Structure of Atom

I
and wavelength of l 000 nm. 10 0 I second 1s r I() The
~ Atomic Models_and Dual Nature of value ofx 1s (Nearest integer)
~~ Electromagnetic Radiation (/1 == 6.63 X l O }-1 .Is. ( 3 00 lo~ms I)
I"'\ \ug.27 2021 ir
I. lfth<.'
, ,,a,l.'kngth
10 for an electron emitted from II-at
, om 1s
8. A metal surface is exposed to 500 nm radiation The
' ' IO m. then energy ab~orbed by the electron 111 its
threshold frequency of the metal for photoelectric current
ground state compared to mmimum energy rcqu1rcd for its
is 4 3 x \0 14 Hz The velocity of ejected electron 1s
escape from the atom. 1s _ _ _ l11ncs. (Nearest integer)
I'"
.Jul II 112 ( I)
IO' ms 1(Nearest integer)
1
[Use: h-6.63 x 10 ',.j Js. 111 0 ==9.0 \0 ' kg]
34 )<
[Gm::n: h 6.626 x 10 Js] !N\, A.u2. 26, 2021 II)\
31
Massofcleclron - 9.1 x 10 kg
9. If the Thomson model of the atom was correct. then the
2. Consider an imaginary ion gx 3 • The nucleus contains result of Rutherford's gold foil experiment would have
·a'% more neutrons than the number of electrons in the been: [Juh 27, .!021 {ll)\
ion The ,·alue of 'a' is __. [nearest integer] (a) All of the a-particles pass through the gold foil
I '\ .J Jh h. 2022 (11)1 without decrease in speed.
3. lfthe ,,ork function ofa metal is 6.63 x 10 19 J, the maximum (b) a-Particles are deflected over a wide range of angles.
waYelength ofthe photon required to remove a photoelectron (c) All a-particles get bounced back by I 80°.
from the metal is _ _ _ mn. (Nearest integer) (d) a-Particles pass through the gold foil deflected by
1
[Gi,·cn : h = 6.63 x IO 34 J s. and c = 3 x I 08 ms ] small angles and with reduced speed.
11' V, .J unc 28, 2022 (I) I 10. A source of monochromatic radiation of wavelength -lOO
4. Hydrogen has three isotopes : protium (1H), deuterium nm provides 1000 J of energy in 10 seconds When this
0
{21-f or D) and tritium (3H or T). They have nearly same radiation falls on the surface of sodium. x , I 0" electron5
chemical properties but different physical properties. They are ejected per second. Assume that wavelength -WO nm 1s
differ in I nc. B. 2022 (II)) sufficient for ejection ofelectron from the surface ofsod mm
(a) number of protons metal. The value ofx is _ _ _ . (1'.earest integer)
(b) atomic number (h == 6.626 >< l O :;.. Js) , ,
(c) electronic configuration 11. Which of the following forms ofhydrogcn emits lo,, cner~
(d) atomic mass ~ particles? _
5. The minimum energy that must be possessed by photons
in order to produce the photoelectric effect with platinum
(a) Proton W (b) Tntium H f
metal is: (c) Protium \ H (d) Deuterium H f
[Given: The threshold frequency of platinum is Electromagnetic radiation of \\a,e\ength 663 nm 1s _1ust
12
1Jx 10 15 s 1 andh 6.6x 10 34 Js.] J 1 2 ,2022(111
16
sufficient to ionise the atom of metal .\ . The 10111z:.1tton
14
(a) 3.21x10 1 (b) 6.24 x 10 J energy of metal A in kJ mo\ 1 is tRoun,kd-1..)ff k) the
19 20
(CJ 8.58 X JO J (<l) 9.76 X ]0 ] nearest integer)
6. A )0 watt bulb emits monochromatic red light ofwavelength [h 6.63 x 10 34 Js, c 3.00 ' 10' ms I.\, 6.02,
of795 nm. I he number of photons emitted per second by 1021 mo\ I] l' '~.2021(\l)\
19
th c bulb is \ I 010 The value or\ IS 13. The \\Ork function of sodium mct,1\ 1-, -i -H , 10 J. \f
1
[ (iJ\'CI\ : /, ().()1 X I() 14
3.0 X I08 ms ]
Js and(' photons of \\'a,e\cngth 100 nm arc 11\Cllknt on the metal,
. [~\ Sl'Jl I '07.1 (11)1 the kinetic encrg~ of the e_1ectcd e\cctrnns ,, 11\ be
7. I l_1c nu1'.1bt.:r ol photons t.:rni ttcd by a monochromatic (Ii 661 10 \1.ls,l 3,\l)'m-,) x \Q2lj_
(singk lrcqucncy) mfran.:d rangc lindc1 or power I mW 1
\\. Sep. 02, 2020 (ll)\
 CH EM IST RY
A- 8 as
cnt s. On e is lab ell ed
Gi ven bel ow arc two sla tcm R.
If I . fa5te<;t dec rro n CJe
cled fro m a 21 oth er 1s lab ell ed as Rl' aso n
14. P Ule mo m en rum of the \ \Sl 'rti on , \ and the en ato m i,
of lig ht ha \·in g
at1 0n erg y of 2s orb ita l of hyd rog
me ta i.rt ac. : aft er the 1rr ad1 ,\,\ ert ion t\ : En
mo me ntu m of the tal ofl ith ium .
ele gth 1. the n for
I "P gre ate r tha n tha tof 2so rbi orb ita ls rn the sam e sub shc ll
of the l1e ht sho uld be. En erg ies of the
«x- tro n the n,n elc ne th Rea <;o n R:
ctc d ph ;,o de ctr on to he in the ato mi c num ber .
e lm eu c encr='} ot- cre dec rea se wit h inc rea se the cor rec t
\,o rk fun ctio n): In the lig ht of the abo
ve sta tem ent s, cho ose
