Conforms to Regulation (EC) No.

1907/2006 (REACH), Annex II - Spain

SAFETY DATA SHEET

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Product name Energol GR-XP 460
Product code 401716-ES01
SDS no. 401716
Product type Liquid.

1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/ Gear lubricant .
mixture For specific application advice see appropriate Technical Data Sheet or consult our company
representative.

1.3 Details of the supplier of the safety data sheet

Supplier BP Oil España, SA
Avenida de Barajas 30,
Parque Empresarial Omega - Edificio D,
Alcobendas,
Madrid, 28108
España

Teléfono +34 902 107 001

Fax +34 902 107 002
E-mail address [email protected]

1.4 Emergency telephone number

EMERGENCY Carechem: +44 (0) 1235 239 670 (24/7)
TELEPHONE NUMBER

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Product definition Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Not classified.
Classification according to Directive 1999/45/EC [DPD]
The product is not classified as dangerous according to Directive 1999/45/EC and its amendments.
See sections 11 and 12 for more detailed information on health effects and symptoms and environmental hazards.

2.2 Label elements

Signal word No signal word.
Hazard statements No known significant effects or critical hazards.
Precautionary statements
Prevention Not applicable.
Response Not applicable.
Storage Not applicable.
Disposal Not applicable.

Supplemental label Contains Amines, C12-14-tert-alkyl. May produce an allergic reaction. Safety data sheet
elements available on request.
Special packaging requirements
Containers to be fitted Not applicable.
with child-resistant
fastenings
Tactile warning of danger Not applicable.
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SECTION 2: Hazards identification

2.3 Other hazards

Other hazards which do Defatting to the skin.
not result in classification

SECTION 3: Composition/information on ingredients

Substance/mixture Mixture
Highly refined base oil (IP 346 DMSO extract < 3%). Proprietary performance additives.
Classification
Product/ingredient Identifiers % 67/548/EEC Regulation (EC) No. Type
name 1272/2008 [CLP]

Base oil - unspecified Varies - See Key to ≥90 Not classified. Not classified. [2]
abbreviations

Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
Occupational exposure limits, if available, are listed in Section 8.

SECTION 4: First aid measures

4.1 Description of first aid measures
Eye contact In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Eyelids
should be held away from the eyeball to ensure thorough rinsing. Check for and remove any
contact lenses. Get medical attention.
Skin contact Wash skin thoroughly with soap and water or use recognised skin cleanser. Remove
contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before
reuse. Get medical attention if irritation develops.
Inhalation If inhaled, remove to fresh air. Get medical attention if symptoms appear.
Ingestion Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if
symptoms occur.
Protection of first-aiders No action shall be taken involving any personal risk or without suitable training.

4.2 Most important symptoms and effects, both acute and delayed
See Section 11 for more detailed information on health effects and symptoms.

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treatment should in general be symptomatic and directed to relieving any effects.

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing In case of fire, use foam, dry chemical or carbon dioxide extinguisher or spray.
media
Unsuitable extinguishing Do not use water jet.
media

5.2 Special hazards arising from the substance or mixture

Hazards from the In a fire or if heated, a pressure increase will occur and the container may burst.
substance or mixture
Hazardous combustion Combustion products may include the following:
products carbon oxides (CO, CO2) (carbon monoxide, carbon dioxide)

5.3 Advice for firefighters

Special precautions for Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a
fire-fighters fire. No action shall be taken involving any personal risk or without suitable training.

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SECTION 5: Firefighting measures
Special protective Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-
fighters (including helmets, protective boots and gloves) conforming to European standard EN
469 will provide a basic level of protection for chemical incidents.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency No action shall be taken involving any personal risk or without suitable training. Evacuate
personnel surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch
or walk through spilt material. Floors may be slippery; use care to avoid falling. Put on
appropriate personal protective equipment.
For emergency responders If specialised clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

6.2 Environmental Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
precautions Inform the relevant authorities if the product has caused environmental pollution (sewers,
waterways, soil or air).

6.3 Methods and material for containment and cleaning up

Small spill Stop leak if without risk. Move containers from spill area. Absorb with an inert material and
place in an appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.
Large spill Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water
courses, basements or confined areas. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container
for disposal according to local regulations. Dispose of via a licensed waste disposal contractor.

