GCM 2015
GCM 2015
GCM 2015
Section
CEREALS IN BREWING AND DISTILLING wheat, barley and rye beers and the beginnings of the
‘national drinks’ of a number of countries.
The history of the cultivation of cereals and the production
of beer and distilled spirits are closely linked. It is widely Wind forward to the present day and what has changed?
claimed that the invention of bread and beer was Mankind’s (and industry’s) reliance on wheat and barley as
responsible for humanity’s ability to develop technology food crops continues, and the demands for cereal crops
and build civilisations, but this was not possible until the today seem to come under the influence of more diverse
widespread development of the first ‘domesticated’ cereal factors such as climate change, exchange rates, sustainable
grains which can be traced back to around twelve thousand industry, population growth etc.
years ago. It is these early Holocene farming communities in
southwest Asia, and the development of the first crops of CEREALS – PRODUCTION
wheat and barley, that gave rise to the brewing and
distilling industries we now take for granted. Cereal grains are members of the monocot families
Poaceae or Gramineae, more commonly known as grasses,
Beer was first believed to have been brewed as early as
cultivated for the edible components of their fruit seeds –
11.5 thousand years ago or shortly after cereal was first
the endosperm, the germ, and the bran. They are grown in
farmed. It is recorded in the written histories of Egypt and
greater quantities and provide more food worldwide than
Mesopotamia, although it is probable that beer-like
any other crop. As whole grains, their natural form, they are
beverage were produced as a result of natural fermentation
a rich source of vitamins, minerals, carbohydrates, fats, oils
of starches or sugars throughout the world where cereals
and proteins. When refined by removing the bran and
were available. Distillation has been around since around
germ the remaining endosperm is mostly carbohydrate and
2000 BC, with perfumes and aromatics being distilled by the
the remaining nutrients are lost. Cereals form the basic diet
Babylonians. Distillation was brought to Europe by the
in some developing nations, with grains in the form of
Moors, and its use spread through the monasteries, largely
maize, rice, wheat or millet being prevalent. In the
for medicinal purposes, such as the treatment of colic,
developed world, cereal consumption is a smaller portion of
palsy, and smallpox. Between 1100 and 1300, distillation
the diet but is much more varied and, in terms of total
spread in Ireland and Scotland, with monastic distilleries
consumption, substantial.
existing in Ireland in the 12th century. Since the islands had
few grapes with which to make wine, barley beer was used
Table 1 shows the growth in annual world cereal production
instead, resulting in the development of whisky. Unlike beer
from 1961, data from the Food and Agriculture
production, it took the development of the art of distillation
Organisation of the United Nations. All but buckwheat and
before specific distilled spirits were first available – rather
quinoa are true grasses (these two are pseudocereals).
than the availability of starch/sugar supply – and it wasn’t
until around 1400 when it was discovered how to distil from
Worldwide production
Grain (millions (106) of metric tons) Notes
2013 2012 2011 2010 1961
A staple food of people in America, Africa, and of livestock worldwide; often called corn or Indian corn in
Maize (corn) 1016 872 888 851 205 North America, Australia, and New Zealand. A large portion of maize crops are grown for purposes other
than human consumption.
The primary cereal of tropical and some temperate regions. Staple food in India, Brazil, Korea, Japan and
Rice 745 720 725 703 285
China
The primary cereal of temperate regions. It has a worldwide consumption but it is a staple food of North
Wheat 713 671 699 650 222
America, Europe, Australia and New Zealand.
Barley 144 133 133 124 72 Grown for malting and livestock on land too poor or too cold for wheat
Sorghum 61 57 58 60 41 Important staple food in Asia and Africa and popular worldwide for livestock
Millet 30 30 27 33 26 A group of similar but distinct cereals that form an important staple food in Asia and Africa.
Formerly the staple food of Scotland and popular worldwide as a winter breakfast food and livestock
Oats 23 21 22 20 50
feed
Triticale 14.5 14 13 14 35 Hybrid of wheat and rye, grown similarly to rye
Rye 16 15 13 12 12 Important in cold climates
A pseudocereal, as it is a Polygonaceae and not a Poaceae or Gramineae, used in Eurasia. Major uses
Buckwheat 2.5 2.3 2.3 1.4 2.5
include various pancake and groats
Fonio 0.6 0.59 0.59 0.57 0.18 Several varieties of which are grown as food crops in Africa
Quinoa 0.10 0.08 0.08 0.08 0.03 Pseudocereal, grown in the Andes
Maize, wheat and rice together accounted for 87% of all Cereal crops, including malting barley, are traded as
grain production worldwide, and 43% of all food calories in commodities around the world where grain from an area of
2003, while the production of oats and rye have drastically surplus (lower price) is traded with an area of deficit (higher
fallen from their 1960s levels. Other grains that are price). This matches supply with demand and brings prices
important in some places, but that have little production together to make a global market and a global price. The
globally (and are not included in FAO statistics), include: availability, and therefore price, of cereal crops is
determined in the short term by the crop size in any
Teff, popular in Ethiopia but scarcely known particular year and the stock level brought forward from
elsewhere. This ancient grain is a staple in the previous year.