en h gb tn c mp ans on IO / \pr il R. 20 I 9 <I I)/ giv en bel ow .
ans we r fro m the op tio ns J.July 27 , 202 2 0)1
., .:J.
I. t exp lan atio n
l
(c) 1. (di 9
1-
(a) Bo th A and Ra re
tru e and R is the cor rec
a ;1 <b) -:;' · 3
lig ht of
on of the me tal 1f the ofA e bu t R is NO T the
cor rec t
I '- \\ hat ,., the "or !. ;un c.:1 we lec 1ro ns of vel oci ty (b) Bo th A an d R are tru
era ;e, pbo
n \ e m~ ill .:.ooo A ~en /Ja n.1 2.2 01 9(1 )}
exp lan ati on of A.
6,J O' m; .5-orrn,? - is fal se.
• kg (c) A 1s tru e but R
\fa -- of ele c,r on= 9,. iO but R is tru e.
if' m' (d) A is fal se
l1!!ht - 3 ,. 1 n 5 dro ps to
~- elo cm of
JO "J, V/h en the exc ite d ele ctr on ofa H ato m fro m
PL md /, con ::a nr- 6.6 :6x 19 22 . xim um nu mb er of em iss ion lines
ron =J 6>< !0 Je \ ' ) the gro un d sta te. the ma
Ch a..z eof cle t..t
(c) 2.1 e\' (dJ -1.0 eV · I'\ , .July 25 , 202 2 (IJ)I
a) 0-9 e\ (bl 3 I e\'
nt wa s pas sed obs erv ed are - - - - gen ato m is r 3
fro m a hea red fila me Bo hr' s orb it of hy dro
16. <\ s.rea.m ofe le: :ro n, por en1 ial dif fer enc e Jft he rad ius of the 3rd
tes ke pt a, a 23. hr' s orb it 1s r 4 .
be t"e en n\o ch arg ed pla
th
an ele ctr on. an d the rad ius of 4 Bo
l'h Jlt !; 'c' an d ma re cha rge an d ma ss of J.Junc 26 , 20 22 fl)!
\·el eng th
ue of h ;_ f•. her e;_ is wa Th en :
res pe an el_\. the n ;be val f2016J 16
,, ave ) is g.' en b_\: (b) 14 = r
~O C'l a,e d wit h ele crr on 9 9
(c) •ne V (d) 2m eV (a) ''.i = 16/j
(a , ~ (b) v ~
d wa vel eng th of 4
esh old wm ele ngc h an
1 - . If; a-.., -_ he ;hr cte d fro m 3 (d) ''.i = 3r1
ryo fpl >o '. e'e ctr on eje (c) I".; = 41"3
rnCTder:.· gt . ;.he \el ocf 41
fO nH ne Ap ril 11 , 101 be use d for
I.h em e;.. ~'1 ace is: gth of lig ht tha t can
24 . Th e lon ges t wa \·e len d sta te is
ato m (Li ) in its gro un
. ) -:?. he(. . ) the ion isa tio n of lith ium esl Integer)
:_h (. (b) ' / - m 1.0 -I. 1s _ _ _ _ _ . ("l ear
fa1 \-- ;;; 10 -1 . x >< IO 8 m. Th e , ·alu c ofx she ll of the
ele ctr on in the firs t
12.h I 1 (G ive n : En erg y of the 3
18 J: h - 6.6 3 ~ IO -t Js and
2h c ';.0 -;_ / __ - . -: -, gen ato m is 2.2 x JO
(d) hy dro
\ m I.O I. 8 1 ll'i 11 .:.s, 2022 (l)J
(c) \ m i.i. 0
c =- 3 x I 0 ms ) d Bo hr orbit
ak on e mo le ofCl Cl bo nd
s in ele ctr on in the sec on
Th e en ~;y req uir ed lO bre e 25 . Th e kin eti c en erg y of an
18. ofl igh t cap abl
1 lon ges t wa \ elength
Cl rs 2.!.2 kl mo I • Th e 1/-
ofb rea kin ~ a 5in gle CI
Cl bo nd ir; l to ~ · Th1.: va lue or IOx is
flO IO J of a hy dro ge n ato m is eq ua .,nwo
(t. =3 ; 10 rru an d\'
~ -6 .02 "l< r-' mo l J.
)
(c) -oo nm (d) -194nm
_. (au is rad ius of Bo
hr' s orb it) ('\.c<1rcst integer
(a) 59 ~n m (b) ~n m sociatcd v,ith
Calculare the \UH elength
(in na no me ter ) ar; , \, ,ug . 7- 2021 (1)1
JCJ. n I 67 [G i\,e n: rr 3.I 4J
a pro ton mO \m g at LO
" JO ms . (M as' >o fpr oto sta tcm cn ts.
f20 09 f 26 . Gn en bd ow an.: tw o atom,
JO ··-k ga nd /z 6.6 3 x IO
l4Jc;J to Ho hr' s mo de l of an
m Sta tem en t I = Ac co rdi ng
(c) l~. On m (d) 03 2n ve loc ity of ele ctr on increa
ses
(aJ OAOnm Cb) 2.5 nm tat ive ly the ma gn itu de of
qu ali as there
ch arg es on the nu clc u-;
r Hy dr og en At om \1,irh de cre ase m po :-i ti\e
~ Bo h_r·s_Mode/ fo so rp tio n Sp ec tra ) ele ctr on by the nu cle us.
Ab is no str on g ho ld on the
~ (Em 1s s1 on an d lo, , ing . ng to Bo hr 's mo de l of
an atom.
:,1dtemeat fro m the fol Sta tem en t II : Ac co rdi increa ses
20. ldenr,f) rL , ..L_;-_ =t de of \'C loc itv of clc ctr on
(Jul) 28. 20 22 (1)1 qu ali tat l\e ]y the ma gn itu
l qu an tum ;um be r.
d the nu de th in ,,h ich
an wi th dec rca -,c in pri nc ipa
<a. A cu-cular pa rh aro un e sta tem ent <,. ch oo se the
mo st
a, Bohr·.., orbii. In the lig ht of the ab ov
..?l~·ctron mO\ e, "p ro po ,ed ( y) in an m the op tio ns givt.:n be
low
electron \\J H' fun cti on ap pro pri ate an sw er fro
lbJ An a~bn<1l i... the on e / '\u g. 26 , 2021 (1)1
mo m
fab1.:
(()
Th e t'\J Slt 'nc e of Bo hr
·, orb ir-., , ~. . ,up po ne d by (a) Bo th Sta tem en
t I an d Sta tem en t JI arc
d C:,tatement fl arc tru e
h _,drogen ,pe dru m lbJ Bo th Sta tem en t I an
4to m1 ,· orbm1J i , .:h
arn crc ri,, ed b \ rht? qu am um bu t Sta tem en t /I 1<; tru l!
(di
le) Sta tem en t l 1~ fal-..e se
nu mb er, n Jn d / on h (d) Sta tem en t Ii~ tru
e bu t St ate me nt lI is fal
 A-9