6.4 Reference to other See Section 1 for emergency contact information.

sections See Section 5 for firefighting measures.
See Section 8 for information on appropriate personal protective equipment.
See Section 12 for environmental precautions.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Protective measures Put on appropriate personal protective equipment.
Advice on general Eating, drinking and smoking should be prohibited in areas where this material is handled,
occupational hygiene stored and processed. Wash thoroughly after handling. Remove contaminated clothing and
protective equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.

7.2 Conditions for safe Store in accordance with local regulations. Store in a dry, cool and well-ventilated area, away
storage, including any from incompatible materials (see Section 10). Keep away from heat and direct sunlight. Keep
incompatibilities container tightly closed and sealed until ready for use. Containers that have been opened must
be carefully resealed and kept upright to prevent leakage. Store and use only in equipment/
containers designed for use with this product. Do not store in unlabelled containers.
Not suitable Prolonged exposure to elevated temperature.

7.3 Specific end use(s)

Recommendations See section 1.2 and Exposure scenarios in annex, if applicable.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
Occupational exposure limits
Product/ingredient name Exposure limit values
Base oil - unspecified INSHT (Spain). Absorbed through skin.
STEL: 10 mg/m³ 15 minutes. Issued/Revised: 1/2008 Form: mist
TWA: 5 mg/m³ 8 hours. Issued/Revised: 1/2008 Form: mist
Whilst specific OELs for certain components may be shown in this section, other components may be present in any mist,
vapour or dust produced. Therefore, the specific OELs may not be applicable to the product as a whole and are provided for
guidance only.

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SECTION 8: Exposure controls/personal protection
Recommended monitoring If this product contains ingredients with exposure limits, personal, workplace atmosphere or
procedures biological monitoring may be required to determine the effectiveness of the ventilation or other
control measures and/or the necessity to use respiratory protective equipment. Reference
should be made to monitoring standards, such as the following: European Standard EN 689
(Workplace atmospheres - Guidance for the assessment of exposure by inhalation to chemical
agents for comparison with limit values and measurement strategy) European Standard EN
14042 (Workplace atmospheres - Guide for the application and use of procedures for the
assessment of exposure to chemical and biological agents) European Standard EN 482
(Workplace atmospheres - General requirements for the performance of procedures for the
measurement of chemical agents) Reference to national guidance documents for methods for
the determination of hazardous substances will also be required.
Derived No Effect Level
No DNELs/DMELs available.

Predicted No Effect Concentration

No PNECs available

8.2 Exposure controls

Appropriate engineering Provide exhaust ventilation or other engineering controls to keep the relevant airborne
controls concentrations below their respective occupational exposure limits.
All activities involving chemicals should be assessed for their risks to health, to ensure
exposures are adequately controlled. Personal protective equipment should only be considered
after other forms of control measures (e.g. engineering controls) have been suitably evaluated.
Personal protective equipment should conform to appropriate standards, be suitable for use, be
kept in good condition and properly maintained.
Your supplier of personal protective equipment should be consulted for advice on selection and
appropriate standards. For further information contact your national organisation for standards.
The final choice of protective equipment will depend upon a risk assessment. It is important to
ensure that all items of personal protective equipment are compatible.
Individual protection measures
Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating,
smoking and using the lavatory and at the end of the working period. Ensure that eyewash
stations and safety showers are close to the workstation location.
Respiratory protection Respiratory protective equipment is not normally required where there is adequate natural or
local exhaust ventilation to control exposure.
In case of insufficient ventilation, wear suitable respiratory equipment.
The correct choice of respiratory protection depends upon the chemicals being handled, the
conditions of work and use, and the condition of the respiratory equipment. Safety procedures
should be developed for each intended application. Respiratory protection equipment should
therefore be chosen in consultation with the supplier/manufacturer and with a full assessment
of the working conditions.
Eye/face protection Safety glasses with side shields.
Skin protection
Hand protection General Information:

Because specific work environments and material handling practices vary, safety procedures
should be developed for each intended application. The correct choice of protective gloves
depends upon the chemicals being handled, and the conditions of work and use. Most gloves
provide protection for only a limited time before they must be discarded and replaced (even the
best chemically resistant gloves will break down after repeated chemical exposures).

