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    Quiz-General Organic Chemistry & Isomerism-Snd - SND

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    ayesha sheikh
    1. The order of basicity is IV > I > III > II. 2. The basic strength order is 4 > 1 > 2 > 3. 3. p-NO2C6H4-CH2 is the most stable species. 4. The stability order of the carbocations is I > III > II > IV.

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    Quiz-General Organic Chemistry & Isomerism-Snd - SND

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    ayesha sheikh
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    1. The order of basicity is IV > I > III > II. 2. The basic strength order is 4 > 1 > 2 > 3. 3. p-NO2C6H4-CH2 is the most stable species. 4. The stability order of the carbocations is I > III > II > IV.

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    QUIZ-GENERAL ORGANIC CHEMISTRY & ISOMERISM-SND_SND_

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    1. The order of basicity is IV > I > III > II. 2. The basic strength order is 4 > 1 > 2 > 3. 3. p-NO2C6H4-CH2 is the most stable species. 4. The stability order of the carbocations is I > III > II > IV.

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    © All Rights Reserved
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    Download as pdf or txt
    18 views4 pages

    Quiz-General Organic Chemistry & Isomerism-Snd - SND

    Uploaded by

    ayesha sheikh
    1. The order of basicity is IV > I > III > II. 2. The basic strength order is 4 > 1 > 2 > 3. 3. p-NO2C6H4-CH2 is the most stable species. 4. The stability order of the carbocations is I > III > II > IV.

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    © All Rights Reserved
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    of 4

    QUIZ (CHEMISTRY)

    GENERAL ORGANIC CHEMISTRY & ISOMERISM


    NAME: ………………................ M.MARKS: M.Time: minutes SUB: CHEMISTRY

    1. In the following compounds:


    O

    .. N
    N N N
    H
    H H
    (I) (II) (III) (IV)

    The order of basicity is


    (A) IV>I>III>II (B) III>I>IV>II (C) II>I>III>IV (D) I>III>II>IV
    2. What is the basic strength order of the following?
    H (2)
    (I) (3) (4) NH
    .. 2
    N: CH3
    ..
    N: C N: C NH
    NH2
    ..

    (A) 1>2>3>4 (B) 4>1>2>3 (C) 4>3>1>2 (D) 3>4>1>2


    3. Which of the following species is most stable?
     
    (A) p-NO2C6H4-CH2 , (B) C6H5CH2 ,

      
    (C) p- C l -C6H4- C H2 , (D) p-H3CO-C6H4- C H2

    4. The stability order of the following carbocations is


    +
    + +
    +
    () () () (V)
    (A) (I)  (II)  (III)  (IV ) (B) (II)  (IV )  (III)  (I)
    (C) (IV )  (III)  (II)  (I) (D) (II)  (III)  (I)  (IV )
    5. The strongest base among the following is
    (A) CH3NH2 (B) C6H5NH2 (C) C6H5NHC6H5 (D) (C6H5)3N
    6. Among the following which is the strongest acid?
    (A) CH3 C HOH (B) C H2  CH2  OH (C) C H2OH  CH2 (D) CH3CH2OH
    | | |
    F F Cl
    7. The stable intermediate among the following is
    (A) NC-CH2+ (B) O2N-CH2+ (C) F3C-CH2+ (D) MeO-CH2+
    8. Which of the following can not show electrometric effect?
    (A) alkenes (B) ketones (C) aldehydes (D) ethers
    9. The correct arrangement of acid strength is decreasing order is
    (A) (CH3)3CCOOH CH3COOH CCl3COOH  O2NCH2COOH
    (B) CH3COOH  (CH3)3C COOH O2NCH2COOH  CCl3COOH
    (C) O2NCH2COOH  (CH3)3CCOOH  CH3COOH  CCl3COOH
    (D) CCl3COOH  O2NCH2COOH  CH3COOH  (CH3)3CCOOH
    10. Among the following which is strongest base
    (A) (B) NH 2 (C) NH2 (D) NH2
    CH2 NH2 CH3

    NO2

    11. The maximum number of stereoisomers possible for 3-hydroxy-2-methyl butanoic acid is
    (A) 1 (B) 2 (C) 3 (D) 4
    12. The enolic form of acetone contains
    QUIZ (CHEMISTRY)
    (A) 9  bonds, 1  bond and 2 lone pairs (B) 8  bonds, 2 bonds and 2 lone pairs
    (C) 10  bonds, 1  bond and 1 lone pair (D) 9  bonds, 2  bonds and 1 lone pair
    13. Geometrical isomerism is shown by
    H I H I
    (A) C=C (B) C=C
    H Br H3C Br

