Light Naphtha Isomerization

(ISOM) & Naphtha Splitter

SHIRAZ OIL REFINERY

DOCUMENT NO. CONTRACT NO.:

Proj. Unit Phase Disc. Type Ser. No.
Material Requisition For ‫پ ش‬/٩٨/٢٢/١٢٧
Rev. Chemicals
SISO 1400 EP PR MR 0001 A1 PAGE : 1 of 19

Material Requisition
For
Chemicals

A1 3-Jul-2021 Issued For Approval A.H V.H A.A

A0 29-May-2021 Issued For Comment A.H V.H A.A
REV. DATE DESCRIPTION PREPARED CHECKED APPROVED
 Light Naphtha Isomerization
(ISOM) & Naphtha Splitter
SHIRAZ OIL REFINERY

DOCUMENT NO. CONTRACT NO.:

Proj. Unit Phase Disc. Type Ser. No.
Material Requisition For ‫پ ش‬/٩٨/٢٢/١٢٧
Rev. Chemicals
SISO 1400 EP PR MR 0001 A1 PAGE : 2 of 19

REVISION INDEX

SHEET REVISION SHEET REVISION

NO. NO.
A0 A1
1 x
2 x
3 x
4 x
5 x
6 x
7 x X

8 x
9 x
10 x
11 x
12 x
13 x
14 x
15 x
16 x
17 x
18 x
19 x
 Light Naphtha Isomerization
(ISOM) & Naphtha Splitter
SHIRAZ OIL REFINERY

DOCUMENT NO. CONTRACT NO.:

Proj. Unit Phase Disc. Type Ser. No.
Material Requisition For ‫پ ش‬/٩٨/٢٢/١٢٧
Rev. Chemicals
SISO 1400 EP PR MR 0001 A1 PAGE : 3 of 19

TABLE OF CONTENT
1. INTRODUCTION ................................................................................................................................................4
1.1 Project Overview ......................................................................................................................................... 4
1.2 Definitions ................................................................................................................................................... 4
1.3 Abbreviations .............................................................................................................................................. 5
2. SCOPE..................................................................................................................................................................5
3. APPLICABLE CODES AND STANDARDS .....................................................................................................5
4. ORDER OF PRECEDENCE................................................................................................................................5
5. REQUISITION SUMMARY ...............................................................................................................................6
5.1. Molecular Sieve ....................................................................................................................................................6
5.2. Adsorbent .............................................................................................................................................................6
5.3. Perchloroethylene .................................................................................................................................................7
6. ENGINEERING DOCUMENTS .........................................................................................................................7
7. DOCUMENTS REQUIRED FROM VENDOR/SUPPLIER...............................................................................9
8. SCOPE OF WORK/SUPPLY ............................................................................................................................10
8.1 Scope of Supply......................................................................................................................................... 10
8.2 Scope of Work ........................................................................................................................................... 10
9. INSPECTION AND TEST.................................................................................................................................11
10. SUPPLIER'S PROPOSAL .................................................................................................................................11
11. DEVIATION FROM PURCHASER’S REQUIREMENTS ..............................................................................11
12. PARTICULAR NOTES .....................................................................................................................................12
12.1 Coordination Meeting................................................................................................................................ 12
12.2 General Notes ............................................................................................................................................ 12
12.3 Technical Notes ......................................................................................................................................... 12
13. FEED DRIER, SGB FEED AND MAKEUP GAS COMPOSITION AND CHARACTERISTICS: ................12
14. GUARANTEE....................................................................................................................................................16
14.1 Turndown Guarantees: .............................................................................................................................. 17
14.2 Pressure Drop Guarantee: .......................................................................................................................... 17
14.3 Chemical Life Guarantees: ........................................................................................................................ 17
15. Test Method........................................................................................................................................................17
16. ANNEXURE: LETTER OF CONFIRMITY .....................................................................................................19
 Light Naphtha Isomerization
(ISOM) & Naphtha Splitter
SHIRAZ OIL REFINERY

DOCUMENT NO. CONTRACT NO.:

Proj. Unit Phase Disc. Type Ser. No.
Material Requisition For ‫پ ش‬/٩٨/٢٢/١٢٧
Rev. Chemicals
SISO 1400 EP PR MR 0001 A1 PAGE : 4 of 19

1. INTRODUCTION

1.1 Project Overview

“Shiraz Oil Refinery” (SOR) located at 22 km from Shiraz, originally designed and constructed for nominal
processing capacity of 40,000 BPSD in 1973 and then expanded to 60,000 BPSD.
The feedstock of the refinery is heavy crude oil from Gachsaran oil field, Sarvestan oil field and condensates
from Dalan gas field. The main products of refinery include Gasoline, Kerosene, Gas oil, Fuel oil, LPG,
Bitumen, Sulfur and Solvents, with total annual capacity of more than 3 million tons.
“Shiraz Oil Refining Company” (SORC) the Owner of the refinery, aims to implement major “Products
Upgrading Project” at SOR, as part of a wider national effort of Iranian government to expand and upgrade
the country’s refining capacity in the next years.
As part of this project, SORC intends to implement a new Naphtha Splitter with the capacity of 6500 BPSD
and a new Isomerization Unit with the capacity of 5000 BPSD in SOR. The purpose of Naphtha Splitter is
to separate light Naphtha from hydroteated Naphtha in order to feed to Isomerization unit. The objective of
the Isomerization unit is to produce Isomerate with the RON of 88 as minimum.
Jondi Shapour Company (JSC) has been awarded to work as EPC contractor of the Project.

