Sds Nitobond Ep BFL

Revision date: 01/06/2020 Revision: 00
SAFETY DATA SHEET

NITOBOND EP BASE
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier

Product name NITOBOND EP BASE
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Adhesive
1.3. Details of the supplier of the safety data sheet

Supplier Berger Fosroc Ltd
Berger House, House 8, Road 2, Sector 3
Uttara, Dhaka 1230
Bangladesh
Tel: +88 02 48953665
Fax: +88 02 48951350
[email protected]
1.4. Emergency telephone number

Emergency telephone +88 02 48953665
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified
Health hazards Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1 - H317 Repr. 1B - H360
Environmental hazards Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410
2.2. Label elements
Hazard pictograms
Signal word Danger
Hazard statements H315 Causes skin irritation.

H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H360 May damage fertility or the unborn child.
H410 Very toxic to aquatic life with long lasting effects.
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NITOBOND EP BASE
Precautionary statements P264 Wash contaminated skin thoroughly after handling.

P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P302+P352 IF ON SKIN: Wash with plenty of water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P501 Dispose of contents/ container in accordance with national regulations.
Contains EPOXY RESIN (Type A) (Number average MW <= 700 ), DIBUTYL PHTHALATE: DBP
Supplementary precautionary P201 Obtain special instructions before use.

statements P202 Do not handle until all safety precautions have been read and understood.
P261 Avoid breathing vapour/ spray.
P272 Contaminated work clothing should not be allowed out of the workplace.
P308+P313 IF exposed or concerned: Get medical advice/ attention.
P321 Specific treatment (see medical advice on this label).
P332+P313 If skin irritation occurs: Get medical advice/ attention.
P333+P313 If skin irritation or rash occurs: Get medical advice/ attention.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage.
P405 Store locked up.
2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.
SECTION 3: Composition/information on ingredients
3.2. Mixtures
reaction product: bisphenol-A-(epichlorhydrin) epoxy resin 60-100%

(number average molecular weight ≤ 700)
CAS number: 25068-38-6 EC number: 500-033-5 REACH registration number: 01-
2119456619-26-XXXX
Classification
Skin Irrit. 2 - H315
Eye Irrit. 2 - H319
Skin Sens. 1 - H317
Aquatic Chronic 2 - H411
DIBUTYL PHTHALATE 5-10%

CAS number: 84-74-2 EC number: 201-557-4
M factor (Acute) = 1
Substance of very high concern (SVHC).
Classification
Repr. 1B - H360Df
Aquatic Acute 1 - H400
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NITOBOND EP BASE
TITANIUM DIOXIDE 1-5%

2119489379-17-XXXX
Classification
Not Classified
PROPAN-2-OL <1%
Classification
Flam. Liq. 2 - H225
Eye Irrit. 2 - H319
STOT SE 3 - H336
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
SECTION 4: First aid measures
4.1. Description of first aid measures

General information Consult a physician for specific advice.
Inhalation Move affected person to fresh air and keep warm and at rest in a position comfortable for
breathing.
Ingestion Rinse mouth thoroughly with water. Do not induce vomiting. Get medical attention
immediately.
Skin contact Rinse immediately with plenty of water. Wash skin thoroughly with soap and water. Get
medical attention if symptoms are severe or persist after washing.
Eye contact Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide
apart. Continue to rinse for at least 15 minutes and get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.
Inhalation May cause coughing and difficulties in breathing.
Ingestion May cause irritation. May cause discomfort.
Skin contact May cause irritation. May cause an allergic skin reaction.
Eye contact May cause severe eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media

Suitable extinguishing media Extinguish with foam, carbon dioxide or dry powder.
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
5.2. Special hazards arising from the substance or mixture
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NITOBOND EP BASE
Specific hazards None known.
Hazardous combustion Thermal decomposition or combustion products may include the following substances:
products Carbon dioxide (CO2). Carbon monoxide (CO).
5.3. Advice for firefighters

Protective actions during Fight fire from safe distance or protected location. Move containers from fire area if it can be
firefighting done without risk. Do not enter storage areas or confined spaces unless adequately
ventilated. Ventilate closed spaces before entering them.
Special protective equipment Self-contained breathing apparatus. Wear protective fire fighting clothing.
for firefighters
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Avoid contact with skin and eyes. Wear protective clothing, gloves, eye and face protection.
6.2. Environmental precautions

Environmental precautions Harmful to aquatic life with long lasting effects. Avoid discharge into drains and the aquatic
environment.
6.3. Methods and material for containment and cleaning up

Methods for cleaning up Absorb in vermiculite, dry sand or earth and place into containers. Label the containers
containing waste and contaminated materials and remove from the area as soon as possible.
Collect and dispose of spillage as indicated in Section 13.
6.4. Reference to other sections

