PNABX861
PNABX861
Preparedfor the
Romanian Energy and Electricity Authority
(RENEL)
Section Page
1 Introdu ction ....................................................................................................... 1-1
1.1 Background ............................................................................................... 1-1
1.2 Report Organization ................................................................................ 1-2
2 Summary, Conclusions, and Recommendations ....................................... 2-1
2.1 Ash Disposal Methods ............................................................................ 2-2
2.2 Industrial and Commercial Uses for Ash........................................... 2-2
2.3 In-Plant Ash Handling Practices ........................................................... 2-5
2.3.1 Bottom Ash ................................................................................... 2-5
2.3.2 Pulverizer Rejects ........................................................................ 2-5
2.3.3 Economizer Ash ........................................................................... 2-6
2.3.4 Fly Ash System ............................................................................. 2-6
2.4 Transport to Impoundment .................................................................. 2-6
2.5 Conclusions and Recommendations .................................................. 2-7
3 Current Ash Handling and Disposal Provisions in Romanian
Power Plants...................................................................................................... 3-1
3.1 Ash Disposal Provisions ........................................................................ 3-1
3.2 Ash collection and Transport to Disposal .......................................... 3-5
3.3 Shortcomings of the Current System .................................................. 3-5
4 Ash Disposal and Soil Reclamation ............................................................. 4-1
4.1 Industrial and Commercial Uses of Ash ............................................ 4-1
4.1.1 High Volume - Low Technology Uses .................................... 4-3
4.1.2 Medium Technology Uses ......................................................... 4-5
4.1.3 High Technology Uses ................................................................ 4-7
Section Page
4.1.4 Research and Marketing Activities.......................................... 4-8
4.1.5 Economic Considerations .......................................................... 4-8
4.2 Ash Disposal by Containment .............................................................. 4-9
4.2.1 Western Ash Disposal Practices .................... 4-10
4.2.3 U.S. Environmental Regulations ............................................. 4-13
4.2.4 Current Ash Disposal Practices in the United States ........... 4-15
4.3 Modern Land Reclamation Practices ................................................... 4-16
4.3.1 Revegetation ................................................................................. 4-16
4.3.2 Engineering Considerations ...................................................... 4-19
4.4 Conclusions and Recommendations .................................................. 4-22
4.4.1 Past Disposal Sites ........................................................................ 4-23
4.4.2 Future Disposal Practices ............................................................ 4-24
4.4.3 Further Studies ............................................................................. 4-28
4.5 Bibliography .............................................................................................. 4-30
5 Western Experience with Ash Handling Systems ................................... 5-1
5.1 Ash Collection .......................................................................................... 5-1
5.2 History of Ash Collection Practices in North America ................... 5-2
5.3 Bottom Ash Handling ............................................................................ 5-3
5.3.1 Submerged Chain Conveyor ..................................................... 5-4
5.3.2 Dry Bottom Ash Conveyor ........................................................ 5-9
5.4 Pulverizer (Mill) Rejects ........................................................................ 5-11
5.4.1 Historic Practice ............................................................................ 5-11
5.4.2 Current Practice ............................................................................ 5-11
Section Page
5.5 Economizer Ash....................................................................................... 5-12
5.5.1 Air-Heater Problems from Plugged Economizer
Hoppers .......................................................................................... 5-13
5.6 Fly Ash ....................................................................................................... 5-14
5.6.1 Fly Ash Systems ........................................................................... 5-15
5.6.2 Pneumatic Fly Ash Removal Systems .................................... 5-18
5.6.3 Vacuum System Controls .......................................................... 5-19
5.6.4 Positive-Pressure System Control ............................................ 5-20
5.6.5 Basic Hopper Design .................................................................... 5-22
5.6.6 Fly Ash Removal Systems and the Precipitator .................... 5-26
5.6.7 Fan Damage from Fly Ash Carryover ..................................... 5-29
5.7 Transport to Impoundment .................................................................. 5-29
5.8 Observations and Suggestions .............................................................. 5-31
5.9 Bibliography .............................................................................................. 5-33
Appendix A
Trip Report to Romania - Ash Disposal - August 9, 1993
Illustrations
Figure Page
3-1 RENEL SCC with all Hydraulic Transport System ..................................... 3-7
3-2 RENEL ESP Dry Ash Removal Using Air Slides ........................................ 3-8
5-1 North American Fly Ash Handling Systems by Boiler Type ................... 5-35
5-2 North American Fly Ash Handling Systems by Boiler Size .................... 5-36
5-3 North American Fly Ash Handling Systems by Fuel Type ...................... 5-37
5-4 North American Fly Ash Handling Systems by Type of Coal ................. 5-38
5-6 Typical Bottom Ash Water Impounded Hopper Collection System ...... 5-40
5-7 Typical Bottom Ash and Economizer Ash System .................................... 5-41
Figure Page
5-18 Magaldi Ash Conveyor with Mechanical Handling System .................... 5-58
5-19 Magaldi Ash Conveyor with Pneumatic Handling System ..................... 5-59
5-20 4 x 300 MWe One-Year Material Balance ...................................................... 5-60
5-23 Typical Hopper and Vertical Shaft Air Heater Configuration ................. 5-63
5-24 Typical Weighted Wire Precipitator ............................................................. 5-64
5-31 Fly Ash Hopper with Fly Ash Intake ............................................................. 5-71
5-32 Fly Ash Intakes with Shut-Off Gates in Horizontal Lines ........................ 5-72
5-33 Fly Ash Fluidizers vs Discharge Diameters ................................................. 5-73
5-34 Location of Forced Draft and Primary Air Fan Inlets Near
Precipitator Hoppers .......................................................................................... 5-74
Tables
Table Page
2-1 Potential Uses of Wastes from Pulverized Coal Firing ............................. 2-4
3-1 Ash Test Results for Type B Fuel - Craiova I Power Plant,
Rom an ia .............................................................................................................. 3-2
3-2 Typical Range of Size Distribution for Ash - RENEL, Romania ............. 3-3
3-3 Ash Storage Areas in Main Power Plants ..................................................... 3-4
4-1 Solid Wastes from U.S. Coal-Fired Power Plants (1990 Production
and Utilization in millions of U.S. tons)...................................................... 4-2
4-2 Potential Uses of Wastes from Pulverized Coal Firing ............................. 4-4
4-3 Elemental Concentrations in Bulk Fly Ashes in the United States ........ 4-14
5-1 List of Submerged Scraper Conveyor Contracts .......................................... 5-8
This topical report has been .prepared by the Bechtel Corporation to summarize the
results of studies for the Romanian National Electric Authority (RENEL), conducted
under contract with the United States Agency for International Development
(USAID). The overall objective for the USAID support of RENEL is to improve the
efficiency of the Romanian power generating sector. In response to specific requests
by RENEL, studies were conducted in the following technical areas:
1. Heavy fuel oil combustion and gas-side corrosion
2. Boiler feedwater treatment and water quality control
3. Ash handling in coal-fired power plants, soils reclamation at full ash
storage piles
Study results in each of these technical areas are presented in separate topical
reports. This report contains the findings related to Study Area 3.
The specific objectives of Study Area 3 were to:
" Review the existing ash handling systems in RENEL's coal-burning
power plants and to suggest potential methods to upgrade these systems
" Review ash handling and storage practices in modem Western power
plants and suggest alternative ash disposal options for Romanian coal
fired power plants
" Discuss methods for soil reclamation and remediation in already filled
ash disposal sites.
1.1 BACKGROUND
Nearly 60 percent of RENEL's thermal power plants are fueled with coal. The
Romanian domestic coal resources consist of low grade brown coal or lignite,
containing high percentages of ash and moisture. There are as much as 15 million
tons of ash produced annually in the coal-fired power plants.
Typically, the ash collected from various points in the flue gas path is pumped in
slurry form to above grade disposal sites near the power plants. Ash handling and
disposal consume significant power. The ash/water weight ratio in the slurry is
1:10. Little, if any of the water is recovered. Consequently, the plants require large
quantities of makeup water. The ash piles have no means for collecting the
conveying water, nor for isolation from Lhe groundwater table. Any chemicals
leached out of the ash are carried to the soil and the subsurface water table, causing
undesirable pollution of the water suppiy.
Another issue facing RENEL is that the currently available disposal sites are
expected to be full in about 5 years. While there is adequate land nearby for future
disposal sites, the land owners are reluctant to sell the land or exchange it for
restored former ash piles.
Ash usage for other industrial purposes absorbs only about 1 percent of the ash
generated in the coal plants.
RENEL has also identified several operational problems that it has encountered in
its present systems. These types of problems have led RENEL to request assistance
from the USAID to accumulate data on the following:
The ash from the power plants is almost exclusively removed by means of slurry
pumping to ash piles near the plants. RENEL is experiencing some problems with
its current ash handling method, and they have been identified as follows:
m The demand for ash supply and pumping power is excessive.
m Ash piles occupy large land area and the supply of suitable land is rapidly
diminishing.
m The slurry pumps have poor reliability.
* The steel pipes used to transport the ash slurry to the ash piles are prone
to clogging, deposit buildup and corrosion/erosion damage.
m The current ash piles are environmentally harmful. Chemicals leaching
from the ash contaminate the groundwater supply. Windblown dust
contaminates the air.
Although several power plants are equipped with provisions for dry collection of
ash for sale to industry, these provisions are rudimentary and have only limited
capacity.
Recognizing the urgent need to find solutions to the above problems, RENEL has
requested assistance from the U.S. AID. The study task, covered in this topical
report and performed by Bechtel Corporation, was conducted in response to this
request. The task represents the initial step of identifying the following:
a Modern Western methods for efficient in-plant ash handling and
disposal methods
m Commercial and industrial uses for the ash
m Potential means for reclaiming the land occupied by the current ash piles
after reaching their storage capacity
n Methods for environmentally benign storage methods for ash disposal
Based on the above information, promising methods for solving the ash handling
and disposal problems are to be recommended for further evaluations.
Any ash that cannot be sold because of poor quality or due to market saturation is
transported off site for landfilling or is impounded at the plant site. In the United
States, power plant ash is considered as nonhazardous waste, suitable for normal
landfilling. However, groundwater monitoring is required at the disposal facilities
to confirm that the water quality is not adversely affected. In the United States,
about 48 percent of the unused fly ash is collected in temporary storage silos for
shipment to landfill sites. Instead of transportation to a landfill site, the ash has
been returned to the mine for reinjection into depleted shafts or for use in
restoration of strip mine land. This method has been used in Europe and the states.
Final ash disposal at or near the plant site is normally done in ash ponds. In the
states, about 52 percent of the ash is sluiced to disposal ponds. Ash piles are not
commonly used. The ponds usually have a primary pond and at least one discharge
pond. Water collected in the discharge ponds is sent back to the plant for reuse. As
much as 90 percent of the water is recycled in some locations. A representative
plant in the midwest United States has ponds covering 113 hectares (280 acres) for a
1,000-MW power plant. The pond has been in use for 20 years and has received 10
million cubic meters of fly ash.
Except in heavy clay soils, the ponds are lined with plastic. High-density
polyethylene liners have shown the least adverse effects to long-term exposure to
coal ash. Groundwater monitoring wells are sunk to the water table to observe any
undesirable leaching from the ponds.
Once the ponds of landfill have reached their capacity, they are capped with several
feet of dirt. Depending on the soil characteristics and expected precipitation, liners
may or may not be used. After capping, the land may be returned for use. There
have been sport centers, golf courses, parks and recreational areas established on
former pond sites.
Some sites have been revegetated to restore their natural state. Since the ash
characteristics vary significantly from coal to another, it is often required to conduct
experiments to determine the most suitable vegetation. The experimental farm on
the Craiova ash pile is a gcod example for such efforts.