    H3C CI H CI
    (C) (D) C=C
    C=C
    H3C Br H3C Cl

    14. Which of the following has the least heat of hydrogenation?


    (A) 1-butene (B) Cis-2-butene (C) trans-2-butene (D) 1- pentene

    15. The compound which gives most unstable carbonium ion on dehydration is
    CH CF3
    3
    (A) CH3-CH2-OH (B) I (C) (D) I
    CH3  C  OH CH3  CH  CH  OH CF3  C  OH
    2
    I I I
    CH CH CF3
    3 3

    16. The number of hyperconjugable hydrogen atom in this species is


    CH3
    CH3—C—CH2
    CH3
    (A) Zero (B) Nine (C) Two (D) Four
    17. Keto-enol tautomerism is observed in
    (A) C6H5-CHO (B) C6H5COCH2COCH3 (C) C6H5-CO-C6H5 (D) All of these
    18. The following compound can exhibit
    CH3 H

    C=C H
    C2H5 C
    CH3 COOH
    (A) geometrical isomerism (B) geometrical and optical isomerisms
    (C) optical isomerism (D) tautomerism
    19. The total number of isomeric optically active monochloro isopentane is:
    (A) two (B) three (C) four (D) one

    20. Which of the following structures are superimpossable?


    H Br Br Me
    Br Me H Me Me Br
    H H
    HO Et Et OH
    Et Me HO Et
    Me
    Me (2) OH Me
    (1) (3) (4)
    (A) 1 and 2 (B) 2 and 3 (C) 1 and 4 (D) 1 and 3
    21. Which one of the following compounds has maximum enol content in solution?
    O O O O
    (A) (B) (C) (D)
    CN
    H3C O CH3
    H3C
    H3C CH3 O

    22. In which of the following alcohols C – O bond breaks (heterolytically) with greatest eases:
    CH3 CH3
    CH3
    (A) CH3CH2CH2OH (B) (C) CH3 – C – OH (D) CH3 – C – CH2 – OH
    CH3 – CH – OH CH3
    CH3
    23. How many possible number of optical isomers can be observed for 2, 3-dichloro, butane-2,3-diol?
    QUIZ (CHEMISTRY)
    (A) 2 (B) 3 (C) 4 (D) 6

    24. The number of asymmetric carbon atoms and the number of optical isomers in CH3(CHOH)2 COOH
    are respectively
    (A) 3 and 4 (B) 1 and 3 (C) 2 and 4 (D) 2 and 3

    25. Assign R and S configuration to the C2 and C3 (carbon atom)


    COOH

    H2 N 2 H

    H 3
    OH

    CH3
    (A) R, R (B) S, S (C) R, S (D) S, R

    26. The number of isomers for the aromatic compounds having M. F. C7H8O is:
    (A) two (B) three (C) four (D) five

    27. Arrange basicity of the given compounds in decreasing order:


    (1) CH3CH2NH2 (2) CH 2  CH  NH 2 (3) CH  C  NH2
    (A) 1 > 2 > 3 (B) 1 > 3 > 2 (C) 3 > 2 > 1 (D) 2 > 3 > 1

    28. Which one of the following compounds will not show tautomerism?
    O CH 3 O
    || | ||
    (A) C H  C  C  CH (B) CH 3  CH 2  C  CH 2  COOC 2 H 5
    6 5 3
    |
    CH 3
    O
    ||
    (C) CH 3  C  CH 3 (D) CH3  CH2  C  N

    29. What is the correct increasing order of bond lengths of the bonds indicated as I, II, III as IV in the
    following compound?

    (A) I < II < III < IV (B) II < III < IV < I (C) IV < II < III < I (D) IV < I < II < III

    30. For which of the following molecules   0:

    (A) Only I (B) I and II (C) Only III (D) III and IV

    
    QUIZ (CHEMISTRY)
    ANSWERS
    GENERAL ORGANIC CHEMISTRY & ISOMERISM

    1. C 2. B 3. D 4. B

    5. A 6. A 7. D 8. D

    9. D 10. A 11. D 12. A

    13. B 14. C 15. D 16. A

    17. B 18. B 19. C 20. D

    21. C 22. B 23. C 24. D

    25. C 26. B 27. A 28. A

    29. D 30. D

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