Msds Parte B HEMPADUR GF 35870

Safety Data Sheet
Hempel's Curing Agent 98870
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 2020/878 - Europe
SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Product name : Hempel's Curing Agent 98870
Product identity : 9887000000
Product type : Curing agent
1.2 Relevant identified uses of the substance or mixture and uses advised against
Field of application : used only as part of two- or multi component products.
Ready-for-use mixture : (see base component)
Identified uses : Industrial applications, Used by spraying.
1.3 Details of the supplier of the safety data sheet 1.4 Emergency telephone number
Company details : HEMPEL A/S Emergency telephone number (with hours of operation)
Lundtoftegårdsvej 91
DK-2800 Kgs. Lyngby +45 45 93 38 00 (08.00 - 17.00)
Denmark See section 4 First aid measures.
Tel.: + 45 45 93 38 00
[email protected]
Date of issue : 21 November 2022
Date of previous issue : 16 November 2021.
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture

Product definition : Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Flam. Liq. 3, H226 FLAMMABLE LIQUIDS
Acute Tox. 4, H302 ACUTE TOXICITY (oral)
Skin Corr. 1B, H314 SKIN CORROSION/IRRITATION
Eye Dam. 1, H318 SERIOUS EYE DAMAGE/ EYE IRRITATION
Skin Sens. 1, H317 SKIN SENSITIZATION
Repr. 2, H361f TOXIC TO REPRODUCTION
STOT RE 2, H373 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE)
Aquatic Chronic 2, H411 AQUATIC HAZARD (LONG-TERM)
See Section 11 for more detailed information on health effects and symptoms.
2.2 Label elements

Hazard pictograms :
Signal word : Danger

Hazard statements : H226 - Flammable liquid and vapor.
H302 - Harmful if swallowed.
H314 - Causes severe skin burns and eye damage.
H317 - May cause an allergic skin reaction.
H361f - Suspected of damaging fertility.
H373 - May cause damage to organs through prolonged or repeated exposure.
H411 - Toxic to aquatic life with long lasting effects.
Precautionary statements :
Prevention : Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Avoid release to the
environment. Do not breathe vapor, mist or spray.
Response : Collect spillage. IF INHALED: Immediately call a POISON CENTER or doctor. IF SWALLOWED:
Immediately call a POISON CENTER or doctor. IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water. Immediately call a POISON CENTER or doctor. IF IN
EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. Immediately call a POISON CENTER or doctor.
Version: 0.08 Page: 1/20

Safety Data Sheet
SECTION 2: Hazards identification

Hazardous ingredients : 4,4'-methylene-bis-cyclohexanamine
4,4'-Isopropylidenediphenol, oligomeric reaction products with 1-chloro-2,3-epoxypropane, reaction
products with 4,4'-methylenebis(cyclohexylamine)
4-tert-butylphenol
m-Xylylene-diamine
2,2,4(or 2,4,4)-trimethylhexane-1,6-diamine
Supplemental label elements :
Special packaging requirements
Containers to be fitted with child- Not applicable.
resistant fastenings :
Tactile warning of danger : Not applicable.
2.3 Other hazards

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.
Other hazards which do not result None known.
in classification :
SECTION 3: Composition/information on ingredients
3.2 Mixtures
Product/ingredient name Identifiers % Regulation (EC) No. 1272/2008 [CLP] Type
benzyl alcohol REACH #: 01-2119492630-38 ≥10 - ≤25 Acute Tox. 4, H302 ATE [Oral] = 1230 mg/kg [1]
EC: 202-859-9 Acute Tox. 4, H332 ATE [Inhalation (vapours)] = 11
mg/l
CAS: 100-51-6 Eye Irrit. 2, H319
Index: 603-057-00-5
4,4'-methylene-bis- REACH #: 01-2119541673-38 ≥10 - ≤25 Acute Tox. 4, H302 ATE [Oral] = 380 mg/kg [1]
cyclohexanamine EC: 217-168-8 Skin Corr. 1B, H314
CAS: 1761-71-3 Eye Dam. 1, H318
Skin Sens. 1B, H317
STOT RE 2, H373 (liver)
(oral)
4,4'-Isopropylidenediphenol, REACH #: 01-2120769907-34 ≥10 - ≤14 Acute Tox. 4, H302 ATE [Oral] = 500 mg/kg [1]
oligomeric reaction products EC: 500-103-5 Skin Corr. 1C, H314 M [Acute] = 1
M [Chronic] = 1
with 1-chloro- CAS: 38294-67-6 Eye Dam. 1, H318
2,3-epoxypropane, reaction Skin Sens. 1A, H317
products with 4,4'-methylenebis Aquatic Acute 1, H400
(cyclohexylamine) Aquatic Chronic 1, H410
xylene REACH #: 01-2119488216-32 ≥5 - ≤10 Flam. Liq. 3, H226 ATE [Dermal] = 1100 mg/kg [1] [2]
EC: 215-535-7 Acute Tox. 4, H312 ATE [Inhalation (gases)] =
5000 ppm
CAS: 1330-20-7 Acute Tox. 4, H332
Index: 601-022-00-9 Skin Irrit. 2, H315
4-tert-butylphenol REACH #: 01-2119489419-21 ≥5 - ≤10 Skin Irrit. 2, H315 M [Chronic] = 1 [1] [3]
EC: 202-679-0 Eye Dam. 1, H318
CAS: 98-54-4 Repr. 2, H361f
Aquatic Chronic 1, H410
m-Xylylene-diamine REACH #: 01-2119480150-50 ≥5 - ≤10 Acute Tox. 4, H302 ATE [Oral] = 930 mg/kg [1] [2]
EC: 216-032-5 Acute Tox. 4, H332 ATE [Inhalation (vapours)] = 11
mg/l
CAS: 1477-55-0 Skin Corr. 1B, H314
Eye Dam. 1, H318
Skin Sens. 1B, H317
Aquatic Chronic 3, H412
EUH071
2,2,4(or 2,4,4)-trimethylhexane- REACH #: 01-2119560598-25 ≥1 - ≤3 Acute Tox. 4, H302 ATE [Oral] = 910 mg/kg [1]
1,6-diamine EC: 247-063-2 Skin Corr. 1A, H314
CAS: 25513-64-8 Eye Dam. 1, H318
Skin Sens. 1A, H317
ethylbenzene REACH #: 01-2119489370-35 ≥1 - ≤3 Flam. Liq. 2, H225 ATE [Inhalation (vapours)] = 11 [1] [2]
EC: 202-849-4 Acute Tox. 4, H332 mg/l
CAS: 100-41-4 STOT RE 2, H373
Index: 601-023-00-4 (hearing organs)
Asp. Tox. 1, H304
toluene REACH #: 01-2119471310-51 ≤0.3 Flam. Liq. 2, H225 - [1] [2]
EC: 203-625-9 Skin Irrit. 2, H315
CAS: 108-88-3 Repr. 2, H361d
Index: 601-021-00-3 STOT SE 3, H336
STOT RE 2, H373
Asp. Tox. 1, H304
See Section 16 for the full text of the H statements declared
above.