1.2 Definitions

Project Light Naphtha Isomerization (ISOM) & Naphtha Splitter

Owner Shiraz Oil Refining Company (SORC)

MC Hirbodan Company (HB)

EPC Contractor JondiShapour Company (JSC)

Purchaser JondiShapour Company (JSC)

The Manufacturer and/or Supplier from which the Equipment or
Vendor/Supplier
Catalyst/Chemical is To Be Purchased.
Licensor The Licensor of Isomerization Unit (UOP)

shall The word “shall” indicates a requirement.

should The word “should” indicates a recommendation.

may The word “may” indicates alternatives are equally acceptable.

 Light Naphtha Isomerization
(ISOM) & Naphtha Splitter
SHIRAZ OIL REFINERY

DOCUMENT NO. CONTRACT NO.:

Proj. Unit Phase Disc. Type Ser. No.
Material Requisition For ‫پ ش‬/٩٨/٢٢/١٢٧
Rev. Chemicals
SISO 1400 EP PR MR 0001 A1 PAGE : 5 of 19

1.3 Abbreviations

BED Basic Engineering Design

BEDP Basic Engineering Design Package

BPSD Barrels Per Stream Day

EPC Engineering, Procurement and Construction

SOR Shiraz Oil Refinery

SORC Shiraz Oil Refining Company

TBA To be defined or approved later.

JSC Jondi Shapour Company

2. SCOPE

This Material Requisition specify the scope of supply and/or work of the items listed in Requisition
Summary, section 5.
This Requisition covers the minimum requirements for the Engineering, Documentation, Materials,
Fabrication, Inspection, Testing, Supplying, Packing, Marking, Shipment, Guarantee and delivery for
“CHEMICALS’’.
Vendor/Supplier shall provide following requirements in strict accordance with conditions stated in this
Requisition and any attached documents. Exceptions, Deviations and Alternatives will be valid only if
approved in writing by PURCHASER.

3. APPLICABLE CODES AND STANDARDS

Engineering specifications and documents, attached to this requisition, listed in section 6 entitled
“ENGINEERING DOCUMENTS”, are applicable for supply of items mentioned in requisition summary.
The Vendor/Supplier is the sole responsible party for the correct application of the contractual documents
and be adhered to all specifications and guarantees.

4. ORDER OF PRECEDENCE

In case of conflict between documents listed in “DOCUMENTS ATTACHED TO THIS REQUISITION”

and the Requisition, the order of priority is:
a) Technical Clarification
b) This Material Requisition
 Light Naphtha Isomerization
(ISOM) & Naphtha Splitter
SHIRAZ OIL REFINERY

DOCUMENT NO. CONTRACT NO.:

Proj. Unit Phase Disc. Type Ser. No.
Material Requisition For ‫پ ش‬/٩٨/٢٢/١٢٧
Rev. Chemicals
SISO 1400 EP PR MR 0001 A1 PAGE : 6 of 19

c) Project Specification
d) UOP Specifications
e) Any conflict between the above documents must be brought to PURCHASER’s attention and written
PURCHASER’s approval shall be obtained before proceeding with designing, purchasing and
manufacturing of any part of the whole package.

5. REQUISITION SUMMARY

5.1. Molecular Sieve

Volume
Item Tag/Part Unit Loading
(Note Chemical Type
Seq. Number no. Method
2)
UOP MOLSIV Adsorbent type HPG-429 (or
1 V-1405A 1.47 m3 Equivalent)
1400 Solid
UOP MOLSIV Adsorbent type HPG-429 (or
2 V-1405B 1.47 m3 Equivalent)
1400 Solid
UOP MOLSIV Adsorbent type HPG-429 (or
3 V-1407A 6.1 m3 Equivalent)
1400 Solid
UOP MOLSIV Adsorbent type HPG-429 (or
4 V-1407B 6.1 m3 Equivalent)
1400 Solid
Notes:
Note 1: For handling losses, a provision of 5% has been considered on the values. Vendor/Supplier to
advise.
Note 2: All given volumes are for 3-5 years.
component types and relevant volumes are typical and shall be specified & finalized by chemical
Vendor/Supplier.

