1

VIDYAPEETH
Atomic Strcture
1. An electron is moving in He+ in which number of 5. An electron jump in such a way Longest
waves formed by the electron is 2. Which is/are wavelength of Lyman series emitted in H-atom.
correct statement? Which is/are correct statement(s).
(A) Energy of electron is –13.6 eV (A) Magnitude of change in De-broglie
(B) Potential energy of electron is 27.2 eV wavelength of electron is equal to 1.058 π Å.
(C) Velocity of moving electron is 2.18 × 106 cm (B) Magnitude of change in orbit radius of
sec–1 electron is equal to 0.529 Å.
(D) Orbit radius of moving electron is 1.058 Å (C) Magnitude of change in velocity of electron
is equal to 1.09 × 106 meter sec–1.
2. Choose the incorrect statement(s):
(A) Increasing order of wavelength is
Micro waves > Radio waves > IR waves > (D) Same wavelength emitted in β-line of Balmer
visible waves > UV waves series in He+.
(B) The order of Bohr radius is (rn : where n is
orbit number for a given atom) 6. Which is/are correct statement about Hydrogen
r1 < r2 < r3 < r4 spectrum?
(C) The order of total energy is (En : where n is (A) Wave length of β-line in Balmer series is
orbit number for a given atom) 16
E1 > E2 > E3 > E4 equal to
3R
(D) The order of velocity of electron in H, He+, (B) Shortest wave length in Paschen series is
Li+, Be3+ species in second Bohr orbit is
9
Be3+ > Li+2 > He+ > H equal to
R
(C) Longest wave length in Lyman series is equal
3. An electron is moving in first excited state of H- 4
atom. It absorb a photon of energy 2.55 eV. Which to
3R
is/are correct statement? (D) Wave length of α-line in Brackett series equal
(A) Magnitude of change in Kinetic energy of
400
electron is equal to 2.55 V. to
9R
(B) Magnitude of change in energy of separation
of electron is equal to 2.55 eV.
7. Which is/are correct statement about Paschen
(C) Magnitude of change in orbit angular
series in Li+2?
h
momentum of electron is equal to . 1
 (A) Wave length of series limit is equal to
(D) Magnitude of change in time period of R
electron is equal to 8.53 × 10–15 sec. 16
(B) Wave length of first line is equal to
7R
4. Photons of energy 2.5 eV are emitted by the bulb 25
(C) Wave length of second line is equal to
of 160W. These photons are incident on a metal of 16R
work function 2 eV. Which is/are correct 36
statement? (D) Wave length of γ-line is equal to
25R
(A) Photo current produce is 64 amp
(B) Photo current produce is 48 amp if efficiency 2
of blub is 75% 8. In a sample of 1 H , Electron present in ground
(C) Stopping potential of photo electron is 0.5 eV state it absorbed a photon and excited to 5th
(D) De-broglie wavelength of photo electron is excited state. After wards electron return to
17.32 Aº ground state which is/are incorrect statement?
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[Given hc = 1240 eV-nm, IE = 14.4 eV] (C) 'xz' plane acts as nodal plane
(D) Magnetic quantum number must be '–1'
(A) Number of spectral lines emitted is 10 14. Choose the correct statement among the following
(B) Wave length of series limit of Lyman series is I. Radial distribution function (ψ2·4πr2dr) give
equal to 91.2 nm probability at a particular distance along one
(C) Longest wave length of Balmer series is chosen direction
equal to 620 nm II. ψ2(r) give probability density at a particular
(D) Number of spectral lines in Balmer series is distance over a spherical surface
equal to 4 III. For 's' orbitals (r)()() = (x, y,z) is

