Sec:Incoming.Sr.

IIT _*COSC CAT-42 Date: 17-05-20

Time: 3HRS 2016-P2 Max.Marks:
KEY SHEET

PHYSICS
1 A 2 C 3 B 4 A 5 B

6 A 7 ABD 8 AC 9 ACD 10 ABC

11 BC 12 BC 13 ABC 14 BCD 15 A

16 A 17 A 18 A

CHEMISRTY
19 B 20 A 21 A 22 B 23 D

24 D 25 ABC 26 BC 27 AC 28 BD

29 BD 30 AB 31 AC 32 D 33 B

34 A 35 B 36 A

MATHS
37 D 38 C 39 C 40 C 41 B

42 B 43 AB 44 ABD 45 BC 46 BCD

47 CD 48 AD 49 ABC 50 AD 51 B

52 B 53 A 54 A
Narayana IIT Academy 17-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_CAT-42_Key & Sol’s
SOLUTIONS
PHYSICS
1. Flux passing through the loop ABCD
(8/ 5) 
0 I  I  8 
  dr  0 n  

2 r 2 5

B  2 B  2
2. Induced emf  , current i0 
2 2R
iB 2
Torque about P     (idx) B.
2
 B   B 
2 2
  8
 2 R  2 
 
So, power P   .   160 Watt
Alternate solution
B 2 2  4
Power = Heat loss in resistance  Ri12   160 Watt
4R
3. Induced current in resistor R
2Brv
I
R
I
Magnetic force on the ring Fm  2 (2r ) B
2
2 2
4B r v

R
When the ring attains terminal velocity  F  0
4 B 2 r 2v
 mg  0
R
mgR
v
4B2r 2
Bv Ba0 n( R1  R2 )
4. I  (n is time in second)
Req R1 R2
So Fext  FB  ma0
 B 2  2 ( R1  R2 )n 
 Fext  a0  m  
 R1 R2 
 10 n 
2
 Fext  1 
 4 
n4
Narayana IIT Academy 17-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_CAT-42_Key & Sol’s
5. Emf induced in the straight segment AC is  AC  0
Emf induced in the circular arc CD is
5a / 2 5a
1 21
 CD   B rdr  B  r 2  2  B a 2
a
2 a 8
21
  5  10  (0.2) 2  5.25 volt
8
  AD   AC   CD  0  5.25  5.25 volt
6.


 t
3
R mv
tan 60   3
1 qB
9 1031 3 9
B 19
   1012
1.6 10 2 3.2
5
 4  10  200i
9
i  107
3.2  8
7. For A :
2a
1
U    0 E 2 4 r 2 dr
a
2
2
 K 2Q 
2a
1
  0 4   2  r 2 dr
a 
2 r 
2a
1 1
  0 4 K 2 4Q 2  2 dr
2 a
r
1 1 1  4Q 2 Q2
 4Q 2    
8 0  a 2 a  16 0 a 4 0 a
For B:
K 2Q K Q 3 K Q
V inner   
a 2a 2 a
For C:
Assuming charge on outer surface of inner shell after closing he switch is Q1 then
KQ1 KQ
 0
a 2a
Q
Q1 
2
3Q
So charge flow is
2
For D :
There is no electric field due to outer charge at common center
Narayana IIT Academy 17-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_CAT-42_Key & Sol’s
8. Flux linked with loop due to its own magnetic field,
I   rI
  0  r2  0
2r
 2

d   r dI
Emf induced     0
dt 2 dt
   r dI
I t
dI 2R
I   0
R 2 R dt 
I0
I
  
0
0 r
. dt ; I  I 0 e 2 Rt / 0  r

2 Rt
3

0 r 3 2 ln10
Now, 10 I 0  I 0 e which gives t  s.
1010
9. Conceptual
10. (a), (b), (c)
Charge on plate B '1 + Charge on plate B1 = Q
A B1 B1 C

 
+ +
A o A
C1  C2  o
C1 C2 2d d

I. Now if only S1 is closed then charge on plate C will still be zero.

 charge on plate B1 = 0
 total charge +Q is on plate B '1 .
 Q amount of charge will flow through S1, so as to form a capacitor C1.
II. Similarly, if only S2 is closed Q amount of charges will flow through S2.
 in both of above cases
charge of amount Q (sign is not taken) is flown
q Q+q

+  + 

A o A
C1  C2  o
2d d

Now, if S1 and S2 both are closed let the distribution charges on the capacitors are
q  Q  q  Q
Now  0  q
C1 C2 3
Q  Q 2Q
 amount of charge is flow through S1 and  Q   i.e., amount of charge
3  3 3
is flown through S2.
11. Q  CBv
  x tan 
 Q  CBvx tan 
i  CBv 2 tan 
F  Bi  Bi  x tan   Bi (vt tan   x0 )
 0
Q 2  CBv ( x0  vt ) tan  
2

U 
2C 2C
Narayana IIT Academy 17-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_CAT-42_Key & Sol’s
12.