Reference to other sections For personal protection, see Section 8. For waste disposal, see Section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling

Usage precautions Wear protective clothing, gloves, eye and face protection. Avoid contact with skin, eyes and
clothing.
Advice on general Good personal hygiene procedures should be implemented. Do not eat, drink or smoke when
occupational hygiene using this product. Wash hands and any other contaminated areas of the body with soap and
water before leaving the work site.
7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place.
Storage class Chemical storage.
7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.
SECTION 8: Exposure controls/Personal protection
8.1. Control parameters

Occupational exposure limits
DIBUTYL PHTHALATE
Long-term exposure limit (8-hour TWA): WEL 5 mg/m³
Short-term exposure limit (15-minute): WEL 10 mg/m³
TITANIUM DIOXIDE
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NITOBOND EP BASE
Long-term exposure limit (8-hour TWA): WEL 10 mg/m³ inhalable dust

Long-term exposure limit (8-hour TWA): WEL 4 mg/m³ respirable dust
PROPAN-2-OL
Long-term exposure limit (8-hour TWA): WEL 400 ppm 999 mg/m³
Short-term exposure limit (15-minute): WEL 500 ppm 1250 mg/m³
WEL = Workplace Exposure Limit.
Ingredient comments WEL = Workplace Exposure Limits
reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700) (CAS:
25068-38-6)
DNEL Workers - Inhalation; Short term systemic effects: 12.25 mg/m³

Workers - Inhalation; Long term systemic effects: 12.25 mg/m³
PNEC - Fresh water; 0.006 mg/l
DIBUTYL PHTHALATE (CAS: 84-74-2)
DNEL Workers - Inhalation; Long term systemic effects: 0.13 mg/m³

Workers - Dermal; Long term systemic effects: 0.19 mg/kg bw/day
PNEC - Fresh water; 10 µg/l

- marine water; 1 µg/l
TITANIUM DIOXIDE (CAS: 13463-67-7)
DNEL Industry - Inhalation; Long term local effects: 10 mg/m³

Consumer - Oral; Long term systemic effects: 700 mg/kg/day

- Sediment (Freshwater); >=1000 mg/kg
- marine water; 1 mg/l
- Sediment (Marinewater); >= 100 mg/kg
- Soil; 100 mg/kg
- STP; 100 mg/l
PROPAN-2-OL (CAS: 67-63-0)
DNEL Workers - Dermal; Long term systemic effects: 888 mg/kg

Workers - Inhalation; Long term systemic effects: 500 mg/m³
PNEC - Fresh water, marine water, Intermittent release; 140.9 mg/l
8.2. Exposure controls
Protective equipment
Appropriate engineering Provide adequate general and local exhaust ventilation. Avoid inhalation of vapours and
controls spray/mists. Observe any occupational exposure limits for the product or ingredients.
Eye/face protection Wear tight-fitting, chemical splash goggles or face shield.
Hand protection Nitrile gloves are recommended.
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NITOBOND EP BASE
Other skin and body Wear appropriate clothing to prevent any possibility of skin contact.
protection
Hygiene measures Good personal hygiene procedures should be implemented. Wash contaminated skin
thoroughly after handling. Do not eat, drink or smoke when using this product.
Respiratory protection Gas filter, type A2.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties

Appearance Liquid.
Colour White
Odour Mild
Odour threshold Not determined.
Flammability (solid, gas) Not applicable.
Other flammability Not applicable.
Relative density 1.51 @ 27°C
Solubility(ies) Insoluble in water
Explosive properties Not considered to be explosive.
Explosive under the influence Not considered to be explosive.

of a flame
Oxidising properties The mixture itself has not been tested but none of the ingredient substances meet the criteria
for classification as oxidising.
9.2. Other information

Other information No data available.
Volatile organic compound This product contains a maximum VOC content of 5 g/l.
SECTION 10: Stability and reactivity
10.1. Reactivity
Reactivity The reactivity data for this product will be typical of those for the following class of materials:
Phenols, cresols.
10.2. Chemical stability

Stability Stable at normal ambient temperatures and when used as recommended.
10.3. Possibility of hazardous reactions

Possibility of hazardous Under normal conditions of storage and use, no hazardous reactions will occur.
reactions
10.4. Conditions to avoid

Conditions to avoid Avoid excessive heat for prolonged periods of time.
10.5. Incompatible materials

Materials to avoid Acids. Alkalis.
10.6. Hazardous decomposition products
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NITOBOND EP BASE
Hazardous decomposition Carbon dioxide (CO2). Carbon monoxide (CO).

products
SECTION 11: Toxicological information
11.1. Information on toxicological effects