9. In a isolated of H-atom, Electron present in ground independent of  and 

state it absorbed a photon and excited to 4th IV. '2p' orbital with quantum numbers, n = 2,
excited state. After wards electron return to  = 1, m = 0, also shows angular dependence
ground state which is/are correct statement? (A) II, IV (B) II, III, IV
(A) Maximum number of spectral line is equal to 4 (C) I, III, IV (D) III, IV
(B) Minimum number of spectral line is equal to 1
(C) One spectral line in Lyman series always 15. Consider the following six electronic
present configurations (remaining inner orbitals are
(D) One spectral line in Balmer series always completely filled) and mark the correct option.
3s 3p 3s 3p 4s 3d
present  
I.     II.    III.     
4s 3d 4s 3p 4s 3d
10. Which of following electronic configuration have IV.       V.     VI. 

 
maximum spin multiplicity?
(A) Stability order : II > I > IV > III
(A)      (B)      (B) Order of spin multiplicity IV > III = I > II
(C) V does violate all the three rules of electronic
(C)      (D)      configuration
(D) If VI represents A then A+ when kept near a
11. Calculate the minimum and maximum number of magnet, acts as paramagnetic substance.
electrons which may have magnetic quantum
number, m = + 1 and spin quantum number,
16. Which is/are correct statement?
1
s=− (A) Number of nodes 3s > 3p > 3d
2 in chromium (Cr): (B) Order of closeness of orbitals 3s > 3p > 3d
(A) 0, 1 (B) 1, 2 (C) Most probable distance from the nucleus
(C) 4, 6 (D) 2, 3 (rmax)3s > (rmax)3p > (rmax)3d
(D) Number of radial nodes 3s > 3p > 3d
12. A hydrogen like species (atomic number Z) is present
in a higher excited state of quantum number n . This 17. Which is/are correct match in following cases?
excited atom can make a transition to the first excited Column-I Column-II
state by successive emission of two photons of R
energies 10.20 eV and 17.0 eV respectively.
Alternatively, the atom from the same excited state
can make a transition to the second excited state by
successive emission of two photons of energy 4.25 eV
(A) r (P) 3s
and 5.95 eV respectively. Determine the value of Z. 2
(A) 1 (B) 2 R
(C) 3 (D) 4

13. Correct statement(s) regarding 3py orbital is/are (B) r (Q) 5d

(A) Angular part of wave function is independent 4r R
2 2

of angles ( and )
(B) No. of maxima when a curve is plotted
between 4r 2 R 2 (r) vs r are '2' (C) r (R) 4s
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(D) Angular probability (S) depend in a mathematical expression or function. It is

