Week 6-CHEM4015-CIVE4140-2023-2024

Download as pdf or txt
Download as pdf or txt
You are on page 1of 24

Waste Treatment Processes

(CHEM4015/CIVE4140)
Week 6
Design of Treatment Systems
Microbial Kinetics and ASP Design

Lecturer Name: Dr Nitin Raut


Dr Amal Al Saadi
Prof Rajamohan Natarajan
Academic Year: 2023-2024
Kinetics of Microbial Growth
 Purpose--primarily to stabilize organic content, usually by removal
via CO2 and conversion to biomass; also coagulates colloidal solids,
can target nutrients like nitrogen and phosphorus for removal
 Bacteria--a wide variety are primary microorganisms responsible for
treatment--empirical formula C5H7O2N; P0.08 if relevant

2
3
Metcalf & Eddy, Inc. (2003). Wastewater engineering: treatment, disposal and reuse.4th edition, McGraw Hill, Inc., New York, NY
Yield Coefficient, Y

 Part of substrate goes to cell material production. Part


goes to energy production.
 Substrate consumption often measured as BOD
 Can be computed from stoichiometrics or energetics for
single compounds
 Measured in laboratory for complex mixtures
 Aerobic Y typically 0.3 to 0.5.
 “Synthesis” or “true” vs. “Observed” yield
4
Substrate Consumption

 Object of biological
wastewater treatment
 Rate of consumption,
dS/dt = rsu
rsu : Rate of substrate concentration change
 Michaelis-Menten expression due to utilization gm/m3.d
 Consequence of enzyme- k : Maximum specific substrate utilization
rate, g substrate/g microorganism.d
substrate reaction kinetics X : Biomass (microorganism) concentration,
E + S  ES E +P gm/m3
S : Growth limiting substrate concentration in
solution, gm/m3
Ks = Substrate concentration at one half the
maximum specific substrate utilization rate,
gm/m3
5
6
Bacterial Growth
Consequence of biological wastewater treatment
Rate of growth, dX/dt = rg
Max specific growth rate = μm (=rgm/X)
Related to substrate consumption by Y

 Substitute 7-14 into 7-12:

7
Microbial Growth
 rg also related to rsu by Y
rg = -Y rsu
 Endogenous decay
Cell material consumed for maintenance energy
 Cell death and predation
rd = kd X
 Therefore:

8
Microbial Growth

9
Specific Growth Rate, μ

10
PART-B
Application of Kinetics to
Bioreactor Design

11
Key Biokinetic Equations

12
General Approach

Develop mass balances for microorganisms and


substrate
Derive equations to predict X and S in terms of
system parameters (design equations)

13
A Simple Case – Single Pass CSTR

14
Assumptions

 System operating at steady state


– Q, So, Xo, S, X, and V all constant
 Reactor is completely mixed
– Reactor concentrations = effluent concentrations
 Xo = 0
note: Active (substrate-removing) microbial concentration, X, is approximated by MLVSS

15
Microorganism Mass (Rate)
Balance – Single Pass CSTR

16
Single Pass CSTR 1/6

17
Single Pass CSTR2/6

18
Single Pass CSTR3/6

19
Single Pass CSTR4/6

20
Single Pass CSTR5/6

21
Single Pass CSTR6/6

22
So controlling performance ain’t that easy!
 Efficiency is a function of X and t
 X is a function of S
 S is a function of t
 So S, X, and efficiency are all interrelated and fixed by t in
a single pass CSTR system. Cannot change any of them
without changing t (i.e., tank volume).
 But if could change X independent of t , then could,
theoretically, obtain any removal efficiency (and X and S)
desired with any size tank.
 Requires a different system than single pass CSTR
23
References

1. Metcalf & Eddy, Inc. (2003). Wastewater engineering:


treatment, disposal and reuse.4th edition, McGraw Hill, Inc.,
New York, NY
2. https://studylib.net/doc/5496826/wastewater-characterization

24

You might also like