. Ans. (D)
Explanation
3. Ans. (C)
Explanation
4. Ans. (C)
Explanation
The conjugate base of compound (C) is stabilized by extended conjugation.
Hence the indicated proton of compound C is most acidic i.e. will have
lowest pKa.
5. Ans. (D)
Explanation
[6] Annulene is aromatic because it is planar.
[8] Annulene and [10] Annulene are both not aromatic because they are not
planar. So, Assertion (A) is not correct.
Reason (R) is correct because planarity is one of the requirements of

aromatic system.
6. Ans. (B)
Explanation
The order of decreasing priority for the functional group is
Hence correct order is
7. Ans. (C)
Explanation
[10] Annulene, although follow (4n + 2)π electron rule, but it is non-aromatic
due to its non planar nature. It is nonplanar due to repulsion of C – H bonds
present inside the ring.
8. Ans. (A)
Explanation
9. Ans. (D)
Explanation
is most stable carbocation
10. Ans. (C)

Explanation
11. Ans. (B)

Explanation
12. Ans. (A)

Explanation
1,3-cyclohexadiene is most stable because it is a neutral molecule. All

others are intermediates and hence less stable.
13. Ans. (D)

Explanation
Conjugate base of acid is always a stronger nucleophile.
14. Ans. (C)

Explanation
It is the staggered conformation with maximum dihedral angle.
15. Ans. (D)

Explanation
Ethylidene chloride is CH3– CHCl2, its IUPAC name is 1,1-Dichloromethane.
16. Ans. (A)

Explanation
The given carbocations are
Carbocation (A) is stabilised by hyperconjugation due to 4α hydrogen

atoms. Carbocation (C) is also stabilised by hyperconjugation due to 4 a
hydrogen atoms but destabilised by −1 effect of O-atom. Carbocation (B) is
most stable as it is stabilised by resonance.
∴ Correct decreasing order of stability is B > A > C
17. Ans. (C)

Explanation
In the rest of the diketones given in the question, the two (C = O) groups are
not in conjugation with each other.
2021
Numerical
Q.1 The dihedral angle in staggered form of Newman projection of 1, 1, 1-Trichloro
ethane is ___________ degree. (Round off to the nearest integer)
27th July Evening Shift 2021
Q.2 The number of sigma bonds in
is _______________.
25th July Morning Shift 2021
Q.3 The number of acyclic structural isomers (including geometrical isomers) for
pentene are ___________.
Numerical Answer Key
1. Ans. (60)
2. Ans. (10)
3. Ans. (6)
Numerical Explanation
Ans 1. 1, 1, 1-Trichloro ethane [CCl3-CH3]
Ans 2.
Numbers of σ bonds = 10
Ans 3.
Q.1 Arrange the following conformational isomers of n-butane in order of their

increasing potential energy:
31st Aug Evening Shift 2021
Q.2 Choose the correct name for compound given below :

31st Aug Morning Shift 2021
Q.3 The compound/s which will show significant intermolecular H-bonding is/are :
27th Aug Evening Shift 2021
Q.4 The number of stereoisomers possible for 1, 2-dimethyl cyclopropane is :
Q.5 Which one of the following compounds is not aromatic?

Q.6 Given below are two statements :
Statement I : Hyperconjugation is a permanent effect.
Statement II : Hyperconjugation in ethyl cation
involves the overlapping of Csp2−H1s bond with empty 2p orbital of other carbon.
Choose the correct option :
Q.7
The correct order of stability of given carbocation is :

Q.8 Which among the following is the strongest acid ?
Q.9 The correct decreasing order of densities of the following compounds is :

Q.10 Which one among the following resonating structures is not correct?
Q.11 Which of the following molecules does not show stereo isomerism?
Q.12 Which of the following compounds does not exhibit resonance?

Q.13
The correct order of their reactivity towards hydrolysis at room temperature is :
Q.14 Which one of the following pairs of isomers is an example of metamerism?