-'~- I 111 ,lit\ gn l'll 'l't ll'' 11t ,pcclr 11 lmc~ llf 11011111; h) lro en
kt \, 1, ,"
1
, n Ix· the cl1ffcrcncc 111 111,1x1mum ind
111111111111111 lh'\Jt1c'n,-1L-s 111 cm I fill' r.1110 \ , , \ y "
1
I \prtl 9, 2019(1)1
(,t) ..J I (b) l) --l (t') 5 ..J (d) 27 'i
J:-. \\ h1d1 nnc t1f1hc ti.,llt'\' Ill!! .1bl.1u1 ,111 dt."c'trnn occupYmg
thl' I, t,rb11.tl 111 .1 ll\ dn,!!t'I; ,ltt'lll 1, 1111.Prrc,t 1 ( l he Bohr
L1 1.1d1th 1s rl·prc~cnt~d b\- ,1 ) I \pril IJ•.ZOJII (11)1
. •nc\ ofreH1lut it1n t1 l'i.:!1Xll\ 111 in ,lll t,rb11 1~ x (.1) rhc pn1b,1bd1t~ dcns1t, t,f lind1ng thl' dc,tn,n ,,
(() I rcc]l1c • 11
ll1,l\llllll111 ,ll the llt1Cict1,
z·' (b) l he ckl' lr11n e,111 bt' ti.,und ,ll .1 dist.rncc 2a0 fr1,m the:
tD) (oulomhic force ofattractitm 011 1hcclcctrt,11 ts ..,_ ,,~ • nueku~
(l') flw m,1g111111de t,f1he pt1tc1111.1l encrg\ 1~ dt,ubk th,11
Choose the most appropriate ans,, cr from the options or Its k111Clll' encrg~ 11n ,111 ,1\ Cf,11,!t'
(d) The tt11,il cnerg~ ofthcelcl'lrl'll 1~ m,1,1mut11 ,, hen 11 t~
crt\ en bdo,, · al ,1 d1st,111ce a 0 th,m the nudeu~ _
C
(a) (C)only (b) (. \ )onl) 36. J lc.1t trcatmcnl 1,r ll1lhCtd,1r p.1111 Ill\ tlh c, r.1d1;1111111 t)t

(c) (A),(C)and(D)only (d) ( \ )and(D)onl) \\il\ clcng th t1L1b11ut l)l)O nm. \\ h1ch spectr.1 I line' t f ll-
1

The ditlcrencc between the radii or 3ni and --l'" orb11s of ,110111 1::. sn11,1blc for tlm- purpo~c ., i.J:111 11. '.!OJ 1) ( l)j
28, I tl1 [R I, IO' cm _t, 6.b ' 10 :-1_1--. , 3 " IO'ms ]
Li' is ~R . The difference bct\wcn the radii of3n and ..i 11
(a) Paschcn. x _,. 3 ( b) P.1sehe11. 5 '3
orbtb ofl-lc is ~V?2. Ratio~ : ~R2 is: SL'(. 05. 2020 (l)] (c) Balmer. :c , 2 (d) L:111a11. Y ' 1
(a) 8:3 (b) 3-~ (c) 2:_3 (d) 3: 2 37. \\"hich of t he graphs sho,\ n bdt1\\ dt1es m11 rc·presenr rhc
The region in the electromagnetic spectrum \\ here the re la11onsh tp bel\\ ccn incidc11r I1gh1 and the deetn1n
29' Balmer series !111es appear is: ~n 0-t 2020 (1)] ejected from meta I surface·? I J:i n. I 0. '.! ll Pl , I) I
(a) \'isible (b) \licnma,e
(c) Infrared (d) L'ltra,iolct

I
JO. The shortest ,,·a\·elength ofH atom in the L)11rnn series is Ar
K.E ,,f
~ s
The longest\\ a, elength in the Balmer series of He is:
[Sep. 04, 202 0 (II); Similar Online, April 8. 2017] (a)
36~
(a) - '1 (b) -
5,., (e)
9t.
- -
(d) 27A1
-_- 0
5 9 5 :,
31. For the Balmer series 111 the spectrum of H atom .

,-R
- II
{~
.,
_ _!_l
., ( ·
the correct statements among
._
(I) 10 Id·
C '
,,1
,,,- 11; ,
(]\)are: I r. 08 '1020 ( I)] (b)
(1) As wa,elength decreases. the l111cs in the series 0
____.. l--'t\.'tlh.' t\l."\ ,,1 hght
converge
(fl) The integer 11 1is equal to 2
(II[) The lines oflongest wa,·e length corresponds to 112 - 3
(IV) The 10nization energy of hydrogen can be ca lculated

