Unit 1 Assignment

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Chemistry 534 Name_______________

Selwyn House Date________________

Unit 1 Gases - Assignment Sheet

1. Differentiate between the following classifications of gases: toxic,


combustible, and volatile. Cite an example of each.

2. Liquid oxygen will vaporize at -182oC. Why can't liquid oxygen exist
at room temperature ? Explain using the terms, intermolecular
attraction and kinetic energy of the molecules.

3. State Avogadro's hypothesis.

4. Helium has a density of 0,1805 g/L at a certain temperature and


pressure. What is the molar volume of this sample of helium ?

5. At 25oC and 101,3 kPa, 14,0 g of hydrogen will occupy what volume?

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Unit 1-Ass. Sheet

6. Acetylene gas is formed as follows:

___CaC2(s) + ___H2O(l) ___Ca(OH)2(s) + ___C2H2(g)

Balance the above equation. Calculate the number of litres of acetylene


gas that would be produced at 25oC and 101,3 kPa if 100,0 g of calcium
carbide was placed into 50,0 mL of water.

7. How many molecules are present in 125 g of a gas that occupies 95 L at


STP ?

8. A chlorine gas tanker broke up in a major highway accident in the Alberta Rockies, in the
month of January
Discuss the movement of the toxic fumes based on:

a) the high altitude

b) the cold temperature

c) the density of the gas

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Unit 1-Ass. Sheet

9. 64,0 g of oxygen and 14,0 g of nitrogen are mixed in a jar. They exert a
pressure of 1,00 x 102 kPa together at 25oC.

a) What are the partial pressures of the two gases ?

b) What is the volume of the container ?

10. If you had a 1,0 L flask of ammonia and a 1,0 L flask of carbon dioxide,
both at STP, which flask has molecules with:

a) the greater total mass ? ________


b) the greater average speed ? ________
c) the greater number of molecules ? ________
d) the greater average kinetic energy ? ________

11. Given the set-up shown below:

10.0L 20.0L
200.0kPa 100.0kPa 5.0L, 200.0kPa

a) Gases A and C (from the balloons) are added to gas B in the


20,0 L container. What would be: PA, PB, PC, and PTotal ?

b) If gas A and gas B react chemically when mixed to form gas C,


(3A + B C )what would be: PA, PB, PC, and PTotal

Unit 1-Ass. Sheet

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12. a) The volume of a gas can be increased by doing what to each of
the following ? (assume only volume is affected by each change)

Temperature ____________

Pressure ____________

Moles ____________

b) The pressure of a gas can be increased by doing what to each of


the following ? (assume only pressure is affected by each change)

Volume ____________

Temperature ____________

Moles ____________

13. The gas inside a balloon of volume 12,3 m3 is heated from 25oC to 125oC.
Find the new volume (in L) of the balloon. Assume P remains constant.

Unit 1-Ass. Sheet

14. A sample of a gas at a pressure of 99 kPa and a temperature of 301 K


is transferred from a container of volume 0,98 L to one of volume

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24 mL. The new temperature is 195 K after transferring. What is the
new pressure of the gas ?

15. A gas occupies a volume of 24,5 L at 298 K and 202,6 kPa. Find its
volume at STP.

16. A compressed gas cylinder contains 106 g of acetylene at a pressure of


5,1 x 103 kPa. After some use of the acetylene by the welder, the
pressure drops to 4,2 x 103 kPa. Find the mass of the acetylene used,
assuming temperature remains constant.

Unit 1-Ass. Sheet

17. A steel container of volume 0,35 L can withstand pressures up to


8,8 x 103 kPa before exploding. What mass of hydrogen gas can be

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stored in this container at 25oC without it exploding ?

18. A 1,00 g sample of water is placed in a sealed, evacuated 1,0 L


container and heated to 225oC. What would be the pressure inside
the container ?

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