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RTD LIQUID

Safety Data Sheet


according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
Issue date: 06/02/2023 Revision date: 06/02/2023 Supersedes version of: 24/05/2022 Version: 14.2

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier


Product form : Mixture
Trade name : RTD LIQUID
UFI : D1A0-30EW-U008-TA5R

1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Main use category : Industrial use,Professional use
Industrial/Professional use spec : Industrial
For professional use only
Use of the substance/mixture : Lubricants, Greases and Release Products

1.2.2. Uses advised against


No additional information available

1.3. Details of the supplier of the safety data sheet

Manufacturer
ROCOL a division of ITW Ltd
Rocol House Wakefield Rd, Swillington
LS26 8BS Leeds – West Yorkshire
United Kingdom
T +44 (0)113 232 2600
customer.service@rocol.com - www.rocol.com

1.4. Emergency telephone number


Emergency number : +44 (0)113 232 2600

Country Organisation/Company Address Emergency number Comment


United Kingdom National Poisons Information Service Dudley Road 0344 892 0111 Only for healthcare
(Birmingham Centre) B18 7QH professionals
City Hospital

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture


Classification according to Regulation (EC) No. 1272/2008 [CLP]
Reproductive toxicity, Additional category, Effects on or via lactation H362
Hazardous to the aquatic environment – Acute Hazard, Category 1 H400
Hazardous to the aquatic environment – Chronic Hazard, Category 1 H410
Full text of H- and EUH-statements: see section 16

Adverse physicochemical, human health and environmental effects


No additional information available

2.2. Label elements


Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :

GHS09

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RTD LIQUID
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

Signal word (CLP) : Warning


Contains : C14-C17 CHLORINATED PARAFFIN
Hazard statements (CLP) : H362 - May cause harm to breast-fed children.
H410 - Very toxic to aquatic life with long lasting effects.
Precautionary statements (CLP) : P201 - Obtain special instructions before use.
P263 - Avoid contact during pregnancy and while nursing.
P308+P313 - IF exposed or concerned: Get medical advice/attention.
P391 - Collect spillage.
EUH-statements : EUH066 - Repeated exposure may cause skin dryness or cracking.
EUH208 - Contains 2-(4-methylcyclohex-3-en-1-yl)propan-2-ol(8000-41-7). May produce an
allergic reaction.

2.3. Other hazards


Contains PBT/vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII

Component
C14-C17 CHLORINATED PARAFFIN (85535-85-9) This substance meets the PBT criteria of REACH regulation, annex XIII
This substance meets the vPvB criteria of REACH regulation, annex XIII

The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting
properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %

Component
C14-C17 CHLORINATED PARAFFIN(85535-85-9) The substance is not included in the list established in accordance with Article 59(1) of
REACH for having endocrine disrupting properties, or is not identified as having endocrine
disrupting properties in accordance with the criteria set out in Commission Delegated
Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605

SECTION 3: Composition/information on ingredients

3.1. Substances
Not applicable

3.2. Mixtures

Name Product identifier % Classification according to


Regulation (EC) No. 1272/2008
[CLP]
C14-C17 CHLORINATED PARAFFIN CAS-No.: 85535-85-9 ≥ 70 Lact., H362
substance listed as REACH Candidate (Medium-chain EC-No.: 287-477-0 Aquatic Acute 1, H400 (M=100)
chlorinated paraffins (MCCP)) EC Index-No.: 602-095-00-X Aquatic Chronic 1, H410
PBT substance; vPvB substance REACH-no: 01-2119519269-
33

2-(4-methylcyclohex-3-en-1-yl)propan-2-ol CAS-No.: 8000-41-7 0.1 – 1 Skin Irrit. 2, H315


EC-No.: 701-188-3 Eye Irrit. 2, H319
REACH-no: 01-2119553062- Skin Sens. 1, H317
49 Asp. Tox. 1, H304
Aquatic Chronic 2, H411
Full text of H- and EUH-statements: see section 16

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RTD LIQUID
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

SECTION 4: First aid measures

4.1. Description of first aid measures


First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice.
First-aid measures after inhalation : Allow affected person to breathe fresh air. Allow the victim to rest.
First-aid measures after skin contact : Wash skin with plenty of water. If skin irritation occurs: Get medical advice/attention.
First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness
persists.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.