5.2. Adsorbent

Volume
Item Seq. Tag/Part Number Chemical Type Unit no. Loading Method
(Note 2)
1 V-1406 2.52 m3 UOP - DS-120 (or Equivalent) 1400 Solid

Notes:
Note 1: For handling losses, a provision of 5% has been considered on the values. Vendor/Supplier to
advise.
Note 2: given volume are for one years.
component types and relevant volumes are typical and shall be specified & finalized by chemical
Vendor/Supplier.
 Light Naphtha Isomerization
(ISOM) & Naphtha Splitter
SHIRAZ OIL REFINERY

DOCUMENT NO. CONTRACT NO.:

Proj. Unit Phase Disc. Type Ser. No.
Material Requisition For ‫پ ش‬/٩٨/٢٢/١٢٧
Rev. Chemicals
SISO 1400 EP PR MR 0001 A1 PAGE : 7 of 19

5.3. Perchloroethylene

Comm &
Item Tag/Part Volume
Performance Test Chemical Type Unit no. Loading Method
Seq. Number (Note 2) (Note 3)
1 - 53.4 m3 12.7 m3 Purity min 99.9 wt% 1400 Solid
Notes:
Note 1: For handling losses, a provision of 5% has been considered on the values. Vendor/Supplier to
advice.
Note 2: given volume are for one years.
Component types and relevant volumes are typical and shall be specified & finalized by chemical
Vendor/Supplier.
Note 3: Chemical consumption is considered based on commissioning and Performance Test for 3
months of process facilities.

A1

Properties Specification Limits

Purity, wt.% 99.9 min
Color, APHA 10 max
Appearance Clear & Free of suspended matter
Specific Gravity @ 25°C 1.617 - 1.621
Nonvolatile Residue, wt. ppm 10 max
Water, wt. ppm 30 max
Chlorides, wt. ppm 1 max
Free Halogen (ASTM D4755) Passes Test
Distillation Range, 760 mm IBP - 120.6°C min
EP - 121.6°C max
Additive (Stabilizer, Inhibitor, etc.), wt. ppm 10 max
Organically combined Oxygen, plus organically combined Nitrogen, wt. ppm 15 max

6. ENGINEERING DOCUMENTS

The project specifications / documents applicable to Vendor /Supplier supply are listed in the table-1, which
are applicable in their entirety unless accepted by Owner / Contractor. It is Vendor/Supplier’s responsibility
to ask the Contractor for any document not received by him but referred in the Material Requisition including
revisions as indicated in Material Requisition.
Engineering specifications and documents, listed in the Material Requisition are applicable for supply of the
items mentioned in this specification.
The Vendor/Supplier is the sole responsible party for the correct application of the contractual documents
and adherence to all specifications attached to Material Requisition and codes as mentioned above.
 Light Naphtha Isomerization
(ISOM) & Naphtha Splitter
SHIRAZ OIL REFINERY

DOCUMENT NO. CONTRACT NO.:

Proj. Unit Phase Disc. Type Ser. No.
Material Requisition For ‫پ ش‬/٩٨/٢٢/١٢٧
Rev. Chemicals
SISO 1400 EP PR MR 0001 A1 PAGE : 8 of 19

The Project Specifications / Documents Applicable (Table-1)

NO. DESCRIPTION DOCUMENT NO. REV.
A General Documents
1 Vendor Documents Handling & Numbering Procedure SISO-1400-GM-DC-PRC-0002 B0
B Technical Documents
2 Existing Utilities Conditions and Site Information Data Book SISO-1400-EB-PR-LIS-0001 B0
3 Job Specification For Inert Ceramic Balls SISO-1400-EB-PR-SP-4201 B0
4 Process Design Basis SISO-1400-EB-PR-DBS-0001 B1
5 Process Flow Diagram – Makeup Gas Section SISO-1400-EB-PR-PFD-0002 B0
6 Process Flow Diagram – Feed and Regeneration Section SISO-1400-EB-PR-PFD-0003 B1
7 Process Flow Diagram – Net Gas Scrubber Section SISO-1400-EB-PR-PFD-0006 B0
8 Chemical Consumption List SISO-1400-EB-PR-LIS-0003 B0
9 P&ID For Makeup Gas Drier A SISO-1400-ED-PR-PID-0123 A2
10 P&ID For Makeup Gas Drier B SISO-1400-ED-PR-PID-0126 A2
11 P&ID Sulfur Guard Bed SISO-1400-ED-PR-PID-0132 A2
12 P&ID For Feed Drier A SISO-1400-ED-PR-PID-0134 A2
13 P&ID For Feed Drier B SISO-1400-ED-PR-PID-0137 A2
14 Engineering Drawing For V-1405AB (Makeup Gas Driers) SISO-1400-ED-ME-DWG-4039 B0
15 Engineering Drawing For V-1407AB (Feed Driers) SISO-1400-ED-ME-DWG-4040 B0
16 Engineering Drawing For V-1406 (Sulfur Guard Bed) SISO-1400-ED-ME-DWG-4008 B0
C Inspection Documents
17 Final Documentation Procedure SISO-1400-GQ-QA-PRC-0001 B0
18 Material Handling & Storage Procedure SISO-1400-GQ-QA-FIP-0001 A1
19 Quality Assurance/Quality Control Plan Procedure SISO-1400-GQ-QA-FIP-0002 B0
Packing, Marking, Shipping and Field Material Handling
20 SISO-1400-GM-GN-PRC-0002 B0
Procedure
D Licensor Documents
21 HOT PENEX General Operating Manual -