Acute toxicity - inhalation
ATE inhalation (vapours mg/l) 65.38
Ingestion May cause discomfort.
Skin contact May cause an allergic skin reaction. May cause irritation.
Eye contact Irritating to eyes.
Target organs Skin Eyes Respiratory system, lungs
Toxicological information on ingredients.
reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)
Acute toxicity - oral
Acute toxicity oral (LD₅₀ 5,000.0

mg/kg)
Species Rat
Notes (oral LD₅₀) NOAEL 750 mg/kg, Oral, Rat
ATE oral (mg/kg) 5,000.0
Acute toxicity - dermal
Acute toxicity dermal (LD₅₀ 20,000.0

mg/kg)
Species Rabbit
Notes (dermal LD₅₀) LD₅₀ >1600 mg/kg, Dermal, Rat
ATE dermal (mg/kg) 20,000.0
Skin corrosion/irritation
Animal data Rabbit Moderately irritating.
Skin sensitisation
Skin sensitisation May cause sensitisation by skin contact.
DIBUTYL PHTHALATE
Acute toxicity inhalation 4.25

(LC₅₀ vapours mg/l)
ATE inhalation (vapours 4.25

mg/l)
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NITOBOND EP BASE
Acute and chronic health INGESTION. May cause stomach pain or vomiting. Inhalation May cause
hazards respiratory system irritation. SKIN CONTACT. May cause skin irritation/eczema.
May cause sensitisation by skin contact. EYE CONTACT. Irritating to eyes.
PROPAN-2-OL

mg/kg)
Species Rat

mg/kg)
Species Rat

(LC₅₀ vapours mg/l)
Species Rat
ATE inhalation (vapours 72.6

mg/l)
Carcinogenicity
IARC carcinogenicity IARC Group 3 Not classifiable as to its carcinogenicity to humans.
SECTION 12: Ecological information
Ecotoxicity The product contains a substance which is toxic to aquatic organisms and which may cause
long-term adverse effects in the aquatic environment.
12.1. Toxicity
Ecological information on ingredients.
Toxicity Ecotoxic to fish / daphnia / algae
Acute aquatic toxicity
Acute toxicity - fish LC₅₀, 96 hours: 3.6 mg/l, Leuciscus idus (Golden orfe)
LC₅₀, 96 hours: 2 mg/l, Oncorhynchus mykiss (Rainbow trout)
Acute toxicity - aquatic EC₅₀, 48 hours: 1.8 mg/l, Daphnia magna

invertebrates
Acute toxicity - aquatic EC50, 72 hours: 11 mg/l, Scenedesmus capricornutum (fresh water algae)
plants
DIBUTYL PHTHALATE
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NITOBOND EP BASE
LE(C)₅₀ 0.1 < L(E)C50 ≤ 1
M factor (Acute) 1
Acute toxicity - fish LC₅₀, 96 hours: 0.85 mg/l, Pimephales promelas (Fat-head Minnow)
LC₅₀, 96 hours: 1.6 mg/l, Salmo gairdneri
Acute toxicity - aquatic LC₅₀, 48 hours: 3.7 mg/l, Daphnia magna

invertebrates
Acute toxicity - aquatic EC₅₀, 96 hours: 0.75 mg/l, Selenastrum capricornutum

plants
PROPAN-2-OL
Acute toxicity - fish LC50, 96 hours: 1400 - 9640 mg/l, Pimephales promelas (Fat-head Minnow)
Acute toxicity - aquatic EC₅₀, 48 hours: 13299 mg/l, Daphnia magna

invertebrates
12.2. Persistence and degradability

Persistence and degradability The product is not expected to be biodegradable.
Persistence and The product is not readily biodegradable.

degradability
12.3. Bioaccumulative potential

Bioaccumulative potential No data available on bioaccumulation.
Partition coefficient log Pow: 3.242
PROPAN-2-OL
12.4. Mobility in soil

Mobility The product contains substances which are insoluble in water and which sediment in water
systems.
Mobility The product has poor water-solubility.
Adsorption/desorption Water - Koc: 445 @ °C

coefficient
PROPAN-2-OL
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NITOBOND EP BASE
Surface tension 22.7 mN/m @ 20°C
12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment
assessment
PROPAN-2-OL
Results of PBT and vPvB This substance is not classified as PBT or vPvB according to current EU criteria.
assessment
12.6. Other adverse effects

Other adverse effects None known.
SECTION 13: Disposal considerations
13.1. Waste treatment methods

General information The generation of waste should be minimised or avoided wherever possible.
Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority. Waste liquid components should be suitable for incineration at
an approved facility.
SECTION 14: Transport information
14.1. UN number
UN No. (ADR/RID) 3082
UN No. (IMDG) 3082
UN No. (ICAO) 3082
UN No. (ADN) 3082
14.2. UN proper shipping name

Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS EPOXY
(ADR/RID) RESIN (Type A) (Number average MW <= 700 ), DIBUTYL PHTHALATE: DBP)
Proper shipping name (IMDG) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS EPOXY
RESIN (Type A) (Number average MW <= 700 ), DIBUTYL PHTHALATE: DBP)
Proper shipping name (ICAO) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS EPOXY
Proper shipping name (ADN) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS EPOXY
14.3. Transport hazard class(es)

ADR/RID class 9
ADR/RID classification code M6
ADR/RID label 9
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NITOBOND EP BASE
IMDG class 9
ICAO class/division 9
ADN class 9
Transport labels
14.4. Packing group

ADR/RID packing group III
IMDG packing group III
ICAO packing group III
ADN packing group III
14.5. Environmental hazards
Environmentally hazardous substance/marine pollutant
14.6. Special precautions for user

EmS F-A, S-F
ADR transport category 3
Hazard Identification Number 90

(ADR/RID)
Tunnel restriction code (-)
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations The Manufacture, storage and import of hazardous chemicals rules 1989.
EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).
Guidance Workplace Exposure Limits EH40.
15.2. Chemical safety assessment

No chemical safety assessment has been carried out.
SECTION 16: Other information
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NITOBOND EP BASE
General information For professional use only. Only trained personnel should use this material.
Revision comments This is the first issue.
Revision date 01/06/2020
Revision 00
SDS number 28679
Hazard statements in full H225 Highly flammable liquid and vapour.

H315 Causes skin irritation.
H331 Toxic if inhaled.
H336 May cause drowsiness or dizziness.
H360 May damage fertility or the unborn child.
H400 Very toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.
The information on this data sheet represents our current data and is reliable, provided that the product is used under the
prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance
literature. Any other use of the product which involves using the product in combination with any other product or any other
process is the responsibility of the user.
12/12
SAFETY DATA SHEET

NITOBOND EP HARDENER
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier

Product name NITOBOND EP HARDENER
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Adhesive
1.3. Details of the supplier of the safety data sheet

Supplier Berger Fosroc Ltd
Berger House, House 8, Road 2, Sector 3
Uttara, Dhaka 1230
Bangladesh
Tel: +88 02 48953665
Fax: +88 02 48951350
[email protected]
1.4. Emergency telephone number

Emergency telephone +88 02 48953665
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified
Health hazards Acute Tox. 4 - H302 Acute Tox. 4 - H332 Skin Irrit. 2 - H315 Eye Dam. 1 - H318 Skin Sens. 1
- H317 Muta. 2 - H341 Carc. 1B - H350 STOT SE 1 - H370 STOT RE 2 - H373
Environmental hazards Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410
Classification (67/548/EEC or -
1999/45/EC)
Human health May cause serious eye damage. Contains a substance/a group of substances which may
cause cancer. May damage organs after repeated exposure.
Environmental The product contains a substance which is toxic to aquatic organisms and which may cause
2.2. Label elements
Hazard pictograms
Signal word Danger
1/15
Hazard statements H302+H332 Harmful if swallowed or if inhaled.

H318 Causes serious eye damage.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H370 Causes damage to organs .
H373 May cause damage to organs through prolonged or repeated exposure.
Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P273 Avoid release to the environment.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water or shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P501 Dispose of contents/ container in accordance with national regulations.
Contains 4,4'-METHYLENEDIANILINE, EPOXY RESIN (Type A) (Number average MW <= 700 ),

PHENYL GLYCIDYL ETHER, SALICYLIC ACID
Supplementary precautionary P201 Obtain special instructions before use.

statements P202 Do not handle until all safety precautions have been read and understood.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof electrical equipment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
P260 Do not breathe vapour/ spray.
P261 Avoid breathing vapour/ spray.
P264 Wash contaminated skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301+P312 IF SWALLOWED: Call a POISON CENTRE/doctor if you feel unwell.
P302+P352 IF ON SKIN: Wash with plenty of water.
P308+P311 IF exposed or concerned: Call a POISON CENTER or doctor.
P308+P313 IF exposed or concerned: Get medical advice/ attention.
P310 Immediately call a POISON CENTER/ doctor.
P314 Get medical advice/ attention if you feel unwell.
P321 Specific treatment (see medical advice on this label).
P330 Rinse mouth.
P332+P313 If skin irritation occurs: Get medical advice/ attention.
P333+P313 If skin irritation or rash occurs: Get medical advice/ attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P370+P378 In case of fire: Use foam, carbon dioxide, dry powder or water fog to extinguish.
P391 Collect spillage.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.
2/15
SECTION 3: Composition/information on ingredients
3.2. Mixtures
4,4'-METHYLENEDIANILINE 30-60%
M factor (Acute) = 1 M factor (Chronic) = 10
Substance of very high concern (SVHC).
Classification
Acute Tox. 3 - H301
Acute Tox. 2 - H330
Skin Sens. 1 - H317
Muta. 2 - H341
Carc. 1B - H350
STOT SE 1 - H370
STOT RE 2 - H373
Aquatic Acute 1 - H400
reaction product: bisphenol-A-(epichlorhydrin) epoxy resin 30-60%

