HW 0304
HW 0304
In this problem, we are given the mass, m = 0.5 kg, which we assume is constant. We are also given the
initial pressure and temperature, P1 = 100 kPa and T1 = 25oC = 298.15 K. The fact that the piston is resting
on stops as heat is added means that the volume is constant. Because we stop adding heat when the
pressure is just enough to raise the piston, we know that the final pressure, P2 = 500 kPa, the pressure
required to raise the piston. We also know that V2 = V1 because of the constant volume process.
We will assume that helium is an ideal gas at these low pressures. We can find the heat from the first law:
Q = U + W = mcvdT + W for an ideal gas. In this constant-volume process the work, W = 0. From
Figure 2-68 on page 102, we see that the heat capacity of helium is essentially constant over a wide range
of temperatures. Thus we can use the constant heat capacity of helium from Table A-2 on page 825: c v =
3.1156 kJ/(kg∙K). The same table gives the gas constant for helium; R = 2.0769 kJ/(kg∙K).
From the equation that Q = mcvdT + W, we see that Q = mcv(T2 – T1) in this (W = 0) case. We do not
know the final temperature, T2, but we can find it from the ideal gas law (and V2 = V1).
= 1,857 kJ .
4-36 A mass of 15 kg of air in a piston-cylinder device is heated from 25 to 77oC by passing current
through a resistance heater inside the cylinder. The pressure inside the cylinder is held constant at
300 kPa during the process and a heat loss of 60 kJ occurs. Determine the electrical energy supply in
kWh.
The first law for this problem can be written as Q = U + W = U + We,out + PdV, where We,out is the
electrical work done by the system. We expect that this will be negative since we see tghat there is an
electrical energy input to the system. We can say that We,in = -We,out = U + PdV – Q.
For this constant pressure process, PdV = P(V2 – V1) where P = P1 = P2 is the constant pressure of 300
kPa. With this work term we can write our first law as follows.
We,in = U + P(V2 – V1) – Q = U2 – U1 + P2V2 – P1V1 – Q = H2 – H1 – Q = m(h2 – h1) – Q
We can find the specific enthalpy change, h2 – h1 = cpdT, where cp can be found from Table A-2(b) on page
826. At the average temperature of (25oC + 77oC)/2 = 51oC = 324.15 K, we can interpolate to find cp =
1.0065 kJ/(kg∙K). With this value of cp (and using Q = -60 kJ because it is a heat loss) we can find the
electrical work input as follows.
4-40 A room is heated by a baseboard resistance heater. When the heat losses from the room on a winter
day amount to 6,500 kJ/h, the air temperature in the room remains constant, even though the heater
operates continuously. Determine the power rating of the heater in kW.
Since the temperature of the air is constant, the internal energy is constant. Thus the heat loss through the
wall is balanced by the heat input from the electric heater. This input must be 6500 kJ/h = (6500 kJ/h)[(1
kW∙h) / (3600 kJ) ] = 1.81 kW .
4-41E A piston-cylinder device contains 3 ft3 of air at 60 psia and 150oF. Heat is transferred to the air in the
amount of 40 Btu as the air expands isothermally. Determine the amount of boundary work during
this process.
From the first law, Q = U + W, with U = mcvdT for ideal gases. We see that U for this process is zero,
since the temperature is constant. Thus, we have W = Q = 40 Btu .
Since we are given V2 = 2 V1, we know that V2 = 2.584 m3. We can now find the work as follows.
W = P1(V2 – V1) = (200 kPa)( 2.584 m3 – 1.292 m3) = 258.4 kPa∙m3 = 258.4 kJ
To compute the change in internal energy, we need the final temperature. We can find this final
temperature from the ideal gas law.
For this large temperature difference we should consider the temperature dependence of the heat capacity.
We can use the ideal gas tables for air on pages 849-50. Interpolating in these tables we find the following
values for the ideal gas internal energy:
u1 = u(300.15 K) = 214.18 kJ/kg u2 = u(1200.6 K) = 933.86 kJ/kg
We can now find the heat transfer, Q = U + W = m(u2 – u1) + W = (3 kg)( 933.86 kJ/kg – 214.18 kJ/kg) +
258.4 kJ. This gives Q = 2,417.5 kJ .