A ri-aijr concern with ash ponds is the control of fugitive dust. There are now
commercially available materials that can be sprayed on the surfaces to prevent such
occurrences.
Largest ash quantities may be used in highway and levee construction. Some
700,000 tonnes of ash was used recently to build a berm behind a levee in the United
States. Similar projects have used large quantities of ash in France and England.
Because of transportation costs, the economically most attractive applications for
unimproved ash are within a 50 km radius of the power plant.
The economics become more attractive if the ash is used to manufacture portland
cement, precast concrete panels, or building blocks for the construction industry.
Such manufacturing plants should be built near the power plants. They do require
some capital investments. However, because of the added value, greater
transportation distances become feasible.
Current research is attempting to use ash as filler material for metal composites,
such as aluminum graphite and aluminum silicon carbide. Cast aluminum-fly ash
composites are under development at the University of Wisconsin.
94-1685c.O06aLW RO/1
Section 2 Summary, Conclusions, and Recommendations
In a more recent development, the water was replaced with air cooling. In addition
to lower water consumption, this design improved the plant thermal efficiency,
since the air helped to combust the residual carbon and the hot air was introduced
into the furnace. Regardless of the cooling method, the SCC allowed dry handling
of the ash.
Operating experience with these conveyors brought about improvements in the
configuration and changes to more durable materials for the chains.
The next logical step will be to conduct site-specific evaluations. Such evaluations
should define the technically and economically preferred solutions to the local
problems. Considering that plant improvement projects require several years from
completion of these studies, it is recommended that the projects be prioritized
according to the urgency of completion. This is particularly applicable to finding
acceptable solutions to the shortage of ash storage capacity.
Data provided by RENEL lists 22 coal-fired power plants. The total generating
capacity is about 10,200 MW. Coal-fired power plants are located in the
mountainous regions in the north, in the plains along the Danube River, the coastal
areas along the Black Sea, and on gently rolling regions in the southwestern part
adjacent to local rivers. Ash storage information was provided for the six most
important plants, representing a generating capacity of about 7,700 MW. Site-specific
information was gathered during the plant visit at Craiova H.
There are coal resources in various regions of the country. Strip mining is the most
frequent recovery method with some underground mining. Rail and truck
transportation is used to deliver the coal to the power plants. Most of the plants
burn low heating value indigenous brown coal. The coal used in Craiova, for
example, has about 29 percent ash and around 41 percent moisture. The higher
heating value is 1,200 to 1,700 kcal/kg (2,200 to 3,100 Btu/lb). On an equal heat input
basis, this coal produces 7 times more ash than a medium quality bituminous U.S.
coal (Illinois No 6).
Table 3-1 lists the ash test results at the Craiova plant. The ash particle size consist
typical for six Romanian coal-fired plants is shown in Table 3-2.
The ash piles are surrounded with a 3 to 6 m (10 to 20 ft) high earthen berm to
confine the deposited ash. As the ash height reaches the top of the berm, a new
berm is constructed slightly inboard from the one below. The outside surface of the
berm has a 3:1 slope. As evident from Table 3-3, ash piles are allowed to reach
heights above 40m (130 ft). There is no water recovery provision at the ash piles.
The transport and rain water are allowed to percolate into the soil beneath the pile.
At Craiova, the outer surface of the berm had only spotty natural vegetation; no
grass mat to prevent washout was evident.
Table 3-1
Ash Test Results for Type B Fuel
0 Craiova I Power Plant, Romania
NOTES: ,/
1) Fusion Temperature: 1120'C 5.
2) Melt Temperature: 1150'C
0
94-1685c.004a/WOshl II
Section 3 Current Ash Handling and Disposal Provisions inRomanian Power Plants
Table 3-2
Typical Range of Size Distribution for Ash
RENEL, Romania
Table 3-3
Ash Storage Areas in Main Power Plants
Plant and Storage Area Land Area Height
Name (hectares/acres) (m/ift) Remarks
TURCENI T.P.P.
Valea Ceplea 161.7/400 0.0/0 To be reused
Storage #2 169.0 / 420 8.5 /28 In operation
ROVINARI TPP
Cicani West 65.4/160 15.0/49 90% full
Cicani East 66.0/163 17.0 / 56 90% full
Beteregea 118.0/290 0.9 / 3 In operation
ISALNITA TPP
Right-bank storage 145.0 / 360 26.0/85 In operation
Left-bank storage 136.0 / 340 32.0 / 105 In operation
MINTIA-DEVA TPP
Mures right bank 63.0 / 156 40.0 / 130 In operation
Bejan Valley 87.0 / 215 26.0 / 85 In operation
DOICESTI TPP
Storage #1 12.0 / 30 38.0 / 125 Exhausted
Storage #2 25.0 / 63 42.0 / 138 Exhausted
Storage #3 10.0/25 28.0/92 To be used
Poiana Mare 48.0 / 120 29.0 / 95 In operation
Storage #5 18.0/45 0.0 Under consideration
CRAIOVA II TPP 120.0/300 30.0/ 100 In operation
In a few instances, where RENEL is able to sell some of the ash, the fly ash from the
electrostatic precipitator is collected in a rudimentary dry system of modest capacity.
Should the industrial demand for ash increase significantly, the present system
would have to be modernized and enlarged. The dry ash handling system is shown
in Figure 3-2.
C5,
=r
C=L)
CL
Ma q 6X En
0.
CD
CA3
C,=
U2 ESP
6/7
CD
cn
Aftmaye cdtr_
CD,
Figure 3-2 RENEL ESP Dry Ash Removal Using Air Slides
000
Section 4
Ash Disposal and Soil Reclamation
Coal-fired power plants generate large volumes of ash which can tie up large tracts
of land for permanent storage. The land use for waste storage may be somewhat
reduced by switching to low ash, higher quality coal, and improving the plant heat
rates. However, these measures may have only limited benefits. While unused,
barren lands may still be available in some regions for permanent ash storage, land
near power plants is too valuable to permit unrestricted use for ash storage in most
of the civilized world. Shortage of land or problems associated with land acquisition
for ash disposal could significantly increase the cost of power generation and
jeopardize operation of many power plants. Proper ash disposal practices are
essential to prevent wasteful land depletion and to minimize adverse
environmental impacts.
Proper ash disposal practices include aggressive marketing to promote industrial use
of ash, proper containment of ash for ultimate disposal, efficient management of
land use, and economic reclamation of land after the ash disposal facilities are dosed.
Current Romanian ash storage practices have been outlined in Section 3 of this
report. This section contains descriptions of potential industrial/commercial use of
ash, modern methods of ash management (storage, disposal, stabilization,
remediation, and reclamation) and methods recommended to improve the current
ash management practices in Romania.
Table 4-1
Solid Wastes from U.S. Coal-Fired Power Plants
(1990 ProO-rlon and Utilization in millions of U.S. tons)
Table 4-2 presents a summary of the potential markets for pulverized coal-fired
plant wastes. The table also provides data on the level of technology employed in
the different usages. Markets for power plant wastes may be divided into the
following categories:
" High volume - low technology uses
" Medium technology uses
• High technology uses
Fly ash, bottom ash, and slag, alone or in mixed form, have been used in the United
States and Europe as structural fill material for roads, construction sites, dams, and
dikes. In the United Kingdom, ash has been used in highway embankments with
particular applications as fill dirt behind bridge embankments. In the United
Kingdom and in France, fly ash was used as structural fill to confine fly ash ponds.
In the United States, a 6 mile-long berm behind a levy was recently constructed with
mixed ash. Approximately 700,000 tonnes of ash, reclaimed from ash ponds, was
used. About 10,000 tonnes of ash was used to construct access ramps in the state of
Delaware. In the state of Pennsylvania, 350,000 tonnes of ash was used to build a
500-meter-long highway embankment.
"Pozzolanic mixtures," consisting of fly ash, activators, aggregate and water, have
been used for years as base layers of asphalted highways.
C. Table 4-2
Potential Uses of Wastes from Pulverized Coal Firing
-. Utilization Markets Conventional By-Product Potential By- Technology Market Major Major Utilization
__
Materials Type() Product Requirements Value
=Volume Advantage Disadvantage Outlook
Cement Cement BA, FA Moderate Moderate High Cost savings Quality control Good
Concrete and Sand, gravel, and BA, FA Moderate Moderate Low Cost savings Quality control Good
construction materials stone
Bituminous Sand and gravel, BA, FA High Low
pavements Low Processing Product Moderate
stone
economics acceptability
Structural fill/fill Soil, stone, sand, BA, FA High Low
materials Low Urban and Product Good
and gravel
industrial acceptability
proximity
Soil stabilization Lime, cement FA Low Moderate High Cost savings - Moderate
Deicer/anti-skid Salt, sand, and BA Moderate-high Low
gravel
Low- Non-corrosive Good
moderate
Roofing granules Stone, sand, and BA Moderate Moderate Low
gravel
Grouting Cement FA Low-modcrate Moderate High Cost savings Ash quality Good
Mineral wood Furnace slag, FA Low Moderate Moderate Market Atypical Moderate
wool rock
Agriculture proximity furnace
Ag-lime FA, FGD High Low Low - Replacement Poor
fertilizers
ratio moderate
Metals recovery(b) Natural ores FA High High High Costs, residue Low
Sulfur recovery Natural sulfur volume
FGD High High Moderate - Costs Low CD
Gypsum Natural gypsum FGD High Moderate Moderate - Product Low
(a) BA = bottom ash; FA = fly ash; FGD = flue gas desulfurization sludge. acceptability C.
0-
(b) Includes aluminum, titanium, iron, and silica.
Adapted from Coal Combustion By-Products Utilization Manual, Vol. 1: Evaluating
the Utilization Option, Table 4-1, EPRI CS-3122, Electric Power L
Research Institute, Palo Alto, California, February 1984. ="
4
9 -1685c.O02a/WO/sh/R 1 1
Section 4 Ash Disposal and Soil Reclamation
Fly ash alone, or mixed with cement, can be used to stabilize other materials. The
cementitious character of the mixture can be used to agglomerate loose particles,
such as soil, or to encapsulate particles. Fly ash-based mixtures have been used to
encapsulate materials, such as flue gas desulfurization scrubber sludge, metal
processing wastes, and low-level nuclear wastes.
The use of ash for soil conditioning has been a subject of research for many years.
The purpose of soil modification is to improve the absorption of nutrients, change
the soil pH (reduce acidity), and improve the drainage and water retention
characteristics or texture.
Fly ash can also be interground with cement clinker or it can be blended directly
with portland cement. ASTM specification C595 for blended hydraulic cements,
currently recognizes three types of cements containing a pozzolan (such as fly ash):
" Type IP. Portland-pozzolan cement for general construction which may
contain 15 to 40 percent of fly ash
* Type IPM. Modified portland cement with less than 15 percent fly ash.
It is noted that production of one barrel of portland cement (170 kg or 375 lb)
consumes about 22 kWh of electricity and thermal energy of about 250,000 kcal (1
million Btu). Blending the portland cement with fly ash could result in substantial
energy saving. Thus, a blend of portland cement and fly ash may be sold at
significantly lower prices.
In addition to the lower material costs, the use of fly ash to concrete mixtures results
in improved workability, lower heat of hydration, reduced water requirement, and
lower drying shrinkage. The finished concrete has reduced permeability, higher
strength, and better resistance to chemical attack (including sulfates).
Fly ash and bottom ash have been extensively used as substitutes for sand and
gravel in cement concrete and in bituminous (asphal-based) concrete.
Fly ash-based light weight aggregates have found application as a substitute for sand
and gravel in concrete, a substitute for gravel in asphalt road surfaces (on city
streets), and for insulating material and light weight roofs.
Wisconsin Electric Co. has built a light weight aggregate plant that will utilize all the
ash produced in its coal-fired plants. The products will be used in precast concrete
and to insulate concrete and mineral fillers.
technically feasible, they are far from economic at this time. Attempts are also
under way to extract hazardous metals, such as lead, chromium, and manganese.