(number average molecular weight ≤ 700)
2119456619-26-XXXX
Classification
Eye Irrit. 2 - H319
Skin Sens. 1 - H317
PHENYL GLYCIDYL ETHER 10-30%

Classification
Acute Tox. 4 - H302
Acute Tox. 4 - H332
Skin Sens. 1 - H317
Muta. 2 - H341
Carc. 1B - H350
STOT SE 3 - H335
MICA POWDER 1-5%

Classification
Not Classified
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XYLENE <1%
2119488216-32-0000
Classification
Flam. Liq. 3 - H226
Acute Tox. 4 - H312
Acute Tox. 4 - H332
ETHYLBENZENE <1%
Classification
Flam. Liq. 2 - H225
Acute Tox. 4 - H332
STOT RE 2 - H373
Asp. Tox. 1 - H304
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
SECTION 4: First aid measures
4.1. Description of first aid measures

General information When symptoms persist or in all cases of doubt seek medical advice.
Inhalation Move affected person to fresh air and keep warm and at rest in a position comfortable for
breathing. Get medical attention.
Ingestion Do not induce vomiting. Rinse mouth thoroughly with water. Never give anything by mouth to
an unconscious person. Get medical attention immediately.
Skin contact Rinse immediately with plenty of water. Remove contaminated clothing. Wash contaminated
clothing before reuse. Get medical attention.
Eye contact Remove any contact lenses and open eyelids wide apart. Rinse immediately with plenty of
water. Continue to rinse for at least 15 minutes. Get medical attention immediately.
4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.
Inhalation Harmful by inhalation. May cause coughing and difficulties in breathing.
Ingestion May cause stomach pain or vomiting. May cause discomfort.
Skin contact May cause an allergic skin reaction. May cause skin irritation.
Eye contact Causes serious eye damage.
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media

Suitable extinguishing media Extinguish with foam, carbon dioxide or dry powder.
4/15
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
5.2. Special hazards arising from the substance or mixture

Specific hazards Containers can burst violently or explode when heated, due to excessive pressure build-up.
Hazardous combustion Carbon monoxide (CO). Carbon dioxide (CO2). Oxides of nitrogen.
products
5.3. Advice for firefighters

Protective actions during Move containers from fire area if it can be done without risk. No action shall be taken without
firefighting appropriate training or involving any personal risk. Fire residues and contaminated fire-fighting
water must be disposed of in accordance within the local regulations.
Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Avoid contact with skin and eyes. Wear protective clothing, gloves, eye and face protection.
6.2. Environmental precautions

Environmental precautions Harmful to aquatic life with long lasting effects. Avoid discharge into drains and the aquatic
environment.
6.3. Methods and material for containment and cleaning up

Methods for cleaning up Absorb in vermiculite, dry sand or earth and place into containers. Label the containers
containing waste and contaminated materials and remove from the area as soon as possible.
Collect and dispose of spillage as indicated in Section 13.
6.4. Reference to other sections

Reference to other sections For personal protection, see Section 8. For waste disposal, see Section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling

Usage precautions Wear protective clothing, gloves, eye and face protection. Avoid contact with skin, eyes and
clothing.
Advice on general Good personal hygiene procedures should be implemented. Do not eat, drink or smoke when
occupational hygiene using this product. Wash hands and any other contaminated areas of the body with soap and
water before leaving the work site.
7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place.
Storage class Flammable corrosive storage
7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.
SECTION 8: Exposure controls/Personal protection
8.1. Control parameters

Occupational exposure limits
4,4'-METHYLENEDIANILINE
5/15
Long-term exposure limit (8-hour TWA): WEL 0.01 ppm 0.08 mg/m³
Carc, Sk
PHENYL GLYCIDYL ETHER
Long-term exposure limit (8-hour TWA): WEL 1 ppm 6.2 mg/m³
Short-term exposure limit (15-minute): WEL
MICA POWDER
Long-term exposure limit (8-hour TWA): WEL 0,8 mg/m³ respirable dust
Long-term exposure limit (8-hour TWA): WEL 10 mg/m³ total dust
XYLENE
Sk
ETHYLBENZENE
Sk
WEL = Workplace Exposure Limit.
Carc = Capable of causing cancer and/or heritable genetic damage.
Sk = Can be absorbed through the skin.
reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700) (CAS:
25068-38-6)
DNEL Workers - Inhalation; Short term systemic effects: 12.25 mg/m³