Safety Data Sheet
SECTION 3: Composition/information on ingredients

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit, see section 8.
[3] Substance of equivalent concern
SECTION 4: First aid measures
4.1 Description of first aid measures

General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth
to an unconscious person.
If breathing is irregular, drowsiness, loss of consciousness or cramps: Call 112 and give immediate
treatment (first aid).
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15
minutes, occasionally lifting the upper and lower eyelids. Seek immediate medical attention.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Give nothing by
mouth. If unconscious, place in recovery position and get medical attention immediately.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use
recognized skin cleanser. Do NOT use solvents or thinners. In case of burns flush with water until the
pain ceases. While flushing remove clothing from the affected area unless it is burnt into the skin. If
hospital treatment is necessary flushing must continue during transfer and until the hospital staff takes
over the treatment.
Ingestion : If swallowed, seek medical advice immediately and show this container or label. Keep person warm
and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so
that vomit will not re-enter the mouth and throat.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that
fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing
apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes severe burns. May cause an allergic skin reaction.
Ingestion : Harmful if swallowed.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains
4.3 Indication of any immediate medical attention and special treatment needed

Safety Data Sheet
SECTION 4: First aid measures

Notes to physician : If gasses have been inhaled, from the decomposition of the product, symptoms may be delayed. Treat
symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested
or inhaled.
Specific treatments : No specific treatment.
SECTION 5: Firefighting measures
5.1 Extinguishing media

Extinguishing media : Recommended: alcohol resistant foam, CO2, powders, water spray.
Not to be used: waterjet.
5.2 Special hazards arising from the substance or mixture

Hazards from the substance or Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated,
mixture : a pressure increase will occur and the container may burst, with the risk of a subsequent explosion.
This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material
must be contained and prevented from being discharged to any waterway, sewer or drain.
Hazardous combustion products : Decomposition products may include the following materials: carbon oxides nitrogen oxides
halogenated compounds
5.3 Advice for firefighters

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any
personal risk or without suitable training. Fire will produce dense black smoke. Exposure to decomposition products may cause a health
hazard. Cool closed containers exposed to fire with water. Do not release runoff from fire to drains or watercourses. Fire-fighters should
wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a
basic level of protection for chemical incidents.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures

Avoid all direct contact with the spilled material. Exclude sources of ignition and be aware of explosion hazard. Ventilate the area. Avoid
breathing vapor or mist. Refer to protective measures listed in sections 7 and 8. No action shall be taken involving any personal risk or
without suitable training. If the product contaminates lakes, rivers, or sewers, inform the appropriate authorities in accordance with local
regulations.
6.2 Environmental precautions

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material.
6.3 Methods and materials for containment and cleaning up

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Use spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the same
hazard as the spilled product.
6.4 Reference to other sections

See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.
SECTION 7: Handling and storage
7.1 Precautions for safe handling

Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Prevent the creation of flammable or
explosive concentrations of vapors in air and avoid vapor concentrations higher than the occupational exposure limits. In addition, the
product should be used only in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment
should be protected to the appropriate standard. To dissipate static electricity during transfer, ground drum and connect to receiving
container with bonding strap. No sparking tools should be used.
Avoid inhalation of vapour, dust and spray mist. Avoid contact with skin and eyes. Eating, drinking and smoking should be prohibited in area
where this material is handled, stored and processed. Appropriate personal protective equipment: see Section 8. Always keep in containers
made from the same material as the original one.