Ethiopia. It is high in fiber and protein. Its flour is
often used to make injera. It can also be eaten as a A look at definitions of ‘beer’ available from various sources
warm breakfast cereal similar to farina with a shows an interesting range of ingredients – as well as
chocolate or nutty flavour. Its flour and whole water, hops, and yeast various definitions also call for
grain products can usually be found in natural ‘malted barley’, or ‘malted cereals’, or just ‘cereals’ , so
foods stores. despite a reliance on barley crops during beer’s long history
Wild rice, grown in small amounts in North there are alternatives to all-barley malt brewing. Clearly this
America is not a new proposition; looking back over the 125 years of
Amaranth, ancient pseudocereal, formerly a staple the Institute of Brewing and Distilling’s history there are
crop of the Aztec Empire and now widely grown in many references to these ‘alternative’ uses of cereals. The
Africa Brewers Journal’ of November 1886 reported “a very happy
Kañiwa, close relative of quinoa idea that was originated by Messrs Gillman, Spencer Ltd,
who had a competitive exhibition of beers brewed with
Several other species of wheat have also been their patent rice and torrified barley malts. Over 100
domesticated, some very early in the history of agriculture: brewers responded to the invitation, their prospects of
substantial prizes apparently having proved an incentive
Spelt, a close relative of common wheat not to be neglected.” This ‘idea’ eventually evolved into the
Einkorn, a wheat species with a single grain Brewing Industry International Awards, which today
Emmer, one of the first crops domesticated in the demonstrate how far the brewers have moved from being
Fertile Crescent almost exclusively dependant on malted barley. There is
Durum, the only tetraploid species of wheat also a long history of beers made with malted wheat
currently cultivated, used to make semolina around the world, as well as brewing in areas where the
Kamut, an ancient relative of durum with an most popular cereals are not available, such as with
unknown history sorghum and millet in Africa.
Increased production of cereals over the last 40 years has The distilled spirits industry, outside of the traditional of
largely kept pace with population growth over the same grain distilling, has managed to diversify during its
period of time (3.0 billion to 6.9 billion estimated). A development into fruit, sugar, and simple-starch based
fourfold growth in maize, a staple food of people in the products as were able to be locally sourced. There has also
Americas, Africa, and of livestock worldwide, has been the developed a much more varied use of cereals, and less of a
biggest driver of this increase. Wheat as the primary cereal reliance on a supply of a single malted cereal. A good
of temperate regions, and barley grown for malting and example of this is the North American whiskey industry
livestock, have both increased threefold, whereas rice (as where a wide variety of cereals, both malted and un-
paddy, or wholegrain rice) as the primary cereal of tropical malted, are used to produce a wide range of whiskey styles.
and some temperate regions has seen a doubling in
production. Oats and rye have seen a fall in production as Key types of American whiskies listed in the US Code of
demand for them has fallen, oats once being the staple Federal Regulations:
food of Scotland and other cold climates. - Rye whiskey, mash contains at least 51% rye.
- Rye malt whiskey, mash contains at least 51% malted
Today’s brewing and distilling industry competes with a rye.
number of sources for this farmed resource. Traditional - Malt whiskey, mash contains at least 51% malted
food and drink now is competing with other industries such barley.
as the bioethanol, and with world population expected to - Wheat whiskey, mash contains at least 51% wheat.
hit 9.5 billion people by 2050 it is expected that this growth - Bourbon whiskey, mash contains at least 51% corn.
in cereal production will continue. Some people may argue - Corn whiskey, mash contains at least 80% corn.
that we will reach crisis point with our abilities to feed
ourselves, and sustainability of food and drink supplies of
the future will become increasingly important or indeed
critical, but I will leave these discussions to others and focus
on the use of the cereals available today for the production
of beer and distilled spirits.
Barley and other cereals such as wheat, maize, rice, oats, As stated before, malted barley is the main raw material
and sorghum belong to the family of grasses (Gramineae). used in the brewing of beer. Malt provides the sugar that
Barley is classified as: will be fermented into alcohol in the brewing process.
Barley is a cereal traditionally grown in mild varying
Family = Gramineae. climates and for centuries it has been used in the
Subfamily = Festucoideae production of beer.