7.
 Light Naphtha Isomerization
(ISOM) & Naphtha Splitter
SHIRAZ OIL REFINERY

DOCUMENT NO. CONTRACT NO.:

Proj. Unit Phase Disc. Type Ser. No.
Material Requisition For ‫پ ش‬/٩٨/٢٢/١٢٧
Rev. Chemicals
SISO 1400 EP PR MR 0001 A1 PAGE : 9 of 19

8. DOCUMENTS REQUIRED FROM VENDOR/SUPPLIER

Vendor/Supplier documentation (after purchase order) shall be in line with the requirements specified in
Table-2.
The project specifications / documents applicable (Table-2)

Issue Intervals

No. Description Purchase Ordered

Bid Stage Final
Q/Type Book
Q/Type Date P.O.I

1 Vendor/Supplier’s Questionnaire 2/C

- - - -

2 Deviation / Alternatives (If Any) 2/C

- - - -
Vendor/Supplier Print Index and Schedule (VPIS) 2W
4 - 4/C+1/CD R
(Note 1) +Monthly -

5 Performance letter indicating chemical performance 2/C 4/C+1/CD 2W R X

Chemicals/Catalyst Specification including physical

6 2/C 4/C+1/CD 2W R X
and Chemicals properties
Technical instruction for Chemicals characteristic,
7 handling, storing, transportation and other required 2/C 4/C+1/CD 2W R X
procedures

8 Assistance instruction for shipping 2/C 4/C+1/CD 2W R X

9 Material Safety Data Sheet (MSDS) for Chemicals 2/C 4/C+1/CD 2W R X

10 Chemicals Catalogue 2/C 4/C+1/CD 2W R X

11 Other Technical documents, if any 2/C 4/C+1/CD 2W R X

Documents related to inspection and test certificate

12 2/C 4/C+1/CD 2W R X
of Chemicals

13 Vendor/Supplier’s reference list 2/C - - - -

3W before
14 Packing type and list 2/C 4/C+1/CD I X
shipping

15 Vendor/Supplier’s Quality Assurance Plan 2/C At Bid R

- Stage -

16 Vendor/Supplier’s Progress Report E Monthly R

- -
 Light Naphtha Isomerization
(ISOM) & Naphtha Splitter
SHIRAZ OIL REFINERY

DOCUMENT NO. CONTRACT NO.:

Proj. Unit Phase Disc. Type Ser. No.
Material Requisition For ‫پ ش‬/٩٨/٢٢/١٢٧
Rev. Chemicals
SISO 1400 EP PR MR 0001 A1 PAGE : 10 of 19

17 Vendor/Supplier Quality Control Plan 4/C+1/CD 3W A X

-
List of Documents to Be Included In Vendor 2 M Before
18 - E + 1/CD A X
/Supplier Final Data Book Delivery
Vendor/Supplier Final Data Book (Including 2 W After
19 - - R X
Inspection Data Book) Delivery
6 W Before
20 Commissioning and Operation Manual 2/C 4/C+1/CD R X
Delivery
6 W Before
21 Chemicals Loading and Unloading Manual 2/C 4/C+1/CD A X
Delivery

22 Chemicals Loading Diagram 2/C 4/C+1/CD 2W A X

Legends:

(1) Q=Quantity, C=Copy, T=Transparent, P=Polyester, CD=Compact Disc, E=E-File

(2) W=Week After Order Placement, M=Month After Order Placement
(3) A= For Approval R=For Review, I=For Information
(4) X=Documents to Be Submitted at The Final Inspection / Data Book

Note: No Drawing / Document Could Be Reviewed Before Receiving VPIS.

9. SCOPE OF WORK/SUPPLY

9.1 Scope of Supply

In particular, the supply shall include but not limited to the following items:

- Chemicals
- Extra amount of Chemicals for loading and unloading losses, according to VENDOR/SUPPLIER
advise.
- Documentation as Per “DOCUMENTS REQUIRED FROM VENDOR/SUPPLIER”.
- All necessary devices for Loading and Unloading. (If any)

9.2 Scope of Work

- Material Procurement.
- Documentation as per “DOCUMENTS REQUIRED FROM VENDOR/SUPPLIER”
- Inspection and Tests at shop
- Manufacturing
- Supervision for chemical loading and start-up at site
- Packing & Preparation for Shipment
 Light Naphtha Isomerization
(ISOM) & Naphtha Splitter
SHIRAZ OIL REFINERY

DOCUMENT NO. CONTRACT NO.:

Proj. Unit Phase Disc. Type Ser. No.
Material Requisition For ‫پ ش‬/٩٨/٢٢/١٢٧
Rev. Chemicals
SISO 1400 EP PR MR 0001 A1 PAGE : 11 of 19

10. INSPECTION AND TEST

Vendor/Supplier shall consider any other necessary tests and inspections for covering guarantee and
warranty and prepare QCP which will accompany Tender Proposal. It shall include as a minimum, Inspection
and test activities, Procedure references, Acceptance criteria, Documentation and Certification to be
provided.