Safety Data Sheet
SECTION 7: Handling and storage

7.2 Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations. Store in a cool, well-ventilated area away from incompatible materials and ignition sources.
Keep out of the reach of children. Keep away from: Oxidizing agents, strong alkalis, strong acids. No smoking. Prevent unauthorized
access. Containers that are opened must be carefully resealed and kept upright to prevent leakage.
7.3 Specific end use(s)

See separate Product Data Sheet for recommendations or industrial sector specific solutions.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters

Product/ingredient name Exposure limit values
xylene EU OEL (Europe, 1/2022). [xylene, mixed isomers] Absorbed through skin.
TWA: 50 ppm 8 hours.
TWA: 221 mg/m³ 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 442 mg/m³ 15 minutes.
m-Xylylene-diamine EU OEL (Europe, 2/2010). Absorbed through skin.
(ACGIH) C: 0.1 mg/m³
ethylbenzene EU OEL (Europe, 1/2022). Absorbed through skin.
toluene EU OEL (Europe, 1/2022). Absorbed through skin.
Recommended monitoring procedures

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment.
Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres -
Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy)
European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure
to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of
procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Derived effect levels
Product/ingredient name Type Exposure Value Population Effects
benzyl alcohol DNEL Long term Inhalation 22 mg/m³ Workers Systemic
DNEL Long term Dermal 8 mg/kg bw/day Workers Systemic
4,4'-methylene-bis-cyclohexanamine DNEL Long term Inhalation 1 mg/m³ Workers Systemic
DNEL Long term Dermal 0.1 mg/kg bw/day Workers Systemic
xylene DNEL Long term Inhalation 77 mg/m³ Workers Systemic
DNEL Long term Dermal 180 mg/kg bw/day Workers Systemic
m-Xylylene-diamine DNEL Long term Dermal 0.33 mg/kg bw/day Workers Systemic
DNEL Long term Inhalation 1.2 mg/m³ Workers Systemic
2,2,4(or 2,4,4)-trimethylhexane-1,6-diamine DNEL Long term Oral 0.05 mg/kg bw/day Workers Systemic
ethylbenzene DNEL Long term Dermal 180 mg/kg bw/day Workers Systemic
DNEL Long term Inhalation 77 mg/m³ Workers Systemic
toluene DNEL Long term Dermal 384 mg/kg bw/day Workers Systemic
DNEL Long term Inhalation 192 mg/m³ Workers Systemic
Predicted effect concentrations

Safety Data Sheet
Product/ingredient name Compartment Detail Value Method Detail

benzyl alcohol Soil 0.456 mg/kg wwt Assessment Factors
Sewage Treatment Plant 39 mg/l Assessment Factors
Sediment 5.27 mg/kg wwt Assessment Factors
Marine water sediment 0.527 mg/kg wwt Assessment Factors
Marine 0.1 mg/l Assessment Factors
Fresh water 1 mg/l Assessment Factors
4,4'-methylene-bis-cyclohexanamine Fresh water 0.08 mg/l -
Marine water 0.008 mg/l -
Sewage Treatment Plant 3.2 mg/l -
Soil 27.2 mg/kg -
Marine water sediment 13.7 mg/kg -
Fresh water sediment 137 mg/kg -
xylene Fresh water 0.327 mg/l -
Fresh water sediment 12.46 mg/kg -
Soil 2.31 mg/kg -
m-Xylylene-diamine Fresh water 0.094 mg/l -
Soil 0.045 mg/kg -
Sewage Treatment Plant 10 mg/l -
2,2,4(or 2,4,4)-trimethylhexane-1,6-diamine Soil 10 mg/kg -
Sewage Treatment Plant 72 mg/l -
Fresh water 0.102 mg/l -
ethylbenzene Fresh water 0.1 mg/l -
Soil 2.68 mg/kg -
toluene Fresh water 0.68 mg/l -
Soil 2.89 mg/kg -
8.2 Exposure controls

Appropriate engineering controls
Arrange sufficient ventilation by local exhaust ventilation and good general ventilation to keep the airborne concentrations of vapors or dust
lowest possible and below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-
station location.
Individual protection measures
General : Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be
worn when soiling is so great that regular work clothes do not adequately protect skin against contact
with the product. Safety eyewear should be used when there is a likelihood of exposure.
Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,
using lavatory, and at the end of day.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the assessment indicates a higher degree of
protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face
respirator may be required instead.
Hand protection : Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. The
quality of the chemical-resistant protective gloves must be chosen as a function of the specific
workplace concentrations and quantity of hazardous substances.

Safety Data Sheet

Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the
appropriate type. Below listed glove(s) should be regarded as generic advice:
Recommended: Silver Shield / Barrier / 4H gloves, polyvinyl alcohol (PVA), Viton®

May be used: nitrile rubber
Short term exposure: neoprene rubber, butyl rubber, natural rubber (latex), polyvinyl chloride (PVC)
Body protection : Personal protective equipment for the body should be selected based on the task being performed and
the risks involved handling this product.
Wear suitable protective clothing. Always wear protective clothing when spraying.
Chemical-resistant apron.
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator. If
working areas have insufficient ventilation: When the product is applied by means that will not generate
an aerosol such as, brush or roller wear half or totally covering mask equipped with gas filter of type A,
when grinding use particle filter of type P. When the product is applied by spraying and for continuous
or prolonged work always wear an air-fed respirator e.g. hood with supply of fresh or compressed air or
a full face, powered air purifying filter. Be sure to use an approved/certified respirator or equivalent.
Environmental exposure controls
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental
protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to
reduce emissions to acceptable levels.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties

Physical state : Liquid.
Color : Transparent
Odor : Solvent-like
pH : Testing not relevant or not possible due to nature of the product.
Melting point/freezing point : Testing not relevant or not possible due to nature of the product.
Boiling point/boiling range : Testing not relevant or not possible due to nature of the product.
Flash point : Closed cup: 46°C (114.8°F)
Evaporation rate : Testing not relevant or not possible due to nature of the product.
Flammability : Highly flammable in the presence of the following materials or conditions: open flames, sparks and
static discharge and heat.
Lower and upper explosive 0.8 - 13 vol %
(flammable) limits :
Vapor pressure : Testing not relevant or not possible due to nature of the product.
Vapor density : Testing not relevant or not possible due to nature of the product.
Specific gravity : 1.027 g/cm³
Partition coefficient (LogKow) : Testing not relevant or not possible due to nature of the product.
Auto-ignition temperature : Lowest known value: 300°C (572°F) (4,4'-methylene-bis-cyclohexanamine).
Decomposition temperature : Testing not relevant or not possible due to nature of the product.
Viscosity : Aspiration hazard (H304) Not classified. Testing not relevant due to nature of the product.
Explosive properties : Slightly explosive in the presence of the following materials or conditions: open flames, sparks and
static discharge and heat.
Oxidizing properties : Testing not relevant or not possible due to nature of the product.
9.2 Other information

Solvent(s) % by weight : Weighted average: 38 %
Water % by weight : Weighted average: 0 %
VOC content : 258.3 g/l
TOC Content : Weighted average: 216 g/l
Solvent Gas : Weighted average: 0.068 m³/l

Safety Data Sheet
SECTION 10: Stability and reactivity
10.1 Reactivity
No specific test data related to reactivity available for this product or its ingredients.
10.2 Chemical stability

The product is stable.
10.3 Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.
10.4 Conditions to avoid

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat
or sources of ignition.
10.5 Incompatible materials

Highly reactive or incompatible with the following materials: oxidizing materials.
Reactive or incompatible with the following materials: reducing materials.
10.6 Hazardous decomposition products

When exposed to high temperatures (i.e. in case of fire) harmful decomposition products may be formed:
Decomposition products may include the following materials: carbon oxides nitrogen oxides halogenated compounds
SECTION 11: Toxicological information
11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008

Exposure to component solvent vapor concentrations may result in adverse health effects such as mucous membrane and respiratory
system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may cause some of the above effects by
absorption through the skin. Symptoms and signs include headaches, dizziness, fatigue, muscular weakness, drowsiness and, in extreme
cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, resulting
in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause irritation and reversible
damage. Accidental swallowing may cause stomach pain. Chemical lung inflammation may occur if the product is taken into the lungs via
vomiting.
Inhalation of a corrosive substance may result in health effects such as stinging, coughing and in extreme cases, dyspnoea or loss of
consciousness with a risk of lung damage, possibly lung oedema. Cauterization of skin and mucous membrane. If splashed in the eyes, the
liquid may cause ireversible damage. Accidental swallowing may cause stinging and cauterization to mouth, oesophagus and stomach.
Symptoms and signs include bloody vomiting, chock and loss of consciousness.
Acute toxicity
Product/ingredient name Result Species Dose Exposure
benzyl alcohol LC50 Inhalation Dusts and mists Rat >4178 mg/m³ 4 hours
LD50 Oral Rat 1230 mg/kg -
4,4'-methylene-bis- LD50 Dermal Rabbit 2110 mg/kg -
cyclohexanamine
4,4'-Isopropylidenediphenol, LD50 Oral Rat 500 - 2000 mg/kg -
oligomeric reaction products with
1-chloro-2,3-epoxypropane,
reaction products with 4,4'-
methylenebis(cyclohexylamine)
xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours
LC50 Inhalation Vapor Rat 6350 ppm 4 hours
LD50 Dermal Rabbit >4200 mg/kg -
4-tert-butylphenol LC50 Inhalation Dusts and mists Rat >5600 mg/m³ 4 hours
LD50 Dermal Rabbit 2288 mg/kg -
m-Xylylene-diamine LC50 Inhalation Dusts and mists Rat 1.34 mg/l 4 hours
LD50 Dermal Rabbit >3100 mg/kg -
2,2,4(or 2,4,4)-trimethylhexane- LD50 Oral Rat 910 mg/kg -
1,6-diamine
ethylbenzene LD50 Dermal Rabbit >5000 mg/kg -
toluene LC50 Inhalation Vapor Rat >20 mg/l 4 hours
Acute toxicity estimates