Gloves should be chosen in consultation with the supplier / manufacturer and taking account of
a full assessment of the working conditions.

Recommended: Nitrile gloves.

Breakthrough time:

Breakthrough time data are generated by glove manufacturers under laboratory test conditions
and represent how long a glove can be expected to provide effective permeation resistance. It
is important when following breakthrough time recommendations that actual workplace
conditions are taken into account. Always consult with your glove supplier for up-to-date
technical information on breakthrough times for the recommended glove type.
Our recommendations on the selection of gloves are as follows:

Continuous contact:

Gloves with a minimum breakthrough time of 240 minutes, or >480 minutes if suitable gloves
can be obtained.
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SECTION 8: Exposure controls/personal protection
If suitable gloves are not available to offer that level of protection, gloves with shorter
breakthrough times may be acceptable as long as appropriate glove maintenance and
replacement regimes are determined and adhered to.

Short-term / splash protection:

Recommended breakthrough times as above.

It is recognised that for short-term, transient exposures, gloves with shorter breakthrough times
may commonly be used. Therefore, appropriate maintenance and replacement regimes must
be determined and rigorously followed.

Glove Thickness:

For general applications, we recommend gloves with a thickness typically greater than 0.35 mm.

It should be emphasised that glove thickness is not necessarily a good predictor of glove
resistance to a specific chemical, as the permeation efficiency of the glove will be dependent
on the exact composition of the glove material. Therefore, glove selection should also be based
on consideration of the task requirements and knowledge of breakthrough times.
Glove thickness may also vary depending on the glove manufacturer, the glove type and the
glove model. Therefore, the manufacturers’ technical data should always be taken into account
to ensure selection of the most appropriate glove for the task.

Note: Depending on the activity being conducted, gloves of varying thickness may be required
for specific tasks. For example:

• Thinner gloves (down to 0.1 mm or less) may be required where a high degree of manual
dexterity is needed. However, these gloves are only likely to give short duration protection and
would normally be just for single use applications, then disposed of.

• Thicker gloves (up to 3 mm or more) may be required where there is a mechanical (as well
as a chemical) risk i.e. where there is abrasion or puncture potential.

Skin and body Use of protective clothing is good industrial practice.

Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before handling this
product.
Cotton or polyester/cotton overalls will only provide protection against light superficial
contamination that will not soak through to the skin. Overalls should be laundered on a regular
basis. When the risk of skin exposure is high (e.g. when cleaning up spillages or if there is a
risk of splashing) then chemical resistant aprons and/or impervious chemical suits and boots
will be required.
Refer to standards: Respiratory protection: EN 529
Gloves: EN 420, EN 374
Eye protection: EN 166
Environmental exposure Emissions from ventilation or work process equipment should be checked to ensure they
controls comply with the requirements of environmental protection legislation. In some cases, fume
scrubbers, filters or engineering modifications to the process equipment will be necessary to
reduce emissions to acceptable levels.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Appearance
Physical state Liquid.
Colour Brown. [Dark]
Odour Not available.
Odour threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boiling Not available.
range
Pour point -12 °C
Flash point Closed cup: 226°C (438.8°F) [Pensky-Martens.]
Evaporation rate Not available.
Flammability (solid, gas) Not available.

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SECTION 9: Physical and chemical properties
Upper/lower flammability or Not available.
explosive limits
Vapour pressure Not available.
Vapour density Not available.
Relative density Not available.
Density <1000 kg/m³ (<1 g/cm³) at 15°C
Solubility(ies) insoluble in water.
Partition coefficient: n-octanol/ Not available.
water
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Kinematic: 460 mm2/s (460 cSt) at 40°C
Kinematic: 30.5 mm2/s (30.5 cSt) at 100°C
Explosive properties Not available.
Oxidising properties Not available.

9.2 Other information

No additional information.

SECTION 10: Stability and reactivity

10.1 Reactivity No specific test data available for this product. Refer to Conditions to avoid and Incompatible
materials for additional information.