 Motional EMF = Bv

 Motional EMF = Bv / 2
13. +Q is same on A and +Q, -Q are induced on B
14.
(A)
Narayana IIT Academy 17-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_CAT-42_Key & Sol’s
15 & 16.     R 2  3B0  2 B0   B0 R 2
 
t  t 
2 2
  2B0 R 
2

t 
  
 B

17 and 18.
PC and CQ are parallel. So, equivalent resistance of the circuit is R / 2 . In static condition, current
through the battery as I  2V / R .
F2
C
P  Q

F1

T1 mg T2
The current through CP and CQ is i  I / 2  V / R .
Hence, F1  F2  Bir
Consider the FBD of ring and the blocks FBD of ring:
Consider torque about ‘C’,
T1r  F1r / 2  F2 r / 2  T2 r
FBD of block: T1  mg and T2  2mg
So, mgr  Bir 2 / 2  Bir 2 / 2  2mgr
mg V mg
or i or 
Br R Br
mgR
or v
Br
Net torque of tension
BVr 2
 T2  T1  r  mgr  .
R

CHEMISTRY
19. The cell reaction is: H 2  g   I 2  s   2 H   aq   2 I   aq 
2 2
0.0591  H    I  
Ecell  Ecell 
0
log
2  
PH 2

 H    0.1
2 2
0.0591
0.7714  0.535  log
2 1
pH  3
0.0591  Fe 2 
20. EE  0
log10
1  Fe3 
0.0591 0.1
 0.77  log  0.711V
1 0.01
Narayana IIT Academy 17-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_CAT-42_Key & Sol’s
21. Half cell Reaction E 0
L.H.S. H 2  2 H   2e  EOX 0  0.00V
R.H.S. Zn 2  2e   Zn 0
Ered  0.76V
Net  zn 2  H 2  Zn  2 H  , Ecell
0
 0.76V
2
 H   0.0591
K  log K
 Zn 
2
n
0.0591
Ecell  Ecell
0
 log K
n
2
.0591 log10  H 


0.4  0.76 
2 0.3
 H   4.60 10 M
 6

 HSO3  H   SO32
0.4M 4.6 106 6.4 103
 H    SO32  4.6 106  6.4 103
Ka  
  7.3  108
HSO3 0.4
pK a  7.13
Zn 2  aq   4 NH 3  aq   Zn  NH 3 4  aq  E 0  0.28
2
22.
RT ln K f  nFE 0  2  0.28  96500
0.56  96500
ln K f   21.81
8.314  298
K f  3  109
23. Conceptual
24. Conceptual
25. Conceptual
26. The half cell which has higher value of SRP undergo reduction
Cl2  aq   2e   2Cl   aq  ECl0 / Cl   1.36V
2

Br2  aq   2e   2 Br   aq  EBr
0
/ Br 
 1.09V
2

Cl2 will undergo reduction & Br will undergo oxidation.
Cl2  aq   2 Br   aq   2Cl   aq   Br2  aq  0
Ecell  0.27V
G 0   ve spontaneous
(C) S 2O82  have higher SRP.
27. Conceptual
28. Conceptual
29. Conceptual
30. Conceptual
31. Conceptual
32. Ptotal  PHNO3  PNO2  PH 2O  PO2
 PNO2  4 PO2 and PH 2O  2 PO2
 Ptotal  PHNO3  7 PO2
 30  2  PO2  7
Narayana IIT Academy 17-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_CAT-42_Key & Sol’s
28
 PO2  4
7
4
PNO .PH22O .PO2
Kp  2
4
PHNO3

 4  4   2  4 4
4 2

 4
2
K p  K c  RT  g  K c  0.08  400 
H 3

 K c  32
33. Conceptual
34. Conceptual
35. Zn  Fe 2  Fe  Zn 2
0.0591
E  E0  log K eq
n
Given, E  0.2905
 0.02905  0.0295log10
 0.02905  0.0295log10
 0.2905  0.0295
 0.32
0.0591
 E0  log K eq
2
0.0591
 0.32  log K eq
2
0.32
 K eq  10 0.0295
36.  H    Ka  c  1.8 105  101  1.8  106
2 H   2e   H 2

  0
0.059 PH 2
ERed n  Ered
0
 log 2
0
ERe dn
2  H 


0.059  1  0.059
ERed n   log  6 
 6  log 1.8  
2  1.8  10  2 
0.059
ERed n    5.74  0.169V
2