Tribe = Triticeae
Genus = Hordeum
Malting Barley
Maltsters commonly malt two species of barley:
Endosperm
b) The endosperm comprises hard insoluble starch, Germ
which is the food reserve to be used by the
growing germ of the grain. The embryo calls for
the release of enzymes and production of further Root
enzymes which travel into the endosperm,
During the malting process however, the cell walls and the During germination two major changes occur:
protein will be dissolved by other enzymes which are
produced naturally as the seed grows. The barley selected Firstly, hormones stimulate the production of enzymes in
for processing into malt must meet certain specific the aleurone layer.
requirements:-
Secondly, these enzymes start to act.
It must be capable of growth. The key stage of the During malting they will break down the gummy cell walls
malting process is germination when the barley seed and break down the protein matrix. This breakdown
starts to grow. This growth needs to be rapid and even; releases the starch granules making them accessible for
barley that is ‘dormant’ takes a long time to start conversion into sugar.
growing.
The changes taking place during germination are called
It must have a relatively low proportion of protein. The
‘modification’. The maltster can influence the degree of
lower the protein, the higher the amount of
modification during malting by controlling the moisture
carbohydrate. (Protein levels are measured by
content of the grain, its temperature and the time allowed
measuring nitrogen content.)
for germination. During germination the seed grows
The corns should be of an even size. That way they are
rootlets and a shoot.
more likely to grow evenly and will be more consistent Close up of the effect
of enzymes on the
in milling at the brewery. endosperm.
GERMINATING
The corns should be bold. Bold corns contain more BARLEY
starch by proportion and therefore have a higher extract Cell walls dissolved.
potential.
Protein dissolved.
The barley must be of a ‘malting variety’. Malting
varieties have a more open endosperm which accepts Starch granules
water readily during steeping, encouraging rapid and Shoot
released
even breakdown of endosperm cell walls.
The corns must be undamaged and free of disease.
Water
Growing Barley
Barley
Plant
Burner
Steep Tank
or Boiler
Extractable Very low, as Very high because the starch Kilning does not change the level of
carbohydrate. enzymes have not granules have been released. extractable carbohydrate but it does fix
developed. They are now accessible to it by reducing moisture and stopping
enzymes that convert starch germination.
into sugar.
Colour. Very low. Very low. Colour is produced when sugars and
soluble protein react together at high
temperature.
Protein Malting grade Nitrogen level reduces slightly Kilning does not change the nature of
2 row barleys for during germination as rootlets the proteins and carbohydrate but it
(measured from the pale ale malts have and shoots are produced. does fix them by stopping germination.
Total Nitrogen nitrogen levels of Much of the protein is
content – about 1.4% to 1.9%, solubilised by enzyme activity. Kilning temperatures will reduce some
depending on the enzyme activities by denaturing the
% w/w TN brewer's malt Important parameter is ratio of protein.
x 6.25 specification the Total Soluble Nitrogen
= % Protein) (protein from 8.7% (TSN) to the Total Nitrogen Lighter kilned malts (lower colour) tend
to 11.9%) (TN) in the malt. to have higher enzyme levels).
Brewers in some Known as Soluble Nitrogen Roasted malts have no enzyme content.
countries may use 6 Ratio (SNR) or Kolbach Index.
row barleys, which
have protein levels
up to 14% (2.0-2.3%
nitrogen) and
correspondingly
higher enzyme
content.
Drum Malting
Figure 1 Floor Malting (Source: Warminster Maltings)
Galland developed the drum malting process and built his
It is important to note that in floor malting there is no air first plant in 1873. Drum malting would become the most
flow through the germinating barley and there is no common commercial malting process of the late 1800’s and
automatic turning machine. This results in the need to turn early 1900s.
the malt frequently by hand using shovels. As a result, floor
malting is very labour intensive. Drum malting makes use of a rotating drum for
germination. The rotation of the drum gently turns the
If done with proper care, floor malting can produce green malt, preventing matting of the rootlets, provides
consistent malt; however it is very labour intensive. Also temperature regulation, and facilitates air flow.
piece size is very small compared to modern malting
methods.
Figure 2 shows a typical drum malting system. A large door
Floor malting is most practical for small batch sizes. in the side of the drum allows for loading of grain into the
Because the grain is spread out fairly thin, a large amount drum via a loading conveyor. The same door is used for
of floor space is required for large-scale operations. There unloading when the drum is rotated such that the door
are currently no large-scale commercial floor malting faces downward to an unloading conveyor.
facilities in existence. The last large commercial operation
was in association with the Stella Artois company in A mechanical drive system consisting of wheels and gears
Belgium. This operation shut down in the late 1980s. At the slowly rotates the drum. Drum motion is slow, nearly
present time, floor malting, is only performed by small imperceptible to the human eye.
specialty maltsters and hobbyists.