Fly ash can also be used as a filler in metal composites, such as aluminum graphite
and aluminum silicon carbide. Fly ash tends to improve the wear qualities. Cast
aluminum-fly ash composites, using inexpensive casting techniques, were produced
at the University of Wisconsin. Up to 25 percent (by weight) fly ash was incorporated
in Alloy 2014 and A-356 aluminum-silicon casting alloy.
Benefits of these activities are not likely to create a massive demand for ash in the
near term.
The American Coal Ash Association (ACAA) promotes uses of coal ash and has
represented coal ash producers as well as marketers since 1968. ACAA membership
is available in the United States and abroad for interested international
organizations (ACAA, 1991). In addition to the ACAA which is a trade associaion,
other commercial entities, such as fly ash cc .tractors are actively involved in
transportation, sale, utilization, and proper disposal of ash in the United States. For
example, the Trans-Ash Company has moved millions of tons of ash across the
United States since the 1970s (TA, 1993).
these costs (particularly those associated with land purchases) will increase. Once all
the nearby land is used up, the ash will have to be transported over greater distances
for disposal. A more expensive mode of transportation may also have to be
employed.
The market value of unimproved ash is quite low. To the buyer, the biggest cost
item is the transportation, which limits the distance of use point from the plant.
The prospect of sales to greater distances can be improved if the plant can bear a part
of the transportation costs (to the limit of savings in operating costs).
The economics may be more attractive if the ash can be converted to more valuable
forms, such as light weight aggregate or brick or structural panels. The manu
facturing facilities should be built near the ash piles. The value added in these
products will allow marketing further away and may even produce some profit. It
must be recognized, however, that such ventures will require capital expenditures
to construct the new manufacturing plant and to carry out certain retrofit in the
power plant itself (e.g., retrofitting for dry ash handling).
In most countries, it was found that successful marketing of ash involved aggressive
educational and sales efforts.
Wet ash transportation and site operation may be simpler and less expensive for
some power plants if the ash storage/disposal facility is on land owned by the plant,
21
Section 4 Ash Disposal and Soil Reclamation
1987). The impoundments are almost always on site, consisting of a primary pond
and, at least, one discharge pond. The treated water from the discharge pond is
usually recycled or discharged in the surface waters (rivers) under special permits
from the state agencies.
The sizes of these ponds are typically on the order of 50 to 400 acres ( 20 to 160
hectares), depending on the plant operation and site location. The operation of a
1000-MW power plant in the midwest United States is cited as a typical example.
The primary pond at this plant has a capacity of about 280 acres (113 hectares). This
pond received approximately 10 million cubic meters of ash (fly ash and bottom ash)
over a period of 20 years at a rate of approximately 500,000 cubic meters of ash per
year. The pond was divided into two segments by a dike and an upper and a lower
pond. The lower pond was connected to the discharge pond; both of these ponds
were unlined (EPRI, 1992).
Comanagement of Wastes
Some power plants dispose of their combustion by-products collectively in a single
disposal facility, a practice generally referred to as comanagement of wastes. The by
product includes both the high-volume wastes (such as coal ash) and low-volume
wastes (such as boiler cleaning liquids and waste treatment sludges). Nationwide,
about 80 percent of the by-products are disposed of either in ponds or landfills.
Ponds account for approximately 44 percent of the management facilities (EPRI,
1991). This percentage has varied over the years. For example, in 1974, statistical
data indicate that 30 percent of ash was trucked to disposal sites and 70 percent was
sluiced to ponds; whereas, in 1978, the data indicate that 49 percent was trucked
offsite and 51 percent was sluiced to the ponds (EPRI, 1987). It is apparent that the
trend has been to more trucking (dry collection), and less sluicing.
'2)3
Section 4 Ash Disposal and Soil Reclamation
yards (380,000 cubic meters) of ash were sluiced in the 60-acre pond system (EPRI,
1991).
Sluice Water
The quantity of ash generated at a typical 1000-MW power plant in the United States
may vary from about 180,000 metric tons per year (tpy) if the plant is using coal to
about 340,000 tpy if the plant is using lignite (EPRI, 1987). The volume of generated
ash is difficult to estimate for a typical plant as the volume depends on many factors,
including quality of coal, plant efficiency, and plant operational features. However,
making certain assumptions, it may be estimated that the ash generated in a 1000-
MW power plant may amount to about 300,000 tons of solids per year. Wet sluicing
the ash at such a plant may generate approximately 900 million gallons per year of
sluice water: a ratio by weight of 12.5 parts water per one part ash (EPRI, 1991). This
is a large volume of water to manage, considering the quantities of ash generated
annually in the United States. In 1990 alone, the U.S. electric utilities generated
approximately 64 million metric tons of coal ash (Table 4-1).
Ash in the United States is sluiced at a solid content of 5 to 15 percent by weight.
Reduction of water may have potential savings in energy consumption, cost, and
environmental benefits. It is important to recognize that reduction of water in the
sluice should not be done without corresponding reduction of the pumping time so
as to maintain adequate flow velocity in the sluice pipes. Reduction of flow velocity
increases the chances of ash settlement during the transport which would, in turn,
plug the conduits, and could result in extra cost of delays, repairs, and replacement
of parts. Therefore, cost savings from water reduction is always weighed against risk
of ash deposition and plugging.
Another measure for cost savings and realization of environmental benefits is to
recycle most of the sluice water. For example, a midwestern utility which operates
10 power plants in the region, typically recycles 80 to 90 percent of sluice water. In
addition, the midwestern utility has retrofitted all of its power plants with dry ash
handling systems to reduce use of water and take advantag;e of dry disposal systems
(EPRI, 1987).
Dry Collection
Concern with dry collection has been mainly dust control at the plant and during
the landfilling operation. Spraying water is common for dust control measures.
However, water spraying at the plants is avoided in some cases because of the
pozzolanic nature of some fly ash which sets up as a result of moisture and makes it
21
Section 4 Ash Disposal and Soil Reclamation
difficult to remove the ash from temporary storage silos. In such circumstances, the
fly ash is blown dry in the temporary silos or bins, and wetting is done during or
after the ash is loaded on the trucks for shipment to the ultimate disposal site (EPRI,
1987). In some cases, other dust suppressant chemicals may be used such as the
polymeric surface binders by Chem-Jet Inc. During the placement of ash in a
landfill, it is generally required that the ash be kept covered with a layer of soil or
liner except for a limited area needed for the daily operation.
Leachate Control
When filled to capacity, ponds or landfills are capped with a layered soil system Pnd
reclaimed as described in Section 4.3. In addition to dust control, the function of the
cap is to limit direct public access to the ash, minimize precipitation leaching into
the subgrade, and reduce any potential for adverse environmental impact.
Although coal ash is considered nonhazardous, groundwater in U.S. disposal sites is
regularly monitored to ascertain the impact of ash leachate. This topic is discussed
in the next Subsection 4.2.3. The chemistry of leachate depends on various factors,
including the soil attenuation, availability of water, and the chemical content of ash
which varies from plant to plant. To develop typical values for ash chemistry
during one study, a group of 40 fly ash bulk samples was obtained from coal-burning
power plants across the continental United States. Four of these fly ash samples
were selected for detail laboratory analysis as summarized in Table 4-3. The analyses
revealed 28 trace elements in fly ash (fresh or weathered). Boron was found to be
the most mobile element. Vanadium, chromium, and arsenic and other elements
were 'also detected as shown in Table 4-3.
Leachate control in the landfills and in the ash ponds with large volumes of sluice
water has been a major consideration with ash management practices in the United
States. Although most of the ponds and landfills used for ash disposal in the United
States were unlined in the past, the modern trend is to line the ponds or to switch to
dry collection system.
0O
Section 4 Ash Disposal and Soil Reclamation
Table 4-3
Elemental Concentrations in Bulk Fly Ashes in the United States
Approximately 70 percent of all coal ash in the United States is generated in 17 states
of which 14 regulate coal ash as solid wastes. Liner installation is a mandatory
requirement in 12 states, and 16 states have waste management requirements for
coal ash. The U.S. EPA feels that the state programs for coal ash management are
adequate and improving (DER, 1993). Therefore, local state regulations will probably
dominate management of ash as nonhazardous industrial waste, adopting the
federal regulations (Subtitle D of RCRA) as minimum requirements.
Whether the disposal facilities (ponds or landfills) are lined or unlined, a major
concern is to verify and confirm that the generated leachate, if any, does not have
statistically significant impact on the downgradient groundwater. Unless it is
certain that the subsoil is quite impermeable, the groundwater downgradient of the
ash disposal facilities is regularly monitored for indicator parameters or site-specific
constituents of concern.
Depending on the local geohydrology, a synthetic liner at the bottom of the pond or
landfill may be omitted if it can be demonstrated by design and/or monitoring that
the objectives of Subtitle D can be achieved without a liner. The groundwater
monitoring system may consist of three downgradient wells and one upgradient
well, although number and configuration of wells are heavily dependent on the site
geohydrology.
Once the pond or landfill is filled to capacity, the facility is closed under the
minimum requirement of Subtitle D. The cap cover system generally consists of
several feet of soil with or without liner and a drainage system depending on the
climatologic conditions at the site as negotiated with the local state environmental
agencies. The cover usually consists of grass; however, asphalt or concrete may be
designed for parts or all of the cover provided the objectives of Subtitle D are
satisfied. The cover material may be designed to suit the facility owner's real estate
needs, such as parking, storage, landscape, or recreation. However, reclamation of
the closed facility may be dictated by other factors, such as the value of real estate in
the area, environmental demands imposed by the local community, and future
land-use plans.
4.3.1 Revegetation
Containment of ash, as described in Section 4.2, has precedence over any
reclamation requirements. However, reclamation activities can be performed
together with the containment activities to satisfy environmental concerns and land
use planning requirements. Combining the containment and reclamation needs
could be an attractive cost-cutting option. An ash landfill reclamation program in
the state of Arkansas is cited below (Snow, 1993) as an example of combining
reclamation and containment activities to realize cost savings.
AP&L Reclamation
As a result of an environmental impact study conducted for the White Bluff power
plants in the state of Arkansas, the utility company, Arkansas Power and Light
Company (AP&L), was committed to reclaim its coal ash disposal site in Arkansas
and restore the original vegetation. The state permit requirements for the White
Bluff reclamation consisted of a daily soil cover over the ash as it was disposed of in
the landfill, and a final soil cover to support vegetation; the required thickness of
the final soil cover was 30 inches. The state had estimated that the cost of this cover
system in 1982 dollar values would be approximately $7,000 per acre ($17,000 per
hectare).
As a cost-cutting measure, AP&L conducted an ash reclamation research program
which successfully demonstrated that test plots with 6-inch and 12-inch soil covers
had the best vegetation growth. As a result, the state issued a variance to the
original permit requirements, granting a reduction in thickness of the final soil
cover from the originally specified 30 inches to a revised thickness of 12 inches.
This variance was estimated to drop the cost (in 1982 dollars) from $7,000 per acre
down to $4,000 per acre ($10, 000 per hectare). This was a cost saving of more than
0.5 million dollars over the life of the ash disposal landfill site which occupied an
area of approximately 110 acres (45 hectares). The ash landfill was successfully
restored to support a luxuriant growth of perennial native Arkansas switch grass,
providing cover for the landfill and food for the wildlife (Snow, 1993).