Safety Data Sheet
Product/ingredient name Oral Dermal Inhalation Inhalation Inhalation

mg/kg mg/kg (gases) (vapors) (dusts and
ppm mg/l mists)
mg/l
Hempel's Curing Agent 98870 1330.5 12533.1 56968.7 46.4
benzyl alcohol 1230 11
4,4'-methylene-bis-cyclohexanamine 380 2110
4,4'-Isopropylidenediphenol, oligomeric reaction products 500
with 1-chloro-2,3-epoxypropane, reaction products with
4,4'-methylenebis(cyclohexylamine)
xylene 3523 1100 5000
4-tert-butylphenol 2951 2288
m-Xylylene-diamine 930 11
2,2,4(or 2,4,4)-trimethylhexane-1,6-diamine 910
ethylbenzene 3500 11
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure
benzyl alcohol Eyes - Visible necrosis Rabbit - -
Skin - Mild irritant Rabbit - -
4,4'-methylene-bis-cyclohexanamine Eyes - Severe irritant Rabbit - 24 hours 10 microliters
Skin - Severe irritant Rabbit - -
4,4'-Isopropylidenediphenol, Skin - Severe irritant Rabbit - -
xylene Eyes - Severe irritant Rabbit - 24 hours 5 milligrams
Skin - Irritant Rabbit - -
Skin - Moderate irritant Rabbit - 24 hours 500 milligrams
4-tert-butylphenol Eyes - Severe irritant Rabbit - 24 hours 50 Micrograms
Skin - Mild irritant Rabbit - 24 hours 500 milligrams
m-Xylylene-diamine Eyes - Severe irritant Rabbit - 24 hours 50 Micrograms
Respiratory - Severe irritant Rabbit - -
Skin - Severe irritant Rabbit - 24 hours 750 Micrograms
ethylbenzene Eyes - Mild irritant Rabbit - -
Respiratory - Mild irritant Rabbit - -
Skin - Mild irritant Rabbit - 24 hours 15 milligrams
toluene Eyes - Mild irritant Rabbit - 0.5 minutes 100 milligrams
Skin - Moderate irritant Rabbit - 24 hours 20 milligrams
Sensitizer
Product/ingredient name Route of exposure Species Result
4,4'-methylene-bis-cyclohexanamine skin Guinea pig Sensitizing
4,4'-Isopropylidenediphenol, skin Mouse Sensitizing
Mutagenic effects
No known significant effects or critical hazards.
Carcinogenicity
Reproductive toxicity
Suspected of damaging fertility.
Teratogenic effects
Specific target organ toxicity (single exposure)

Product/ingredient name Category Route of exposure Target organs
toluene Category 3 Narcotic effects
Specific target organ toxicity (repeated exposure)

Safety Data Sheet
Product/ingredient name Category Route of exposure Target organs

4,4'-methylene-bis-cyclohexanamine Category 2 oral liver
ethylbenzene Category 2 - hearing organs
toluene Category 2 - -
Aspiration hazard
Product/ingredient name Result
ethylbenzene ASPIRATION HAZARD - Category 1
toluene ASPIRATION HAZARD - Category 1
Information on the likely routes of exposure
Routes of entry anticipated: Oral, Dermal, Inhalation.
Potential chronic health effects
Sensitization : Contains 4,4'-methylene-bis-cyclohexanamine, 4,4'-Isopropylidenediphenol, oligomeric reaction
products with 1-chloro-2,3-epoxypropane, reaction products with 4,4'-methylenebis(cyclohexylamine),
m-Xylylene-diamine. May produce an allergic reaction.
11.2 Information on other hazards
Endocrine disrupting properties : See Section 15 for details.
Other information : No additional known significant effects or critical hazards.
SECTION 12: Ecological information
12.1 Toxicity
Do not allow to enter drains or watercourses. Toxic to aquatic life with long lasting effects.
Product/ingredient name Result Species Exposure
benzyl alcohol Acute EC50 230 mg/l Daphnia 48 hours
Acute IC50 770 mg/l Algae 72 hours
Acute LC50 460 mg/l Fish 96 hours
4,4'-methylene-bis-cyclohexanamine Acute EC50 140 mg/l Algae 72 hours
Acute EC50 6.84 mg/l Daphnia 48 hours
Acute LC50 >100 mg/l Fish 96 hours
4,4'-Isopropylidenediphenol, Acute LC50 13 mg/l Fish 96 hours
4-tert-butylphenol Acute EC50 14 mg/l Algae 72 hours
Acute EC50 3.4 mg/l Daphnia 48 hours
Acute LC50 1.6 mg/l Fish 48 hours
Acute LC50 5140 - 5620 µg/l Fresh water Fish - Pimephales promelas 96 hours
Chronic NOEC 2.3 mg/l Fresh water Fish - Cyprinus carpio - Adult 28 days
m-Xylylene-diamine Acute EC50 20.3 mg/l Algae 72 hours
Acute EC50 15.2 mg/l Daphnia - Daphnia 48 hours
Acute LC50 87.6 mg/l Fish - Leuciscus idus 96 hours
Acute NOEC 4.7 mg/l Daphnia 21 days
2,2,4(or 2,4,4)-trimethylhexane- Acute EC50 29.5 mg/l Algae 72 hours
1,6-diamine
ethylbenzene Chronic NOEC <1000 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours
toluene Chronic NOEC <500000 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours
Chronic NOEC 1000 µg/l Fresh water Daphnia - Daphnia magna 21 days
12.2 Persistence and degradability

Product/ingredient name Test Result Dose Inoculum
benzyl alcohol OECD 301A 301A Ready 95 - 97 % - Readily - 21 days - -
Biodegradability - DOC Die-Away
Test
OECD 301C 301C Ready 92 - 96 % - Readily - 14 days - -
Biodegradability - Modified MITI
Test (I)
xylene OECD 301F Ready 90 - 98 % - Readily - 28 days - -
Biodegradability - Manometric
Respirometry Test
- >60 % - Readily - 28 days - -
4-tert-butylphenol OECD 301A Ready 98 % - Readily - 28 days - -
Biodegradability - DOC Die-Away
Test