Workers - Inhalation; Long term systemic effects: 12.25 mg/m³
SALICYLIC ACID (CAS: 69-72-7)
DNEL Workers - Inhalation; Long term systemic effects: 5 mg/m³

Workers - Dermal; Long term systemic effects: 2.3 mg/kg bw/day
Workers - Inhalation; Long term local effects: 5 mg/m³
General population - Inhalation; Long term systemic effects: 4 mg/m³

- marine water; 0.020 mg/l
- Sediment (Freshwater); 1.42 mg/kg dw
- Soil; 0.17 mg/kg dw
- STP; 16.2 mg/l
MICA POWDER (CAS: 12001-26-2)
Ingredient comments Dust contains respirable crystalline silica. Prolonged and/or massive inhalation of
respirable crystalline silica dust may cause lung fibrosis, commonly referred to as
silicosis. Principal symptoms of silicosis are cough and breathlessness.
Occupational exposure to respirable dust should be monitored and controlled. The
product should be handled using methods and techniques that minimise or
eliminate dust generation. The product contains less than 1% w/w RCS (respirable
crystalline silica) as determined by the SWERF method. The respirable crystalline
silica content can be measured using the “Size-Weighted Respirable Fraction –
SWERF” method. All details about the SWERF method is available at
www.crystallinesilica.eu
6/15
XYLENE (CAS: 1330-20-7)

Workers - Inhalation; Short term systemic effects: 289 mg/m³
Workers - Dermal; Long term systemic effects: 180 mg/kg/day

- STP; 6.58 mg/l
ETHYLBENZENE (CAS: 100-41-4)

Workers - Dermal; Long term systemic effects: 180 mg/kg bw/day

8.2. Exposure controls
Protective equipment
Appropriate engineering Provide adequate general and local exhaust ventilation.

controls
Eye/face protection Wear tight-fitting, chemical splash goggles or face shield.
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn if
a risk assessment indicates skin contact is possible. Wear protective gloves made of the
following material: Butyl rubber. Nitrile rubber. Viton rubber (fluoro rubber).
Hygiene measures Provide eyewash station and safety shower. Discard contaminated shoes and clothing. Do not
smoke in work area. Do not eat, drink or smoke when using this product. Wash promptly with
soap and water if skin becomes contaminated. Wash at the end of each work shift and before
eating, smoking and using the toilet. Use appropriate skin cream to prevent drying of skin.
Respiratory protection If ventilation is inadequate, suitable respiratory protection must be worn. Gas filter, type K.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties

Appearance Liquid
Colour White
Odour Amine.
Flash point Not determined.
Relative density 1.51 @ 27°C
Solubility(ies) Miscible in water
Explosive properties Not considered to be explosive.
Explosive under the influence Not considered to be explosive.

of a flame
7/15
Oxidising properties The mixture itself has not been tested but none of the ingredient substances meet the criteria
for classification as oxidising.
9.2. Other information

Other information No data available.
Volatile organic compound This product contains a maximum VOC content of 5 g/l.
SECTION 10: Stability and reactivity
10.1. Reactivity
Reactivity The reactivity data for this product will be typical of those for the following class of materials:
Amines.
10.2. Chemical stability

Stability Will decompose at temperatures exceeding 200°C.
10.3. Possibility of hazardous reactions

Possibility of hazardous Under normal conditions of storage and use, no hazardous reactions will occur.
reactions
10.4. Conditions to avoid

Conditions to avoid Avoid heat.
10.5. Incompatible materials

Materials to avoid Alkali metals. Oxidising agents. Acids.
10.6. Hazardous decomposition products

Hazardous decomposition Carbon monoxide (CO). Carbon dioxide (CO2). Oxides of nitrogen.
products
SECTION 11: Toxicological information
11.1. Information on toxicological effects

ATE oral (mg/kg) 655.39

ATE inhalation (gases ppm) 36,630.04
ATE inhalation (dusts/mists 1.32

mg/l)
Ingestion May cause stomach pain or vomiting.
Skin contact May cause an allergic skin reaction. Causes skin irritation.
Eye contact Causes serious eye damage.
Acute and chronic health Suspected of causing cancer. Suspected of causing genetic defects.
hazards
Target organs Liver Kidneys
Toxicological information on ingredients.
8/15
Acute toxicity oral (LD₅₀ 260.0

mg/kg)
Species Guinea pig

mg/kg)
Species Rat

(LC₅₀ dust/mist mg/l)
Species Rat
ATE inhalation 0.46

(dusts/mists mg/l)
Carcinogenicity
IARC carcinogenicity IARC Group 2B Possibly carcinogenic to humans.