4.2. Most important symptoms and effects, both acute and delayed
No additional information available

4.3. Indication of any immediate medical attention and special treatment needed
No additional information available

SECTION 5: Firefighting measures

5.1. Extinguishing media


Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixture


No additional information available

5.3. Advice for firefighters


Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire fighting water from entering the environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures


6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders


Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.

6.2. Environmental precautions


Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment.

6.3. Methods and material for containment and cleaning up


Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.
Collect spillage.

6.4. Reference to other sections


See Section 8. Exposure controls and personal protection.

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RTD LIQUID
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

SECTION 7: Handling and storage

7.1. Precautions for safe handling


Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent
formation of vapour. Avoid contact during pregnancy/while nursing. Avoid breathing
dust/fume/gas/mist/vapours/spray.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and other exposed areas
with mild soap and water before eating, drinking or smoking and when leaving work.

7.2. Conditions for safe storage, including any incompatibilities


Storage conditions : Keep only in original container. Keep container closed when not in use.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight.

7.3. Specific end use(s)


No additional information available

SECTION 8: Exposure controls/personal protection

8.1. Control parameters


8.1.1 National occupational exposure and biological limit values
No additional information available

8.1.2. Recommended monitoring procedures


No additional information available

8.1.3. Air contaminants formed


No additional information available

8.1.4. DNEL and PNEC


No additional information available

8.1.5. Control banding


No additional information available

8.2. Exposure controls


8.2.1. Appropriate engineering controls
No additional information available

8.2.2. Personal protection equipment

Personal protective equipment:


Avoid all unnecessary exposure.
Personal protective equipment symbol(s):

8.2.2.1. Eye and face protection

Eye protection:
Chemical goggles or safety glasses

8.2.2.2. Skin protection

Hand protection:
Wear protective gloves. Nitrile rubber gloves

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RTD LIQUID
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

8.2.2.3. Respiratory protection

Respiratory protection:
Not required for normal conditions of use. In case of insufficient ventilation, wear suitable respiratory equipment. Wear a respirator conforming to
EN140 with Type A filter or better

8.2.2.4. Thermal hazards


No additional information available

8.2.3. Environmental exposure controls

Consumer exposure controls:


Avoid contact during pregnancy/while nursing.
Other information:
Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties


Physical state : Liquid
Colour : brown.
Odour : characteristic.
Odour threshold : Not available
Melting point : Not available
Freezing point : Not available
Boiling point : Not available
Flammability : Non flammable.
Explosive limits : Not available
Lower explosion limit : Not available
Upper explosion limit : Not available
Flash point : > 100 °C
Auto-ignition temperature : > 200 °C
Decomposition temperature : Not available
pH : Not available
Viscosity, kinematic : ≈ 110 mm²/s
Solubility : insoluble in water.
Partition coefficient n-octanol/water (Log Kow) : Not available
Vapour pressure : Not available
Vapour pressure at 50°C : Not available
Density : Not available
Relative density : ≈ 1.1
Relative vapour density at 20°C : Not available
Particle characteristics : Not applicable

9.2. Other information


9.2.1. Information with regard to physical hazard classes
No additional information available

9.2.2. Other safety characteristics


VOC content : 0 g/l

SECTION 10: Stability and reactivity

10.1. Reactivity
No additional information available

10.2. Chemical stability


Not established.

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RTD LIQUID
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

10.3. Possibility of hazardous reactions


Not established.

10.4. Conditions to avoid


Direct sunlight. Extremely high or low temperatures.

10.5. Incompatible materials


Strong acids. Strong bases.

10.6. Hazardous decomposition products


fume. Carbon monoxide. Carbon dioxide.

