Week 6-CHEM4015-CIVE4140-2023-2024
Week 6-CHEM4015-CIVE4140-2023-2024
Week 6-CHEM4015-CIVE4140-2023-2024
(CHEM4015/CIVE4140)
Week 6
Design of Treatment Systems
Microbial Kinetics and ASP Design
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Metcalf & Eddy, Inc. (2003). Wastewater engineering: treatment, disposal and reuse.4th edition, McGraw Hill, Inc., New York, NY
Yield Coefficient, Y
Object of biological
wastewater treatment
Rate of consumption,
dS/dt = rsu
rsu : Rate of substrate concentration change
Michaelis-Menten expression due to utilization gm/m3.d
Consequence of enzyme- k : Maximum specific substrate utilization
rate, g substrate/g microorganism.d
substrate reaction kinetics X : Biomass (microorganism) concentration,
E + S ES E +P gm/m3
S : Growth limiting substrate concentration in
solution, gm/m3
Ks = Substrate concentration at one half the
maximum specific substrate utilization rate,
gm/m3
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Bacterial Growth
Consequence of biological wastewater treatment
Rate of growth, dX/dt = rg
Max specific growth rate = μm (=rgm/X)
Related to substrate consumption by Y
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Microbial Growth
rg also related to rsu by Y
rg = -Y rsu
Endogenous decay
Cell material consumed for maintenance energy
Cell death and predation
rd = kd X
Therefore:
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Microbial Growth
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Specific Growth Rate, μ
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PART-B
Application of Kinetics to
Bioreactor Design
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Key Biokinetic Equations
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General Approach
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A Simple Case – Single Pass CSTR
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Assumptions
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Microorganism Mass (Rate)
Balance – Single Pass CSTR
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Single Pass CSTR 1/6
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Single Pass CSTR2/6
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Single Pass CSTR3/6
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Single Pass CSTR4/6
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Single Pass CSTR5/6
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Single Pass CSTR6/6
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So controlling performance ain’t that easy!
Efficiency is a function of X and t
X is a function of S
S is a function of t
So S, X, and efficiency are all interrelated and fixed by t in
a single pass CSTR system. Cannot change any of them
without changing t (i.e., tank volume).
But if could change X independent of t , then could,
theoretically, obtain any removal efficiency (and X and S)
desired with any size tank.
Requires a different system than single pass CSTR
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References
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