(c)
from \\'a\'e number of these lines
(a) (I), (III). (I\')
(l). (Il).(l\')
(b) (I). (II). ( LIi )
(d) ( U).( [11 ),( l\')
:n. The radius of the second Bohr orbll 111 terms of the Bohr
(d
Id
<'
~,r

f
()
/__
____. l·J\"\lll\.' ll\.., ,,f l1gh1

radius. a 0• in Li 2 is: IJ , n 08 2(P0 (11)1

(a) 2u_ll --1 a ~
t 1
_a 0
0 l.. l ,,1
3 (b) -9- (c) , (d) 9
33. The ratio oftl1, h J • .
fl , c s on est \\'a\ elcm?.th ot t\\'O spectrn I series
o 1)dro"cn . " . - - (d)
seric . "' spectrum ts tound to be about 9. The spectral
•(a) l\
s arc·.
I \pril 10, 2019 (11)] ()
_ _ . . lntl.'th1t, ,,1 ltg.h1
111
(c) B·. an and Pa,sc . ·hen (b) BalmcrandBrnckctl
iackett and Pfi.md (d) Paschen and Pfund
 A-10
ght in the uJtraVIO et re' Kl
Ihe ground ,tate 1.-ncrg) of hydmgcn atr,m 15 11 6 e '. 47. f xcllccl hyrlrcww a'<xn emit \ lJc:rJCY the Cflergy fa
at 2 47 / 1/J II/ V,Jlh th! rcq . Aprll 12 2014
1ont1ne
I he energy of ~cone.I cxc11cd stale ,,f Ile 10n m .. v 1~.
~mglc photor
flan 10 2019 m, '°l11rnlar20u2J
1
(/, (j{jJ / f(} '-]<;/ 2f/$(J/ J(J lj
(,1) 5-l -~ fbJ 14 le/ GJJ4 /dJ 27 2 11, J lb) · ' J
la/ 8JJ4 l / I(J ~ J Id I fi). J 11 / I IJ ( 5 , y I ..... ,
W. lurcnw; 1onlinco/a1,,m1ch\droocnfrom11 81011 11 the
" __,t; I f ' (c) Jf,4()/J(J s.;aawms1s4J., ";
e fga<,cous h' 1 1,,r /e, a
'" 1,,ni1al1<in cncrg l ~ t a ·1 1 . zr1 ..•
'bl 1rcqu..... of Jrnht
, r. -cy
plot of wa\i! numlx.-r ( ~ Jagatn5t ( • will b:: /The Rydlx.-rg
1 ..,,,.
fh1; lowest r<J,~ 1 e onlin \pn
n• sodium a torr' is fi ()22 / '(J '1101 J
con tant, R1, t~ m v.avenumb...'r unit/ Jan 9, 2019 ll)J (!, r,r,26/1? Js."- ~(bJ 4-f./ ()~'>
laJ I mcar with intercept R11 la/ ".50 / I() s (dJ : 24 / fJ ,;
15 / 10 '<; 'inc in the Balmer
(b) 1':on linear (cJ 3. fthc first em1ss1<m • . ., "!JI 31
( C) Lmear v. tth ~lope R1
49. The wa,c number o . . 1onlint \pril 2-- -
scncs off /-srcctrum is .
(d) Linearn1th ~lope R11
(f{ Rydberg consiantJ
40. Which of the following statements ,s false'!
- jOnline \pril J6,2fJISJ 5R fbJ _?_I{ (c) 6P
. I . I t J·cal field is called (a) 36 4rJ(J , ill ha\e a frequen0 of
/a) Splntmg of;,pcctra Imes ,n e cc r · , · p, Jmer sen es\,
so. Thcllm1ting line m "a (Onl n \fa\-, :!0121
Stark effect bod oes - 3 29 / IO • c;clc<; ">)
(b) hcquencyofemittccl radiation from a black Yg h
(Pydbergconstant,R, - . 3 ,9 / 10 •5
from a lower wavelength to higher wavelength as t e
(aJ 8.22/IO'~stl
IO • ., ((db)) .,.::·;6-,:10
__ s
temperature increases
(CJ Photon has momentum a: well as wa\'elength (cJ 3.65 / h itted for the tran'>iuon n ..! ton
SJ. The frequencyof!•g teml to the transnion in H atom
Rydberg constant has unit of ener~y
(d) lectric = 2 of the He J<; equa . ? 2 II R~
. . fthe photoe!ectron from metal ,n the photoe ding which of the following
41. £JCCtJOn o a I n 0.5V when correspon _ 10 (b n _3 to 11 _ 2
effect expe,-riment can be stopped by pp yifug . fthe (a) 11 - 2 to 11 -= I >
. sed The work nct1on o (dJ n - 3 to 11 • 1
0 . .
the radia1ion of25 nm JS u ronlmeApn ·1 JS 2018 (JJ/ (C)ll-41011 3 1 (f
,
metal 1s: V (d 5eV The iontzauon enthalpy ofh~drogen atom is 1.3 L I J
(a) 4eV (bJ 5.5 eV (cJ 4.5 e J .. 52· • Th ergv required to excite the electron m the
. h hvdrogen atom undergoes trans1tJOn mo1 . c en , ? • ?008
42. The electron m t e , . 6 Th. atom from II - I to II - ,., -
from higher orbitals to orbital of rad!us 211: pm. JS (a) 8.51 x IOS J mol . (b) 6.56 10: J mol
1rans1tion is associated with : /Online ~pnl 9, 20171 (c) 756x JO-~Jmol {d) 9.84/ 10 Jmol
(aJ Lyman series (bJ Balmer sen~
53. According 10 Bohr's theor), 1he angular momentum of ar
(cJ Paschen series (dJ Brackettsene~
Which of the following is the energy ofa possible excited electron in 5th orbit is 1006
43 2 15 (aJ IO h r. {b) 2.5 h n:
· state of hydrogen ? f 0 1
(aJ 3.4eV (bJ 6.8eV (c) JJ6eV (d) --6.8eV (c) 25 h n (d) 1.0 lz :t
4-t The energy ofan electron in first Bohr orblt ofl /-atom 1s 54. The wa,..clength of the radiation emmcd. \\ht:n m a
13.6 cV. The energy value ofelectron m the i!Xcited state hydrogen atom electron falls from mfinll) to stat1onai;,
of Li: is: /Online April 9, 2014; ,imllar 201 OJ state I, would be (Rydberg constant l 09- I 0~ m )
(aJ 27.2cV (bJ 30.6cV (a) 406nm (b) 192nm 20041
(cJ 30.GcV (d) 27.2cV (c) 91nm (d) 9.J/10 nm
.c;5_ In Bohr series oflmes ofh)drogt.'11 <,pectrnm, the third line
. • 18 ( I I from the red end corre,<,pond-. to \\htch one of the follo"'m~
.J'i. Hased on the i!quat10n· l\.L - 2.0 /. 10 J 2- 2 )
112 111 mtcr-orb11 j.imps ofthe electron for Bohr orbit.. rn df: atom
of hydrogen 2 JI
the v.a\ dcngth ofthe light that must be absorbed to excite
hydrogen dcctron from Jc\cl 11- ! to /e\el 11 2 v..1/1 be: (a) 5 , 2 (bJ 4 ➔ I
//, 6.625, JO 34 Js,< 3 / J(J ms J (CJ 2 ,5 ldJ ,2
)Online \pril 11 2014 ~imil, r20H
(,1/ I 325 · I() 'm
(c) 2 650 l(J m
(b/ U2~ / J(J 1 m
Id/ 5 J(J() I() 1 m
46. I l III and e arc the m:1~s and charic ofth1.: n~\ oh 111~ elemon
---
S6
I Dual Behaviour of Matter and
Heisenberg Uncertainty Principle
The mrn1mum unc rtamt) m th~ pc...c of an elce,tron in an
in th1.: orb11 of rnt!iu~ r /or hjdro;c-n mom, the IOl~I cncr!!v
lme-d1mer, onal re on ,t len !th 2.i 1\\ here a Bohr
of tht: fL'\ oh lllg ch:ctron \\1/1 be· o h 2 ~-
rat11 , "2 9 pm! 1 km,
)
'(Jl\en \IJ ofclcctr n 91 / iO k, Plan k'~conslalll
(iJJ
1 e-
(b) (CJ
mi (dJ \\JI 2
2 h 663/!0 J')J
I r 2r
 A-11
¢f fl]' B:NI
::;- L
,, ,J\ dcngth ol ,111 ckctron ,111d" neutron\\ ii I bccomc
1
Lqu h ii ,\h..:n the ,cloc1t) Pl thc electron 1s , tunes the
ln1cnsll}
\ l , 1,- l,f ncutrt,n f he \,due of, is - (''... ca rest (a) of black hod,
0... 1 (\l,1ss of electron
1 1c"cr) 1-; 9.1 10 ll kn
rad1a1ion ·
~- ;;. •aild mass o f
lt
I ,utronis 16 JO - kg) . l'\\,Juh 26,2 I Wavelength
.,fl 11
If the uncer1,1111t) 111 \ cloe1tJ ,111d position of a mmutc
pJrucle 111 ~pace :.ire. 2.--l " IO