SECTION 11: Toxicological information

11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008


Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified

C14-C17 CHLORINATED PARAFFIN (85535-85-9)


LD50 oral rat > 4000 mg/kg bodyweight Animal: rat

LD50 dermal rabbit > 13500 mg/kg bodyweight Animal: rabbit

2-(4-methylcyclohex-3-en-1-yl)propan-2-ol (8000-41-7)
LD50 oral rat > 2000 mg/kg

LD50 dermal rat > 2000 mg/kg


Skin corrosion/irritation : Not classified
Additional information : Repeated exposure may cause skin dryness or cracking.
Serious eye damage/irritation : Not classified
Additional information : Based on available data, the classification criteria are not met
Respiratory or skin sensitisation : Not classified
Additional information : Based on available data, the classification criteria are not met
Germ cell mutagenicity : Not classified
Additional information : Based on available data, the classification criteria are not met
Carcinogenicity : Not classified
Additional information : Based on available data, the classification criteria are not met
Reproductive toxicity : May cause harm to breast-fed children.
Additional information : May cause harm to breast-fed children.
STOT-single exposure : Not classified
Additional information : Based on available data, the classification criteria are not met
STOT-repeated exposure : Not classified
Additional information : Based on available data, the classification criteria are not met

C14-C17 CHLORINATED PARAFFIN (85535-85-9)


NOAEL (oral, rat, 90 days) 100 mg/kg bodyweight Animal: rat, Guideline: OECD Guideline 408 (Repeated Dose 90-
Day Oral Toxicity in Rodents)
Aspiration hazard : Not classified
Additional information : Based on available data, the classification criteria are not met

RTD LIQUID
Viscosity, kinematic ≈ 110 mm²/s

2-(4-methylcyclohex-3-en-1-yl)propan-2-ol (8000-41-7)
Viscosity, kinematic 8 – 10 mm²/s

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RTD LIQUID
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

11.2. Information on other hazards


11.2.1. Endocrine disrupting properties
No additional information available

11.2.2. Other information


Potential adverse human health effects and : Based on available data, the classification criteria are not met
symptoms

SECTION 12: Ecological information

12.1. Toxicity
Ecology - water : Very toxic to aquatic life with long lasting effects.
Hazardous to the aquatic environment, short–term : Very toxic to aquatic life.
(acute)
Hazardous to the aquatic environment, long–term : Very toxic to aquatic life with long lasting effects.
(chronic)

C14-C17 CHLORINATED PARAFFIN (85535-85-9)


LC50 - Fish [1] > 10000 mg/l Test organisms (species): Alburnus alburnus

LC50 - Fish [2] > 5000 mg/l Test organisms (species): Alburnus alburnus

EC50 - Crustacea [1] 0.0059 mg/l Test organisms (species): Daphnia magna

EC50 - Other aquatic organisms [1] 0.006 mg/l

EC50 72h - Algae [1] > 3.2 mg/l Test organisms (species): Pseudokirchneriella subcapitata (previous names:
Raphidocelis subcapitata, Selenastrum capricornutum)

EC50 96h - Algae [1] > 3.2 mg/l Test organisms (species): Pseudokirchneriella subcapitata (previous names:
Raphidocelis subcapitata, Selenastrum capricornutum)

LOEC (chronic) 0.018 mg/l Test organisms (species): Daphnia magna Duration: '21 d'

NOEC (chronic) 0.01 mg/l Test organisms (species): Daphnia magna Duration: '21 d'

12.2. Persistence and degradability

RTD LIQUID
Persistence and degradability May cause long-term adverse effects in the environment.

12.3. Bioaccumulative potential

RTD LIQUID
Bioaccumulative potential Not established.

12.4. Mobility in soil


No additional information available

12.5. Results of PBT and vPvB assessment

Component
C14-C17 CHLORINATED PARAFFIN (85535-85-9) This substance meets the PBT criteria of REACH regulation, annex XIII
This substance meets the vPvB criteria of REACH regulation, annex XIII

12.6. Endocrine disrupting properties


No additional information available

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RTD LIQUID
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

12.7. Other adverse effects


Additional information : Avoid release to the environment.