Pneumatic Malting
th
In the 19 century, the first pneumatic maltings were
developed. Pneumatic malting is any process alternative to
floor malting that forces a stream of cool, humidified air
through the germinating grain. The invention of pneumatic
malting represented the first major advancement from
floor malting. It was first introduced in the mid-1800s, and
reached commercial success in the late 1800s.
Lausmann System
The Lausmann system is another type of moving batch
system, similar in many respects to the Wanderhaufen
system. This system, shown in Figure 5, uses a series of
moveable germination beds. The green malt is moved
forward from one bed to the next as the germination cycle
progresses. To accomplish this, the beds are equipped with
jacks to raise and lower them as needed. As one
compartment is raised, the turner moves the green malt
from that compartment to the next compartment, which is
Figure 3: Drum Malthouse slowly lowered as it fills with grain. As in the Wanderhaufen
system, one advantage is that the conveyor reverses bed
The Wanderhaufen System top to bottom on each transfer.
The Wanderhaufen system is another modern malt plant However, the Lausmann system has the following
design. Unlike the other methods that perform the disadvantages:
germination cycle in one place, the Wanderhaufen system Batch size is limited.
is a moving batch process. The Wanderhaufen system uses Irregular air flow. The edges of the piece are
a long bed area called a germination “street” that holds sloped.
multiple pieces. A transfer conveyor that is similar to a High maintenance costs. Mechanically complex.
large excavating machine advances the green malt to a new Difficult sanitation.
location on the bed in place of a turning machine. One
advantage of this system is that the action of the conveyor
reverses the bed top to bottom on each transfer.
Flexi Malt systems were very popular in the late 1960s and
early 1970s, however after the energy crisis of the 1970s,
their popularity waned due to excessive energy costs.
Recently there has been some new interest in Flexi Malt
systems, particularly in Europe, where some Flexi Malt
houses have been built using stainless steel structures
Figure 6 Buhler-Miag Tower Malting System instead of concrete. Construction of the vessels in stainless
steel overcomes much of the energy potential associated
The Seeger tower design, shown in Figure 7, is another type with this design.
of tower malting system. This system is similar to the
Buhler-Miag tower malting system except that it uses a
separate kiln building to house the kiln. For optimum
kilning, the depth of the grain bed should be less than the
bed depth in the germination bed. Having the kiln located
in a separate building allows the kiln to have a larger
MALTING LOSS
During the malting process, barley respires producing
energy for growth. As the grain respires it consumes and
expends integral substrates (e.g. carbohydrates and
protein) in the production of new tissue, CO2, water and
heat energy. This consumption depletes the extract
available to the brewer, recognised as a reduction in the
total dry weight of the grain and represents malting loss.
Malting loss is also enhanced as materials leach from the
grain during steeping. Typically malting loss is described in
Table 1.
BARLEY GROWING
Family = Gramineae
Subfamily = Festucoideae
Tribe = Triticeae
Genus = Hordeum
BARLEY VARIETIES
Two and Six Rowed Barley
Awn(s)
Lateral grain in 6
rowed; sterile
spikelet
in 2 rowed
Central grain,
develops from the
central spikelet in
both varieties
Glumes
Segment
of Rachis
Spikelet Spikelet
Ear Ear
group group
The most important factor during harvesting is the moisture The grower wants varieties that have high yield, are easy to
content of the grain. Following harvest the crop must be harvest, will mature within the local growing season, won’t
sufficiently dried to prevent germination and reduce the succumb to disease, and will garner the extra money when
risk of microbial infections occurring prior to use. If dried sold for malting. The grower is thus very likely to buy seed
incorrectly the quality of the grain will deteriorate in store. with improvements in any of these areas without reducing
the quality of other traits.
The barley harvest differs from growing region to growing
region because of weather conditions. Likewise, the maltster wants barley with plump kernels,
high extract potential, moderate protein, high starch
In some regions harvest weather conditions are typically content, high enzyme potential, a strong husk for efficient
dry, so the barley can be cut and immediately threshed. The mash separation in the lauter tun, and low beta glucan for
mature barley kernel moisture content must be less than good filtration in both the lauter tun and the beer filter. The
13.5% before it can be harvested. Moisture content above maltster will encourage the grower to produce varieties
13.5% leads to quality problems during storage, such as loss that meet these malting needs.
of viability, increase in microorganism growth, development
of off odours, and heat damage. However, elsewhere the If a plant breeder develops a variety that meets all the
cut barley is laid on the stubble to air dry for a few days needs of the grower and the maltster, the breeder will sell a
before it is combined and threshed. Rain or heavy dews lot of seeds and benefit financially. Unfortunately, the
during the harvest necessarily alter the harvest time line. perfect malting barley does not yet exist, and in theory it
never will. The very foundation of breeding and the nature
European harvest practice is to cut and thresh the barley of the intricate end-use (brewing) requirements means that
when its moisture content is about 15% to 25% and then even the best current variety can be further improved for
lower the moisture to less than 13.5% with air dryers prior agronomic and malting characteristics.
to storage.
