Revision date: 08/06/2020 Revision: 1024 Supersedes date: 01/02/2019

SAFETY DATA SHEET

ZOK 27

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name ZOK 27

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Mục đích Cleaning compound, turbine engine gas path. Corrosion inhibitor. Hợp chất tẩy rửa, đường dẫn khí động
sử dụng cơ tuabin. Chất ức chế ăn mòn.
1.3. Details of the supplier of the safety data sheet
Supplier McGean-Rohco Singapore Pte Ltd
No.6 Gul Link, Singapore 629376
(65) 6863 2296
[email protected]

Manufacturer ZOK International Group

Airworthy House
Elsted Marsh
Midhurst
West Sussex
GU29 0JT
+44 (0) 333 700 2727
[email protected]

1.4. Emergency telephone number

Emergency telephone +44 333 700 2727 (Mon-Fri 08:30 - 17:00 GMT)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Eye Irrit. 2 - H319

Environmental hazards Not Classified

2.2. Label elements

Hazard pictograms

Signal word Warning

Hazard statements EUH208 Contains Ethanol,2,2'-[[(methyl-1H-benzotriazol-1-yl)methyl]imino]bis-(9Cl). May

produce an allergic reaction.
H319 Causes serious eye irritation.

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Precautionary statements P264 Wash contaminated skin thoroughly after handling.

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/ attention.

UFI UFI: Y300-D0CY-800K-2Y44

Detergent labelling 5 - < 15% non-ionic surfactants, < 5% anionic surfactants

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients Thành phần / Thông tin về các thành phần

3.2. Mixtures

Isotridecylalcohol, ethoxylated 10-30%

CAS number: 69011-36-5

Classification Phân loại mức độ nguy hiểm (vui lòng xem chú thích tại mục 16, trang 10)
Acute Tox. 4 - H302
Eye Irrit. 2 - H319

3-butoxypropan-2-ol 1-5%
CAS number: 5131-66-8 EC number: 225-878-4 REACH registration number: 01-
2119475527-28-XXXX

Classification
Skin Irrit. 2 - H315
Eye Irrit. 2 - H319

Oleoyl Sarcosinic Acid 1-5%

CAS number: 110-25-8 EC number: 203-749-3 REACH registration number: 01-
2119488991-20-XXXX
M factor (Acute) = 1

Classification
Acute Tox. 4 - H332
Skin Irrit. 2 - H315
Eye Dam. 1 - H318
Aquatic Acute 1 - H400

Ethanol,2,2'-[[(methyl-1H-benzotriazol-1-yl)methyl]imino]bis- <1%
(9Cl)
CAS number: 80584-88-9 EC number: 279-501-3 REACH registration number: 01-
2119982397-21-XXXX

Classification
Acute Tox. 4 - H302
Eye Dam. 1 - H318
Skin Sens. 1B - H317

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The full text for all hazard statements is displayed in Section 16.
Ingredient notes Ethanol,2,2'-[[(methyl-1H-benzotriazol-1-yl)methyl]imino]bis-
(9Cl) CAS no. 80584-88-9 / 88477-37-6

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation Move affected person to fresh air at once. Rinse nose and mouth with water. Get medical
attention if any discomfort continues.

Ingestion Do not induce vomiting. Rinse mouth thoroughly with water. Get medical attention if any
discomfort continues.

Skin contact Remove affected person from source of contamination. Take off immediately all contaminated
clothing and wash it before reuse. Wash skin thoroughly with soap and water. Get medical
attention if irritation persists after washing.

Eye contact Remove affected person from source of contamination. Rinse immediately with plenty of
water. Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least
15 minutes. Get medical attention if irritation persists after washing. Show this Safety Data
Sheet to the medical personnel.

4.2. Most important symptoms and effects, both acute and delayed
Inhalation Vapours may irritate throat/respiratory system. Symptoms following overexposure to vapour
may include the following: Coughing, chest tightness, feeling of chest pressure.

Ingestion May cause stomach pain or vomiting.

Skin contact Prolonged contact may cause redness, irritation and dry skin.

Eye contact Irritating to eyes. Symptoms following overexposure may include the following: Redness.
Pain.

4.3. Indication of any immediate medical attention and special treatment needed
Specific treatments Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media The product is not flammable. Use fire-extinguishing media suitable for the surrounding fire.
Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog.

5.2. Special hazards arising from the substance or mixture

Specific hazards None known.

Hazardous combustion Carbon monoxide (CO). Carbon dioxide (CO2).

products

5.3. Advice for firefighters

Protective actions during No specific firefighting precautions known.
firefighting

Special protective equipment Use air-supplied respirator, gloves and protective goggles.
for firefighters

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet.

