a SET-3 ries RP5PS/5 wera aS HATA ar. cose 96/5/3 tai. mare yls | aigis loti perme Se Candidates must write the QP. Code on the title page of the answer-book. | be NOTE | () Persia a a we yew Agha |) Please check that this question | qwstl paper contains 23 printed pages- | GD gansta ed fra ae-wai 93s (II) Please check that this question | a paper contains 33 questions. (nye H afet ga A sik Rema I) wa aie a aterell rer gieraT WE- gen fad | QV) Fen we a AK fret ye wa a (IV) ea, wegen Bower ar ais ora fer | % ay wea wishes tea WV) % * % * - non the right hand ide of the question paper should be written on the title page of the answer-book by the candidate. Please write down the serial number of the question in the answer-book before attempting it. 15 minute time has been allotted QP. Code give * ana fear ran ®t ea—va a freer aie, to read this question paper. The # 10.15 #3 fear Sem | 10.15 A auestion paper wit Sa : at 10.15 a.m. From 10.15 a.m, 10.30 38 we wierd Bat WHA 19.39 a.m., the candidates will ei ote ge stale er aan afer read the question paper only and ge are se el Fer | will not write any answer on the answer-book during this period. TARE faa (Baier) CHEMISTRY (Theory) Pratt ara: 3 92 fama 36 : 70 Maximum Marks : 70 1 win PTO, @ scanned with OKEN ScannerGENERAL INSTRUCTION Read the following instructions carefully and follow them : (i) This question paper contains 83 questions, All questions are compulsory. (ii) Question paper is divided into FIVE sections - Section A, B, C D and E. (iit) Section A - question number I to 16 are multiple choice type Each question carries 1 mark. questions. (iv) Section B - question number 17 to 21 are very short answer 8 questions. Each question carries 2 marks. 29 to 28 are short answer type questions. (v) Section C - question number Each question carries 3 marks. (vi) Section D - question number 29 and 30 are case-based questions. Each question carries 4 marks. (vii) Section E - question number 81 to 83 are long answer type questions. Each question carries 5 marks. tuestion paper. However, an (witi) There is no overall choice given in the @ ons in all the Sections except internal choice has been provided in few quest section A. (ix) Kindly note that there candidates. (x) Use of calculator is NOT allowed. is a separate question paper for Visually Impaired SECTION -A Question No. 1 to 16 are Multiple Choice type Questions, carrying 1 mark each. 16x 1=16 1, Van't Hoff factor for K,SO, solution, assuming complete ionization is (a) 1 @) 3 © 18 @) 2 56/5/3/22 3 PTO. @ scanned with OKEN Scanner2, Dilution affects both conductivity as well as molar conductivity. Effect of dilution on both is as follows : (A) both increase with dilution. (B) both decrease with dilution. (©) conductivity increases whereas molar conductivity decreases on dilution, (D) conductivity decreases whereas molar conductivity increases on dilution. 8. Which of the following species can act as the strongest base? (A) OH™ (8) CgH,O™ o- (©) RO ©) O2N 4. Inwhich of the following molecules, C atom marked with asterisk is chiral ? D i i Oo Ld oo © Afar cay a D H L. te MD pyo% [“*oH,cH, ™ p77 "cx, CH, CH (A) 1,0, 10 (8) 1,0, 10, IV (©) I, WL,IV @) LI, Iv 56/5/3/22 5 nnn P.T.O. @ scanned with OKEN Scanner‘The rate of a reaction increases sixteen times when the concentration of 5. the reactant increases four times. The order of the reaction is, (A) 25 ®) 20 © 15 (D) 05 6. Which of the following cell is used in hearing aids? (A) Mercury cell (B) H,- 0, fuel cell (©) Dry cell (D) Ni-Cd cell 7. Isotonic solutions have the same (A) density (B) refractive index (C)_ osmotic pressure (D) volume 8, Transition metals are known to make interstitial compounds. Formation of interstitial compounds makes the transition metal (A) more hard (B) more soft (©) more ductile (D) more metallic 9, Auto-oxidation of chloroform in air and light produces a poisonous gas known as (A) Phosphine (B) Mustard gas (C) Phosgene (D) Tear gas 56/5/3/22 1 wan PTO. \ @ scanned with OKEN ScannerOut of the following alkenes, the one which will produce tertiary butyl alcohol on acid catalysed hydration is (A) CH,CH,CH = CH, (®) CH,CH = CH, (C) CH,- CH=CH- CHy ©) (CH),C= CH, 11. The correct name of the given reaction is Ar-N}X°_Cu