The AP&L ash reclamation research program was the most extensive program ever
performed in the United to evaluate plant adaptability to ash reclamation sites. The
program was initiated in early 1982 by starting a greenhouse testing setup and using
potential reclamation plant materials. The program was conducted jointly by AP&L
and the Soil Conservation Service Plant Material Center of the U.S. Department of
Agriculture at Coffeyville, Mississippi. Prior to this program, the Central Electric
Generating Board (CEGB) of the United Kingdom had developed feasible and
economic methods for reclamation of coal ash wastes. The CEGB had successfully
minimized the amount of soil needed for reclamation, and identified plant species
that could grow in coal ash/soil matrix. For economic considerations and
expediency, the AP&L research program adopted most of the CEGB reclamation
methods applied previously.
The AP&L program involved screening over 100 plants to study the growth
potential in ash and soil/ash mixtures. The study revealed many species potentially
adaptable for reclamation of the White Bluff landfill site. Thirty-two types of
grass/legumes and 17 species of trees/shrubs were planted in replicates; these were
planted in five test plots occupying a 1-acre parcel of land at the White Bluff site.
The test plots were set up to field test the adapted materials for site reclamation,
evaluate effect of fertilizers on the selected species, and determine minimum soil
coverage required for ash reclamation.
The test plots were set up measuring 60 feet by 100 feet on plan dimensions (18 by 30
meters). Each plot was subdivided into 40 subplots and used for various selected
plants. One of the test plots was used as a control plot where no soil was added to
the ash, planting directly in the ash. In the other four test plots, the ash was disked
to break the cementitious surface before it was blended with acidic clay soils. The
thickness of blended soil (soil cover) in each test plot was different: 12 inches of soil
cover in one plot, 6 inches in the second plot, 3 inches in the third plot, and only 1
inch in the fourth plot. Each plot was fertilized using 50 pounds of fertilizer (10-20
10 brand) per plot. Eleven grass/legume species were identified having the best
growth. Only one of the tree species (Black Locust or Robinia pseudoacacia) proved
successful in long-term survival and adaptability to ash.
Cap Design
Clayey soils are generally selected for cap design to prevent excessive infiltration of
irrigation water or precipitation through the cap. The pH value and the type of top
soil are also dictated by the vegetation cover selected for the cap. A geomembrane
liner is sometimes used in combination with the clay soil to further reduce
permeability of the cap. Any excess run-off or excess infiltration is generally
collected by a surface or subsurface drainage system which may include a synthetic
geodrain or a layer of drainage material.
The cap grading is generally limited to 2 or 3 percent to control erosion caused by
surface run-off. On steeper side slopes, light weigh synthetic mats (such as Enkamat)
are sometimes used to protect erosion and promote heavy plant growth. Enkamat
(one of many brand names) is a flexible lightweight geomatrix of nylon mono
filaments fused together such that approximately 90 percent of the geomatrix is open
space. The mat is available in thickness ranges of 0.4 to 0.75 inches (1 to 2 cm). The
synthetic mat provides considerable open space for anchorage of the root system on
the slopes. Once the root system holds, the vegetation takes over and provides a
natural erosion control. The mat is then hidden underneath this thick vegetation
while still retarding the water flow and reducing erosion (AEC, 1993).
Other erosion control blankets are available in the market, such as Hi-Velocity
Curlex Blankets. If vegetation is not desirable on sloped areas, flexible concrete
revetment blocks could be used for erosion protection; one brand name for such
Dust Control
Johnson March Systems Inc. is marketing a dust control product (Compound SP)
for protection of stockpiles of cinders, fly ash, and other similar dusty fine materials
stored outdoors. Compound SP is a blend of synthetic, organic, long chain of
polymers in a water base. The SP compound, when sprayed on the pile surface,
binds the top most particles to one another and develops a surface crust. The
compound acts as a surface binder forming an interlocking polymer chain to create a
flexible surface crust. The crust is tough, durable, and resistant to the wind or rain
action. Because the moisture can still penetrate the surface crust, heavy run-off is
avoided and erosion is forestalled. Thus, the crust controls gutting of the pile
surface due to heavy winds and rainstorms (JMS, 1989).
The surface crust achieves a high degree of elasticity, providing a long life
expectancy for the crust. A single application of compound SP 301 to the pile surface
will provide protection for a period of 6 months to a year. Another product (SP 400)
provides effective protection for a period of up to 4 years. The life expectancy of the
crust depends, to a large extent on the climatic conditions as long as the crust surface
is not disturbed by animals, equipment, or people. If the surface is disturbed, the
localized area is re-sprayed to patch up the surface crust. Thus, the slope surface can
be re-sprayed locally and periodically. As an alternative for re-spraying, the surface
crust can also be seeded for vegetation. Germination of seeds in the crust is'possible
since the crust is porous, allowing rainfall penetration and air flow through the
crust (JMS, 1989).
The normal application rate for Compound SP is 1 gallon per 100 square feet (0.4
liters per square meter) of surface area, costing approximately 9 cents per square foot
($1 per square meter). The compound is applied undiluted as it is received from the
supplier. It may be applied with any type of spraying equipment. To avoid wash off
and rain dilution, there should be no rainfall on the sprayed surface within 24 hours
of application (JMS, 1989).
Compound SP was first used successfully in 1982 at a refractory site in California.
Laboratory analyses performed by the product users indicated that the organic
surface binder had no adverse environmental impact. The residue and ash content
analyses have confirmed that the organic binder produces a non-toxic ashless
combustion residue (Zanko, 1984).
Another compound marketed by Johnson March Systems, Inc. is a dust suppressant
(Compound M-R) which dampens and agglomerates the dust particles, making
them too heavy to be airborne. The treated material can be handled for storage or
reclamation almost dust free. The compound uses less than 1 percent moisture
with a normal application rate of one part M-R to 1,000 parts water. Compound M-
R, when mixed with water, lowers the surface tension of water from 75 dynes/cm to
below 25 dynes/cm. This drop in surface tension provides tremendous wetting and
penetrating power to the mix. The dust suppression effect of Compound M-R, if
properly applied, is carried over through handling, storage, and reclamation (JMS,
1989).
Although Compound M-R acts as a dust suppressant, it does not provide protection
against rain or wind erosion since it does not provide a crust similar to what is
provided by Compound SP described earlier. Therefore, application strategy for the
two types of compounds are different. While SP is applied on the surface of a
stockpile, Compound M-R is applied on the material as it is being handled prior to
stockpiling.
The current market price for Compound M-R is approximately $6 per gallon ($1.60
per liter), depending on the size of purchase order. At this price, the material cost
would be approximately $1 per 150 tons of treated ash, using 0.5 percent moisture
content by weight of dry ash and a normal mix proportion (one part M-R to 1,000
parts water). This cost does not include shipment of material to the site or minimal
cost of spraying.
Many dust suppressant materials are available in the market to efficiently control
the dust without using excessive water. While water can be used as a dust
suppressant, it has several disadvantages, such as requiring frequent re-allocation,
acting as a vehicle for transport of possible contaminants, and contributing to
production of leachate. Under some circumstances, using dust suppressant products
may be more cost effective than using water if the long-term expenditures and
liabilities are factored in the cost/benefit analysis.
Other Considerations
Other engineering and design considerations for site restoration may include slope
stability problems, liquefaction potential due to earthquakes, and additional
containment features such as installation of slurry walls or subsurface groutirig.
_7C3
Section 4 Ash Disposal and Soil Reclamation
6
Section 4 Ash Disposal and Soil Reclamation
ash management practices are significantly improved to reduce the future land
needs for ash disposal.
This section presents general and conceptual plans recommended to improve the
current ash management practices of coal-fired power plants in Romania. These
conclusions and recommendations are based on limited data and, therefore, cannot
be used as detailed design. Although detailed cost analysis is not within the scope of
this report, cost values are provided in some cases for comparison and discussion
purposes only. Obviously, material and labor costs vary significantly depending on
many factors including geographic location, design details, project size, market
conditions, and contractual details.
The past ash management practices generally favor minimum capital expenditure
even if the long-term costs a,e high or unknown; this tendency is specially
pronounced in cash-starving economies. However, initial capital investment is
unavoidable if the current ash management practices are to be modernized in order
to realize considerable long-term cost savings. In developing our recommendations,
we have tried to avoid capital intensive options and considered only the practical
options appropriate for Romania. Minimum modifications are recommended for
the past ash disposal sites to avoid excessive capital expenditure. However,
significant changes are recommended for future ash disposal practices to alleviate the
majority of ash management problems currently facing the coal-fired power plants in
Romania. The proposed plans for the past disposal sites are discussed in Subsection
4.4.1. Recommendations for future ash disposal practices are presented in Subsection
4.4.2. The last subsection (4.4.3) provides a list of follow-on studies and steps required
to implement the recommended improvements.
If properly applied, farming the ash piles as a method of land reclamation could be
more economical than revegetation. To have long-term success, a reclamation
Landfillsand Impoundments
The use of landfills and impoundments, rather than ash piles, is recommended for
future ash disposal. This would be a major deviation from the current practice of
disposing of ash almost exclusively at ash pile disposal sites. While most of the ash
is kept above ground at ash pile disposal sites, ash is cointained and buried mainly
below ground in impoundments and landfill sites. There are s.veral advantages
and long-term benefits to disposal by containment (landfills or impoundments).
Construction of a landfill or an impoundment requires a relatively high initial
capital expenditure for excavation and soil stockpiling. However, cons Tuction of
ash pile disposal facilities is not substantially cheaper, considerini, the cost of labor
and material required to complete the perimeter berms which are constructed in
stages. Furthermore, excavation could be minimized in most sites by taking
advantage of the natural topography. For example, some containment sites are
constructed by berming up the side of a hill or placing a dike at lower point of a
valley.
The soil excavated for construction of a landfill or an impoundment could be used
for on-site construction or landscaping, sold or given away for free haul-off, easily
seeded for reclamation, and/or used for closure of the ash disposal facility (landfill
or impoundment) when the storage capacity is depleted. While some surplus
stockpile of soil may remain above grade at a landfill or impoundment site, huge
piles of ash remain above grade at an ash pile disposal site. Reclamation, removal
or reuse of surplus soil stockpiles would be considerably easier and less expensive
than maintenance or reclamation of a huge pile of ash. None of the above options
for soil stockpiles can be easily implemented for ash piles which could be a constant
source of pollution requiring costly remedies and taking up a large tract of land with
little or no use.
ReclaimingAsh Piles
Reclamation of an ash pile is considerably more expensive than reclamation of a
landfill or an impoundments since considerable slope areas are involved with the
ash piles. Once reclamation is completed, the reclaimed ash pile has several
disadvantages over the reclaimed landfill or impoundment. The elevation at the
top of the pile is considerably higher than the adjacent farm lands, requiring
additional cost of pumping for irrigation water. Farming on a hill side is more
difficult than on the flat farm lands. Furthermore, the major elevation difference is
a psychological barrier to the farmers who are not willing to swap their flat farm
lands and move on to cultivate on top of anomalous hills in the landscape which
are created by the ash piles. On the other hand, reclaimed landfills and
impoundments are generally flat and blend in well with the natural topography
without creating anomalous hills.
Sluicingthe Ash
Sluicing the ash (slurry) to the impoundments and landfills requires considerably
less energy and costs much less than pumping the slurry uphill to top of the ash
piles. Pumping gets progressively more difficult as the ash piles build up and the
disposal facility reaches near capacity. No such progressive pumping load is
developed as the impoundments or landfills approach their capacities. Therefore,
cost of pumping and maintenance is considerably higher for the ash piles. The ratio
of water to ash has to be higher and the slurry has to be more fluid at the ash pile
disposal sites to facilitate more strenuous pumping demands. Higher water ratios
q41
Section 4 Ash Disposal and Soil Reclamation
increase pumping costs, result in additional wasteful water loss, and create extra
leachate for potential transport of more contaminants.