SECTION 13: Disposal considerations

13.1. Waste treatment methods


Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to hazardous or special waste collection point, in accordance with local,
regional, national and/or international regulation.
Ecology - waste materials : Avoid release to the environment.

SECTION 14: Transport information


In accordance with ADR / IMDG / IATA / ADN / RID
ADR IMDG IATA ADN RID

14.1. UN number or ID number


UN 3082 UN 3082 UN 3082 UN 3082 UN 3082

14.2. UN proper shipping name


ENVIRONMENTALLY ENVIRONMENTALLY Environmentally hazardous ENVIRONMENTALLY ENVIRONMENTALLY
HAZARDOUS HAZARDOUS substance, liquid, n.o.s. HAZARDOUS HAZARDOUS
SUBSTANCE, LIQUID, SUBSTANCE, LIQUID, SUBSTANCE, LIQUID, SUBSTANCE, LIQUID,
N.O.S. N.O.S. N.O.S. N.O.S.

Transport document description

UN 3082 UN 3082 UN 3082 Environmentally UN 3082 UN 3082


ENVIRONMENTALLY ENVIRONMENTALLY hazardous substance, ENVIRONMENTALLY ENVIRONMENTALLY
HAZARDOUS HAZARDOUS liquid, n.o.s. (C14-C17 HAZARDOUS HAZARDOUS
SUBSTANCE, LIQUID, SUBSTANCE, LIQUID, CHLORINATED SUBSTANCE, LIQUID, SUBSTANCE, LIQUID,
N.O.S. (C14-C17 N.O.S. (C14-C17 PARAFFIN), 9, III N.O.S. (C14-C17 N.O.S. (C14-C17
CHLORINATED CHLORINATED CHLORINATED CHLORINATED
PARAFFIN), 9, III, (-) PARAFFIN), 9, III, MARINE PARAFFIN), 9, III PARAFFIN), 9, III
POLLUTANT

14.3. Transport hazard class(es)


9 9 9 9 9

14.4. Packing group


III III III III III

14.5. Environmental hazards


Dangerous for the Dangerous for the Dangerous for the Dangerous for the Dangerous for the
environment: Yes environment: Yes environment: Yes environment: Yes environment: Yes
Marine pollutant: Yes

No supplementary information available

14.6. Special precautions for user

Overland transport
Classification code (ADR) : M6
Special provisions (ADR) : 274, 335, 375, 601

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RTD LIQUID
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

Limited quantities (ADR) : 5l


Excepted quantities (ADR) : E1
Packing instructions (ADR) : P001, IBC03, LP01, R001
Special packing provisions (ADR) : PP1
Mixed packing provisions (ADR) : MP19
Portable tank and bulk container instructions (ADR) : T4
Portable tank and bulk container special provisions : TP1, TP29
(ADR)
Tank code (ADR) : LGBV
Vehicle for tank carriage : AT
Transport category (ADR) : 3
Special provisions for carriage - Packages (ADR) : V12
Special provisions for carriage - Loading, unloading : CV13
and handling (ADR)
Hazard identification number (Kemler No.) : 90
Orange plates :

Tunnel restriction code (ADR) : -


EAC code : •3Z

Transport by sea
Special provisions (IMDG) : 274, 335, 969
Limited quantities (IMDG) : 5L
Excepted quantities (IMDG) : E1
Packing instructions (IMDG) : LP01, P001
Special packing provisions (IMDG) : PP1
IBC packing instructions (IMDG) : IBC03
Tank instructions (IMDG) : T4
Tank special provisions (IMDG) : TP1, TP29
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-F
Stowage category (IMDG) : A

Air transport
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y964
PCA limited quantity max net quantity (IATA) : 30kgG
PCA packing instructions (IATA) : 964
PCA max net quantity (IATA) : 450L
CAO packing instructions (IATA) : 964
CAO max net quantity (IATA) : 450L
Special provisions (IATA) : A97, A158, A197
ERG code (IATA) : 9L