11. SUPPLIER'S PROPOSAL

Vendor/Supplier shall provide all Data/Documents that have been requested in “DOCUMENTS REQUIRED
FROM VENDOR/SUPPLIER”.
Also the Bid must include the following information in order to be taken into consideration:
Price Shall Be Broken Down as Follows:
- Chemicals
- Loading and unloading special equipment (if any)
- Transportation (DDP at site)
- Site Assistance Services / Supervision (man-day rate)
Vendor/Supplier Shall Also Specify and Confirm the Following Terms in His Quotation:
- Delivery Time
- Quotation Validity
- Supply of all items is exactly as per subject Requisition, except items that have been clearly identified
in Vendor/Supplier Deviation form.
- Guarantees
- Guarantees period (life time)
- Expected period time (life time)
- Sub-contractor / Sub-supplier (if any) List
- Chemicals Shelf Time

12. DEVIATION FROM PURCHASER’S REQUIREMENTS

Vendor/Supplier’s Proposal shall be in strict conformity with PURCHASER’s requirements. Unless

Exceptions, Deviations or Alternatives are clearly identified in Vendor/Supplier Deviation form, attached to
the Invitation to Tender Letter, the requirements and conditions in this attachment and all documents attached
to the Requisition is deemed to be accepted by Vendor/Supplier.
PURCHASER has no responsibility to discover any deviations entered in Vendor/Supplier’s Proposal other
than specifically listed in the form, and those Deviations which are not listed in the consolidated deviation
list shall be disregarded.
 Light Naphtha Isomerization
(ISOM) & Naphtha Splitter
SHIRAZ OIL REFINERY

DOCUMENT NO. CONTRACT NO.:

Proj. Unit Phase Disc. Type Ser. No.
Material Requisition For ‫پ ش‬/٩٨/٢٢/١٢٧
Rev. Chemicals
SISO 1400 EP PR MR 0001 A1 PAGE : 12 of 19

13. PARTICULAR NOTES

13.1 Coordination Meeting

- After order is awarded, VENDOR/SUPPLIER shall, upon receipt of PURCHASER’s notice, send
a sufficient number of qualified personnel to PURCHASER’s office at Vendor/Supplier cost to hold
the Kickoff Meeting: 1 Day, after 2 weeks of Purchase Order.
- Before minimum 2 weeks of Manufacturing Commencement, Pre Inspection Meeting shall be held
at Vendor/Supplier’s Shop.
- Technical Meetings at Vendor/Supplier’s shop (whenever required).

13.2 General Notes

- All Documents / Drawings shall be written only in English.

- All changes and modifications on Vendor/Supplier Documents shall be clearly clouded marked with
Revision Mark. PURCHASER will take no action on any change without such marking.
- However, when Vendor/Supplier Print is marked with “Approved as Noted”; manufacturing
activities can be performed if PURCHASER's Comments incorporated as indicated.
- All Vendor/Supplier Drawings and Documents shall be provided in accordance with “Vendor
Documents Handling & Numbering Procedure”.
- SI Units shall be used for measurements.
- All E-Files should be provided in original format (e.g AutoCAD, Word, Excel & etc.)
- After Material Takeoff being reviewed, Vendor/Supplier is responsible for supply of any shortage
material. No delivery impact due to late supply of material is accepted.

13.3 Technical Notes

- An additional contingency quantity for losses during handling will be recommended at the time the
chemicals order is placed.
- Any special requirements/terms for start-up and other activities which is not normally available in
plant shall be notified by Vendor/Supplier in Bid stage.

14. FEED DRIER, SGB FEED AND MAKEUP GAS COMPOSITION AND CHARACTERISTICS:

Feed Drier, SGB Feed and Makeup Gas composition are tabulated as Table 3 as below. Vendor/Supplier
shall carefully consider the composition in technical proposal.
 Light Naphtha Isomerization
(ISOM) & Naphtha Splitter
SHIRAZ OIL REFINERY

DOCUMENT NO. CONTRACT NO.:

Proj. Unit Phase Disc. Type Ser. No.
Material Requisition For ‫پ ش‬/٩٨/٢٢/١٢٧
Rev. Chemicals
SISO 1400 EP PR MR 0001 A1 PAGE : 13 of 19

Feed Drier, SGB Feed and Makeup Gas Composition (Table-3)

