La Courbe D'étalonnage: C (PPM) ABS 10 0.1 20 0.3 30 0.45 40 0.6 50 0.75 60 0.9

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C (ppm) ABS

10 0.1
20 0.3
30 0.45
40 0.6 La courbe d'étalonnage
50 0.75 1
60 0.9 0.9 0.9
f(x) = 0.0157142857142857 x − 0.0333333333333333
0.8 R² = 0.997252747252747 0.75
0.7
0.6 0.6

Absorption
0.5
0.45 ABS
0.4 Linear
0.3 0.3 (ABS)
0.2
0.1 0.1
0
0 10 20 30 40 50 60 70
Concentration ppm
ge

0.9
333333333

ABS
Linear
(ABS)

60 70
Temp(min) Qt adsorbe Qe-Qt log(Qe-Qt)
0 0.302 1.018 0.007747778
5 0.94 0.38 -0.4202164034
10 1.194 0.126 -0.8996294549
15 1.258 0.062 -1.2076083105 Courbe de la cénitique d'adsorpti
20 1.296 0.024 -1.6197887583 1.4 1.296 1.3
f(x) = 0.0276857142857143 x1.258
+ 0.671857142857143
25 1.3 0.02 -1.6989700043 1.194
R² = 0.652845104501272
1.2
30 1.32 0
1 0.94

Qt Adsorbe (mg/g)
0.8

0.6

0.4
0.302

0.2

0
0 5 10 15 20 25
Temp (min)
be de la cénitique d'adsorption
1.296 1.3 1.32
7142857143
1.194 x1.258
+ 0.671857142857143
04501272

Qt
ad-
sorbe

10 15 20 25 30 35
Temp (min)
Temp(min) Qt adsorbe T/Qt
0 0.302 0
5 0.94 5.31914894
10 1.194 8.37520938
15 1.258 11.9236884
20 1.296 15.4320988
25 1.3 19.2307692 Pseudo second ordre
30 1.32 22.7272727 25
22.7272727272727
f(x) = 0.736156772544384 x + 0.815960902427863
20 R² = 0.996252062710507 19.2307692307692

15 15.4320987654321
T/Qt

T/Qt
11.9236883942766 Logarithmic (T/Qt
10 Linear (T/Qt)
8.37520938023451
5 5.31914893617021

0 0
0 5 10 15 20 25 30 35
Temp (min)
ordre

7272727272727
2427863
92307692

21
T/Qt
Logarithmic (T/Qt)
Linear (T/Qt)

35
Temp(min) Qt adsorbe Log(Qe-Qt)
0 0.302 0.007747778
5 0.94 -0.4202164034
10 1.194 -0.8996294549
15 1.258 -1.2076083105
20 1.296 -1.6197887583
25 1.3 -1.6989700043 Pseudo premier ordre
30 1.32 0.2
0.00774777800073
0
0 5 995 10 15 20 25 30 35
-0.2 f(x) = − 0.0710873418972498 x − 0.0844857518495518
R² = 0.972567048938096
-
-0.4
0.42021640338319

Log(Qe-Qt)
-0.6 Log(Qe-Qt)
-0.8 - Linear (Log(Qe-
0.89962945488243 Linear (Log(Qe-
-1 7
-1.2 -
1.20760831050175
-1.4
-1.6 -
1.61978875828839-
-1.8 1.69897000433602

Temp (min)
1.32
emier ordre

30 35
− 0.0844857518495518

Log(Qe-Qt)
Linear (Log(Qe-Qt))
Linear (Log(Qe-Qt))

50175

-
-
78875828839
1.69897000433602
Cr Qt
4.796 1.0408
7.853 1.4294
10.401 1.919
Isothérme Qt=F(T)
16.133 2.77
3 2.77

2.5 f(x) = 0.15490807889429 x + 0.272359186171258


R² = 0.996737382594722
1.919
2

Qt Absorbe
1.4294 Qt
1.5 Linear (Qt)
1.0408 Linear (Qt)
1

0.5

0
4 6 8 10 12 14 16 18
Concentration résiduelle
Qt
Linear (Qt)
Linear (Qt)
Cr Qt C/Qt Ce
4.796 1.0408 4.60799385 5
7.853 1.4294 5.49391353 10
10.401 1.919 5.42001042 15
16.133 2.77 5.82418773 20
Isothérme de langmuir
25
20
20
15 x − 47.0902899032402
f(x) = 11.1664940141788
15 R² = 0.798332525072048 Co
10 Lin
10 Lin

Ce/Qe
5
5

0
4.4 4.6 4.8 5 5.2 5.4 5.6 5.8 6
Ce
me de langmuir

20

15
788 x − 47.0902899032402
048 Column D
10 Linear (Column D)
Linear (Column D)

.4 5.6 5.8 6
Ce Qe ln(Ce) ln(Qe)
4.796 1.0408 1.56778224 0.03998965
7.853 1.4294 2.06089562 0.35725478
10.401 1.919 2.34190196 0.65180422
16.133 2.77 2.78086686 1.01884732

Isothérme de franlish
1.2

1 1.01884732019925
f(x) = 0.817561691964792 x − 1.27173789852423
R² = 0.991598312873013
0.8
0.65180421702556

Ln(Qe)
0.6 3

0.4 0.35725477580374
1
0.2
0.03998964821615
0 84
1.4 1.6 1.8 2 2.2 2.4 2.6 2.8 3
Ln(Ce)
franlish

1.01884732019925
173789852423

.65180421702556
3

80374 ln(
Qe)

.4 2.6 2.8 3
T(k) Ci Abs initiale Abs finale Ce Qt
298 10 0.79 0.021 3.458 1.3084
303 10 0.79 0.009 2.69 1.462
323 10 0.79 0.0003 2.14 1.572
,

Q=F(t)
1.8
1.572
1.6 1.462
f(x) = 0.00910285714285715 x − 1.35621333333333
1.3084
1.4 R² = 0.827218379783786
1.2
1 Qt
Linear (

Qt
0.8
Linear (
0.6
0.4
0.2
0
295 300 305 310 315 320 325
T(k)
1.572
333333333

Qt
Linear (Qt)
Linear (Qt)

325
1/T Ln(Kd) Ce Qt Kd=Q/C
0.00335 -0.97188537 3.458 1.3084 0.378369
0.0033 -0.60973583 2.69 1.462 0.54349442
0.00309 -0.30845714 2.14 1.572 0.73457944

Ln(Kd) = F(1/T)
0
0.003 0.0031 0.0032 0.0033 0.0034
-0.2
-
0.30845713502674
f(x) = − 2223.00651998868
5 x + 6.58733505559928
-0.4 R² = 0.852415681662002
Ln(Kd)
-

Ln(kd)
Linear (Ln(Kd)
-0.6 0.60973583228616
1 Linear (Ln(Kd)

-0.8
-
-1 0.97188537057900
7

-1.2
1/T
T)
3 0.0034

+ 6.58733505559928
Ln(Kd)
- Linear (Ln(Kd))
.60973583228616
1 Linear (Ln(Kd))

-
0.97188537057900
7

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