MATERIAL SAFETY DATA SHEET

SELENIUM (METAL)
Revision : 00 Date: 05.03.2019 MSDS Number : 3152

Section 1 - Chemical Product and Company Identification

1.1 Product Name : SELENIUM (METAL)

Synonyms :-
CAS No. : 7782-49-2
HS Code : 2804 90 00
Molecular Weight : 78.96 g/mol
Chemical Formula : Se
Product Code : A 3152, A 3153, A 3154
Brand : SMART-LAB
1.2 Manufacturer :PT.Smart-Lab Indonesia
Address :Taman TeknoBangunMultiguna Blok M/36,BSD Sektor XI Serpong,
Tangerang - Indonesia
Website :www.smartlab.co.id
Email :[email protected]
For information :Telp: +62-21- 7588 0205(Hunting) , fax:+62-21-7588 0198
1.3 Application : General Chemical reagent
Emergency Telephone: +62-21-7588 0205(Hunting)

Section 2 - Hazards Identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral (Category 3), H301
Acute toxicity, Inhalation (Category 3), H331
Specific target organ toxicity - repeated exposure (Category 2), H373
Chronic aquatic toxicity (Category 4), H413

For the full text of the H-Statements mentioned in this Section, see Section 16

2.2 Label elements

Labelling according Regulation (EC) No 1272/2008

Pictogram

Signal word Danger

Hazard statement(s)
H301 + H331 Toxic if swallowed or if inhaled
H373 May cause damage to organs through prolonged or
repeated exposure.
H413 May cause long lasting harmful effects to aquatic life.

Precautionary statement(s)
P261 Avoid breathing dust.
P301 + P310 IF SWALLOWED: Immediately call a POISON
CENTER/doctor.
P311 Call a POISON CENTER /doctor.
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SELENIUM (METAL)
Revision : 00 Date: 05.03.2019 MSDS Number : 3152

Supplemental Hazard Statements none

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Section 3 - Composition, Information on Ingredients

3.1 Substances
Synonyms : Selenium
Formula : Se
Molecular weight : 78.96 g/mol
CAS-No. : 7782-49-2
EC-No. : 231-957-4

Hazardous ingredients according to Regulation (EC) No 1272/2008

Component Classification Concentration

Selenium
CAS-No. 7782-49-2 Acute Tox. 3; STOT RE 2; Aquatic
<=100 %
EC-No. 231-957-4 Chronic 4; H301, H331, H373, H413
Index-No. 034-001-00-2

For the full text of the H-Statements mentioned in this Section, see Section 16.

Section 4 - First Aid Measures

4.1 Description of first aid measures

General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact

Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Take victim
immediately to hospital. Consult a physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water.
Consult a physician.

4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11

4.3 Indication of any immediate medical attention and special treatment needed
No data available

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Revision : 00 Date: 05.03.2019 MSDS Number : 3152

Section 5 - Firefighting Measures

5.1 Extinguishing media

Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.2 Special hazards arising from the substance or mixture

Selenium/selenium oxides

5.3 Advice for firefighters

Wear self-contained breathing apparatus for firefighting if necessary.

5.4 Further information

No data available

Section 6 - Accidental Release Measures

6.1 Personal precautions, protective equipment and emergency procedures

Wear respiratory protection. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate
ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.

6.2 Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.

6.3 Methods and materials for containment and cleaning up

Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers
for disposal.

6.4 Reference to other sections

For disposal see section 13.

Section 7 - Handling and Storage

7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust
ventilation at places where dust is formed. For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store under inert gas.
Storage class (TRGS 510): Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous
materials causing chronic effects

7.3 Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

Section 8 - Exposure Controls, Personal Protection

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SELENIUM (METAL)
Revision : 00 Date: 05.03.2019 MSDS Number : 3152

8.1 Control parameters

8.2 Exposure controls
Appropriat engineering controls
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling
the product.
Personal protective equipment

Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal
technique (without touching glove's outer surface) to avoid skin contact with this product.
Dispose of contaminated gloves after use in accordance with applicable laws and good
laboratory practices. Wash and dry hands.

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC
and the standard EN 374 derived from it.

Full contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril® (KCL 740, Size M)

Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril® (KCL 740, Size M)

Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be
selected according to the concentration and amount of the dangerous substance at the specific
workplace.

Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use (EN 143)
respirator cartridges as a backup to engineering controls. If th full-face supplied air
respirator. Use respirators and components tested and approved under appropriate
government standards such as NIOSH (US) or CEN (EU).

Control of environmental exposure

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into
the environment must be avoided.

Section 9 - Physical and Chemical Properties

9.1 Information on basic physical and chemical properties

Appearance Form: powder, pellets
Colour: light grey
Odour No data available
Odour Threshold No data available

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SELENIUM (METAL)
Revision : 00 Date: 05.03.2019 MSDS Number : 3152

pH No data available
Melting point/freezingpoint Melting point/range: 217 °C - lit.
Initial boiling point and boiling range 684.9 °C - lit
Flash point Not applicable
Evaporation rate No data available
Flammability (solid, gas) No data available
Upper/lower flammability or No data available
explosive limits No data available
Vapour pressure No data available
Vapour density No data available
Relative density 4.81 g/cm3 at 25 °C
Water solubility insoluble
Partition coefficient: noctanol/water log Pow: 5
Auto-ignition temperature No data available
Decomposition temperature No data available
Viscosity No data available
Explosive properties No data available
Oxidizing properties No data available