STREAM No. 135 209 204
Makeup Gas to Drier Fresh Feed Sulfur Guard Bed Charge
Description (kmol/hr)
(kmol/hr) (kmol/hr)
SOR EOR SOR EOR SOR EOR
HYDROGEN 90.69 89.98
METHANE 18.9 18.76
ETHANE 9.32 9.25
ETHYLENE
PROPANE 5.36 5.32 1.43E-06 1.43E-06 1.43E-06 1.43E-06
PROPYLENE_2001Review
ISOBUTANE 1.28 1.27 4.70E-04 4.70E-04 4.70E-04 4.70E-04
n-BUTANE 1.28 1.27 0.05 0.05 0.05 0.05
trans-2-BUTENE_2001Review
NEOPENTANE
ISOPENTANE 0.51 0.51 48.67 48.67 48.67 48.67
n-PENTANE 0.26 0.25 68.35 68.35 68.35 68.35
1-PENTENE_2001Review
CYCLOPENTANE 10.82 10.83 10.83 10.83
2,2-DIMETHYLBUTANE 2.3 2.42 0.98 0.98
2,3-DIMETHYLBUTANE 29.7 31.23 2.2 2.2
2-METHYLPENTANE 128.95 138.61 31.82 31.82
3-METHYLPENTANE 83.03 91.36 22.6 22.6
n-HEXANE 0.13 0.13 85.39 93.33 44.52 44.52
1-HEXENE_2001Review 5.96E-09
METHYLCYCLOPENTANE 81.52 88.31 25.68 25.68
CYCLOHEXANE 69.76 57.96 10.22 10.22
BENZENE 9.17 9.17 9.17 9.17
2,2-DIMETHYLPENTANE 0.21 0.26
2,4-DIMETHYLPENTANE 0.64 0.62 0.34 0.34
2,2,3-TRIMETHYLBUTANE 0.15 0.16 0.06 0.06
3,3-DIMETHYLPENTANE 0.16 0.15
2,3-DIMETHYLPENTANE 0.72 0.71 0.52 0.52
2-METHYLHEXANE 2.02 2.02 1.61 1.61
3-METHYLHEXANE 0.72 0.73 0.38 0.38
3-ETHYLPENTANE 0.07 0.08 0.05 0.05
n-HEPTANE 0.11 0.12 0.01 0.01
1-HEPTENE_2001Review 1.21E-04
1,1-DIMETHYLCYCLOPENTANE 1.03 1.17 0.63 0.63
 Light Naphtha Isomerization
(ISOM) & Naphtha Splitter
SHIRAZ OIL REFINERY

DOCUMENT NO. CONTRACT NO.:

Proj. Unit Phase Disc. Type Ser. No.
Material Requisition For ‫پ ش‬/٩٨/٢٢/١٢٧
Rev. Chemicals
SISO 1400 EP PR MR 0001 A1 PAGE : 14 of 19

trans-1,3-DIMETHYLCYCLOPENTANE 1.51 1.95 0.34 0.34

trans-1,2-DIMETHYLCYCLOPENTANE 1.27 1.54 0.51 0.51
METHYLCYCLOHEXANE 3.86 3.82 8.83E-04 8.83E-04
ETHYLCYCLOPENTANE 0.06 0.09
TOLUENE 1.04E-04 1.04E-04 1.04E-04 1.04E-04
3-METHYLHEPTANE 7.51E-04 1.07E-03 2.3E-09 2.3E-09
n-OCTANE
1-OCTENE_2001Review
113-MCC5 2.1E-03 0.02 1.32E-06 1.32E-06
1,1-DIMETHYLCYCLOHEXANE 0.05 0.06
1M-ci3-ECC5 5.2E-04 0.01
ISOPROPYLCYCLOPENTANE 9.2E-05 9.63E-04
n-PROPYLCYCLOPENTANE 5.77E-0.5 6.02E-04
ETHYLCYCLOHEXANE 0.11 0.14

Feed Drier, SGB Feed and Makeup Gas Characteristics are tabulated as Table 4 as below. Vendor/Supplier
shall carefully consider the characteristics in technical proposal.
Feed Drier, SGB Feed and Makeup Gas Characteristics (Table-4)
STREAM 135 209 204
Sulfur Guard Bed
Description Makeup Gas to Drier Fresh Feed Charge
SOR EOR SOR EOR SOR EOR
Phase V V L L L L
Temperature °C 38 38 38 38 150 150
Pressure kg/cm2[g] 45.1 45.1 12.5 12.5 17.8 17.8
Total Mass Vapor Fraction 1 1
Total Mole Flow kmol/h 127.7 126.7 630.4 653.9 279.5 279.5
Total Mass Flow kg/h 1218 1208 52297 54344 22185 22185
Total Molecular Weight 9.5 9.5 83 83.1 79.4 79.4
Total Enthalpy 10^6 kcal/h -0.76 -0.75 -26.57 -27.71 -9.78 -9.78
Total Mass Enthalpy kcal/kg -624.45 -624.485 -507.98 -509.83 -440.8 -440.8
Vapor Mole Flow kmol/h 127.7 126.7
Vapor Mass Flow kg/h 1218 1208
Vapor Molecular Weight 9.5 9.5
Vapor Actual Volume Flow m3/h 72 72
Vapor Standard Volume
norm m3/h 2863 2840
Flow
Vapor Actual Density kg/m3 16.9 16.9
Vapor Enthalpy 10^6 kcal/h -0.76 -0.75
Vapor Mass Enthalpy kcal/kg -624.47 -624.44
 Light Naphtha Isomerization
(ISOM) & Naphtha Splitter
SHIRAZ OIL REFINERY