called a wave function and is denoted by the
of 3Px on θ and φ
Greek letter psi, ψ. The wave function is obtained
MATCH THE COLUMN
by solving an equation of quantum mechanics
18. Column-I Column-II
(Schrodinger's equation). Its square, ψ2, density
(A) Electron moving in (P) Radius of orbit in
probability of finding an electron per unit volume
2nd orbit in He+ ion which moving is
called probability.
0.529 Å
The wave function and its square, ψ2, have values
(B) Electron moving in (Q) Total energy of
3rd orbit in H-atom electron is (–) for all locations about a nucleus. Figure (i) shows
13.6 × 9 eV values of ψ2 for the electron in the lowest energy
(C) Electron moving in (R) Velocity of electron level (1s) of the hydrogen atom along a line
starting from the nucleus. Note that ψ2 is large
2.188  106
1st orbit in Li+2 ion is
3
m/sec near the nucleus (r = 0) . The value of ψ2
(D) Electron moving in (S) De-broglie decreases rapidly as the distance from the nucleus
2nd orbit in Be+3 ion wavelength of increases, but ψ2 never goes to exactly zero,
150 although the probability does become extremely
electron is Å small at large distances from the nucleus. This
13.6
means that an atom does not have a definite
boundary, unlike in the Bohr model of the atom.
19. Match the parameters of column-I with column-II
as they are directly proportional.
Column-I Column-II
(A) f (P) n3
(B) T (Q) Z2
1
(C) En (R) 2 Figure (ii) shows another view of this electron
n
1 probability. The graph plots the probability of
(D) r (S) Z finding the electron at spherical surface at
n
particular distances from the nucleus, rather than
Where, Frequency = f, Time period = T, Energy of
the probability at a point. Even though the
nth orbit = En, radius of nth orbit = rn, Atomic
probability density of finding the electron at a
number = Z, Orbit number = n:
point near the nucleus is high, the volume of any
spherical shell there is small. Therefore, the
Question No. 20 to 22 (3 questions) probability of finding the electron within a shell is
In 1926 Erwin Schrodinger, guided by de Broglie's greater at some distance from the nucleus.
work, devised a theory that could be used to find
the wave properties of electrons in atoms and
molecules. The branch of physics that
mathematically describes the wave properties of
submicroscopic particles is called quantum
mechanics or wave mechanics.
Quantum mechanics does not allow us to describe
the electron in the hydrogen atom as moving in an 20. Select the correct order of initials T(True) or (F)
orbit. What it allows us to do is make statistical False for following statements.
statements about where the electron is in the atom. (I) R(r) v/s r curve for 3s intersect x -axis at 2
For example, we can obtain the probability of points other than infinity.
finding an electron at a certain point in a hydrogen (II) The distance of maximum probability for 3s is
atom. Although we cannot say that an electron will higher than 3p.
be at a particular position at a given time, we can (III) Radial probability density of electron
say that the electron is likely (or not likely) to be belonging to 2s is zero at nucleus.
at this position. (IV) Outside any orbital probability of finding an
Information about a particle in a given energy electron is exactly zero.
level (such as an electron in an atom) is contained (A) FTFT (B) TTTF
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(C) TTFF (D) TFTF 24. Write the number of correct statements among the
following.
21. The distance of spherical nodes for '3s' orbital 1. Orbit angular momentum quantised.
from nucleus is 2. Energy of photon remains quantised.
 3. Charge remains quantised.
( )
1 − 2r
R 3s = 3/2
6 − 6 +  2
e 2
where = 4. Number of photons must remains conserved.
9 3a 0 na 0
5. Isodiaphers have same isotopic number.
(A) zero, infinity 7. Photocurrent increase when intensity of
(B) 14a 0 , 4a 0 incident light increases provided (ν ≥ ν0),
9+3 3 9−3 3 where ν threshold frequency.
(C) a0 , a0 8. Photocurrent increase when intensity of
2 2
(D) None of these incident light increases provided (λ ≥ λ0),
where ν threshold frequency.
9. Velocity of photo electron increase when
1  6r r 2  − r/3a0
22. The radial part R(r) =  − 2 e intensity of light increase.
9 6a 3/2
0  0
a a0 
10. Photo current increase when frequency of
represent which orbital incident light increases.
(A) 3s (B) 3d 11. Stopping potential of photo electron increase
(C) 3p (D) 2s when frequency of incident light increase.
12. Kinetic energy of photo electron increase
23. Find the wavelength of the first line of He+ ion when wave length of incident light increases.
spectral series whose interval between extreme 13. Collision of photon is perfectly elastic.
1 1  14. Time lag of photon is zero.
− = 2.7451 104 cm−1 
line is    15. All electromagnetic radiation move with the
 1 2 
speed of light.
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ANSWER KEY
1. (A,D)
2. (A,C)
3. (B,C,D)
4. (A,B,D)
5. (A,B,C,D)
6. (A,B,C,D)
7. (A,B,C,D)
8. (A,B)
9. (A,B,C)
10. (B)
11. (D)
12. (C)
13. (B,C)
14. (D)
15. (B,C,D)
16. (B,C,D)
17. (A,B,C,D)
18. (A→S) (B→R) (C→Q) (D→P)
19. (A→Q) (B→P) (C→Q,R) (D→R,S)
20. (C)
21. (C)
22. (C)
23. (4689 Å)
24. (9)