It is more feasible to recycle sluice water from an impoundment than from an ash
pile facility because water is contained better in a pond. Landfills have the
additional advantage that the ash can be transported dry and compacted. During the
placement of the ash in the landfill, the moisture on the dry ash can be adjusted to
achieve higher compaction and reduce storage space requirements. One ton of
loosely dumped coal ash requires approximately 1.25 cubic yards (0.95 cubic meters)
of storage space. The same ash, properly compacted at its optimum moisture
content, requires only about 0.8 cubic yards (0.60 cubic meters) of space (Loftus, 1976).
This is a saving of approximately 35 percent in the required storage space, a
tremendous benefit over a long-term operation.
Transportation/Disposal
Dry transportation of ash and disposal at an independent off-site landfill may be an
economically attractive option when land acquisition immediately close to the
power plant is not feasible. Long-term independent transporters may be used for
hauling ash in dumper trucks or pneumatic pressurized tankers. Similar
independent transport companies in the United States (TA, 1993) haul ash for utility
companies at rates of about 10 to 50 cents per ton per loaded mile, depending on the
location, distance, and volume.
Another significant improvement for ash disposal problems can be realized by using
the dedicated trucks delivering coal to the power plants. Rather than leaving the
plants empty, these trucks could be used to haul off ash to the coal mines and use
ash for land restoration. This can be accomplished only if the coal mines are strictly
required to reclaim the mined areas. The enforcement of reclamation at the coal
mines may be encouraged by promoting public awareness, impacting local policies,
preparing stricter specifications for mining, and aggressive marketing.
Commercial/Industrial Use
It is also recommended to invest on aggressive marketing effort to promote
commercial/industrial use for the dry ash. As described earlier, the U.S. national
average for industrial use of ash is approximately 30 percent of the coal ash
generated by the power plants (Table 4-1). Through aggressive marketing, a U.S.
utility company was successful in selling approximately 70 percent of its generated
coal ash for industrial use, as discussed earlier in Section 4.1.
The available information indicates that the national average for industrial use of
ash in Romania is less than 1 percent of the generated coal ash by the country's
power plants. This is extremely low and does not compare with either 30 percent or
70 percent values cited above. It is clear that investment in aggressive marketing is
needed to promote industrial use of ash in Romania. The impact of establishing a
larger market for industrial use of ash could be major savings in disposal cost of ash,
significant reduction in storage space requirements, and major decrease in land
needs for future ash disposal.
In the United States, independent companies such as Trans Ash (TA, 1993) bid to
haul off fly ash from the utility sites. The price of fly ash in the eastern United
States is currently about $5 per ton for class F ash (non cementitious) and $10 per ton
for Class C (cementitious). The cost varies with the market fluctuations and
sometimes utilities take bids for free haul. These independent companies help
develop markets for the ash, buy it from the utilities, transport the ash, and sell it to
the end users. Also, as a trade association, the ACAA promotes markets for
industrial and commercial use of coal ash. The ACAA has international members
and represents many entities, including utility and coal companies (ACAA, 1991).
RENEL could promote market for coal ash use in Romania by seeking membership
with trade associations such as ACAA and by assisting or encouraging independent
contractors to engage in ash marketing. Companies, such as Trans Ash (TA, 1993),
may be solicited to initiate an ash transport and marketing network in the country.
A list of potential markets for industrial use of ash was provided in Section 4.1.
As discussed earlier in this report, some power plants have less than 5 years to
continue operation before the available land for ash disposal is depleted.
Implementation of the approved plan has to be completed within this critical period
of 5 years if the power plan operation is to continue without interruption.
Therefore, any site assessment and engineering planning should be initiated
expeditiously considering the estimated schedule of activities provided above. Also,
the power plants should be prioritized on the basis of their needs for modernization.
This prioritization would help allocate appropriate schedule time and budget for
reclamation of the existing disposal facilities and modernization of ash
management practices at each plant.
4.5 BIBLIOGRAPHY
American Coal Ash Association, Inc. (ACAA, 1991), "1991 Coal Combustion By
product Production and Consumption," Washington, DC 20006.
American Coal Ash Association, Inc. (ACAA, 1993), "American Coal Ash
Publication List," Washington, DC 20006, April 1993.
Electric Power Research Institute (EPRI, 1988), "Laboratory Testing of Fly Ash Slurry,"
Snow, Barry L. of Arkansas Power & Light Co., "Reclamation Program Cuts Coal
Ash Disposal Costs," Power EngineeringMagazine,January 1993.
Zanko, Mark of Kaiser Refractories, "Polymeric Surface Binder Controls Chromium
Ore Dust," Chemical Process, December 1984.
This section discusses experience and practices with ash handling in coal-fired
power plants in the United States and in other western countries. The evolution of
systems and practices for ash collection and handling. Also discussed are the
characteristics and operation of modern methods.
In addition to the quantity of ash, the type of ash also has a bearing on the ash
handling equipment. The type (chemical constituents) can affect the distribution of
the ash within the boiler and its auxiliaries as well as the means of transport. Coals
with low ash fusion temperatures, usually referred to as slagging coals, will deposit a
greater amount of ash in the furnace and subsequently produce a greater amount of
bottom ash. Coals with high calcium and magnesium ash can cause pipe scaling
In the United States, the ash handling systems are typically designed for intermittent
operation, usually once per shift, allowing time for maintenance between
operations. In other Western countries, particularly where lower grade coals with
high ash content are burned, the systems are designed for continuous removal.
There are three major transport system options for disposal: wet impoundment, dry
impoundment, and off-site ash transport. These options have been site and end-use
dependent. The type of transport utilized is dependent on the disposal option.
Wet impoundment of ash was common in North America until the 1970's when
environmental regulations presented problems to this method of disposal. With
this type of system, the ash is hydraulically sluiced to the wet impoundment.
n Pneumatic conveyance of the ash to the disposal area. Both dense and
dilute-phase systems are economically limited to distances of about 500
meters because of the high transport velocities required for longer
distances. Typically, a velocity of 1800 mr/min. is required for a 500m
long transport.
Off-site disposal, the final option, always uses a c. y transport system with storage
hoppers or bins for temporary ash storage, awaiting transport off site by either truck
or rail.
Figures 5-1 through 5-4* show the statistical distribution of ash handling system uses
as functions of boiler type, boiler size, fuel type and coal type.
Starting in the 1980's, drag conveyors appeared on the North American continent
but largely in applications involving non-slagging ash. An example of this
application is the fluid bed boilers that became common in the late 1980's.
In the early 1980's, the submerged chain conveyor (SCC) (see Figures 5-7 and 5-8)
began to replace water impounded hoppers and sluicing systems for bottom ash
collection in new and retrofitted installations. However, during that period, there
was also a large decline in the number of pulverized coal-fired boilers constructed,
so the benefits of this change may be yet to be confirmed.
To gain some perspective on the reasons leading up to this change, a look at the
factors immediately preceding this period is helpful. Prior to the Clean Air
legislation of the 1970's in the United States, most of the power generated by coal
fired plants using Eastern United States coal. Much of these coals have a high sulfur
All figures for this section have been placed at the end of the text.
content and tendency for slagging (i.e., have low ash fusion temperatures). These
coals produce a very fluid ash in the furnace that tends to flow into the ash
collection hopper. When the ash does not flow and adheres to the furnace walls
(and this is more the rule than the exception), it has a tendency to break from the
walls and fall in large pieces, called clinkers, into the bottom ash hopper. Many
operators believed that the SCC would not be suitable for handling this type of ash.
Several elements needed to be considered. A large amount of water was required
for quenching. Large pieces of ash occasionally dropped into the hopper. A breaker
for these large pieces was needed.
However, several factors combined to increase the interest in SCCs for bottom ash
removal. These included:
" An increased number of installations in Europe and other Western
countries.
" Longer North American experience time with earlier installations.
" The appearance of the fluid bed boiler on the U.S. power market with its
need for continuous ash removal.
" A change in the U.S. coal usage from Eastern to Western coals because of
the lower sulfur content of the Western coals.
The switch to Western coals forced a retrofit of the ash handling systems. Boilers
designed to burn Eastern coals had to be changed to allow handling the greater
amount of ash, typical for Western coals. Because of space limitations imposed by
the clearance under the boiler, the continuous removal of ash afforded by the SCC
made it a logical choice for retrofit applications. Because of the simultaneous
decline in the construction of large coal-fired boilers in North America, a true test of
the SCC method of ash removal has not occurred in ,heNorth American market.
This is not th,ecase in Europe where submerged scraper chains have been the
standard for years.
dry and wet bottom boilers, crushed brown coal fired boilers, stoker fired boilers,
prepared refuse fuel, and municipal solid waste plants. The style of submerged
conveyor is adapted to suit the ash characteristics. In the North American utility
market, most SCCs employ a water filled upper trough with an exposed lower
return trough.
European equipment has evolved from small power boilers to the current large
utility installations. In North America, the specifications are more stringent for
large boilers. The equipment is designed for higher peak loads and startup with
stored ash. The result is more costly installations than their European counterparts.
Ash capacities of the SCC will depend upon furnace size, the method of firing,
slagging characteristics of the coal, fineness of pulverized coal, washing of coal, etc.
For bituminous coals, 10 to 15 percent of the total ash is typically collected in the
furnace bottom, although in many installations bottom ash exceeds 20 percent.
Figure 5-9 shows the typical ash distribution within a boiler as a function of coal
type. The estimate on lower rank coals is calculated from dust loadings. The peak
ash rates on dry bottom furnaces, resulting from soot blowing or load shedding, can
be three to four times the normal rates. Experience in firing oil shale and high ash
content brown coals with higher specific weight ash show approximately a 30
percent bottom ash collection rate. Figures 5-10a through 5-10c present the
distribution of ash collection rates as a function of coal type and unit size.
Water depths in the upper trough of SCCs are normally 1.0 to 1.5 meters. The drive
size, based on continuous removal, is specified at chain speeds of up to 6 m/min.
SCCs are not normally designed for startup with an ash load. Therefore, the system
must be emptied after a shutdown.
The SCC housing is designed to carry stored ash loads while being moved sideways
from beneath the boiler for maintenance. It should be noted that modern
submerged-chain conveyors do allow maintenance while the boiler is in operation.
The water-impounded hoppers have sliding plates immersed in water troughs to
create a furnace seal for normal operation and for maintenance.
SCC Improvements
Over the years, improvements have been made in the chain, idlers, and the chain
tension stations. Except for units cooled by sea water, the chain has changed from
high-tensile mining chain to carburized alloy chain. This alloy has greater abrasion
resistance. Through shafts and overhung jack-shaft idlers with water seals have
At the end of the SCC, the ash is sized by a stationary grate and then crushed to a
suitable size for conveyance. Economizer ash can be sluiced into the SCC but, in
most cases, the economizer ash is kept separate from the SCC system. After sizing,
the ash is conveyed to temporary storage silos in preparation for offsite
transportation or is sluiced to on-site impoundment. The conveying means and the
location of the final disposal will determine the size of the silos and transfer
structures.
Table 5-1
UST OF SUBMERGED SCRAPER CONVEYOR CONTRACTS
SCC Maximum
No. of Boiler Discharge
Company Units Capacity Capacity (t/h)
Southwestern Public Service Two (2) 520 MW 45
Roy Tolk Station
Electric Geherating Authority of Thailand - Four (4) 150 MW 44
Mah-Moh Station
Alton Packaging Corporation One (1) 350,000 lb/hr 6.6
Alberta Power Company - Battle River No. 4 One (1) 150 MW 21
Container Corporation One (1) 700,000 lb/hr 15
Electricity Supply Commission (South Six (6) 600 MW 125
Africa)
A.E. Staley Mfg. Company, Decatur, IL Three (3) 125,000 lb/hr 5.6
City of Edmonton - Genesee Station Two (2) 400 MW 55
Lower Colorado River Authority One (1) 450 MW 100
Fayette No. 3
Eastman Kodak, Rochester, NY One (1) 550,000 lb/hr 4
National Thermal Power Corp. Two (2) 500 MW
Uttar Pradesh India
Israel Electric Two (2) 550 MW 40
China Steel Corporation Three (3) 440,000 lb/hr 5
Franco Tosi for Bophuthatswana One (1) 60 MW 10
Connecticut Resource - Recovery Authority Three (3) 230,000 lb/hr 9
Honolulu Resource - Recovery Authority Two (2) 245,000 lb/hr 9
Electric Generating Authority of Thailand Two (2) 300 MW 32
Mah-Moh Station
CPS of San Antonio - J.K. Spruce Station One (1) 520 MW 45
Old Dominion Elec. Co. - Clover Station Two (2) 400 MW 30
Tex-Mex - CFS Unit Two (2) 80 MW 30
Conveyor Housing
The conveyor housing contains air ports, which can be adjusted, that allow air to
enter. The air cools the ash and the conveyor, and exits to the boiler through the
furnace bottom opening. The air amounts to 0.5 to 1.0 percent of the boiler's
combustion air requirement. The combustion air is reduced accordingly. The ash
exits the conveyor at a temperature of approximately 1351C.