DOCUMENT NO. CONTRACT NO.:

Proj. Unit Phase Disc. Type Ser. No.
Material Requisition For ‫پ ش‬/٩٨/٢٢/١٢٧
Rev. Chemicals
SISO 1400 EP PR MR 0001 A1 PAGE : 15 of 19

Vapor Pseudocritical
C -172 -172
Temperature
Vapor Pseudocritical
kg/cm2[a] 22.89 22.89
Pressure
Vapor Compressibility 0.986 0.986
Vapor Specific Heat kcal/(kg.°C) 0.931 0.931
Vapor CP/CV 1.289 1.289
Vapor Viscosity cP 0.012 0.012
Vapor Thermal kcal/(h.m.°
0.089 0.089
Conductivity C)
Vapor H2 Partial Pressure kg/cm2[a] 32.66 32.34
Vapor H2S Mole Fraction
Vapor H2O Mass Flow kg/h
Liquid Mole Flow kmol/h 630.4 653.9 279.5 279.5
Liquid Mass Flow kg/h 52297 54344 22185 22185
Liquid Molecular Weight 83 83.1 79.4 79.4
Liquid Actual Volume Flow m3/h 78.5 81.8 42.8 42.8
Liquid Standard Volume
m3/h 76.43 79.62 33.12 33.12
Flow
Liquid Actual Density SPG 0.666 0.665 0.518 0.518
Liquid Enthalpy 10^6 kcal/h -26.57 -27.71 -9.78 -9.78
-
Liquid Mass Enthalpy kcal/kg -507.98 -440.8 -440.8
509.83
Liquid Vapor Pressure kg/cm2[a] 0.56 0.55 11.87 11.87
Liquid Std Density kg/m3 684 683 670 670
L1 Mole Flow kmol/h 630.4 653.9 279.5 279.5
L1 Mass Flow kg/h 52297 54344 22185 22185
L1 Molecular Weight 83 83.1 79.4 79.4
L1 Actual Volume Flow m3/h 78.5 81.8 42.8 42.8
L1 Standard Volume Flow m3/h 76.43 79.62 33.12 33.12
L1 Actual Density SPG 0.666 0.665 0.521 0.518
L1 Enthalpy 10^6 kcal/h -26.57 -27.71 -9.8 -9.78
-
L1 Mass Enthalpy kcal/kg -507.97 -441.83 -440.8
509.82
L1 Std Density kg/m3 684 683 670 670
L1 Pseudocritical
°C 234 233 222 222
Temperature
L1 Pseudocritical Pressure kg/cm2[a] 34.5 34.28 34.76 34.76
L1 Surface Tension dyn/cm 16.8 16.7 5.3 5.3
L1 Viscosity cP 0.294 0.289 0.096 0.095
kcal/(h.m.°
L1 Thermal Conductivity 0.095 0.095 0.061 0.06
C)
L1 UOP K 12.3 12.3 12.5 12.5
 Light Naphtha Isomerization
(ISOM) & Naphtha Splitter
SHIRAZ OIL REFINERY

DOCUMENT NO. CONTRACT NO.:

Proj. Unit Phase Disc. Type Ser. No.
Material Requisition For ‫پ ش‬/٩٨/٢٢/١٢٧
Rev. Chemicals
SISO 1400 EP PR MR 0001 A1 PAGE : 16 of 19

kcal/(kg.°
L1 Specific Heat 0.53 0.532 0.684 0.687
C)

15. GUARANTEE

PURCHASER expects following guarantees to be met by the Chemical VENDOR/SUPPLIER for feed rate.
All of the following items should be included in the technical offer clearly as table below:

DRIER/BED CHEMICAL INFORMATION

Chemical Name
Vendor/Supplier Name
Factory Address
Operating Parameters Unit Data
SOR Temperature @ 88.5 RONC
°C
EOR Temperature @ 88 RONC
H2/ HC mol. Ratio (MIN) mol/mol
Benzene Content In Isomerate vol%
WHSV
C2CL4 Injection Rate (Note 1) kg/hr
Pressure Drop Across the Drier/Bed kg/cm2
Max C7+ in Feed kg/hr
Chemical Life
Total Life year
Shelf Life year
Chemical Physical Properties Unit Data
Shape
Diameter mm
Surface area m2/gr
Total Pore volume
Tapped Bulk Density kg/m3
Loading Density
Crushing Strength N
Attrition Loss wt%
Chemical Properties Unit Data
Active Metal Content wt%
Chloride Content wt%
Nitrogen Poison Level ppm wt
Sulphur Poison Level ppm wt
Water Content Poison Level ppm wt
Other Poison ppm wt
Technical Support
Reference List
Technical Service
 Light Naphtha Isomerization
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SHIRAZ OIL REFINERY

DOCUMENT NO. CONTRACT NO.:

Proj. Unit Phase Disc. Type Ser. No.
Material Requisition For ‫پ ش‬/٩٨/٢٢/١٢٧
Rev. Chemicals
SISO 1400 EP PR MR 0001 A1 PAGE : 17 of 19

Performance Guarantee (Note 2)

Liability
Note1: Vendor/Supplier to advise Chloride agent type and required injection flow rate in SOR and EOR.
Note 2: Chemical VENDOR/SUPPLIER shall stand guarantee for yield, product specification, RON of
product, Benzene content on product 0% vol.