9.2 Other safety information

No data available

Section 10 - Stability and Reactivity

10.1 Reactivity
No data available

10.2 Chemical stability

Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

No data available

10.4 Conditions to avoid

Avoid moisture

10.5 Incompatible materials

Strong oxidizing agents, Do not store near acids., Amides, Carbides, Metals, Nickel, Nitric acid, Nitrogen
trichloride, Oxygen, Potassium, Zinc

10.6 Hazardous decomposition products

Hazardous decomposition products formed under fire conditions. - Selenium/selenium oxides Other
decomposition products - No data available
In the event of fire: see section 5

Section 11 - Toxicological Information

11.1 Information on toxicological effects

Acute toxicity
LD50 Oral - Rat - 6,700 mg/kg(Selenium)
Remarks: Behavioral:Somnolence (general depressed activity). Lungs, Thorax, or
Respiration:Dyspnea. Nutritional and Gross Metabolic:Changes in:Other changes

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SELENIUM (METAL)
Revision : 00 Date: 05.03.2019 MSDS Number : 3152

Skin corrosion/irritation
No data available(Selenium)

Serious eye damage/eye irritation

No data available(Selenium)

Respiratory or skin sensitisation

No data available(Selenium)

Germ cell mutagenicity

No data available(Selenium)

Carcinogenicity
This product is or contains a component that is not classifiable as to its classification.(Selenium)
IARC: 3 - Group 3: Not classifiable as to its carcinogenicity to humans (Selenium)

Reproductive toxicity
No data available(Selenium)

Specific target organ toxicity - single exposure

No data available(Selenium)

Specific target organ toxicity - repeated exposure

No data available

Aspiration hazard
May cause damage to organs through prolonged or repeated exposure.

Additional Information
RTECS: VS7700000
anemia, Vomiting, Diarrhoea, Cough, Difficulty in breathing, Acute selenium poisoning produces central
nervous system effects, which in signs of intoxication can include skin eruptions, lassitude, gastrointest
odorous ("garlic") breath, and partial loss of hair and nails. Chronic ex pallor, coating of the tongue,
anemia, irritation of the mucosa, lumbar p previously mentioned symptoms. Chronic contact with selenium
compounds ma moderate emotional instability., Dermatitis, garlic-like breath odor, pallor, nervousness,
depression(Selenium)

Section 12 - Ecological Information

12.1 Toxicity
Toxicity to fish
mortality NOEC - Cyprinodon variegatus (sheepshead minnow) - 2 mg/l - 96.0 h(Selenium)
mortality LOEC - Oncorhynchus mykiss (rainbow trout) - 7.8 mg/l - 96.0 h(Selenium)

Toxicity to daphnia and other aquatic invertebrates

LC50 - Daphnia magna (Water flea) - 0.43 mg/l - 48 h(Selenium)

Toxicity to algae
EC50 - Pseudokirchneriella subcapitata - 99 mg/l - 72 h(Selenium)

12.2 Persistence and degradability

No data available

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Revision : 00 Date: 05.03.2019 MSDS Number : 3152

12.3 Bioaccumulative potential

Bioaccumulation
Lepomis macrochirus - 60 d - 640 µg/l(Selenium)
Bioconcentration factor (BCF): 7.7

12.4 Mobility in soil

No data available(Selenium)

12.5 Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

12.6 Other adverse effects

No data available

Section 13 - Disposal Considerations

13.1 Waste treatment methods

Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material
with a combustible solvent and burn in a chem scrubber.

Contaminated packaging
Dispose of as unused product.

Section 14 - Transport Information

14.1 UN number
ADR/RID: 3288 IMDG: 3288 IATA: 3288
14.2 UN proper shipping name
ADR/RID: TOXIC SOLID, INORGANIC, N.O.S. (Selenium)
IMDG: TOXIC SOLID, INORGANIC, N.O.S. (Selenium)
IATA: Toxic solid, inorganic, n.o.s. (Selenium)
14.3 Transport hazard class(es)
ADR/RID: 6.1 IMDG : 6.1 IATA: 6.1
14.4 Packaging group
ADR/RID: III IMDG: III IATA: III
14.5 Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
14.6 Special precautions for user
No data available

Section 15 - Regulatory Information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.2 Chemical safety assessment
For this product a chemical safety assessment was not carried out

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SELENIUM (METAL)
Revision : 00 Date: 05.03.2019 MSDS Number : 3152

Section 16 - Additional Information

Full text of H-Statements referred to under sections 2 and 3.

H301 Toxic if swallowed.
H301 + H331 Toxic if swallowed or if inhaled
H331 Toxic if inhaled.
H373 May cause damage to organs through prolonged or repeated exposure.
H413 May cause long lasting harmful effects to aquatic life

HMIS (U.S.A.):
Health Hazard: 1
Fire Hazard: 0
Reactivity: 0
Personal Protection: -

National Fire Protection Association (U.S.A.):

Health: 2
Flammability: 0
Reactivity: 0

Further information
The above information is believed to be correct but does not purport to be all inclusive and shall be used only as
a guide. The information in this document is based on the present state of our knowledge and is applicable to
the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties
of the product. PT. Smartlab Indonesia Corporation and its Affiliates shall not be held liable for any damage
resulting from handling or from contact with the above product. See www.sigmaaldrich.com and/or the reverse
side of invoice or packing slip for additional terms and conditions of sale.

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