mg/kg)
Species Rat
Notes (oral LD₅₀) NOAEL 750 mg/kg, Oral, Rat

mg/kg)
Species Rabbit
Skin corrosion/irritation
Animal data Rabbit Moderately irritating.
Skin sensitisation
Skin sensitisation May cause sensitisation by skin contact.
PHENYL GLYCIDYL ETHER
9/15

mg/kg)
Species Mouse

mg/kg)
Species Rabbit
Acute toxicity inhalation 5,000.0

(LC₅₀ gases ppmV)
Species Rat
ATE inhalation (gases 5,000.0

ppm)
SALICYLIC ACID
Acute toxicity oral (LD₅₀ 891.0

mg/kg)
Species Rat
Notes (inhalation LC₅₀) LC50 >0.9 mg/l, Inhalation, Rat
XYLENE
Carcinogenicity
IARC carcinogenicity IARC Group 3 Not classifiable as to its carcinogenicity to humans.
ETHYLBENZENE
Carcinogenicity
IARC carcinogenicity IARC Group 2B Possibly carcinogenic to humans.
SECTION 12: Ecological information
Ecotoxicity The product contains a substance which is toxic to aquatic organisms and which may cause
10/15
12.1. Toxicity
Toxicity The product contains a substance which may cause long-term adverse effects in the
environment.
LE(C)₅₀ 0.1 < L(E)C50 ≤ 1
M factor (Acute) 1
Acute toxicity - fish LC₅₀, 96 hours: 20.6 mg/l, Oryzias latipes (Red killifish)
Chronic aquatic toxicity
M factor (Chronic) 10
Toxicity Ecotoxic to fish / daphnia / algae
Acute toxicity - fish LC₅₀, 96 hours: 3.6 mg/l, Leuciscus idus (Golden orfe)
LC₅₀, 96 hours: 2 mg/l, Oncorhynchus mykiss (Rainbow trout)
Acute toxicity - aquatic EC₅₀, 48 hours: 1.8 mg/l, Daphnia magna

invertebrates
Acute toxicity - aquatic EC50, 72 hours: 11 mg/l, Scenedesmus capricornutum (fresh water algae)
plants
SALICYLIC ACID
Acute toxicity - fish LC₈₀, : 90 mg/l, Leuciscus idus (Golden orfe)

LC₅₀, 96 hours: 1.3 mg/l, Pimephales promelas (Fat-head Minnow)
Acute toxicity - aquatic EC₈₀, 24 hours: 105 mg/l, Daphnia magna

invertebrates
XYLENE
Toxicity Not considered toxic to fish.
12.2. Persistence and degradability

Persistence and degradability The product is not readily biodegradable.
Persistence and The product is not readily biodegradable.

degradability
XYLENE
11/15
Persistence and Expected to be not readily biodegradable.

degradability
12.3. Bioaccumulative potential

Bioaccumulative potential Bioaccumulation is unlikely to be significant because of the low water-solubility of this product.
12.4. Mobility in soil

Mobility The product is insoluble in water.
Mobility The product has poor water-solubility.
Adsorption/desorption Water - Koc: 445 @ °C

coefficient
XYLENE
Mobility The product is insoluble in water.
12.5. Results of PBT and vPvB assessment

assessment
assessment
12.6. Other adverse effects

Other adverse effects None known.
SECTION 13: Disposal considerations
13.1. Waste treatment methods

General information The generation of waste should be minimised or avoided wherever possible.
Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority. Waste liquid components should be suitable for incineration at
an approved facility.
Waste class For disposal within the EC, the appropriate code according to the European Waste Catalogue
(EWC) should be used.
SECTION 14: Transport information
14.1. UN number
UN No. (ADR/RID) 3082
UN No. (IMDG) 3082
12/15
UN No. (ICAO) 3082
UN No. (ADN) 3082
14.2. UN proper shipping name

Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS 4,4'-
(ADR/RID) METHYLENEDIANILINE, EPOXY RESIN (Type A) (Number average MW <= 700 ))
Proper shipping name (IMDG) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS 4,4'-
METHYLENEDIANILINE, EPOXY RESIN (Type A) (Number average MW <= 700 ))
Proper shipping name (ICAO) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS 4,4'-
Proper shipping name (ADN) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS 4,4'-
14.3. Transport hazard class(es)

ADR/RID class 9
ADR/RID classification code M6
ADR/RID label 9
IMDG class 9
ICAO class/division 9
ADN class 9
Transport labels
14.4. Packing group

ADR/RID packing group III
IMDG packing group III
ICAO packing group III
ADN packing group III
14.5. Environmental hazards
Environmentally hazardous substance/marine pollutant
14.6. Special precautions for user

EmS F-A, S-F
ADR transport category 3
Hazard Identification Number 90

(ADR/RID)
Tunnel restriction code (-)
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
13/15
Transport in bulk according to Not applicable.