BARLEY BREEDING
Development of new varieties
Traditionally barley breeding has involved the selection and
Barley, rice, corn, and hops form the agricultural foundation crossing of varieties. Barley, as a self-pollinating crop
of brewing and distilling. The higher the quality of these produces genetically identical offspring. Breeders introduce
raw materials, the higher the quality of the finished variety by preventing self-pollination (removing the
products. Over time, these individual agricultural anthers) and then fertilising the plant with pollen from
components have been manipulated to provide specific, another. Superior plants from the progeny are then
desired characteristics. selected and allowed to grow and pollinate naturally. For
example the variety Proctor was created in this manner.
Development of new crop varieties is driven by competition
among plant breeders. Farmers and growers are forever
looking for ways to increase the yield from their planted
Learning Material 2015 17
In the simplest cases two parent barley varieties are strain should show improvements in yield, malt quality and
crossed, seed is harvested and grown normally. The first disease resistance by the third generation.
(F1) generation grown from the cross, which contains
chromosomes with genes from both parents, is said to be Potential new varieties must then pass through micro-
heterozygous and does not breed true. malting and brewing trials before full plant trials prior to
trade acceptance.
Successive generations become more homozygous (purer)
and selections are made initially for the first three or four Alternative methods of plant breeding have involved
generations on visual appearance and disease resistance. producing induced mutations or have examined naturally
Occasionally backcrossing is employed where the F1 occurring ones. However, many mutations are deleterious
generation is immediately re-crossed to one of the parents. and many otherwise desirable mutations have associated
Alternatively, multiple crosses may be carried out where characteristics that make them undesirable. Examples of
two F1 generations with different parents are crossed. mutated barley that has been successful or have created
interest are Golden Promise (gamma-ray mutant of
Various techniques have been developed to shorten the Maythorpe) and Glacier, a natural mutant of an American
time taken between the initial cross and the production of a six-row barley. Glacier had 40% amylose in its starch
pure strain. The earliest method was to grow spring barley instead of the normal 20%. There are various chemical
crosses in New Zealand during the UK winter and thus mutants of Triumph that lack anthocyanogens.
obtain two generations within a year.
Before the new cultivar can be recognised and
Newer techniques involve producing haploid plants with recommended by national regulatory body’s (e.g. DEFRA in
half the normal number of chromosomes, treating them the UK, or The Malting Barley Research Institute in Canada)
with a chemical (colchicine) which induces chromosome it must first be seen to show distinctiveness, uniformity and
doubling, resulting in a diploid (normal chromosome stability. This is known as the DUS test and this test can
number) homozygous plant. The haploid plants can be take up to three years to complete. National List (NL) trials
produced either by tissue culturing pollen from the F1 establish DUS.
generation or by crossing the F1 generation with a wild
barley Hordeum bulbosum. In the latter case, the DUS is the acronym for:
chromosomes from Hordeum bulbosum are lost during
division, resulting in a haploid plant. Distinctiveness - that a variety is in some way
distinct from other varieties.
Plumage Archer x Kenia After each challenge has been accomplished is it surprising
to note that less than one in every 100,000 crossed
offspring make it to variety status.
F11
RL2 Provisional Approval (1)
Candidates for Full Approval will normally have been
awarded Provisional Approval 1 based on micro-malting
results. To gain Full Approval, the Malting Barley Committee
must have evidence of satisfactory pilot scale and
commercial performance in the maltings/brewery/distillery.
F11
Provisional Approval (2)
A variety should normally progress to Full Approval with
one year of commercial trials. Where there has been
insufficient satisfactory malting, brewing or distilling trials
to award Full Approval in one year of commercial trials, the
Malting Barley Committee may award Provisional Approval
2 to denote that a variety has not been rejected and is still
progressing through the approval process.
Foreign Seeds Any non-barley seed in the Throughout malting, and indeed any grain-handling
sample, including wheat, wild environment, great care is taken to remove both dust and
any material that could generate a spark. This is to prevent
oats, weeds etc.
dust explosions which can be both violent and dangerous.
Varietal Separate other varieties using Each machine is hooked up to a dust collection system and
Purity morphological identifiers will not run if the dust collection system is not running.