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6.2. Environmental precautions

Environmental precautions Avoid discharge to the aquatic environment. Collect and dispose of spillage as indicated in
Section 13.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Stop leak if safe to do so. Small Spillages: Absorb spillage with non-combustible, absorbent
material. Collect and place in suitable waste disposal containers and seal securely. Flush
contaminated area with plenty of water. Collect and dispose of spillage as indicated in Section
13. Large Spillages: Contain and absorb spillage with sand, earth or other non-combustible
material. Collect and place in suitable waste disposal containers and seal securely. Flush
contaminated area with plenty of water. Collect and dispose of spillage as indicated in Section
13.

6.4. Reference to other sections

Reference to other sections For personal protection, see Section 8. For waste disposal, see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Avoid spilling. Avoid contact with skin and eyes.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store at temperatures between 4°C and 50°C. Store in tightly-closed, original container. Store
in a dry place.

Storage class Chemical storage.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Occupational exposure limits
Dipropyleneglycol Methyl Ether
Long-term exposure limit (8-hour TWA): WEL 50 ppm 308 mg/m³ vapour
WEL = Workplace Exposure Limit.

Triethanolamine (CAS: 102-71-6)

Ingredient comments No exposure limits known for ingredient(s).

8.2. Exposure controls

Protective equipment

Appropriate engineering Provide adequate ventilation. Observe any occupational exposure limits for the product or
controls ingredients. Avoid inhalation of vapours and spray/mists.

Eye/face protection Wear chemical splash goggles.

Hand protection Wear protective gloves made of the following material: Nitrile rubber.

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Other skin and body Wear appropriate clothing to prevent any possibility of skin contact.
protection

Hygiene measures Do not smoke in work area. Wash at the end of each work shift and before eating, smoking
and using the toilet. Wash promptly with soap and water if skin becomes contaminated.
Promptly remove any clothing that becomes contaminated. Use appropriate hand lotion to
prevent defatting and cracking of skin. When using do not eat, drink or smoke.

Respiratory protection Respiratory protection may be required if excessive airborne contamination occurs. Use
approved respirator if air contamination is above an acceptable level. Wear a respirator fitted
with the following cartridge: Organic vapour filter.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Liquid.

Colour Colourless to pale yellow.

Odour Characteristic.

Odour threshold Not applicable.

pH pH (concentrated solution): 7.2-7.5

Melting point 0°C

Initial boiling point and range 100°C @ 760 mm Hg

Flash point > 100°C Pensky-Martens closed cup.

Evaporation rate Not applicable.

Flammability (solid, gas) Not relevant.

Upper/lower flammability or Lower flammable/explosive limit: Not applicable. Upper flammable/explosive limit: Not
explosive limits applicable.

Vapour pressure Not relevant.

Vapour density Not relevant.

Relative density 1.01 @ 20°C

Solubility(ies) Miscible with water.

Partition coefficient log Pow: < 3

Auto-ignition temperature Not relevant.

Decomposition Temperature Not applicable.

Viscosity 10.44 cSt @ 20°C

Explosive properties Not considered to be explosive.

Oxidising properties The mixture itself has not been tested but none of the ingredient substances meet the criteria
for classification as oxidising.

9.2. Other information

Volatile organic compound This product contains a maximum VOC content of 50 g/L. Average VOC content: 41.2 g/L

SECTION 10: Stability and reactivity

10.1. Reactivity

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Reactivity There are no known reactivity hazards associated with this product.

10.2. Chemical stability

Stability Stable at normal ambient temperatures and when used as recommended.

10.3. Possibility of hazardous reactions

Possibility of hazardous No potentially hazardous reactions known.
reactions

10.4. Conditions to avoid

Conditions to avoid Avoid excessive heat for prolonged periods of time.

10.5. Incompatible materials

Materials to avoid Strong oxidising agents. Strong reducing agents.

10.6. Hazardous decomposition products

Hazardous decomposition Heating may generate the following products: Carbon monoxide (CO). Carbon dioxide (CO2).
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity - oral
ATE oral (mg/kg) 4,508.57

Acute toxicity - inhalation

ATE inhalation (dusts/mists 84.05
mg/l)

Serious eye damage/irritation

Serious eye damage/irritation Causes serious eye irritation.

Skin sensitisation
Skin sensitisation May cause sensitisation by skin contact.

Germ cell mutagenicity

Genotoxicity - in vitro Does not contain any substances known to be mutagenic.

Genotoxicity - in vivo Does not contain any substances known to be mutagenic.

Carcinogenicity
Carcinogenicity Does not contain any substances known to be carcinogenic.

Reproductive toxicity
Reproductive toxicity - fertility Does not contain any substances known to be toxic to reproduction.

Reproductive toxicity - Does not contain any substances known to be toxic to reproduction.
development

Specific target organ toxicity - single exposure

Target organs No specific target organs known.

Specific target organ toxicity - repeated exposure

Target organs No specific target organs known.

Toxicological information on ingredients.

Isotridecylalcohol, ethoxylated

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Acute toxicity - oral

ATE oral (mg/kg) 500.0

Serious eye damage/irritation

Serious eye Irritation of eyes is assumed.

damage/irritation

Respiratory sensitisation

Respiratory sensitisation Not known.