Hydraulically operated doors are used to isolate the furnace bottom hopper such that
maintenance can be performed on the conveyor. Typically, 8 hours of storage are
provided in the hopper for the maintenance work to be done.
The belt is a stainless steel mesh covered with stainless steel plates, fastened with
rivets and arranged to form a continuous plate. The mesh is supported on steel
rollers along the forward and return runs and guided around steel drums at each
end (see Figure 5-15). One drum is the drive wheel and the other maintains tension
on the belt. Rollers and drums have exterior supports and bearings, isolated from
the heat within, and can be changed from outside the unit without dismantling the
unit. The belt speed is in the order of 15 to 18 m/min.
Because the ash is not quenched in water, it can continue to burn on the conveyor as
it is being transported, thereby reducing the unburned carbon in the ash and
allowing this heat to return to the boiler. This produces two desirable results, one is
an increase in boiler efficiency and the second, is an ash that is more suitable for use
in cement making. By screening, different size products may be obtained and sold
for various end uses such as cement production. Since the system uses no water,
impoundment is simplified and transport costs are reduced.
Plant Efficiency
An increase in plant efficiency is realized because:
" No heat is lost to water in the conveying system.
" No pumping power is used for supplying water to the collection system
" The water does not have to be pumped as part of the transport system
and
" Water does not have to be pumped back in the reclaim system.
The system eliminates settling ponds; therefore, there is no ash contaminated water.
This eliminates problems concerning environmental regulations. Other advantages
are no water treatment chemicals or equipment and elimination of water freezing
problems in cold climates.
In addition, there is no auxiliary cooling water system requiring piping, pumps, or
heat exchangers. This, of course, eliminates corrosion, erosion, and scaling
problems.
Figure 5-16 depicts the amount of unburned carbon in bottom ash for various coals
and for wet and dry collection systems. It is this carbon that accounts for losses in
the furnace and makes the ash unsuitable for cement making purposes. Figure 5-17
compares the sources of various losses between the dry and wet collection systems.
Figure 5-18 shows a typical dry ash conveyor with a mechanical handling system,
while Figure 5-19 shows the same system with a pneumatic handling system. Plant
specific factors and economic considerations govern the implementation of one
system over the other.
Figure 5-20 shows the materials balance for a dry and a wet system for a 4 x 300 MWe
plant. This arrangement was used for an economic study that resulted in the
payback period being as short as 1.7 years.
A study performed for a U.S. utility generating 5 t/h of bottom ash compared a wet
hopper with hydraulic sluicing to a de-watering bin. In addition, trucking to an on
site impoundment with a dry ash conveyor showed a net saving in operating costs
of U.S. $ 1.1 million for 1 year.
The practice on many of the older plants was to collect the reject material on a
sequential basis, and hydraulically sluice, using jet pumps, to the bottom ash
hopper. This method was discontinued in favor of providing a jet pump for each
pulverizer hopper. This practice allows emptying more than one hopper at a time,
and discharging into a collection tank.
The discharge of the material directly into the bottom ash hopper was discontinued
when it was found that the mater splashing onto the lower furnace tubes was
causing stress corrosion cracking. With an SCC, it is possible to introduce mill
rejects outside the water seal plates eliminating the problem. This is also true for
the dry bottom ash conveyor.
Mill rejects gathered by the dry collection and transport systems are conveyed by
either pneumatic or mechanical means. The amount of material and the distance
transported would dictate the choice.
to enlarge the hopper opening to between 400 mm and 450 mm in diameter and put
an ash-receiving tank, dry or wet, depending upon the calcium content of the ash,
below the hoppers to get the ash out of the boiler gas stream as expeditiously as
possible. In a design such as this with receiving tanks below, the hoppers have
essentially zero holdup time and act only as chutes.
hoppers. The objective is to minimize the number of larger particles (500 microns
or greater) going to the air heater and causing blockage. On units where this
numerical simulation has been applied and corrective measures applied, the capture
rate of 500 microns and larger particles improved by 10 to 24 percent.
Corrective procedures involve the addition of baffles in the gas stream and plates to
prevent rebounding of particles already in the hopper area. Of course, the capacity of
the economizer ash handling system must be evaluated to determine its adequacy.
If the ash and flue gas entering the precipitator are well distributed, all precipitator
hoppers in any row perpendicular to the gas flow will collect the same quantity of
ash per unit time. More fly ash will be collected in the rows of hoppers closer to the
precipitator inlet than in the rows toward the rear of the precipitator. The inlet row
of hoppers can collect from 40 to 100 times as much fly ash as does the rearmost row.
Boilers burning high volatile subbituminous and lignitic coals, with a high
percentage of calcium oxide and magnesium oxide in their ash, produce ash that is
made up of small particles. The small particle size contributes to compaction in the
hoppers, while the high calcium content can lead to the rapid formation of fly ash
concrete in hoppers that are contacted by moisture.
Most pulverized-coal fly ash is hygroscopic. In the hopper outlets, the ash particles
are surrounded by stagnant flue gas. On startup, shutdown, at low boiler loads, or
during the ash-removal process, the local gas temperature in the hoppers can be
below the acid dew-point (120-150'C) or below the water dew-point (approximately
55-60 0 C). Under such conditions, in which acid or water is produced by
condensation, agglomeration and/or cementing of the particles can take place,
resulting in hopper plugging and the inability to remove the collected ash from the
hoppers.
In pressure systems, an air-lock feeder transfers fly ash from the hoppers at low
pressure to a transport pipeline at a higher pressure. Compressors or blowers
provide the airflow and pressure to convey the ash. All such systems presently in
operation in North American power plants are of the dilute-phase type. Dense
phase systems are used extensively in other industries and a great deal of experience
is available.
Hopper flow problems result from the compaction of the material in the hoppers.
The degree of compaction in a hopper is affected by the moisture content of the
solid, the size and shape of the particles, the height of the material, and vibration
caused by external plant equipment. Compaction in a gravity-flow hopper will
manifest itself as arching and "rat-holing." Externally mounted hopper vibrat.ors, if
operated incorrectly, will increase compaction and worsen the problem.
It is frequently difficult to maintain the ash freely flowing if it has been stored after
exposure to flue gases containing moisture and sulfur. Therefore, the storage of ash
in collection hoppers should be avoided.
Continuous removal of fly ash from precipitator fly ash outlets can help to reduce
power consumption. However, the primary purpose of continuously removing fly
ash from precipitator hoppers is to avoid shorting of precipitator plates by
accumulated ash. Whatever type of continuous removal equipment is used, it
should provide for continual emptying of hoppers without significant residence
time to avoid cooling and subsequent plugging problems.
Mechanical flight conveyors have been successfully used in Europe for the
continuous removal of fly ash from precipitator hoppers. Such devices have the
return run above the carrying run, with the conveying elements confined in a
totally enclosed casing to minimize the possibility of air infiltration. The flights are
not in contact with the bottom of the trough, which eliminates wear of the trough
floor.
Figure 5-27 is a conceptual arrangement of such equipment, combined with a
conventional pneumatic conveying system.
In some types of systems, this valve is fully opened or closed on a signal from the
downstream vacuum switches. This ensures that the fly ash will leave the hopper
at the proper flow rate and that excessive ash will not flow from the hopper and
plug the discharge line. The air is provided to the system through check valves
located at the inlet of each branch of hoppers.
The positive-pressure dilute-phase system connects to each hopper using an airlock
type feeder (Figure 5-29). Theoretically, due to its cycle of operation, the positive
pressure is never communicated to the hopper. Practically, this is not true; the
feeder can be considered as a chamber separated from the hopper by an inlet gate and
from the conveying line by a discharge gate. The chamber is alternatively
pressurized to conveying line pressure or vented to hopper pressure or less to allow
the chamber o be emptied or filled. Although there are several modes of operation,
the above can take place on a 2-minute cycle and continuously. To obtain a
continuous flow of material into the conveying line, a minimum of two feeders
working in sequence must be maintained.
There are two commonly used types of intakes: the first (Figure 5-30) uses a disc
type gate between the intake and conveying line; full-load control is accomplished
by opening and closing the gate with full conveying air flow supplied through an air
intake in each conveying line. The second type (Figure 5-31) introduces most of the
conveying air either through the intake itself or from the hopper above. This type
of intake, which in effect is a 90-degree elbow, isolates the hopper from the
conveying line by virtue of its shutoff gate being in the horizontal line. The air
intake at the end of the conveying line is normally restricted and requires a fairly
large pressure drop to admit full conveying air. A scavenger valve, located
downstream of the ash intakes and before any riser, is used for full-load regulation.
With both types of intake, after the initial discharge of material from a hopper,
almost all the conveying air or gas comes from the hopper and not from an outside
source.
The majority of vacuum systems use full-load control, whether by valves using a
scavenger valve or the method employing opening and closing of the fly ash
intakes. Each provides equal results. "Full load" is defined as the system design
vacuum measured at the inlet to the vacuum producer.
When a hopper is empty of all material, the system vacuum drops to a level
approaching that of air flow alone. A no-load vacuum switch is set to close between
no load and full load vacuum and is used to energize the transfer mechanism. The
contacts of the no-load vacuum switch are in series with a time-delay relay. When
the no-load vacuum remains for a time, the sequence switch is energized which
transfers operation from one hopper to the next. The sequence switch also controls
the branch line gates and the water supply valve. The use of the time-delay
prevents transfers due to momentary low-vacuum readings.
An airlock feeder is required to introduce fly ash into the conveying line.
In the first method, one-half of the total number of feeders in one branch line
discharges material to the conveying line. During this time the other feeders are in
the process of venting, filling and pressurizing. Each feeder operates on a cycle of
about two minutes and is continuous until all the material stored in the hoppers
has been discharged. When this occurs, the operating pressure drops to a no-load
value. A no-load pressure switch, in series with a time-delay transfers operation to
the next branch line or to shutdown.
In the second mode, only one feeder per branch line is active at any one time. A
second feeder is vented, filled and pressurized just prior to the end of the active
feeder's cycle. The bottom gate of the active feeder closes and that of the second
feeder opens. Operation continues in this manner until each feeder of the branch
line has operated a set number of times. When this occurs, operation is transferred
to the next branch line or to shutdown.
For a feeder to receive material, it is at a pressure equal to or less than the hopper to
which it is connected. This is accomplished by a vent system that allows the air in
the feeder compartment and the displaced air from the incoming material to be
vented.
Dense-phase transport systems show much promise for future ash collection uses
because of the economies of operation and the longer expected life for the transport
piping.
-I
Section 5 Western Experience with Ash Handling Systems
a Fly ash transport system: to take the ash from the transfer silos and
convey it to ash storage silos for loading into mobile equipment.
The maximum continuous fly ash production is expected to be 128 tons per hour.