(M 1re,t integer)
(Gl\cn:h 6.626x)OMJs) l'\,Junc27,
26

fl·,pccll\cl), fhe mass ofthc particle in g is

(ms I) ,md Io 7 (m)

(b)
Kincllc
encrg1 of
photocl~clron,
I ~/
Rb/ _
K '-a

0 f- rcqucnc} of mc1dcn1
fhc energy of one mok of photons of radiation 1· rad1auon
59. "a,clcngth 300 nm i,
21
(G ,cn:h 6.6, x 10 \4Js. ",\ 602 x 10 11101 '·
, 13 JO~ rns ) !June 24, 2022 (11)1
(a) 235 k.l mnl
(cl 399 k.l mo! 1
1 (b) ]25 kJ mo! •
(d) -135 kJ mo! '
6 1
(c) C'")il~lHT''j -\bsorpuon ,pec1rum
IJ
\n ..,ccckratcd electron ha:-. speed of5 x I 0 ms \\ ith an
60. unccrt J111) ofO 02° o. The unccrtaint~ in finding its location
\\h1le 1n motJOn 1, r IO 9m. The value ofx is 1
{~earc~t integer) [L se mas~ of electron - 9.1 x I kg. 03 Internal
( d) energ) of
h 6.63 10 "'h.r: J 1-1) j'\\,Jul) 25,2021 (11)1 Ar
6 I. The wa\ clength ol electrons accelerated from rest through J(O .ll)O 51 ) 600
a potenua! ditTere'lCC o' -10 k \ ,., , IO ,: 111 The\ alue of T.:mperarure, KJ
Bohr
rJ:, • (Nearest integer) The de Broglie \\.ti dength ofan electron in the ➔
66. orbit is· J 111. 09. 2 2
Gi,en: \la'>s of c'eetron 9 ' IO kg
Charge on an electron 1.6 IO C (a) 27tau (b) .t7rai1
Planck'scorstJnt <,61 iO Js '\\.Jul, 20.2021 (II)) (c) 61w, (d) 8TT3i
62. \\bcn hght of\\a\clcn!,'1h 2-18 nm falls Oil a met.ii of thrc:,hold Ir the de Broglie\\ a1 dcngth of the electron 111 11· Bohr

L"ller~ 3.0 cV. the de-Broght \\a, clcn!,.'1h ofemitted electron~ 67. orbit in a h:drogen1c atom 1s equal to 1.5 rw 1 (a 1s Bohr
,s A. (Round ofTto the !\..,arcst Jnterer). rad1us).thenthc,alueof11Z1s .,n.12.'.! 9 Il)l
34 (a) 0.-IO (b) 1.50
i:L,e: , 1 = J.73,h = 6.61.1<! 0 Js, (cl 1.0 (d) 0.75
!i ilJ r he de Broglie wa,elength (t,) associated \\1th a
31
3.0xiO m'> ;I cV 1.6XIO J] 68. photoclectron \anc~ 1\ 1th the frequenc> (1) of the 111c1dent
111c=9.Jxi0 kg.c
I''· ,1nrch 16 2021 (1)1 radiation as. [1
0
is threshold frequency]·
pan. ll,'.!019(11)1
6t A ball ,,e,ghing JO g is moving\\ 11h a, cloc1tyof90 11l!i ,
. I
If the uncl.!rtamty Jl1 it:, \Clocit) is 5° o, then the uncertain!} . I (bl 1. oc---T
1111tspl"J11on•~ JO H111.(Rountkdoffto (a) / , O C -
(\'-\'()) (v-v0 J-1

the ncare,l mtcgcr) . I

14
!'\\, J•ch. 26, 2021 ((1)1
[Gi\ en. h 6.63 IO Js] . I (d) 1, oc---T
M \ proton and .1 Lil nuclcu, arc accelerated b) the ~a111e (cl 1• oc ---T (v-v 0 l2
poicnt·a . Ifi. and '·r denote the de Broglie \I a, clcngihs (v - vol2
1·11
1
The d,-0,ogh<'s ""ele,g<h of""""'. P'~"' :" Ii,,,
o• L it of'! f' atom ,s: jOnfinc \pnl I". _01 li (11)1
,111 d proton re,pecll\ ch.
. then the \ a Iue O 1· -1··I'
- 69
' o r or -~9 ,
1
B h , .., bo --,9A (bl 2rt' 0-'- ·"'
' Ill lhc1,luel1fn, ,'\,.feh.24.2021(01 (a) ➔ _,_