Safety Data Sheet
SECTION 12: Ecological information

m-Xylylene-diamine OECD 301B 301B Ready 49 % - Inherent - 28 days - -
Biodegradability - CO₂ Evolution
Test
2,2,4(or 2,4,4)-trimethylhexane- EU EC no. 440/2008, Annex C.4-A 7 % - Not readily - 28 days - -
1,6-diamine
ethylbenzene - >70 % - Readily - 28 days - -
toluene - 100 % - Readily - 14 days - -
Product/ingredient name Aquatic half-life Photolysis Biodegradability

benzyl alcohol - - Readily
xylene - - Readily
4-tert-butylphenol - - Readily
m-Xylylene-diamine - - Inherent
2,2,4(or 2,4,4)-trimethylhexane- - - Not readily
1,6-diamine
ethylbenzene - - Readily
toluene - - Readily
12.3 Bioaccumulative potential

Product/ingredient name LogPow BCF Potential
benzyl alcohol 0.87 1.37 low
4,4'-methylene-bis-cyclohexanamine 2.03 - low
xylene 3.12 8.1 - 25.9 low
4-tert-butylphenol 3 44 - 48 low
m-Xylylene-diamine 0.18 2.69 low
2,2,4(or 2,4,4)-trimethylhexane-1,6-diamine -0.3 - low
ethylbenzene 3.6 - low
toluene 2.73 90 low
12.4 Mobility in soil

Soil/water partition coefficient No known data avaliable in our database.
(KOC) :
Mobility : No known data avaliable in our database.
12.5 Results of PBT and vPvB assessment

Product/ingredient name PBT P B T vPvB vP vB
This mixture does not contain any substances that are assessed to be a PBT or a vPvB.
12.6 Endocrine disrupting properties

May cause endocrine disruption.
12.7 Other adverse effects
SECTION 13: Disposal considerations
13.1 Waste treatment methods

The generation of waste should be avoided or minimized wherever possible. Residues of the product is listed as hazardous waste. Dispose
of according to all state and local applicable regulations. Waste should not be disposed of untreated to the sewer unless fully compliant with
the requirements of all authorities with jurisdiction. Spillage, remains, discarded clothes and similar should be discarded in a fireproof
container.
European waste catalogue no. (EWC) is given below.
European waste catalogue (EWC) : 08 01 11*
Packaging
The generation of waste should be avoided or minimized wherever possible. Waste packaging should be recycled. Incineration or landfill
should only be considered when recycling is not feasible.

Safety Data Sheet
SECTION 14: Transport information
Transport may take place according to national regulation or ADR for transport by road, RID for transport by train, IMDG for transport by
sea, IATA for transport by air.
14.1 14.2 14.3 14.4 14.5
UN / ID no. Proper shipping name Transport hazard class(es) PG* Env* Additional information
ADR/RID UN3469 PAINT, FLAMMABLE, CORROSIVE 3 III Yes. The environmentally

Class 8 hazardous substance mark
is not required when
transported in sizes of ≤5 L
or ≤5 kg.
Tunnel code (D/E)
IMDG UN3469 PAINT, FLAMMABLE, CORROSIVE. 3 III Yes. The marine pollutant
Class (4,4'-Isopropylidenediphenol, 8 mark is not required
oligomeric reaction products with when transported in
1-chloro-2,3-epoxypropane, reaction sizes of ≤5 L or ≤5 kg.
products with 4,4'-methylenebis Emergency schedules
(cyclohexylamine)) F-E, S-C
IATA UN3469 PAINT, FLAMMABLE, CORROSIVE 3 III Yes. The environmentally

Class 8 hazardous substance mark
may appear if required by
other transportation
regulations.
PG* : Packing group
Env.* : Environmental hazards
14.6 Special precautions for user

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the
product know what to do in the event of an accident or spillage.
14.7 Maritime transport in bulk according to IMO instruments
Not applicable.
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorization - Substances of very high concern
Annex XIV
None of the components are listed.
Substances of very high concern
Ingredient name Intrinsic property Status Reference number Date of revision
4-tert-butylphenol Endocrine disrupting Candidate ED/71/2019, 7/16/2019
properties for environment EU/2019/1194
Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles
Not applicable.
Other EU regulations
Seveso category This product is controlled under the Seveso III Directive.
Seveso category
P5c: Flammable liquids 2 and 3 not falling under P5a or P5b
E2: Hazardous to the aquatic environment - Chronic 2
15.2 Chemical Safety Assessment

Yes.