CN/KCN, Ar-CN+Ny (A) Sandmeyer's reaction (B) Gabriel Phthalimide synthesis (©) Carbyl amine reaction (D) Hoffmann bromamide degradation reaction 12. The specific sequence in which amino acids are arranged in a protein is called its (A) Primary structure (B) Secondary structure (C) Tertiary structure (D) Quaternary structure 56/5/9/22 9 wwe PTO. 1 @ scanned with OKEN ScannerAssertion (A) and the other Inbe anawer to these questions from For questions number 13 to 16, two statements are given one labelled ay Hod np Reason (R). Select the correct he coden (A), (B), (6) and (D) as given below : (A) (B) (©) (D) 13. Assertion (A): The units of rate con Reason (R) + In zero order reaction, a4. Assertion (A): Reason (R) 15, Assertion (A) : p-methoxyphenol is a Both Assertion (A) and Reason (R) are true and Reason (R) is the corn ot explanation of the Assertion (A). Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct explanation of Assertion (A). Assertion (A) is true, but Reason (R) is false. Assertion (A) is false, but Reason (R) is true. stant of a zero order reaction and rate of reaction are the same. the rate of reaction is independent of the concentration of reactants. Zr and Hf are of almost similar atomic radii. : This is due to Lanthanoid contraction. tronger acid than m-methoxy phenol. Reason (R) : Methoxy group exerts +R effect at both ortho and para position. 56/5/8/22 11 awww PTO. @ scanned with OKEN ScannerAsserti 3 i ton (A): Inversion of Configuration is observed when . 1-Bromobutane is hydrolysed, aso} : ion ij m(R) + The reaction is Sy2 and proceeds with the formation of transition state, Loe SECTION-B WE (@)- Carry out the following conversions : “GY Nitrobenzene to Aniline 1 (8) Aniline to Phenol 1 OR ©) () Write a chemical test to distinguish between Dimethyl amine and Ethanamine. 1 Gi) Write the product formed when benzene diazonium chloride is treated with KI. 1 18 Define the following terms : 1x2 (@Y Limiting molar conductivity (,°m) Fuel cell 10Ctassity the following sugars into monosaccharides and disaccharides : 2 Sucrose, Lactose, Glucose, Fructose Resistance of a conductivity cell filled with 0.2 mol L-! KCI solution is 200 A. If the resistance of the same cell when filled with 0.05 mol L-! KC) solution is 620 0, calculate the conductivity and molar conductivity of 0.05 mol L~! KCI solution. The conductivity of 0.2 mol L~! KCI solution is 0.0248 S om”. 2 21, A first order reaction takes 40 min for 75% decomposition. Caleulate rate F sonata, a {Given : log 2 = 0.80, log 4 = 0.60] 56/5/3/22 13 wee PTO, ‘ f a @ scanned with OKEN Scanner ooy SECTION-C 22. A compound ‘X’ with molecular formula CgHgN reacts with CH,S0,CI to give a solid, insoluble in alkali, Identify ‘X' i : 7 fy ‘X’ and give the IUPAC name of the product. Write the reaction involved. zi 28/ Account for the following : 1x8 (a) /Haloalkanes react with AgCN to form isocyanide as main product. Allyl chloride shows high reactivity towards Sy1 reaction, ( Haloarenes are extremely less reactive towards nucleophilic substitution reactions. 24. Write the IUPAC names of the following coordination compounds (any three) . ()/{Co(NH,),CINO,)]CI (NINH) ICL, © K,cr(c,0,)3} (@{Cofen),Bry)* 1x3 25, Draw the structures of major product(s) in each of the following reactions : 1x8 0 [Ag(NH3)o]* OH™ on [AgQNHs)2} CHO Hy CH C=C HO ~G-CHs J of NaCN/HCI ( > COOH ene the emf of the following cell : NaOl a Ni(s) + 2Ag*(0.01 M) —> Ni** (0.1 M) + 2Ag(s) Given that Egy = 1.05 V, log 10 = 1 56/5/3122 15 ween PTO. @ scanned with OKEN Scannerae 27. 29. Give the structure of the major product expected from the following reactions : 1x3 (a) Reaction of propanal with methyl magnesium bromide followed by hydrolysis. ; {b)” Reaction of phenol with Br, in CS». ZL / Reaction of propene with diborane followed by oxidation. « Uv ‘The rate constant of a reaction quadruples when the temperature changes from 700 K to 720 K. Calculate the activation energy for this reaction. [log 2 = 0.30, log 4 = 0.60, 2.303 R = 19.15 J K7 mol] SECTION -D ‘The following questions are case-based questions. Read the case carefully and answer the questions that follow : The oxidation number of the central atom in a complex is defined as the charge it would carry if all the ligands are removed along with the election pairs that ate shared with the central atom. Similarly the charge on the complex is the sum of the charges of the constituent parts ie. the sum of the charges on the central metal ion and its surrounding ligands. Based on this, the complex is called neutral if the sum of the charges of the ‘constituents is equal to zero. However, for an anion or cationic complex, the sum of the charges of the constituents is equal to the charge on the coordination sphere. Based on the above information, answer the following questions : oY ‘What isthe secondary viene of Co in [Co(NH),Cl,}"? 