Q.15
Among the given species the Resonance stabilised carbocations are :
Q.16 Given below are two statements :

Statement I : C2H5OH and AgCN both can generate nucleophile.
Statement II : KCN and AgCN both will generate nitrile nucleophile with all reaction
conditions.
Choose the most appropriate option :
18th March Evening Shift 2021
Q.17 In the following molecule,
Hybridisation of Carbon a, b, and c respectively are :

Q.18 Compound with molecular formula C3H6O can show :
18th March Morning Shift 2021
Q.19 Which of the following is an aromatic compound?

Q.20 Which of the following is least basic?
Q.21 Match List - I with List - II :
List - I List - II
Test/Reagents/Observation(s) Species detected
(a) Lassaigne's Test (i) Carbon
(b) Cu(II) oxide (ii) Sulphur
(c) Silver nitrate (iii) N, S, P, and halogen
(d) The sodium fusion extract (iv) Halogen Specifically
gives black precipitate with
acetic acid and lead acetate
The correct match is :

Q.22 Among the following, the aromatic compounds are :
Choose the correct answer from the following options :
Q.23 In
molecule, the hybridization of carbon 1, 2, 3 and 4 respectively, are :
26th Feb Evening Shift 2021

Q.24 Which of the following is 'a' FALSE statement ?
26th Feb Morning Shift 2021
Q.25 The correct order of acid character of the following compounds is :
25th Feb Evening Shift 2021
Q.26 Which one of the following compounds is non-aromatic?
24th Feb Evening Slot 2021

Q.27 The correct order of the following compounds showing increasing tendency
towards nucleophilic substitution reaction is :
24th Feb Evening Slot 2021
MCQ Answer Key
1. Ans. (C) 10. Ans. (A) 19. Ans. (A)

2. Ans. (D) 11. Ans. (C) 20. Ans. (A)
3. Ans. (A) 12. Ans. (D) 21. Ans. (C)
4. Ans. (D) 13. Ans. (A) 22. Ans. (B)
5. Ans. (C) 14. Ans. (D) 23. Ans. (A)
6. Ans. (C) 15. Ans. (C) 24. Ans. (A)
7. Ans. (A) 16. Ans. (D) 25. Ans. (C)
8. Ans. (D) 17. Ans. (A) 26. Ans. (D)
9. Ans. (A) 18. Ans. (D) 27. Ans. (D)
MCQ Explanation
Ans 1. More stable less potential energy.

Stability order : I > III > IV > II
So
Potential energy : II > IV > III > I
Ans 2.
First prioritise the groups according to CIP rule

It is (2E)-2-Bromo-hex-2-en-4-yne
Ans 3. (a) Shows intra molecular H-bonding

(b) Shows significant intermolecular H-bonding
(c) It do not show intermolecular H-bonding due to steric hindrance.
Ans 4.
Ans 5.
Ans 6. Statement I : It is correct statement
Ans 7.
Ans 8.
Strongest acid because its conjugate base is aromatic

Ans 9. The density order
Ans 10.
It is unstable Resonating Structure (due to similar charge on adjacent atom).
Ans 11.
Ans 12. CH3−CH2−CH = CH−CH2−NH2
No conjugation thus resonance is not possible.
Ans 13.
Ans 14.
Ans 15.
Ans 16. Both C2H5OH and AgCN can generate nucleophile.

KCN generates nitriles on substitution reactions with haloalkanes where AgCN
generates isonitriles on substitution reactions with haloalkanes. Because KCN is
ionic and has ‘C’ nucleophilic centre whereas AgCN is covalent and has ‘N’
nucleophilic centre.
Ans 17.
Ans 18. C3H6O (degree of unsaturation = 1)
Functional group isomerism.
Ans 19. A compound which has (4n + 2)π electrons completely delocalised over the
cyclic ring is aromatic.
Here 6 π electrons are present which follow the rule.
Ans 20. Basic strength ∝ availability of lone pair.
••
In this case lone pair of is highly participating in resonance.
𝑁
Ans 21. (i) Lassaigne test is used to detect N, S, P, X element
(ii) Carbon and hydrogen are detected by heating the compound with copper (ii)
oxide.
(iii) Halides are detected by silver nitrate
(iv) Sodium fusion extract gives black ppt. with acetic acid and lead acetate to
confirm the presence of sulphur.
Ans 22.
Ans 23.
Ans 24. Carius method is used in the estimation of halogen and sulphur in organic
compounds.
Ans 25. Acidic strength
Since carboxylic acids are more acidic than phenols.