Skin sensitisation

Skin sensitisation Not known.

3-butoxypropan-2-ol

Acute toxicity - oral

Acute toxicity oral (LD₅₀ 2,100.0

mg/kg)

Species Rat

ATE oral (mg/kg) 2,100.0

Oleoyl Sarcosinic Acid

Acute toxicity - oral

Acute toxicity oral (LD₅₀ 9,200.0

mg/kg)

Species Rat

ATE oral (mg/kg) 9,200.0

Acute toxicity - inhalation

Acute toxicity inhalation 1.37

(LC₅₀ dust/mist mg/l)

Species Rat

ATE inhalation 1.37

(dusts/mists mg/l)

SECTION 12: Ecological information

Ecotoxicity Not regarded as dangerous for the environment.

12.1. Toxicity
Acute aquatic toxicity
Acute toxicity - fish LC₅₀, 96 hours: 33 mg/l, Marinewater fish
EC₅₀, 96 hours: >0.02 %, Pimephales promelas (Fat-head Minnow)

Acute toxicity - aquatic EC₅₀, 48 hours: >0.01 %, Daphnia magna

invertebrates

Acute toxicity - aquatic plants EC₅₀, 72 hours: 8.1 mg/l, Marinewater algae

Acute toxicity - LC₅₀, 10 days: 1267 mg/kg, Activated sludge

microorganisms

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12.2. Persistence and degradability

Persistence and degradability The surfactant(s) contained in this product complies(comply) with the biodegradability criteria
as laid down in Regulation (EC) No. 648/2004 on detergents. The product is biodegradable
but it must not be discharged into drains without permission from the authorities.

Biodegradation The substance is readily biodegradable.

Biological oxygen demand < 0.1 g O₂/g substance

Chemical oxygen demand < 8.5 g O₂/g substance

12.3. Bioaccumulative potential

Bioaccumulative potential The product does not contain any substances expected to be bioaccumulating.

Partition coefficient log Pow: < 3

12.4. Mobility in soil

Mobility The product is miscible with water and may spread in water systems.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects

Other adverse effects None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information Waste should be treated as controlled waste. Dispose of waste to licensed waste disposal site
in accordance with the requirements of the local Waste Disposal Authority.

Disposal methods Collect and place in suitable waste disposal containers and seal securely. Dispose of waste to
licensed waste disposal site in accordance with the requirements of the local Waste Disposal
Authority.

SECTION 14: Transport information

General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, ADR/RID).

14.1. UN number
Not applicable.

14.2. UN proper shipping name

Not applicable.

14.3. Transport hazard class(es)

No transport warning sign required.

14.4. Packing group

Not applicable.

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

No.

14.6. Special precautions for user

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Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations The surfactant(s) contained in this product complies(comply) with the biodegradability criteria
as laid down in Regulation (EC) No. 648/2004 on detergents.
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (SI 2009
No. 716).

EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).

Guidance Workplace Exposure Limits EH40.

Authorisations (Annex XIV No specific authorisations are known for this product.
Regulation 1907/2006)

Restrictions (Annex XVII No specific restrictions on use are known for this product.
Regulation 1907/2006)

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

Inventories
EU - EINECS/ELINCS
All the ingredients are listed or exempt.

Canada - DSL/NDSL
All the ingredients are listed or exempt.

US - TSCA
All the ingredients are listed or exempt.

Australia - AICS
All the ingredients are listed or exempt.

Japan - ENCS
All the ingredients are listed or exempt.

Korea - KECI
All the ingredients are listed or exempt.

China - IECSC
All the ingredients are listed or exempt.

Philippines – PICCS
All the ingredients are listed or exempt.

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New Zealand - NZIOC

All the ingredients are listed or exempt.

SECTION 16: Other information

General information Only trained personnel should use this material.

Classification procedures Eye Irrit. 2 - H319: Calculation method.

according to Regulation (EC)
1272/2008

Issued by Craig Appleby - Chemist

Revision date 08/06/2020

Revision 1024

Supersedes date 01/02/2019

SDS number 4524

SDS status Approved.

Hazard statements in full H302 Harmful if swallowed. Nguy hiểm nếu nuốt phải
H315 Causes skin irritation. Gây kích ứng da
H317 May cause an allergic skin reaction. Có thể gây phản ứng dị ứng da
H318 Causes serious eye damage. Gây tổn thương mắt nghiêm trọng
H319 Causes serious eye irritation. Gây kích ứng mắt nghiêm trọng
H332 Harmful if inhaled. Có hại nếu hít phải
H400 Very toxic to aquatic life. Rất độc đối với động thực vật thủy sinh
H412 Harmful to aquatic life with long lasting effects. Có hại cho đời sống thủy sinh với những ảnh hưởng
lâu dài
EUH208 Contains Ethanol,2,2'-[[(methyl-1H-benzotriazol-1-yl)methyl]imino]bis-(9Cl). May
produce an allergic reaction.

Signature Craig Appleby

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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