10.2 Chemical stability The product is stable.

10.3 Possibility of Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions Under normal conditions of storage and use, hazardous polymerisation will not occur.

10.4 Conditions to avoid Avoid all possible sources of ignition (spark or flame).

10.5 Incompatible materials Reactive or incompatible with the following materials: oxidising materials.

10.6 Hazardous Under normal conditions of storage and use, hazardous decomposition products should not be
decomposition products produced.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity estimates
Route ATE value
Not available.
Information on the likely Routes of entry anticipated: Dermal, Inhalation.
routes of exposure
Potential acute health effects
Inhalation Vapour inhalation under ambient conditions is not normally a problem due to low vapour
pressure.
Ingestion No known significant effects or critical hazards.
Skin contact Defatting to the skin. May cause skin dryness and irritation.
Eye contact No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Inhalation May be harmful by inhalation if exposure to vapour, mists or fumes resulting from thermal
decomposition products occurs.
Ingestion No specific data.
Skin contact Adverse symptoms may include the following:
irritation
dryness
cracking
Eye contact No specific data.

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SECTION 11: Toxicological information
Delayed and immediate effects and also chronic effects from short and long term exposure
Inhalation Overexposure to the inhalation of airborne droplets or aerosols may cause irritation of the
respiratory tract.
Ingestion Ingestion of large quantities may cause nausea and diarrhoea.
Skin contact Prolonged or repeated contact can defat the skin and lead to irritation and/or dermatitis.
Eye contact Potential risk of transient stinging or redness if accidental eye contact occurs.
Potential chronic health effects
General No known significant effects or critical hazards.
Carcinogenicity No known significant effects or critical hazards.
Mutagenicity No known significant effects or critical hazards.
Developmental effects No known significant effects or critical hazards.
Fertility effects No known significant effects or critical hazards.

SECTION 12: Ecological information

12.1 Toxicity
Environmental hazards Not classified as dangerous

12.2 Persistence and degradability

Expected to be biodegradable.

12.3 Bioaccumulative potential

This product is not expected to bioaccumulate through food chains in the environment.

12.4 Mobility in soil

Soil/water partition Not available.
coefficient (KOC)
Mobility Spillages may penetrate the soil causing ground water contamination.

12.5 Results of PBT and vPvB assessment

PBT Not applicable.
vPvB Not applicable.

12.6 Other adverse effects

Other ecological information Spills may form a film on water surfaces causing physical damage to organisms. Oxygen
transfer could also be impaired.

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product
Methods of disposal Where possible, arrange for product to be recycled. Dispose of via an authorised person/
licensed waste disposal contractor in accordance with local regulations.
Hazardous waste Yes.
European waste catalogue (EWC)
Waste code Waste designation
13 02 05* mineral-based non-chlorinated engine, gear and lubricating oils

However, deviation from the intended use and/or the presence of any potential contaminants may require an alternative waste
disposal code to be assigned by the end user.
Packaging
Methods of disposal Where possible, arrange for product to be recycled. Dispose of via an authorised person/
licensed waste disposal contractor in accordance with local regulations.
Waste code European waste catalogue (EWC)
15 01 10* packaging containing residues of or contaminated by dangerous substances
Special precautions This material and its container must be disposed of in a safe way. Empty containers or liners
may retain some product residues. Avoid dispersal of spilt material and runoff and contact with
soil, waterways, drains and sewers.

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SECTION 14: Transport information

ADR/RID ADN IMDG IATA
14.1 UN number Not regulated. Not regulated. Not regulated. Not regulated.

14.2 UN proper - - - -
shipping name
14.3 Transport - - - -
hazard class(es)

14.4 Packing - - - -
group
14.5 No. No. No. No.
Environmental
hazards
Additional - - - -
information

14.6 Special precautions for Not available.

user

14.7 Transport in bulk Not available.

according to Annex II of
MARPOL 73/78 and the IBC
Code

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorisation
Substances of very high concern
None of the components are listed.
Annex XVII - Restrictions Not applicable.
on the manufacture,
placing on the market
and use of certain
dangerous substances,
mixtures and articles
Other regulations
REACH Status The company, as identified in Section 1, sells this product in the EU in compliance with the
current requirements of REACH.
United States inventory All components are listed or exempted.
(TSCA 8b)
Australia inventory (AICS) All components are listed or exempted.
Canada inventory All components are listed or exempted.
China inventory (IECSC) All components are listed or exempted.
Japan inventory (ENCS) All components are listed or exempted.
Korea inventory (KECI) All components are listed or exempted.
Philippines inventory All components are listed or exempted.
(PICCS)
Taiwan inventory (CSNN) All components are listed or exempted.