Inland waterway transport


Classification code (ADN) : M6
Special provisions (ADN) : 274, 335, 375, 601
Limited quantities (ADN) : 5L
Excepted quantities (ADN) : E1
Equipment required (ADN) : PP
Number of blue cones/lights (ADN) : 0

Rail transport
Classification code (RID) : M6
Special provisions (RID) : 274, 335, 375, 601
Limited quantities (RID) : 5L
Excepted quantities (RID) : E1
Packing instructions (RID) : P001, IBC03, LP01, R001
Special packing provisions (RID) : PP1
Mixed packing provisions (RID) : MP19

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RTD LIQUID
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

Portable tank and bulk container instructions (RID) : T4


Portable tank and bulk container special provisions : TP1, TP29
(RID)
Tank codes for RID tanks (RID) : LGBV
Transport category (RID) : 3
Special provisions for carriage – Packages (RID) : W12
Special provisions for carriage - Loading, unloading : CW13, CW31
and handling (RID)
Colis express (express parcels) (RID) : CE8
Hazard identification number (RID) : 90

14.7. Maritime transport in bulk according to IMO instruments


Not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations

REACH Annex XVII (Restriction List)


Contains no substance(s) listed on REACH Annex XVII (Restriction Conditions)

REACH Annex XIV (Authorisation List)


Contains no substance(s) listed on REACH Annex XIV (Authorisation List)

REACH Candidate List (SVHC)


Contains substance(s) listed on the REACH Candidate List in concentrations ≥ 0.1 % or SCL: Medium-chain chlorinated paraffins (MCCP) (EC 287-
477-0, CAS 85535-85-9)

PIC Regulation (Prior Informed Consent)


Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)

POP Regulation (Persistent Organic Pollutants)


Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants)

Ozone Regulation (1005/2009)


Contains no substance(s) listed on the Ozone Depletion list (Regulation EU 1005/2009 on substances that deplete the ozone layer)

VOC Directive (2004/42)


VOC content : 0 g/l

Explosives Precursors Regulation (2019/1148)


Contains no substance(s) listed on the Explosives Precursors list (Regulation EU 2019/1148 on the marketing and use of explosives precursors)

Drug Precursors Regulation (273/2004)


Contains no substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on the manufacture and the placing on market of certain
substances used in the illicit manufacture of narcotic drugs and psychotropic substances)

15.1.2. National regulations


No additional information available

15.2. Chemical safety assessment


No chemical safety assessment has been carried out
For the following substances of this mixture a chemical safety assessment has been carried out:
C14-C17 CHLORINATED PARAFFIN

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RTD LIQUID
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878

SECTION 16: Other information

Indication of changes
Section Changed item Change Comments

Supersedes version of Added

Issue date Added

Revision date Modified

Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labelling and packaging of substances
and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and
amending Regulation (EC) No 1907/2006.
Other information : None.

Full text of H- and EUH-statements:


Aquatic Acute 1 Hazardous to the aquatic environment – Acute Hazard, Category 1

Aquatic Chronic 1 Hazardous to the aquatic environment – Chronic Hazard, Category 1

Aquatic Chronic 2 Hazardous to the aquatic environment – Chronic Hazard, Category 2

Asp. Tox. 1 Aspiration hazard, Category 1

EUH066 Repeated exposure may cause skin dryness or cracking.

EUH208 Contains 2-(4-methylcyclohex-3-en-1-yl)propan-2-ol(8000-41-7). May produce an allergic reaction.

Eye Irrit. 2 Serious eye damage/eye irritation, Category 2

H304 May be fatal if swallowed and enters airways.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.

H362 May cause harm to breast-fed children.

H400 Very toxic to aquatic life.

H410 Very toxic to aquatic life with long lasting effects.

H411 Toxic to aquatic life with long lasting effects.

Lact. Reproductive toxicity, Additional category, Effects on or via lactation

Skin Irrit. 2 Skin corrosion/irritation, Category 2

Skin Sens. 1 Skin sensitisation, Category 1

Safety Data Sheet (SDS), EU

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental
requirements only. It should not therefore be construed as guaranteeing any specific property of the product.

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