1 (0) What type of isomerism is shown by the complex [Cr(H,0),JCl, and [Cr(H,0),CICI, - H,0 ? 1 56/5/3/22 17 enn P.T.O. @ scanned with OKEN Scanner(c) Write the electronic configuration of d‘ ion on the basis of crystal field theory when ‘ @) ay

P Gi) ay>k OR * (6 Find the oxidation state and coordination number of the central metal ion in [Co(H,0) (CN) (en)2]?* 30. Certain organic compounds are required in small amounts in our diet but their deficiency causes specific disease. These compounds are called vitamins. Most of the vitamins cannot be synthesized in our body but plants can synthesize almost all of them. So they are considered as essential focd factors. However, the bacteria of the gut can produce some of the vitamins required by us. All the vitamins are generally available in our diet. The term ‘vitamin’ was coined from the words vital + amine, since the earlier identified compounds had amino group. Vitamins are classified into two groups depending upon their solubility in water or fat namely-fat soluble vitamins and water soluble vitamins. Ce What is the other name of Vitamin B,? (b) Name the vitamin whose deficiency causes increased blood clotting time. 1 (©) Xerophthalmia is caused by the deficiency of which vitamin ? Give two sources of this vitamin. 2 OR of Why can’t vitamin C be stored in our body ? Name the disease caused by the deficiency of this vitamin. 2 56/5/3/22 19 nnn P.T.O. @ scanned with OKEN Scanner31. (@) (i Ishan’s automobile radiator is filled with 1.0 kg of water. How SECTION -E many grams of ethylene glycol (Molar mass = 62 g mol!) must Ishan add to get the freezing point of the solution lowered to — 2.8 °C. K; for water is 1.86 K kg - mol-. Gi) What type of deviation from Raoult’s law is shown by ethanol and acetone mixture ? Give reason. OR (0) GY Boiling point of water at 750 mm Hg pressure is 99.68 °C. How much sucrose (Molar mass = 342 g mol") is to be added to 500 g of water such that it boils at 100 °C ? (K, for water = 0.52 K kg mol"), (ii) State Henry’s law and write its any one application. B+2 32. (a) An organic compound (A) with the molecular formula CyH, 0 forms 2, 4:DNP derivative, reduces Fehling solution and undergoes Cannizzaro reaction, On vigorous oxidation, it gives 1, 2-benzene dicarboxylic acid. (Identify the compound (A) and write its IUPAC name. (ii) Write the reaction of compound (A) with (1) 2, 4-Dinitrophenyl hydrazine and (2) Febling solution ii) Write the equation of compound (A) when it undergoes Cannizzaro reaction. Q2+2+1 OR §6/5/3/22 21 nny P.T.O, d @ scanned with OKEN Scanner©) ~@~“Account for the following : 1x2 (1)}The alpha (a)-hydrogens of aldehydes and ketones are acidic in nature. (Q_-Ofidation of aldehydes is easier than ketones. Gi) Arrange the following in : a (D-Becreasing reactivity towards nucleophilic addition reaction propanal, acetone, benzaldehyde. (2)~ Increasing order of boiling point : ‘fopane, Ethanol, Dimethylether, Propanal Git) Give simple chemical test to distinguish between Benzoic acid and Benzaldehyde. 33. Attempt any five of the following : + CeCIM is easily oxidised to Ce(IV). Comment, (2) E°(Mn”*/Mn) is -1.18 V. Why is this value highly negative in comparison to neighbouring d block elements ? . Which element of 8d series has lowest enthalpy of atomisation and why? (@) What happens when sodium chromate is acidified ? «(0 Zn, Cd and Hg are soft metals. Why ? (©) Why is permanganate titration not carried out in the presence of Hel? * (@ The lower oxides of transition metals are basie whereas the highest are amphoteric/acidic. Give reason. S6i5/8/20 23 4 @ scanned with OKEN Scanner