(rachilla hair length, awn
Barley Separation
smoothness, husk adherence,
Separation takes place in long, rotating cylinders (Figure 1)
husk smoothness, number of that remove all grains that are shorter than barley,
lateral vein barbs) on varietal including broken half grains and small weed seeds. The
identification flowcharts. cylinder has pockets or indentations on its interior surface
into which only the weed seeds and half grains will fit. Only
Blight Tan to dark brown spots distal to debris is retained in these indentations. As the cylinder
the germ or dark brown to black rotates further the retained material is ejected at the apex
coloration at the germ end of into a central trough for extraction. Broken grains are
the kernel. Fusarium infection especially undesirable as they will not malt normally; they
can manifest as pink corns. pick up moisture easily and they harbour bacterial and
fungal infections.
Mould Microflora growth along the
crease of the kernel. Barley Grading
The barley is next subjected to grading, a relatively slow
Skinned and One third or more of the husk is process. Grading is used to segregate grains of different
Broken missing or a loose husk that sizes. Different sized grains germinate at different rates,
Kernels exposes the germ, or part of the leading to non-homogeneous batches of malt. For instance,
germ is missing. small grains will hydrate and respire vigorously expending
oxygen faster than large grains. The small grains will bolt,
Immature The kernels are green. malting more rapidly and modify to a greater extent than
Kernels the larger grains. If unchecked, the malt will contain
proportions of under-modified large grains, and over
modified small grains, each of which will behave differently
PREPARATION OF BARLEY FOR MALTING in the brewhouse.
Barley and malt are stored in deep silos, some with During grading barley flows over vibrating screens or sieves
capacities in excess of 3000 tonnes, or flat stores which may fabricated with slots of defined sizes (Figure 2). Plump
be much larger. As a living tissue, prolonged storage in grains pass over the screen, whilst the thinner grains fall
such conditions can suffocate the barley grain. To prevent through and are subject to further screening.
Sequential
sieves
Barley
1st 3rd Thin 2nd
grade grade s grade
1) 2)
Figure 2. Schematic representation of 1) barley separation Three types of by-products are generated.
and 2) barley grading.
Feed barley - Small kernels of barley that pass
Repeated sieving can result in two or three grades of through a 2.25mm screen during barley cleaning.
barley:
st Offal or dockage - Straw, husk, hull and some dust
1 grade: The plumpest grains, usually comprising from the aspiration of all machinery. (Mainly
over 95% of the grain bulk, used to produce barley cleaners and dust systems)
standard malt.
nd Culms (also rootlets or sprouts) - Small malt
2 grade: Thinner grains, may be used for kernels, rootlets, husk, and husk from kiln and malt
speciality malts. cleaning.
rd
3 grade & “thins”: Are unacceptably small for
Any material which has safe nutritional value to
malting and are sold as animal feed.
animal feed may be pelleted for ease of storage
and transportation. This would not normally
Usually two grades are sufficient separation – one bold include barley screenings (feed barley) as it is easy
grade for malting, and the smaller corns (screenings) to be
enough to handle by itself.
sold into the feed grain market. Once graded the barley is
stored ready for use. Grain is transported around the Drying and Storage
maltings in various ways including:
Grain harvested from the field will vary in moisture content
from around 12% in some growing regions, to 15% in a dry
year in others, to 30% in a wet year. Whatever the moisture
Bucket elevators. at intake, the grain must be dried down to 12 - 13% (or less)
Screw conveyors.
for safe storage. Above 13% moisture, barley is susceptible
Pneumatic systems. to insect or mite attack and since the grain may be stored
Endless belts. for many months it is obviously essential that this risk be
removed. Even if the eggs of grain weevil or saw tooth
The barley and malt cleaning processes result in the
beetle are present they are unable to grow and multiply if
creation of a significant amount of co-products. While the moisture of the grain is less than 12% and the
o
these co-products represent barley mass that cannot be temperature is below 15 C.
turned into malt, they are not simply thrown away.
If moisture levels exceed 13%, the grain can start to respire
and generate heat, leading to moisture transfer through the
bulk and possible condensation in cooler areas. If action is
not taken to correct this, further heat build-up will occur
and further respiration. Concentrated areas of heat known
Drying Methods
Fumigation
Air On 45-55°C Insect infestation in barley creates sanitation problems in
the storage bins and malt house, and can damage barley
On-farm drying can be poorly managed, as dryers are often quality. If infestation is detected in a bulk, specialist
specified for drying feed wheat, which can be done at contractors can be employed to administer phosphine
higher temperatures and therefore higher throughput treatment, usually from solid formulations such as
rates. This information is misleading to those unaware of aluminium phosphide. The time of treatment needs to be
the vital importance of germ viability to malting barley. In long enough to kill active insects as well as insects
itself, on-farm drying is not a problem - it is the subsequently hatching from eggs.
management and control that has given rise to problems in
the past. Phosphine is the only fumigant approved by some brewers
for direct contact with barley. It is extremely poisonous to
insects (and people), but leaves no post-application residue.
Phosphine is usually not detectable 7 to 10 days after
fumigation.