The fly ash collection system is designed to collect 300 tons per hour, and the
transport system, to transport 240 tons per hour.
The fly ash collection system must remove sufficient material from 8 air preheater
and 60 precipitator hoppers such that ash buildup will not interfere with operation.
It uses a vacuum system for removal of the fly ash from the air heater and
precipitator hoppers, with transport to an intermediate transfer silo. From the
transfer silo, a positive-pressure pneumatic system conveys the ash to disposal.
The trend in North America is to dry transport and disposal (impoundment) with
off-site removal, for either sale or landfilling. Environmental regulations have also
contributed significantly to the choice of dry and off-site disposition of ash.
'1)1
Section 5 Western Experience with Ash Handling Systems
Pneumatic conveyance will have greater use of dense-phase transport due to the
favorable economics involved.
Pumping to disposal will use low ash/water ratios to minimize the amount of water
in the disposal area. The 1:1 ratio described later will become common.
The survey reviewed operation and maintenance and detailed specific problems.
From the respondents, 36.4 percent indicated that the precipitators had "frequent
failures,", 42.0 percent reported "infrequent," and 20.5 percent indicated that the
precipitators have "very seldom" failed. Discharge electrode failures, raper/vibrator
failures, and collecting-plate failures were documented. The report indicated that
35.2 percent of the problems were with discharge electrodes and 31.8 percent were
with dust removal systems. It was assumed that some of the emitting electrode
failures were caused by hopper blockage and shorting of high voltage bus sections.
The report stated that, "the removal of ash, once precipitated, has historically been
one of the major causes of precipitator malfunction, as well as a contributory factor
to other problems such as discharge electrode failure." Ash hopper plugging caused
the majority of problems.
Fly ash flows as a liquid above the dew-point, but when cooled below 120'C to 150'C
for coal fly ash and 175°C for oil fly ash, its hygroscopic nature causes agglomeration
and caking. To avoid problems, fly ash must be maintained above its dew point
temperature.
Even if flue gas temperatures are above the dew-point, hopper skin temperatures at
the throat area can be lower, because of the heat-sink effect of the ash system
hardware and deteriorated insulation. The agglomeration problem can be
aggravated by severe weather conditions and exposed hoppers facing a prevailing
wind. Condensation, corrosion, and plugging problems are also caused by gas leaks
in the hopper, leaks at the inlet and outlet breaching, and the shell.
Flue gas conditioning with sulfur trioxide and ammonia for enhanced precipitator
collection can aggravate evacuation problems by producing increased agglomeration
of the fly ash.
Electrostatic precipitator maintenance costs may be as high as 10 percent of the
installed cost per year, making it economically justifiable to correct hopper blockage.
" Use alarms to detect high-voltage grounds and hopper ash levels that
have made contact with the high-voltage system. High-voltage current
can heat the fly ash to fusion temperatures and form large glass-like
clinkers when the ash fills the area between the electrodes. Ash fusion
temperatures typically range far higher than the temperature necessary to
cause failure of emitting electrodes. In extreme instances, large areas of
collecting plates can melt.
" Increase the discharge-valve and associated piping sizes from 200 mm to
300 min diameter where high dust-collection rates are expected. The
increased throat diameter of 300 mm reduces plugging problems.
Low internal temperatures do occur in precipitator hoppers. In one instance
reported, internal gas temperatures of 37°C were measured in operating precipitator
hoppers while the temperature of flue gas passing over the collecting plates was
150'C, and an outside (ambient) temperature of 25 to 32°C. The rear-end hoppers in
a precipitator cool down because of the smaller amounts of ash they collect, and
temperature measurements have shown that these hoppers can have essentially
ambient temperatures. Leakage of air through the fly ash intake valves at the
bottom of the hoppers is also a reason for the low internal hopper temperature.
Fly ash intake valves may open and close nearly 250,000 times per year. Under such
conditions, valve seats will wear, resulting in air leakage into the hopper. With a
pressure pneumatic system, air can be forced into the hopper at pressures as high as
100 psig (in a dense-phase system). With vacuum systt:c.s, the motive force for
inducing air into precipitator hoppers is the suction maintained in the precipitator
by the induced-draft fans. This suction can create a vacuum of about 50 cm H20 in
the precipitator. With either system, there is a pressure differential that can result
in leakage of cool air into precipitator hoppers, leading to condensation of moisture
in the flue gas.
A European utility, burning a 40 to 50 percent ash coal for over 25 years, experienced
leaky fly ash intake valves that had been worn by the passage of abrasive fly ash.
This condition resulted in leakage of air and cooling of the inside of the hoppers.
The leaking valves caused the interiors of the hoppers to cool below the water dew
point. This cooling led to flue gas condensation and accumulations of fly ash in the
hoppers, causing precipitator electrodes to short circuit. The high calcium fly ash
formed large pieces of concrete like material that required manual removal.
In general, bottom ash slurry velocities rarely exceed 2.7 m/s (9 ft/sec).
It must also be kept in mind that these figures are for segregated sluicing of ash and
that if bottom and fly ash are mixed for a common system, then other criteria must
be observed. It has been reported that ash volumes on the order of 50 percent by
volume of the ash/water slurry have been successfully sluiced in Poland and
Russia. However, the number of installations and the type of piping material used
as well as the type of pump utilized is unknown.
Recently, two U.S. utilities in the arid Southwestern part of the country have
installed ash transport systems using a 1:1 ratio of water to ash in an effort to
conserve water. Unlike most other ash transport pumping systems, these use
The disadvantages are high initial cost and low efficiencies compared to other types
of materials handling pumps. Typically, these efficiencies are less than 50 percent.
These pumps can be configured with multiple disc sets and can achieve high
capacities and discharge pressures.
So far, the results with pumping ash are mixed. One utility has discontinued the
experiment. This is not to imply that without more testing, they cannot successfully
be used in this service, since they have been successful in pumping other slurry
materials.
Over the years, many types of piping materials and wear resistant fittings have been
used in an attempt to reduce the wear from abrasions and prolong the life of the
systems. Heavy wall steel pipe, heat treated alloy steels, case hardened steel, solid
basalt, basalt lined, and various plastic piping materials have been used in transport
systems with varying degrees of success. The ash composition, size, the transport
water quality and the velocity within the system are all contributing conditions in
selecting a suitable material.
Fittings, most notably elbows, have also had various materials and configurations
investigated. Extra long sweep, wear backs that are replaceable and recessed entry
areas have all been utilized. See Figure 5-35.
Another material, urethane-lined steel pipe, has given excellent service in handling
abrasive bottom ash. It should be noted that this material is expensive.
When burning coal with such a high ash content, it is good practice to continuously
remove ash from the economizer, air preheater, and in applicable cases, the
precipitator.
Although plants utilizing air slides were not observed, it is assumed the air slides
operated intermittently (i.e., not continuously conveying). If compressed air
consumption is not excessive, these slides can be fitted with rotary air locks at the
hopper discharge and operated in a continuous mode.
Air slides present elevation difficulties since the slide must decline to the top of the
intermediary hoppers, limiting their height and, to that extent, capacity. It also
requires dual handling systems and several additional dust collection devices.
Increasing the size of the existing ash disposal pile will entail extending the area of
the ash pile, or increasing the height of the pile, or both, which will require
increased head from the pumps. With dry transport of fly ash, the required flow
capacity for the existing pumps will decrease. This decrease may allow the pumps to
be used without modification for an extended ash pile for some time.
With continued hydraulic transport of the ash, the piping as it wears out from
erosion, can possibly be replaced with pipe of a different material having improved
wear ability and a longer service life than steel pipe.
Two such pipe materials that were reviewed are basalt-lined steel pipe and ceramic
core fiberglass reinforced epoxy pipe. Both have been used extensively for ash
transport in power plants, and both give significantly longer service life compared to
steel.
On-site disposal utilizing trucks rather than other means of conveyance should
certainly be studied.
5.9 BIBLIOGRAPHY
1. Combustion, Fossil Power Systems, Joseph G. Singer, Editor, Comb.
Engineering, Inc., 1981.
2. Singer, Jos. G., et. al., Design for Continuous Ash Removal: Alternative
Concepts in Ash Handling, American Power Conf., Chicago, Ill., April 23,
1979.
3. Caron, M.B., et. al., Steam-Generator Availability as Affected by Ash-Handling
Equipment, Amer. Power Conf., Chicago, Ill., April 26, 1982.
4. Singer, Jos, C., Design for Better ESP/Fabric-Filter Hopper Operation and
Maintenance, Air Pollution Control Assn. 76th Annual Meeting, Atlanta,
GA., June 19, 1983.
5. Loftus, W.E., Ash Handling, Storage & Utilization, Amer. Power Conf.,
Chicago, Ill., April 1976.
6. Morgan, J.C. and Flandermeyer, G.L., Ash Handling Conversion: Labadie
Plant, Power-Gen Americas '93, Dallas, TX., November 1993.
7. Paul, J.C., et. al., Economizer Hopper Design Improvements to Reduce Ash
Pluggage of Regenerative Air Preheaters, Power-Gen Americas '93, Dallas,
TX., November 1993.
8. Materials Handling Handbook, 2nd Edit., R.A. Kulwiec, Editor, John Wiley &
Sons, NY, NY, 1985.
9. Bayles, Jr., W.H., Andrew, W.D., Ash-Handling Systems-Applications to
Industrial Plants, Amer. Power Conf., Chicago, Ill., April, 1982.
10. Dynamic Air Conveying Systems, St. Paul, MN., Sales literature.
13. Carrea, A., et. al., Bottom Ash Dry Extraction Helps to Achieve Zero Water
Discharge and Gives Additional Benefits, Power-Gen '93, Dallas, TX.,
November, 1993.
p,
Section 5 Weslern Experience with Ash Handling Systems
14. Dry system improves ENEL bottom ash handling, R. Tarli and M. Voltan,
Power Engineering, November, 1993.
15. Technology of dry removal of heavy ashes, United Conveyor Corp., Magaldi
Industrie Srl, technical publication.
23. W.A. Kitchen and R.E. Lawrence, "Operating Experience and Design
Consideration Of Continuous Bottom Ash Removal Systems For Utility
Boilers," Proceedings of the America Power Conference, Vol. 44 488-499 (1982)
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Typical Materials
August 9, 1993
TRIP REPORT
Under US AID Contract, Bechtel is to ,espo.d ".o ,peciic requests from RENEL for
technical assistance in the ayea:, crit2cia to inp'.ving operational efficiency of
Romanian power generating plants. A:; a initi~i s.ep in identifying specific areas of
concern, a trip was arrainged for th, 5e.J-'-l tec',ni :a1 team to meet with the RENEL
personnel and visit one or two typical plant s.:te&. The Bechtel technical team on
this trip consisted of Roy, Murrhrk; Bol.. STeigerwald; Joe, Westsik; and myself. Joe
was the task leader.
The scope of my trip was to coilect rJov-ation ih ;. area of specialty which relates
to ash storage, containirertL, and r.clar;atior.. Th- other members of the trip were
to address issue" such as ash handtir, corroiic,, cavitaion, and fuel combustion
efficiencies.
This report incdudes orly what wa.; ob.:kred _d Lhe pertinent data provided to us
On Monday and Tuesday (July 10 an.' 2..w w:. wilh RENEL Technical Director,
Ing. Ion Barbiesacu and a grouy .- b. .,:.: .taff representing RENEL, Institute
of Power Studies and Design (ISP.. and thE:..Aergy Research and Modernizing
Institute (ICEMENERG) 1"he foilr..:. pa.ag~aphs present a summary ofmy
cement/concrete plants,
brick kilns,
lime kilns,
drilling mud production, aund
construction.
The use of ash in construction industr-i (as fill material) is generally limited by the
transportation cost over a distance of approximately 20 Kilometers (12.5 miles).