Annex II of MARPOL 73/78
and the IBC Code
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations The Manufacture, storage and import of hazardous chemicals rules 1989.
EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).
Guidance Workplace Exposure Limits EH40.

Hazard Label Data:-
Named Ingredients: epoxy resin (number average molecular weight <700)
butanediol-1,4-diglycidylether
UN Number: 3082
Symbol(s): Xi
Risk Phrases: Irritating to eyes and skin
May cause sensitisation by skin contact
Safety Phrases: In case of contact with eyes, rinse immediately with plenty of water and seek
medical
advice.
After contact with skin, wash immediately with plenty of soap and water.
Wear suitable gloves and eye/face protection.
Contains epoxy constituents. See information supplied by the manufacturer.
EC Directives: Dangerous Substances Directive, 67/548/EEC and adaptations.
Dangerous Preparations Directive, 88/379/EEC.
Safety Data Sheets Directive, 91/155/EEC.
Hazardous Waste Directive,91/689/EEC.
Statutory Instruments: Chemicals (Hazard Information and Packaging for Supply)
(Amendment) Regs. 1996 (SI
1092).
Control of Substances Hazardous to Health Regs. 1994 (SI 3246).
Health & Safety at Work, etc. Act 1974.
Environmental Protection Act 1990.
Codes of Practice: Waste Management. The Duty of Care.
Operational Provisions of the Road Traffic (Carriage of Dangerous Substances in packages
etc.) Regs. 1986 (COP 17).
Guidance Notes: Occupational skin diseases: health and safety precautions (EH 26).
Storage of packaged dangerous substances [HS(G)71].
The above publications are available from HMSO
15.2. Chemical safety assessment

No chemical safety assessment has been carried out.
SECTION 16: Other information
General information For professional use only. Only trained personnel should use this material.
Revision comments This is the first issue.
Revision date 02/06/2020
14/15
Revision 00
SDS number 28692
Hazard statements in full H225 Highly flammable liquid and vapour.

H226 Flammable liquid and vapour.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H318 Causes serious eye damage.
H330 Fatal if inhaled.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H370 Causes damage to organs .
H373 May cause damage to organs through prolonged or repeated exposure.
H373 May cause damage to organs (Hearing organs) through prolonged or repeated
exposure.
H400 Very toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
The information on this data sheet represents our current data and is reliable, provided that the product is used under the
prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance
literature. Any other use of the product which involves using the product in combination with any other product or any other
process is the responsibility of the user.
15/15

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SAFETY DATA SHEET

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

1.3. Details of the supplier of the safety data sheet

1.4. Emergency telephone number

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Environmental hazards Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410

2.2. Label elements

Signal word Danger

Hazard statements H315 Causes skin irritation.

Precautionary statements P264 Wash contaminated skin thoroughly after handling.

Supplementary precautionary P201 Obtain special instructions before use.

2.3. Other hazards

SECTION 3: Composition/information on ingredients

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin 60-100%

DIBUTYL PHTHALATE 5-10%

TITANIUM DIOXIDE 1-5%

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation May cause coughing and difficulties in breathing.

Ingestion May cause irritation. May cause discomfort.

Eye contact May cause severe eye irritation.

SECTION 5: Firefighting measures

5.1. Extinguishing media

5.2. Special hazards arising from the substance or mixture

Specific hazards None known.

5.3. Advice for firefighters

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental precautions

6.3. Methods and material for containment and cleaning up

6.4. Reference to other sections

SECTION 7: Handling and storage

7.1. Precautions for safe handling

7.2. Conditions for safe storage, including any incompatibilities

Storage class Chemical storage.

7.3. Specific end use(s)

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Long-term exposure limit (8-hour TWA): WEL 10 mg/m³ inhalable dust

Ingredient comments WEL = Workplace Exposure Limits

DNEL Workers - Inhalation; Short term systemic effects: 12.25 mg/m³

PNEC - Fresh water; 0.006 mg/l

DIBUTYL PHTHALATE (CAS: 84-74-2)

DNEL Workers - Inhalation; Long term systemic effects: 0.13 mg/m³

PNEC - Fresh water; 10 µg/l

TITANIUM DIOXIDE (CAS: 13463-67-7)

DNEL Industry - Inhalation; Long term local effects: 10 mg/m³

PNEC - Fresh water; 0.127 mg/l

PROPAN-2-OL (CAS: 67-63-0)

DNEL Workers - Dermal; Long term systemic effects: 888 mg/kg

PNEC - Fresh water, marine water, Intermittent release; 140.9 mg/l

8.2. Exposure controls

Eye/face protection Wear tight-fitting, chemical splash goggles or face shield.

Hand protection Nitrile gloves are recommended.

Respiratory protection Gas filter, type A2.

SECTION 9: Physical and chemical properties