Safety Data Sheet
SECTION 16: Other information

Abbreviations and acronyms : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]
EUH statement = CLP-specific Hazard statement
RRN = REACH Registration Number
DNEL = Derived No Effect Level
PNEC = Predicted No Effect Concentration
Full text of abbreviated H statements : H225 Highly flammable liquid and vapor.
H226 Flammable liquid and vapor.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H336 May cause drowsiness or dizziness.
H361d Suspected of damaging the unborn child.
H361f Suspected of damaging fertility.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
EUH071 Corrosive to the respiratory tract.
Full text of classifications [CLP/GHS] : Acute Tox. 4 ACUTE TOXICITY - Category 4
Aquatic Acute 1 AQUATIC HAZARD (ACUTE) - Category 1
Aquatic Chronic 1 AQUATIC HAZARD (LONG-TERM) - Category 1
Asp. Tox. 1 ASPIRATION HAZARD - Category 1
Eye Dam. 1 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
Eye Irrit. 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2
Flam. Liq. 2 FLAMMABLE LIQUIDS - Category 2
Flam. Liq. 3 FLAMMABLE LIQUIDS - Category 3
Repr. 2 TOXIC TO REPRODUCTION - Category 2
Skin Corr. 1A SKIN CORROSION/IRRITATION - Category 1A
Skin Corr. 1B SKIN CORROSION/IRRITATION - Category 1B
Skin Corr. 1C SKIN CORROSION/IRRITATION - Category 1C
Skin Irrit. 2 SKIN CORROSION/IRRITATION - Category 2
Skin Sens. 1 SKIN SENSITIZATION - Category 1
Skin Sens. 1A SKIN SENSITIZATION - Category 1A
Skin Sens. 1B SKIN SENSITIZATION - Category 1B
STOT RE 2 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
STOT SE 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - Category 3
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification Justification
FLAMMABLE LIQUIDS On basis of test data
ACUTE TOXICITY (oral) Calculation method
SKIN CORROSION/IRRITATION Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION Calculation method
SKIN SENSITIZATION Calculation method
TOXIC TO REPRODUCTION Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) Calculation method
AQUATIC HAZARD (LONG-TERM) Calculation method
Notice to reader
Indicates information that has changed from previously issued version.
The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It provides
guidance on health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guarantee
of the technical preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.

Safe Use of Mixture Information
This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the
product's Safety Data Sheet and labels.
General description of the process covered
Indoor or outdoor spray painting by professionals for specialist applications, with good general room ventilation plus respiratory protection
This safe use information is : Professional spray painting, near-industrial setting
linked to Expert judgment
Sector(s) of use : Industrial uses - Professional uses
Product category(ies) : Coatings and paints, thinners, paint removers
Operational conditions
Place of use : Indoor or outdoor use
Range of application/Process : Assumes a good standard of occupational hygiene and safety management has been implemented.
conditions Assumes that activities are undertaken with appropriate and well maintained equipment by trained
personnel operating under supervision.
Others : Depending on actual conditions of application. Please consult your local HEMPEL representative
for further advise.
Risk management measures (RMM)

Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes per
hour
Preparation of material for PROC05 More than 4 Good general room 3-5 Wear a respirator Use eye protection Wear chemical-resistant
application hours ventilation - Outdoors conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with
factor of at least 10. specific activity training.
Loading of application PROC08b More than 4 Good general room 3-5 Wear a respirator Use eye protection Wear chemical-resistant
equipment and handling hours ventilation - Outdoors conforming to EN140 with according to EN 166. gloves (tested to EN374)
of coated parts before an assigned protection in combination with
curing factor of at least 10. specific activity training.
Industrial application of PROC07 More than 4 Good general room 3-5 Use a properly fitted, air- Use eye protection Wear chemical-resistant
coatings by spraying hours ventilation - Outdoors purifying or air-fed according to EN 166. gloves (tested to EN374)
respirator. EN 14594 with in combination with
an assigned protection specific activity training.
factor of at least 20.
Film formation - force PROC04 More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
drying, stoving and other hours ventilation - Outdoors according to EN 166. tested to EN374.
technologies
Cleaning PROC05 More than 4 Good general room 3-5 Wear a respirator Use eye protection Wear chemical-resistant
hours ventilation - Outdoors conforming to EN140 with according to EN 166. gloves (tested to EN374)
Waste management PROC08b More than 4 Good general room 3-5 Wear a respirator Use eye protection Wear chemical-resistant
hours ventilation - Outdoors conforming to EN140 with according to EN 166. gloves (tested to EN374)
See chapter 8 of this Safety Data Sheet for specifications.
The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.
Page: 14/20
Indoor spray painting by professionals with efficient ventilation such as spray booth or local exhaust ventilation
This safe use information is : Professional spray painting, near-industrial setting - Level I
linked to HMP I/PW 01a
Place of use : Indoor use
conditions

hour
Preparation of material for PROC05 More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
application hours (mechanical) room according to EN 166. tested to EN374.
ventilation
Loading of application PROC08b More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
equipment and handling hours (mechanical) room according to EN 166. tested to EN374.
of coated parts before ventilation
curing
Industrial application of PROC07 More than 4 Local exhaust Refer to Wear a respirator Use eye protection Wear suitable gloves
coatings by spraying hours ventilation relevant conforming to EN140 with according to EN 166. tested to EN374.
technical an assigned protection
standards factor of at least 10.
Film formation - force PROC04 More than 4 Enhanced 5 - 10 None None None
drying, stoving and other hours (mechanical) room
technologies ventilation
Cleaning PROC05 More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
hours (mechanical) room according to EN 166. tested to EN374.
ventilation
Waste management PROC08b More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
ventilation
Page: 15/20
Indoor painting by professionals by dipping or with brush, roller, putty knife etc. with enhanced ventilation or local exhaust ventilation (LEV)
This safe use information is : Professional low-energy painting, near-industrial setting - Level I
conditions