0.529 , (dl 0.529A

(Round ,•cl o 1n to l h L' nearc-.t 1nte!!er)
.
(\h" ~1fl I ,, , tune, m,1,, lit proton l
C ' -
(c ) -2rc
·"'
63. fhc figure th t 1, not ,1 dtrC'l.l n1,1111fe,ta110n of the quantum
o atom,"
natun: I l'-il'P• 02. ;!0211 (Ill
A-12 CHEMIS r~~y

70. At temperature T. t11c 77. Wlmh of the following sets of q11,1ntum numhcrs 18 not
a,cragc k111ct1c c11c1gy nf any
nllowccl'' [.July 2~, 2022 (l)I
• 'I I
particle is · k7 lhc de Brnglic \\a,clcnfth fi,llnws the (;i) II l, I 2, 1111 0, ,\ I 2
2
onki . I20llJ (~). 1 111,. Onl11H' \pril 11, 20I<:i i I
2, 1111 2, ,\ I
(.1) \ 1s1bk plwt\111 I hcrmal 11cutrnn I hc111wl clcctro11 (h) II 1,1 2
(bl l he, 111.11 111llWll l hL'llllal clcctrn11 Visible photon I
1, 1111 1, s
(cl I hn111,1l p1 l1ll1ll \ !\Ible photo11 ri1cr,nal electron (c) II 1,1 2
(tll \ ,,,hk ph1l\l111 I lu:rmal electron f hcrmal neutron I
O,s -
71. l hL' de HroghL' ,, a, clcngth of a particle of 111ass 6.6J g (d) II l I 0, 1111 2
I
11w, 1:1g ,, 1th a, L'ioc1t_', of I 00 111s is: 7H. Thcnumbcrofradial nodes and total numhcrofnodcsin
!Onlim• \pril 12, 20141
11 1
4p orbital rcspcct1vcly arc: 1.JundO, 2022 (l)j
35
(a) 10 nm (b) 10 111 (c) 10 111 (d) 10 ' 111
(a) 2a nd 3 (b) 2and2 (c) 3and4 (d) 4and4
72. If 1hd..111ct ,c c11erg) of an electron is increased friur ti mes, 1

the ,,a,clcngth of the de-Broglie wave associated with it 79. Which oftl1c fol/owing statements arc correct ' 1
,,ould become !Online May 19, 20121 (/\) The electronic con figuration of Cr is fAr] 3d~ 4s .
one fourth
(:i) (b) half (B) The magnetic quantum number may have a negative value.
(c) fou rt1111es (d) twotimcs (C) Jn the ground state ofan atom, the orbitals arc filled
-3, In an atom. an electron ,s moving with a speed of600 111/s in order of their increasin g energies.
,1ith an accuracy of0.005%. Certainity with which34the (D) The total number of nodes arc given by n 2.
position ofthe electron can be located is ( /, =6.6 x IO kg Choose the most appropriate answer from the options
31
m2s 1• mass of electron, eIll = 9.1 x IO kg): given below : j.June 1-9 2022 (f)I
[2002 (S), 2006(S), 20091
3 (a) (A),(C)and(D)only (b) (A)ancl(B)only
(a) 5.10 x IO 3m (b) 1.92 x JO · m
(c) (A)and(C)only (d) (A),(B)and(C)only
(c) 3.84 x JO 3 111 (d) I.52x 10 -4 111
80. Which of th e foll owing is the correct plot for the probability
• Quantum Mechanical Model of Atom density 11t2(r) as a :fi.mction of distance' r' of the electron
form the nucleus for 2s orbita l? !June 29, 2022 (11 )1
74. Gi,·en below are the quantum numbers for 4 electrons.
A. n = 3. I= 2, m = L ms= -1- J '2 (July 29, 2022 (II)]
1
B. n =4. /= L m1 =0, m5 =+1/2
C. n =4. /=2. m 1 =-2, m5 =-1 '2
D. n = 3,/ = I, m 1 = -1, ms=+ 1 '2
The correct order ofincreasing energy is:
~) D < B <A<C ~) D <A<B<C
~ B< D <A<C ~) B <D<C<A
2
75. The correct decreasing order of energy, for the orbitals ~I (r)
having. following set of quantum numbers:
[Jul) 27 2022 (11)1 (c)
(A) 11=3.l =O. m=O (B) 11 4, I 0, 111 0 r~
(() II 3, /=I.Ill 0 (D) 11 3, I 2, Ill 1
(b) (B) (D) .>(C)>(A) 81. Consider the following statements: June 28 2022 (II)!
(aJ (D) >(B) .> (C) > (A)
(B) .> (D) > (A) (d) (BJ > (C) > (D) .> (A) (A) Tl:c prin cipa l quantum nu111bcr · ,, · is a pos1t1ve integer
(cJ (C)
76. .Vfatch List-/ with List-JI (July 27, 2022 (11)1 w1thvalucsof'11' 1,2,3, ....
List-I List-II (B) The azi111uthal quantum number ·r for a given ·11'
(f) Dipole moment (principal quantum nu111bcr) can h,1\C \~alucs as
(II) Bonding molecular orbita l ·r o, 1. 2, .... 11
\ \' (C) Magnetic orbital quantum nu111~r ·111 • fora particular
(C) _b '.<! (llf) Anti-bonding molccualr orbital '/' (azi111uthal quantum number) has (2/ t I) values.
2
(D) Y'\10 y1 A ,- 'fJB (IV)Bond order (0) ± I '2 arc the two possible oncntatwns of electron spin.
(a) (A)-(11).(B)-(]), (C}(IVJ,{D}-(11/J (U For/ 5, then.:,, ill be a total of9 orbital.
(b) (A)-(111), (8)-(IVJ, (C)-(1), (DJ-(ll) Which of the abo\ c statements correct?
(c) (A)-(111), (8)-(1), (C)-(IV), (O)-(ll) (a) (AJ,( B)and(C) (b) (A),(C),(D)and(E)
(d) (A)-(lll), (B)-(IV), (C)-(11), (DHI)
(c) (A). (C) and (D) (d) (A), (B), (C) and (D)
..p