15.2 Chemical Safety This product contains substances for which Chemical Safety Assessments are still required.
Assessment

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SECTION 16: Other information

Abbreviations and acronyms ADN = European Provisions concerning the International Carriage of Dangerous Goods by
Inland Waterway
ADR = The European Agreement concerning the International Carriage of Dangerous Goods by
Road
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
CAS = Chemical Abstracts Service
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]
CSA = Chemical Safety Assessment
CSR = Chemical Safety Report
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
DPD = Dangerous Preparations Directive [1999/45/EC]
DSD = Dangerous Substances Directive [67/548/EEC]
EINECS = European Inventory of Existing Commercial chemical Substances
ES = Exposure Scenario
EUH statement = CLP-specific Hazard statement
EWC = European Waste Catalogue
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as
modified by the Protocol of 1978. ("Marpol" = marine pollution)
OECD = Organisation for Economic Co-operation and Development
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
RID = The Regulations concerning the International Carriage of Dangerous Goods by Rail
RRN = REACH Registration Number
SADT = Self-Accelerating Decomposition Temperature
SVHC = Substances of Very High Concern
STOT-RE = Specific Target Organ Toxicity - Repeated Exposure
STOT-SE = Specific Target Organ Toxicity - Single Exposure
TWA = Time weighted average
UN = United Nations
UVCB = Complex hydrocarbon substance
VOC = Volatile Organic Compound
vPvB = Very Persistent and Very Bioaccumulative
Varies = may contain one or more of the following 101316-69-2 / RRN 01-2119486948-13,
101316-70-5, 101316-71-6, 101316-72-7 / RRN 01-2119489969-06, 64741-88-4 / RRN
01-2119488706-23, 64741-89-5 / RRN 01-2119487067-30, 64741-95-3 / RRN
01-2119487081-40, 64741-96-4/ RRN 01-2119483621-38, 64741-97-5 / RRN
01-2119480374-36, 64742-01-4 / RRN 01-2119488707-21, 64742-44-5 / RRN
01-2119985177-24, 64742-45-6, 64742-52-5 / RRN 01-2119467170-45, 64742-53-6 / RRN
01-2119480375-34, 64742-54-7 / RRN 01-2119484627-25, 64742-55-8 / RRN
01-2119487077-29, 64742-56-9 / RRN 01-2119480132-48, 64742-57-0 / RRN
01-2119489287-22, 64742-58-1, 64742-62-7 / RRN 01-2119480472-38, 64742-63-8,
64742-64-9, 64742-65-0 / RRN 01-2119471299-27, 64742-70-7 / RRN 01-2119487080-42,
72623-85-9 / RRN 01-2119555262-43, 72623-86-0 / RRN 01-2119474878-16, 72623-87-1 /
RRN 01-2119474889-13, 74869-22-0 / RRN 01-2119495601-36, 90669-74-2 / RRN
01-2119970171-43
Full text of abbreviated H Not applicable.
statements
Full text of classifications Not applicable.
[CLP/GHS]
Full text of abbreviated R Not applicable.
phrases
Full text of classifications Not applicable.
[DSD/DPD]
History
Date of issue/ Date of 29/01/2016.
revision
Date of previous issue 02/12/2014.
Prepared by Product Stewardship
Indicates information that has changed from previously issued version.
Notice to reader

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SECTION 16: Other information
All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information
contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information in this data sheet.

The data and advice given apply when the product is sold for the stated application or applications. You should not use the
product other than for the stated application or applications without seeking advice from BP Group.

It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. The BP
Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material,
from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the
product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or
using the product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be
affected of any hazards described in this sheet and of any precautions that should be taken. You can contact the BP Group to
ensure that this document is the most current available. Alteration of this document is strictly prohibited.

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