A reference laboratory will be introduced to VENDOR/SUPPLIER in order to carry out performance tests
of chemical and product quality. The successful bidder (winner of the bid) shall deliver a specified value of
sample of its chemical and relevant tests of performance, before receiving any payment from the purchaser.
It should be noted that reference laboratory approval is just considered before PO placement and
VENDOR/SUPLLIER performance guarantee of chemical after PO for start-up will remain in
VENDOR/SUPPLIER commitment.
VENDOR/SUPLLIER to start-up the driers based on product specifications in accordance of MR documents.
The contract will be signed after reference laboratory approval.

15.1 Turndown Guarantees:

The targeted guaranteed turndown ratio is 50% of design feed for the unit.

15.2 Pressure Drop Guarantee:

- Allowable pressure drop for driers/bed shall be in accordance with relevant Process Flow Diagram –
Make up Gas Section, Document No.: "SISO-1400-EB-PR-PFD-0002" and Feed and Regeneration
Section, Document No.: "SISO-1400-EB-PR-PFD-0003".
- Chemical Vendor/Supplier has to give maximum Pressure drop guarantee in the driers/bed.

15.3 Chemical Life Guarantees:

Chemical life shall be specified by VENDOR/SUPPLIER in technical proposal. (Expected time/guarantee
time).

16. Test Method

The following table is licensor test method for main streams of isomerization unit performance test.
Licensor Test Method (Table 5)
Stream and Test Test Method
Fresh Stock Charge
Composition wt% UOP 690
Total Sulphur, wt. ppm wt. ppm UOP 987
Total Nitrogen, wt. ppm wt. ppm UOP 981
Water wt. ppm UOP 481or Analyzer
 Light Naphtha Isomerization
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SHIRAZ OIL REFINERY

DOCUMENT NO. CONTRACT NO.:

Proj. Unit Phase Disc. Type Ser. No.
Material Requisition For ‫پ ش‬/٩٨/٢٢/١٢٧
Rev. Chemicals
SISO 1400 EP PR MR 0001 A1 PAGE : 18 of 19

Dissolved Oxygen wt. ppm UOP 678

Oxygenated Hydrocarbon - UOP 960
Methanol wt. ppm UOP 569
Peroxides wt. ppm ASTM D-2340
Carbonyl wt. ppm UOP 624
Arsenic wt. ppb UOP 992
Lead wt. ppb UOP 952
Copper wt. ppb UOP 962
Fluorides wt. ppm UOP-991 or ASTM D7359
Bromine Number - UOP 304 or ASTM D2710
RON-clear - ASTM D-2699
MON-clear - ASTM D-2700
Makeup Gas
Composition mol % UOP-539
H2S mol-ppm Detector Tube
NH3, Detector Tube
Water, mol-ppm Analyzer
CO/CO2 mol-ppm UOP 603
HCl, mol-ppm UOP-910 or UOP 930 or Detector Tube
Lead Reactor Effluent
Composition wt% UOP 690
Stabilizer Off-Gas
Composition mol-% UOP-539
H2S, mol-ppm Detector Tube
HCl, mol-ppm
Stabilizer Bottoms UOP-910 or UOP 930 or Detector Tube
Composition, wt% UOP-690
RON-Clear - ASTM D-2699
MON-Clear - ASTM D-2700
RVP - ASTM D-323
HCl - UOP 588
Net Gas Scrubber (to Fuel Gas)
HCl, mol-ppm UOP-910 or UOP 930 or Detector Tube
 Light Naphtha Isomerization
(ISOM) & Naphtha Splitter
SHIRAZ OIL REFINERY

DOCUMENT NO. CONTRACT NO.:

Proj. Unit Phase Disc. Type Ser. No.
Material Requisition For ‫پ ش‬/٩٨/٢٢/١٢٧
Rev. Chemicals
SISO 1400 EP PR MR 0001 A1 PAGE : 19 of 19

17. ANNEXURE: LETTER OF CONFIRMITY

Letter of Conformity
TO: …………………………….

FROM: ................................
(VENDOR)

Herewith we confirm that our quotation ...........................................in response to

(QUOTATION)

Your inquiry....................................... dated ..............................................is fully in

(PURCHASER INQUIRY) (DATE)

Accordance with the conditions as stated therein and we confirm that all technical
requirements as stipulated in the above mentioned inquiry documents have been
adhered to, except deviations listed in the exception/deviations form as follows in
the table with this format:

Sr. Section of the MR Page Article or

Requirement Exception Remarks
No. (Material Requisition) No. Paragraph No.

1
2
…

 No Exception / Deviation
 Exceptions/Deviations are mentioned in the attached Table.
------------------------------------------
Date, Signature
(VENDOR)