~,,...
~
conSI
f':tl·H •it'.m
~ .. --··- .
fi JJow nu set of quantum numbers.
·der the o
1
-
(a) 6.1,4/, 5d,6p
(c) 6s,5f,6d,6p
(b) 6~.sd,5/,6p
(d) 6~.6p,6d,6/
A-13

l!Z· ,, I m, l)2 The correct statement about probabil1tydens1ty (except at

3 3 mfinitedistance from nucleus) 1s : !Sep. OS, 2020 (II))
A, 3 2
2 (a) It can be zero for Is orbital
B 3 (b) ll can be negative for 2p orbital
C 2,, ~ 2 (e) It can be 1..ero for 3p orbital
D ~ ,_nbcr o 1· cori <,;'Cl sets of quantum numbers is (cl) l l can never be zero for 2s orb1 tal
TllC Jilli
I \ lunc27,2022(11)] Consider the hypothetical situation where the a11muthal
9J
. fraJial a nd angular nodes in 4d orbital are quantum number, /, takes values 0, I, 2, .... n I, where n
in. 111~-nun11crl , t1 I Jum 6 2022 (11)1 is the principal quantum number. Then, the element with
rc,pcc11,1,;} 1 (b)3 atomic number: (Sep. 03, 2020 (H)I
d,, an d?_
(a) 1 an i ~ (d) 2 and 1 (a) 9 is the first alkali metal
td I anc the following pairs . of electrons (b) 13 has a half-filled valence subshell
(O!l'>I d er
(e) 8 is the first noble gas
84. I (d) 6 has a 2p-valence subshell
(A) (a) II : 3, I =- I. 1111 = I, /II, - -t 2 94
The number ofsubshells associated with n == 4 and
m =- 2 quantum numbers is: [Sep. 02, 2020 (ll)J
I
(a) 8 (b) 2 (c) 16 (d) 4
(b)n "' 3. J =2,/111-= l,m, =+ 2 95.
The number oforbitals associated with quantum numbers

I
(B)(a)II 3.1 = 2.111 1= - 2.111, =- 2 11 = S, m' = + -2 is:
[Jan 07, 2020 (I), Similar Online \pril 9 20161
(a) 11 (b) 25 (c) 50 (d) IS
I 96. Among the following, the energy of2s orbital is lowest in:
(C) (a) 11 c:4, I =2. 111 1 - 2. m,-=- .... 2 [2017(S);April 12.2019(11)]

(a) K (b) H (c) Li (d) Na

(b)11==3. I =2,m 1 = 2.111, - ,, 97. The electrons are more likely to be found:
The pairs of electron present in degenerate orbitals is/are: [ ..\pril 12, 2019 (1)1
!JUI•- ,.4. 2022 (1)1
(b) OnlyB
t
'I' (x)
(a) Only A
(d) (B)and(C) a
(c) OnlyC t
85. The \'alue of magnetic quantum number of the outermoS
electronofZn ion is _ __ _ . !l'IV,A- 2C21 (11)1
86. The Azimuthal quantum number for the valence electrons C

ofGa ion is _ _ jNV, J- J 20 2021 (I))

(Atomic number of Ga = 31)

87. A ccrta111 orbital has no angular nodes and two radial nodes. . I ·on a and c (b) in the region a and b
(a) 111 t 1e reg1 .
Thcorbital is r h 18 2021 (1)1 . the reoion a (d) only in the region l
(c) on Iy 111
(a) 2p (b) 3p (c) 3s (d) 2s . I between l'l'I" and,. (radial distance) .is sho,m
o .