The objective of steeping is to raise the moisture content of (b) Germinative Energy
the barley to a level which will start the germination The germinative energy of the grain sample is the
process and then allow it to continue so that the enzymes percentage of kernels that germinate at the time of testing
of the grain modify the starchy endosperm. The aim of and gives a measure of the dormancy potential of a sample.
modern steeping is to have the grain uniformly chitted but
no root growth at the end of the steeping period. The grain Method:100 grains are placed on top of filter
should be uniformly hydrated and have a rapid, uniform paper in a petri dish and 4 ml of water added. The
and controllable growth rate. number of grains that have chitted each day are
counted and removed from the plate. After
incubation for 72 hours at 18°C, the grains that
It is crucially important that the moisture content of the
have germinated are expressed as a percentage of
resultant germinating barley is distributed as evenly as the total.
possible between each kernel. If this were not the case then
each kernel would grow at a different rate and unevenly (c) Water Sensitivity Test
modified, poor quality malt would result. The objective of this test is to determine the potential of
the grain sample to grow in excess water – this reflects
conditions during steeping. The method is similar to the GE
METHODS FOR ASSESSING MALTING BARLEY
test, but 8 ml of water replaces the 4 ml and corn counts
are made at 24 hour intervals. Water sensitivity is
Using some basic analytical methods and data it is possible
expressed as the difference (as a percentage) between
to predict the eventual malt quality. Some of these
germination in 4 ml of water and germination in 8 ml of
methods are described below. The predicted data are
water.
compared with customer malt specifications and barley is
then provisionally allocated to individual customers or malt
types. It is common to keep details of each barley Example
reference including variety, merchant, location, contract
After 72 hours incubation, 91 grains of the 100 grain sample
specification and tonnage. Additionally it is good practise
to keep analysis results for nitrogen (TN), TCW, and the have germinated in 4 ml water; only 75 of the 100 grains
placed in 8 ml of water have germinated.
Varietal Constants for each variety. This information may
be used for calculating extract potential.
Therefore, Water Sensitivity = (91-75) = 16
(a) Micromalting
Micromalting is a laboratory process where small samples
of barley can be germinated using processing conditions (d) Germinative Capacity
resembling those in the commercial malting plant. During The germinative capacity of the grain sample is an attempt
micromalting, measurements are recorded for water to quantify the percentage of viable corns within a sample.
uptake and evenness of germination so that This may include the forced growth of grains expressing
recommendations can be made about the readiness of the degrees of dormancy. Most commonly this is achieved
barley for malting, the processing conditions to use, and the using a solution of hydrogen peroxide, to supply the corns
likely quality of the finished malt. with excess oxygen forcing the viable, yet dormant grains to
germinate.
Barley samples that have recovered from dormancy
naturally, or conditioned in the laboratory, are micromalted Method:200 corns are steeped in 200ml of 0.75% (v/v)
to determine the actual malt quality that will be achievable hydrogen peroxide for two days at 18-21°C. The corns are then
when the barley is fully mature. There are different strained and 200 ml of fresh hydrogen peroxide added and the
methods for micromalting ranging from glass jars to barley again incubated at 18-21°C for one day. The germinated
sophisticated commercial equipment. Although these grains are counted and the germination capacity expressed
methods are useful in predicting malt quality they have overleaf.
their pitfalls if the sample size is too small. Basically, the
bigger the sample the more representative it will be of the Germination capacity % (hydrogen
batch of malting barley. peroxide) = 200 – n
So, GC = (200-42)/2 = 79% The Bishop Equation derives potential soluble extract from
the relationship between thousand corn weight (TCW),
After a further 24 hours incubation another 12 grains have total nitrogen content (TN) and a varietal constant. This
germinated. last parameter represents the capability a particular variety
has for achieving good soluble extract. The higher the
The adjusted GC = (200-30)/2 = 85% varietal constant then the higher the malting grade of
barley.
KEYPOINT: A viability test determines the proportion of Rate of transport of gibberellic acid to the
living cells or organisms in a sample. aleurone layer.
For germinative and viability tests maltsters demand a high Potential of aleurone to produce
proportion of viable grains – 98% in the UK, down to 92% endosperm degrading enzymes.
for some European futures contracts. Maltsters have no
way of separating live kernels from dead, so the final malt Rate of enzymatic breakdown and
will always have a small proportion of dead grain. modification of the starchy endosperm.