–I and – R effect increase the acidic strength where as +I and +R effect decrease the
acidic strength of carboxylic acids.
Ans 27.
MCQ (More than One Correct Answer)
Q.1 Which one of the following compounds is aromatic in nature?
MCQ Answer Key
1. Ans. A and D
MCQ Explanation
Ans 1. (a) (Acenaphthene)
→ 10 πe− in cyclic conjugation

⇒ Aromatic
(b)
→ 4 πe− in ring conjugation ⇒ Anti Aromatic

(c)
⇒ 4 πe− in ring conjugation ⇒ Antiaromatic

(d)
6πe− in ring conjugation ⇒ Aromatic

Chem 7 Organic Chem Principles

Uploaded by

Copyright:

Available Formats

Chem 7 Organic Chem Principles

Uploaded by

Document Information

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Chem 7 Organic Chem Principles

Uploaded by

Copyright:

Available Formats

Physical World, Units and Measurements P-1

Organic Chemistry - Some Basic

Q.1. The total number of chiral compound/s from the following is

JEE Main 2023 (Online) 1st February Morning Shift

1. Ans. Correct answer is 2

Q.1. Decreasing order of reactivity towards electrophilic

JEE Main 2023 (Online) 15th April Morning Shift

Q.2. Given below are two statements :

Statement I : Tropolone is an aromatic compound and

In the light of the above statements, choose the correct answer

JEE Main 2023 (Online) 13th April Evening Shift

Q.3. Given below are two statements, one is labelled as Assertion

Assertion A : Order of acidic nature of the following compounds is

In the light of the above statements, choose the correct answer

JEE Main 2023 (Online) 13th April Evening Shift

Q.4. Among the following compounds, the one which shows

Q.5. Given below are two statements, one is labelled as Assertion

Assertion A : A solution of the product obtained by heating a mole

Reason R : A molecule with 2 chiral carbons is always optically

JEE Main 2023 (Online) 11th April Evening Shift

Q.6. The decreasing order of hydride affinity for following

JEE Main 2023 (Online) 10th April Evening Shift

Q.7. The correct order for acidity of the following hydroxyl

JEE Main 2023 (Online) 10th April Evening Shift

Q.9. The correct IUPAC nomenclature for the following compound

Q.10. The descending order of acidity for the following carboxylic

Choose the correct answer from the options given below:

Q.11. The strongest acid from the following is

Q.12. Resonance in carbonate ion is

Which of the following is true?

JEE Main 2023 (Online) 1st February Morning Shift

JEE Main 2023 (Online) 30th January Evening Shift

Q.15. The increasing order of pKa for the following phenols is

Choose the correct answer from the option given below :

Q.16. Match List I with List II

A. Propanamine and N- I. Metamers

B. Hexan-2-one and Hexan-3-one II. Positional

C. Ethanamide and III. Functional

D. o-nitrophenol and p-nitrophenol IV. Tautomers

Choose the correct answer from the options given below :

Q.18. The correct order in aqueous medium of basic strength in

JEE Main 2023 (Online) 25th January Morning Shift

Q.19. Given below are two statements, one is labelled as Assertion

Assertion A : Benzene is more stable than hypothetical

Reason R : The delocalised π electron cloud is attracted more

JEE Main 2023 (Online) 24th January Evening Shift

Q.20. Which will undergo deprotonation most readily in the basic

Q.21. Increasing order of stability of the resonance structures is :

Choose the correct answer from the options given below :

JEE Main 2023 (Online) 24th January Morning Shift

Let's analyze the given statements:

Statement I: Tropolone is an aromatic compound and has 8 π

Based on the analysis, the correct answer is:

Statement I is true, but Statement II is false.

Among A and B; since inductive effect is distance dependent,

As for Reason R, it is false. A molecule with 2 chiral carbons is not

Option A: cis-butene, trans-butenecis-butene, trans-butene cis-

Option C: Benzene, AnisidineBenzene, Anisidine Benzene has a

Option D: 1,4-Dichlorobenzene, 1,3-Dichlorobenzene1,4-