Attempts to find more industrial use for the a5h has been unsuccessful. Ash is not
returned to the coal mines for a variety of reasons including distance, lack of
demand, and/or absence of dedicated transportation systems.
The ash is generally mixed with to water on a i0: 1 weight ratio (water: ash), and the
resulting mix (slurry) is pumped thc- sto'age area (ash piles). Only about 8 percent
of the water is recycled mainly because of drainage loss; the ash is relatively
permeable and the storage area has nr. lining. The ash in these piles is generally
cohesionless with partidcle size in the range of flne sandy silts (fine sand: 0.1 to 5 mm;
silt: 0.1 to 0.002 mam; ). The dry u:it weight of the ash is on the order of 0.75 tons per
cubic meters (50 pounds per cubic fe . .arge p,.mps and steel pipes are used for
pumping the ash from the plant to the storage area. The diameter of these pipes is
on the order of 25 to 50 centimeters ('10 to 20 inches).
is near the top of the berm and after "lae slui-y is drained, another ring of perimeter
• bi-rms and the storage operation
berm is constructed on top of the p~evio
continues. Several berms may be buii, on tor of .ne another in an almost pyramid
fashion until the storage capac.ty is reached; a, dictated by a variety of factors
including pumping capacity to lift: the sur- . to the top of the final berm, slope
stability of individual beris, and slopc of the entire ash pile. For an overall
&abii'iy
slope of 1: 5 (vertical: horizontal) RENIEL has reported a safety factor of 1.2 to 1.3
(based on Fellenius method of analysis) for the storage operation. Only one slope
failure has been reported at the Turcenii Thermal Power Plant which occurred in
April 8, 1993 (See Attachment 1 to this trip report).
Any leachate (water or liquid) collected from tpe piles, if not recycled, is disposed at
surface waters without any special t catment. The leachate is not monitored for
chemical makeup. The typical chemical centent of the ash is provided in
Attachment 1. Based on the RENE% respoase, the ash contains no significant
amount (nil) of toxic elements, carcinogenic su-bstances, or other chemicals of health
concern. The only radioactive materL1 in the ash is Ra 226 which may be in the
range of 3.25 to 8.10 pico Curie per g cam. According to one member of the
ICEMENER, Institute, the levels of doactivit, in coal is about 10 pico Curie per
gram, consisting of Ra 226 and K40 .
Mr. Barbulescu emphasized that considering the restrictions in obtaining land for
future ash piles, RENEL needs technical assistace and recommendations on
measures to accomplish the following:
Mr. Barbulescu suggested that we i,..it two power plants after conclusion of the
meeting: Craiova 1, and Brazi power plants. He indicated that these plants are
neither typical nor the worst pian3. Howew-r, they do have a fair amount of
problems discussed in the mteet:.', and their proximity to Bucharest would
accommodate our schedule. CraiovrTlant operates on coal and has substantial
problems with ash storage. Bra7z P!nt does. not have ash storage problems as it is
not a coal-firing plant, but it doe,; have substant.al problems associated with
corrosion, cavitation of water feed pumps, fuel combustion efficiency, sulfur
removal technology, and breakage of .ome cl czolers (for details of Brazi problems
see trip reports by the other speciali.>ts). Te rneeting was concluded on Tuesday
afternoon on July 20.
Ash 29
Sulfur 0.8
Carbon 19
Hydrogene I
Moisture 41
Others ??? 9.2
Total 100
The analytical data for the ash, measured in 1989, are presented in Table A of
Attachment 1. The annual production of ash at the plant is approximately 3 million
tons per year. The captured dry ash 1-only about 24,000 tons per year. Less than
about 20 percent of the ash consts of the c<onornizer ash and bottomrash. The
particle sizes of the bottom ash and the econo.i.uzer ash are mostly small and mostly
within size ranges of sands (0.1 to 5 m-llimeters), although gravel size particles may
be encountered occasionally. Avprcx"na~ely 99 to 96 percent of the ash has particle
size smaller than 0.2 mm. The e.o.or-.z~r as:, bottom ash and fly ash are generally
mixed together with water and made ""to a Sturr which is then pumped to the ash
storage area. Steel pipes with ar,approx'mat- diameter of 30 centimeters (12 inches)
are used for pumping the slur.y to thc s~trage area which is located approximately 2
kilometers (1.25 miles) away from tfl..e plant site.
N?
water in order to economize in pumping volumne, water usage, and storage room.
However, these attempts have not been successful mainly because of problems
associated with particle segregation in the pipes and pumping difficulties. They
have not tried adding surfaftants or fue-u!ating agerts to the slurry, or separating
the bottom a~h before pumping the shrry.->"
Coal is brought in the plant by dedicated ra-d cal-s ffhat open at the bottom. The 60
ton capacity rail cars are not lined or ccered al the top. The rail cars return to the
coal mines empty. Ash is not sent back to thr- Minss because the miners do not
want it. Strip mining is used for coal miring iine land reclamation is required in
/
The ash storage near the plant .asu±.began in 1964. The closest available low lying
land (river bed?) was selected for the ash storage area about 2 kilometers from the
plant. The current occupied storage area is appr. x".1ate!y 136 hectares (336 acres). It
is projected that within the next 5 years the ash storage will take up an area of over
175 hectares (432 acres) which is the full storage: capacity of the Criova power plant.
Therefore, the plant operation would ha.ve to shut down in 5 years unless new land
is aquired or the ash disposal/storage problem isTesolved. Acquisition of new land
seems very unlikely. Thus, the ash storage problem has to be resolved and
implemented before the end of the fv-,year period.
After discussing the above issues, we .sited tILe plant facilities and drove up on a
dirt road to see the ash storage area. The ash piles and berms are sometimes
indistinguishable as the berms are coveed with dust (ash). Grab samples from the
berm in several locations appeared to be clayey silt with some fine sands. Grab
samples from the ash appeared like silt with some fine sands. Both the berm
material and the ash depos.ts seemad lcl be relatively permeable and easy to drain.
All the ash piles we saw were we 1. ained ,- and relatively or completely dry. We
could not see the actual wet disposal poinat where slurry is dumped off the pipes. It
was explained to us that the actual d.,mp point looks like a shallow pond where the
water drains or it is pumped back for rF.cling.
I could not see any drainage blankets on the slopes of the berms. it seemed that
most of the water would permeate thyough and very little water could be collected
even if there was a drainage blanket. There were no dust control measures and we
were told that dust clouds are cozr na-n on windy days. Dust has been a source of
complaints from the residents in the surrounLding area. Traffic with light-weight
vehicles is possible on the dry em*.nkmeni. Four-wheeL light-weight vehicles
ash deposits; almost like driving on sand
could be tried on the dryvisite- dunes. The
height of te ash pies we w ., the o;de; of 30 meters (100 feet). However,
these piles were still being use.d and could go higher. We were told that the
pumping capacity is a major facto: 1;: Oeterninhig the final height of the piles.
Stage pumping is not used to increase the height imits for the piles.
N'
for
We then visited an experimental plot of Iand where the ash pile was reclaimed
agriculture. The plot of land was problbly about 0.5 hectares (1.2 acres) situated
on
grade.
top of an ash pile approximately 40 meters (130 feet) above the surrounding
tomatoes;
The plot had healthy crops of cotton, peanuts, strawberries, tobacco, and
fruit-bearing rees including apricots, and apples; grape vines; and other shrubberies.
of
We were told that the only reclamation ,,ik perrormed on the ash pile consisted
were
adding fertilizers directly to the ash near the sui-face. All the crops and trees
grown directly on the ash pile with no top soil. T.he wonderful garden appeared like
the reclamation project was very success-u*. Howev'er, there were several problems.
The land was too high up from the irrigation wrte source and the water had to be
pumped at additional costs. Most of the irrigation water was wasted by rapid
drainage into the ash pile as there was ro liner or relatively impermeable soil layer
to retain the moisture. Also, farmers w.re reluctant to try cultivation because they
were suspicious of possible radioactivity in the ash and possible long-term
carcinogenic effect through the agriculti..al prodticts. We tried some of the fruits
and the left the site.
BRAZI POWER PLANT
On Wednesday July 21, we drove from Bucharest to the Brazi Plant which is a fuel
burning power plant situated in the nc.rthern -mountainous region of the country.
Because the winding two-lane highvwray runs fthrough hills and small resort areas, it
tool-,approximately three hours to dri,e to the plant even through it is only about
80 Kilometers north of Bucharest. We .net wit.'.- the plant director, Ing. Dumitrescu
Mircea and visited the plant.
Mr. NMircea explained that this plant I.az been operating since 1961. Several units
have been added to it since. The plian opnrate.. on fuel oil, on gas, or a mixture of
both depending on fuel availability. hig, sulfur content has been a major source of
is
problem at this plant. The sulfur content of fue! oil from the Romanian crude oil
approximately 1 to 2 percent. However, since !982 fuel oil available to the plant has
had higher sulfur contents on the o;-der of 3.5 percent. Because of short fuel supply,
some of the units which are designed to operate. only on gas have had to operate on
fuel oil intermittently. This has comp.unded problems associated with high sulfur
contents, corrosion, and cavitation. After dhe ,:-.eeting, we visited the plant facilities
and left the site. Since the Brazi Pl2:;t operates on fuel, there are no ash pile
problems at this site. Therefore, this pl,-it is not discu.ssed further in my trip report
which is concerned with ash pile stornage prob:erns. Detail discussion of this plant
and its specific problems :nay be four in trip reports by the other members of the
trip.
and
RENEL Response
Bechtel's Initial Qestions n Ash Storage and Reclamation
(Soil Reclamation and Remediation Studies)
I - provide
Please pile=, a the fc.-.,w'., :r . , c the
.n r-d,-eight
v 43., by %each of each ash
(H) pile:
pile and the size of the area, ,yp.-, cbe pi
2 What are the engineering propcitics of the ash within the ash piles in
general? Please provide typic. values, maximum and minimum
values. Include the following fiorma.ion aS much as possible:
Toxic elements
Carcinogenic substance
Radioactive material
Other chemicals of health concern
4 What size equipment, if a.ny, czri be. used on top of these piles? Please
indicate small vehicles, 4-w-,. vehi.,..:,' rubber-tihed vehicles, small
trucks, heavy equipment etc.
5 What are the possibilities of r'mipli t!:ese ash piles and analysis for
chemical and physical propries?
6 - How old are these piles? Giv. 0g.'i' -tmate and range.
Page 1 of 2
7 - Is any historical information av'ailable on any slope failures and /or
sloughing? Please explain.
9 What is the safety factor agairs s!ope failure through the base of or
throgh the mass of these bernis?
10 - What is the overall safety fac;cr agains, gross s!ope failure of the
entire ash pile inclusive of one or more berms?
11 - What is the current production rate of ash in tons per year per plant?
Is this rate to continue?
12 - Has the ash ever been stabijiz:3d chemically? Please explain and
provide details.
13 - What are the past and present practices of ash stabilization in the
country?
14 - What are the past and presc-., practices of ash pile reclamation in the
country?
15 Are annual precipitation data ,vailable for each location for the past
40 years? Please indicate the sourc; address and phone number.
16 - Are seismic data available for the diffe"ent localities? Please indicate
the source address and phone n.umber.
Page 2 of 2 \A
RENEL RESPONSE (July 20)
. !o,
1 n '.i t .L ,-
TURCENI T.P.P.
ROVINARI T.P.P.
ISALNITA T.P.P.
Right-bank storage 145.0 26.0 In operation.
Left-hand storage 136.0 32.0 In operation
MINTIA-DEVA T.F.P.
DOICESTI T.P.P.
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0.05 d 0.05 32
65
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0.2 .5 6 16
0.5 Z + 8
AS. ,,atnun REEL ypo.,e- psnr., the asi n th' piles has not been
trea eccQi ai
lypiCal va-utJs are - -s it PtDIl0s:
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