Thcgiapi . \ rill0,2019()))
88 · A. certain orbital has 11 - 4 and 111 1 3. The number of 98,
below. This represents. I p
radial nodes in this orbital is
(Round off to the Nearest integer). -
. I"-' '\tarch 17,2021 (1)1
89 ·lhcnumber oforb1tal s ,1/ith11 5,m 1 +2 is - - ·
(Roundofftothd,earcst Integer). I'-\, '\tarch 16,2021 (Jl)I
90· The orbital harn1g two radial as ,veil as two angular nodes
IS : lhb,26,2021(01 /'
(b) 2s orbital
(a) 3P (b) 4d (<.:) Sd (<l) 4/ (a) Js orbital (d) 2p orbital
91. In the sixth period,
. the orbitals that are filled are: (c) 1s orbital
l~cp. 05, 2020 (I))
 cHEMIS rn (
A-14
. !I will have the quantum
111 1111 ;1fc1111 how 11w 11 Y orhrt,dl ) - Apr•,19, 20131
~ 2 ., 100 1,nc
99. Thl' l~l)t'kctwnic set l,r il)l1S is
1111111hcrs,11 1,/ 2:111 ""'1/<.Jr I 7
I ,). '00-' ("I. '00" (") • .,011(1("). 2011H (")· (h)
(<J
. ·11. 'fllC) (Ill (") 'i
la)'\ l)' ,llldi\il (h)N. 11 \fp ' .111dO' 10 ( 11\ l'll
'i, Ill I I
(l) I .I '\1 111dl\l~•' (d) 11 1\,1 () ;111dl (;\) JI J 111 112
(B) 11 2. 1 I, 111 •
: . ·rron(-;) 111 ,in atom that can
•
t 00 I Ill' qu.111' t,' ·1 ·1 11nh'r ( I r l1)lll l'il'l I l()Jl,', ,Ill' g1\l'll hcl<m c 1ct..:
1 1111 her o 1•rs
•
r he i11;1x1111t1m rt J f
•1c; nvcn in I A> anc (~)are
I /I 4. ',111 2,111, 12 h,1,c 1h c qt1anlt11n nwnhc ' 1[>nlinc \pril 2.:.. 20111
11 I 1., / '. 111 I. m, I 2. rc:-pccll\Cfy. ( ) 2 ·ind 4 (d) 4 and I
Ill 1 4.t l.m O.m, t I2 a) 25 and I (b) 8 a nd
I
c ' m1...crs n and P:
I\. 11 .~. I I. 1111 I. 111, l 2 . ( . T I b quantum nu "
1 • 06. The electrons idcnll ice y
1 hc ,X)l l l'l'1 N1kr ,,fthl'tr i11l'll'as111g cnc1g1c-. \\' II lK 1 120 12. ~imilar 20051
12007(',), \ !019 (1)1
I (B) II • 4. I ()
l,l) I\ <.. IIJ--.l]s.l (b) I < ff , rrr Iv (;\) II 4. I 3. I. I
(D) If
(·) I\'< 11<- llf< r (dl f <. III < rr rv ? is (C) 11 3. I 2 • . as
' . l .. ·11 ·cics Cl t\1 and Ca b laced in order ofincrca<;1ng energy
1 lt • Ill:
,. ,iLl' ,t
1 ihc ,-;
1 11-c cc1ro111L s L • •
111 ( ( I) I can ep (D) (B),...(C),...(A)
nlk,'k'd In . 1 11 () (C) < (D) < (B)<(A) (b)
(:t):iz111H~lhal quanlulll numbcr of\'a/cncc ~ ,c .. (:) (B) < (D) < (A)< (C) (d) (A) (C),... (B),... (D)
(f,) l'k,·1n111-dcctro11 1111cract1on In the outer or br tals
. h of'the fo llowing sets of quantum numbers rs correct
(d princip;il qua111u111 nu111bc1 of,·alcncc shell to WI1 1c . ? (20041
(,ll nuclcar chargc . . . . . for an electron in4forbital ·
2 \\ h1d1 ,1f1hc follo\\rng c_o111b1nat1011 of~tat~n:ent~ is t1 ue (a) 11 4, I =- 3. 111 = + I. '= + ½
r•,1:irdlll'' 1hc 1n1crprctat1011 of the atomic 01 b1tals. (b) 11 =4, / = 4.m= 4,s- = ½
l.::,• ::- I l ( I I) (J ) I
(c) 11=-4,/=3,m=+ 4,s= +½
\n electron 1n an orbital ofhigh angular 1110111~ntum
(d) 11=3,!=2,m= 2,s=+½
sta,~ a\\·av from the nucleus than an electron 111 the J08. Consider the ground state of Cr atom (X = 24 ). The number
orbital ofl~wer angular momentum. of electrons with the azimuthal quantum numbers. I= I
(2) for a gi,·cn ,·alue of the principal quantum number,
the si;c of the orbit is in,·crsely proportiona l to the and 2 are, respectively _20041
(a) 16and4 (b) 12and5
azunuthal quantum number.
(3) Accordmg to ,\·a,·e mechanics, the ground state (c) 12 and 4 (d) 16 and 5
2
h 109. The number of d-electrons retained in Fe
an!!lllar momentwn is equal to - (AL no. of Fe= 26) ion is
(20031
"" 2n (b) 5
(a) 4
(4) The plot of \j/ ,s r for various azimuthal quantum (d) 3
numbers. shows peak shifting towards higher rvalue. (c) 6
The orbital angular momentum for an electron re'- oh ing m
(a) (1).(4) (b) (1).(2) (c) (1),(3) (d) (2),(3) llO.
The correct set of four quantum numbers for the valence
103. an orbit is given by .jt(l + 1) _}!_. This momentum for an
electron~ of rubidium atom (Z = 37) is: ?.( ..., I 2rt
l J s-eleclron will be given by [2003!
<a) 5.0,0.+- (b) 5,1,0,+-
2 2 I h
I (a) zero (b) !!._ (c) ✓2.}!_ (d) +-.-
(c)
l
5,l,l,-t- (d) 5.0.1.+- 2rc 2rc : ~:,:
2 2
[0111 ID.I L ,'IZ'T fnl T ~ lul 71 1 (~() 119 1 lPl [ 8t I tvJ L.!l£...J L\J 1 t~ Lu:-:t)[Ii]
I ( ') 13
14
( ' > l) 'S
2(1
<\I'-'- 37 (l ) 4')
ANSWER KEYS
( l) (11
(12
I(,) 73 <I l K4'
86
:! ( Il , cl) \L ) .\8 (L) 50 (,I) (')) 74 (I J

.3 ~()()\ I" (l ) 27 Id ) .3•> (,) 51 ( ,1) (,.\ (11 75

~ (c I I(, (b) 28 (C ) 40 (h) ~l (d l (14 ( ) 7(,
5
(1 Cl
I
18
(-:)
(ti)
29
30
(a )
(c)
41
42
( C)
(b)
~-'
54
(15
(l(,
(dJ
\d l
77
78 ( ,1 \
89
1)1)
\~
11)
( <i(l) (a) 31 (b) -43 a) 55 (17 (,I) 71) d) I)\

8 ("' 20 d) 32 ( C) 44 ( c) ~(l (,8 (LI 80 (hl ')2

') \d) 21 (al 33 (a) 45 (a) S7 69 th) 81 ( L) 93

HI 121 22 ( 10) 34 (bJ 46 (d) 58 (22) 70 tu i 82 ( 2) 1)4
-
ll (h) 23 <hl 35 (d) 47 (c ) 59 (c) 71 (a) 83 (a\ 95
12 (l~L 24 (N) 36 (a) 48 (ti) (,{) (58) 72 (b l 84 (b) 9(,

7.