MATHS
f x f  t  dt
x 2

37.
1  x2
 1   1  t2
0

1  x  f ' x   f  x  24   f  x 
2 2

1  x  2 2 1 x 2

dy  2x 
 2 
y  y2
dx  1  x 
Narayana IIT Academy 17-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_CAT-42_Key & Sol’s
1 dy  2x  1
  1
y 2 dx  1  x 2  y
1
 t
y
dt  2x 
 t 1
dx  1  x 2 
3 1  x 2 
 f x  3
x  3x  3
15
f  2  
17
x x

 g  t  dt   g 1  t  g  t  dt  x  x
4 2
38.
0 0
Differential w.r.t. k
x
xg  x    g  t  dt  1  x  g  x   4x 3  2x
0
Again differentiate
g '  x   g  x   12x 2  2
1 1
12 dx 1
 g ' g  10   x 2  1   tan x  0
1

0 0


4
1
x 3
x
39.  .dx 1
 1 2
2
 2 x 
x 
1
2
 x2  t2
x
t 1
 f  x    3
dt   C
t t
x

1  x4
f  0   0  C1  0
x 1
 dx  .sin 1 x 2  C2
1  x4 2
g  0   0  C2  0
1
 g  x   sin 1 x 2
2
Narayana IIT Academy 17-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_CAT-42_Key & Sol’s
1
40. f  x   1  x 7 4

1
g x  1  x 
4 7

f, g are inverse function to each other

1 1
T   f  x dx   g  y dy
0 0
1 1
  f  x dx   x.f '  x dx
0 0
1 0
  f  x  dx   x.f '  x  dx
0 1
1
  f  x  x.f '  x  dx
0

  xf  x   0  0  f 1  0
1

  f  x   2x 
1
3 2
41. dx  0
0

 f  x   2x 3
2
Area   2x 3
1
15

2
dy  1   2
42.   y  x  
dx  x   x
 f  x   x 2  2x  2

 
3
A    x  1  1 dx
2

0
=6
dy
43. 2xy  x 2  y2  1
dx
y t
2

xdt
 x2  t  1
dx
dt t x 2  1
 
dx x x
1
I.F 
x
t x2  1 1
  2 dx  x   C
x x x
Narayana IIT Academy 17-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_CAT-42_Key & Sol’s
 y 2  x 2  1, C  0 as y 1  0


y x 01  3  x 0  2 
1
x
dy e
44.  dx
y2 x 2
1
1
  e x  C
y
lt  f  x   1  1   1
x 0

1
y 1
1 e x

1  2x  1 
2
1 dt 1
45. I  2  tan  C
2 t  t 1 3  3 
x dx
I
 x  2x 2  1  x 2
4

1  x  x  1   x  x  1
2 2

 
2  x 2  x  1 x 2  x  1
1 dx 1 dx
    2
2 x  x 1 2 x  x 1
2

1  1  2x  1   1  2x  1 

  tan    tan    C
3   3   3 

 f  x  dx    2x  6x  6  dx
1 t
46. gt  2

t 1 1
1 1
   x  1 dx   f  x  dx
t 1 t 1
3
2t 7t 2 5
 gt    6t 
3 2 3
g '  t    2t  3 t  2 
1 n  k2 
47. Sn    2  1 
n k 1  n 
f  x   x  1, which is increasing in  0, 1
2

Sn    x 2  1 dx
1

Tn    x 2  1 dx
1

0
Narayana IIT Academy 17-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_CAT-42_Key & Sol’s
4
 Tn   Sn
3
3x  6y
48. 1
K
 3x  8y 
2x 2  2xy  3y 2   0
 k 
Coefficient of x 2  coefficient of y 2  0
  2k 2  9    3k 2  x   0
 1 k  3 or  3
49.
Q
4

S
B
P  A C  4,9 

4
12
2 1
tan   
4 2
PQ  PR  4
2 8
PS  PR cos   4  
5 5
PA  2  2, PB  20  2
50. AB:x  y  2 .....................(1)
PA  PB is maximum when P1 A1B are collinear
2x  3y  1  0 .................... (2)
Solve 1 and 2  P  7,  5 
Equation of tan bisector of AB is y = x ......................... (3)
If PA  PB is minimum,
solve 2 and 3
 1 1 
 P , 
 5 5 

51. f 1  f  x   , f '  x   105x  f  x    0

xf '  x   f  x   cos x
x.f  x   sin x  C
f  0  1  C  0
Narayana IIT Academy 17-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_CAT-42_Key & Sol’s
sin x
f  x  
x
sin 2x sin x
2x x 0
sin x 2
 
2 2
sin x
52.  f  x  dx   x
dx
0 0
2 sin x
 1
 x

2
sin x 
1  dx 
0 x 2
 sin x  2cos x  sin x   0  sin x  0, tan x  2

53 & 54:  x1 , y1   x 2 , y 2 
ax1  by1  C  ax  by 2  C 
 3 2 K
a 2  b2  a 2
 b 2

a  x1  3x 2  b  y1  3y 2 
 k
4 4 
a 2  b2 4
 x  3x 2 y1  3y 2 
Centre :  1 , 
 4 4 
 Centre line on AB
If k  4  r  1