hour
Preparation of material for PROC05 More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
application hours (mechanical) room according to EN 166. tested to EN374.
ventilation
Loading of application PROC08b More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
equipment and handling hours (mechanical) room according to EN 166. tested to EN374.
of coated parts before ventilation
curing
Industrial application of PROC10 More than 4 Local exhaust Refer to Wear a respirator Use eye protection Wear suitable gloves
coatings by other than hours ventilation relevant conforming to EN140 with according to EN 166. tested to EN374.
spraying technical an assigned protection
standards factor of at least 10.
Film formation - force PROC04 More than 4 Enhanced 5 - 10 None None None
drying, stoving and other hours (mechanical) room
technologies ventilation
Cleaning PROC05 More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
ventilation
Waste management PROC08b More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
ventilation
Page: 16/20
Indoor spray painting by professionals for general applications (e.g. decorative), with general room ventilation only (open doors/windows)
This safe use information is : Professional spray painting, indoor (Level I)
linked to CEPE / HMP PW 03a
Sector(s) of use : Professional uses

hour
Preparation of material for PROC05 More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
application hours ventilation according to EN 166. tested to EN374.
Loading of application PROC08a More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
equipment and handling hours ventilation according to EN 166. tested to EN374.
of coated parts before
curing
Professional application of PROC11 More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
coatings by spraying hours ventilation according to EN 166. tested to EN374.
Film formation - force PROC04 More than 4 Good general room 3-5 None None None
drying, stoving and other hours ventilation
technologies
Cleaning PROC05 More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
hours ventilation according to EN 166. tested to EN374.
Waste management PROC08a More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
Page: 17/20
Indoor painting by professionals with brush or roller, with good general room ventilation (open doors/windows)
This safe use information is : Professional painting, indoor brush/roller - Level I
linked to CEPE / HMP PW 04a
Sector(s) of use : Professional uses

hour
Preparation of material for PROC05 More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
application hours ventilation according to EN 166. tested to EN374.
Loading of application PROC08a More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
equipment and handling hours ventilation according to EN 166. tested to EN374.
curing
Professional application of PROC10 More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
coatings by brush or roller hours ventilation according to EN 166. tested to EN374.
Film formation - force PROC04 More than 4 Good general room 3-5 None None None
drying, stoving and other hours ventilation
technologies
Cleaning PROC05 More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
Waste management PROC08a More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
Page: 18/20
Outdoor spray painting by professionals for specialist applications, with respiratory protection
This safe use information is : Professional spray painting, near-industrial setting - Level I
Place of use : Outdoor use
conditions

hour
Preparation of material for PROC05 More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
application hours according to EN 166. tested to EN374.
Loading of application PROC08b More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
equipment and handling hours according to EN 166. tested to EN374.
curing
Industrial application of PROC07 More than 4 Outdoors 3-5 Wear a respirator Use eye protection Wear suitable gloves
coatings by spraying hours conforming to EN140 with according to EN 166. tested to EN374.
an assigned protection
factor of at least 10.
Film formation - force PROC04 More than 4 Outdoors 3-5 None None None
drying, stoving and other hours
technologies
Cleaning PROC05 More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
hours according to EN 166. tested to EN374.
Waste management PROC08b More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
Page: 19/20
Outdoor painting by professionals by dipping or with brush, roller, putty knife etc.
This safe use information is : Professional low-energy painting, near-industrial setting - Level I
Place of use : Outdoor use
conditions

hour
Preparation of material for PROC05 More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
application hours according to EN 166. tested to EN374.
Loading of application PROC08b More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
equipment and handling hours according to EN 166. tested to EN374.
curing
Industrial application of PROC10 More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
coatings by other than hours according to EN 166. tested to EN374.
spraying
Film formation - force PROC04 More than 4 Outdoors 3-5 None None None
drying, stoving and other hours
technologies
Cleaning PROC05 More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
Waste management PROC08b More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
Page: 20/20

Msds Parte B HEMPADUR GF 35870

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Safety Data Sheet

Hempel's Curing Agent 98870

SECTION 1: Identification of the substance/mixture and of the company/undertaking

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

2.2 Label elements

Signal word : Danger

Version: 0.08 Page: 1/20

SECTION 2: Hazards identification

2.3 Other hazards

SECTION 3: Composition/information on ingredients

Version: 0.08 Page: 2/20

SECTION 3: Composition/information on ingredients

SECTION 4: First aid measures

4.1 Description of first aid measures

Version: 0.08 Page: 3/20

SECTION 4: First aid measures

SECTION 5: Firefighting measures

5.1 Extinguishing media

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

6.2 Environmental precautions

6.3 Methods and materials for containment and cleaning up

6.4 Reference to other sections

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Version: 0.08 Page: 4/20

SECTION 7: Handling and storage

7.3 Specific end use(s)

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Recommended monitoring procedures

Version: 0.08 Page: 5/20

SECTION 8: Exposure controls/personal protection

Product/ingredient name Compartment Detail Value Method Detail

8.2 Exposure controls

Version: 0.08 Page: 6/20

SECTION 8: Exposure controls/personal protection

Recommended: Silver Shield / Barrier / 4H gloves, polyvinyl alcohol (PVA), Viton®

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

9.2 Other information

Version: 0.08 Page: 7/20

SECTION 10: Stability and reactivity

10.2 Chemical stability

10.3 Possibility of hazardous reactions

10.4 Conditions to avoid

10.5 Incompatible materials

10.6 Hazardous decomposition products

SECTION 11: Toxicological information

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008

Version: 0.08 Page: 8/20

SECTION 11: Toxicological information

Product/ingredient name Oral Dermal Inhalation Inhalation Inhalation

Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)

Version: 0.08 Page: 9/20