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    Topic 10

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    洪允升
    1. The document discusses chemical equilibrium in a multi-component system with multiple chemical reactions. 2. It defines the equilibrium criterion for such a system as the minimization of Gibbs free energy with respect to mole numbers over time for each component in each phase under constant pressure and temperature. 3. The extent of reaction for each reaction is defined in terms of the change in mole numbers of reactants and products over time according to the stoichiometric coefficients of the chemical reaction.

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    Topic 10

    Uploaded by

    洪允升
    17 views3 pages
    1. The document discusses chemical equilibrium in a multi-component system with multiple chemical reactions. 2. It defines the equilibrium criterion for such a system as the minimization of Gibbs free energy with respect to mole numbers over time for each component in each phase under constant pressure and temperature. 3. The extent of reaction for each reaction is defined in terms of the change in mole numbers of reactants and products over time according to the stoichiometric coefficients of the chemical reaction.

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    1. The document discusses chemical equilibrium in a multi-component system with multiple chemical reactions. 2. It defines the equilibrium criterion for such a system as the minimization of Gibbs free energy with respect to mole numbers over time for each component in each phase under constant pressure and temperature. 3. The extent of reaction for each reaction is defined in terms of the change in mole numbers of reactants and products over time according to the stoichiometric coefficients of the chemical reaction.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    17 views3 pages

    Topic 10

    Uploaded by

    洪允升
    1. The document discusses chemical equilibrium in a multi-component system with multiple chemical reactions. 2. It defines the equilibrium criterion for such a system as the minimization of Gibbs free energy with respect to mole numbers over time for each component in each phase under constant pressure and temperature. 3. The extent of reaction for each reaction is defined in terms of the change in mole numbers of reactants and products over time according to the stoichiometric coefficients of the chemical reaction.

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    © All Rights Reserved
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    Download as pdf or txt
    of 3

    Topic 10 :

    Mature : Equlibrium
    1o 1 Gieriafor efulibinm mulh
    n
    omponent sy 5em
    . _
    ,

    solaed V V , :
    Smax 77 0
    sgen
    =

    C :
    l = 0
    ,

    1 dosed 7 .
    V :
    Amin
    >
    P =
    0

    ☆ G :
    :
    ( dv =
    7ds -

    Pdv G
    + )

    C >| Sameas (
    = JT =
    O

    OP = O

    Gi= for ali 0

    ( dv 2ds Pdv +Ʃ GidNi )


    : -

    l0 .
    2 Chemical reaolionand Giarniafor chemicalequilibrinm ,

    2A +β B γ R+σS

    γ R + OS -α A

    -β
    B
    = Ʃ uiI =
    O
    Mi
    t
    poduce
    -

    reactant

    Ni (t) =
    Nilt : o 1 -

    ui Xe ) ( Xi eatent of an)

    Consider a
    ,
    single muleironponent ayseem .
    I an
    ,
    at onst 下 . P

    zealtor

    qilibrinmcrroria : Gomn
    ⼼ 、 N

    ( t) 鸠
    c 7, , )=
    G Ʃ N iGi
    (
    Ψ

    Ni " Iui (x ) ) G
    P

    =
    , ( (τ . P x , )
    [=| Ʃ
    N3 N4
    ( Ni
    =
    Ni I
    µ i λ *s )
    G

    ,
    G (x) =
    Ʃ (Ni
    0
    uix ) G ( x τ P )
    +
    .
    ,

    找点 ,
    微分 ! Gmm

    & :
    0 at
    equiGb ,
    :
    0 x ?

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