Air in
Barley exits to
germination
vessel
Days
80
barley
75
Less effluent generated Less “washing” of grain, higher BOD 70
and solids in reduced effluent 65
volume
60
More difficult to control final 40 42 44 46 48 50
moisture – often resort to spraying Cast Moisture in % w/w
in germination vessel
Fewer but longer air rests and fewer Attaining Optimal Malt Steep Pattern Considerations
but longer wets mean total steeping The steeping process is focused on the goal of providing the
time is often increased. optimum steep moisture characteristics in the barley. Many
factors are considered when developing the times and
Temperature control at end of the
temperatures that make up a steep pattern recipe. Major
longer air rests may be more difficult
factors include:
Barley characteristics, crop year impact:
(e) Monitoring of Steeping Maturity/water sensitivity
From the outline on the previous page of practical steeping Kernel plumpness
it is obvious that certain key parameters must be monitored Barley type – 2-row vs. 6-row
and recorded in order to control the steeping process. The Steep Time
main considerations are temperature, moisture content Temperature
and germination count.
Steep Pattern Layout
The temperature of the incoming steep fill and re-fill water
is monitored and controlled so that the initial mix Barley Quality Characteristics
st o
temperature of the 1 steep is attained (12-16 C depending The quality characteristics of barley can vary significantly,
on individual barley requirements). The temperature at the especially from one crop year to another. To avoid
end of each air rest is recorded, and also the time taken to unwanted surprises, we perform testing of new crops as
attain this temperature in order to maximise these periods early as possible. From this testing, we are able to develop
in subsequent batches. The laboratory analyses grain optimal steep patterns.
st nd
samples from the end of the 1 steep, end of the 2 steep
and cast stages of steeping to ensure that the moisture Barley Maturity
targets are being attained. Mature, non-water sensitive barley hydrates, or absorbs
water, in a predictable manner. Although small amounts of
Growth counts are performed after casting to ensure the water enter through the distal end and through the
batch is germinating adequately and evenly. Generally longitudinal crease in the husk, called the ventral furrow,
more than 80% of the grains should be chitting at this stage. most water absorption occurs in the embryo; and most of
the water that enters the kernel enters at the embryo end.
(f) After Steeping A typical steep cycle for normal, mature barley is shown
The germinating barley is transferred (cast) into the below.
germinating vessel by gravity or conveyor, depending on NORMAL STEEP CYCLE
the individual malting plant. The empty steeps are then Phase Wet Dry Wet Dry Wet Dry Wet Dry
cleaned to maintain adequate hygiene standards. Normally, Time (hr) 4 5 4 4 3 4 3 3
grain is cast “dry” from the steep but “wet” casting may be
Total Immersion Time 18 hr
practiced. In wet casting the grain is transferred from the
Total Dry Air Rest Time 20 hr
steep as a slurry in water. The pump design must be
Total Steep Time 38 hr
chosen so as not to impair the grain by mechanical damage
from the pump impellor or by excessive pressure (>1bar) Barley Moisture Content at Steep Completion: 43 - 44%
being applied to the grain. Cast moisture has a major effect Immersion Time to Total Steep Time Ratio: 47%
on rate of germination, generally the higher the cast NormalSteepCycle.vsd
moisture the faster the rate of germination – up to a
maximum of around 49% moisture at which point the
kernels begin to lose viability (they can be thought of as
Immersion Phase
The benefit of using colder steep water and a longer steep
In the immersion phase, barley in the steep tank is totally
cycle is that there is a more uniform water uptake and
immersed in water. The primary reason for immersion is to
hydration throughout the entire kernel. This tends to get
raise the moisture content of the barley from about 12% to
the metabolic activity off to a slow but balanced start,
approximately 45% at the end of the steeping process. At
resulting in low consumption of endosperm starches and
the start of the phase, barley is dropped into steeping tanks
reduced malting loss. Thus, even though steeping with
that already have some water in them. This is called a wet
colder water takes more time, it does have some benefits.
steep-in. This procedure cushions the barley to prevent
For best results, barley should be steeped at a temperature
skinning, husk removal, and embryo damage.
between 12C and 16C. Hot water steeping has been used
to reduce root growth and hence malting loss. Water at 30-
During the immersion phase, air is forced into the tank
40oc is applied for 8 hours to kill the embryo. This reduces
bottom through the aeration rings. The initial aeration
root growth and respiration losses. No turning is required
agitates the barley and raises any extraneous material that
during germination. Gibberellic acid may be used to ensure
was not removed during cleaning to the water surface
modification is not adversely affected. In practice excess
where it is skimmed off into the overflow for removal.
acrospire growth occurs so that malting loss shows little
Aeration of the steep water during the immersion phase
improvement and malt quality is poor.
improves grain activity and mixes the grain to achieve more
even water uptake.
Two temperatures affect steeping temperature: steep
water temperature and barley temperature. Some malting
Another function of steeping is to leach undesirable
plants can control steep water temperature; others cannot.
components from the barley husks, primarily polyphenols
Those that cannot control the steep water temperature
and tannins. Polyphenols give beer an astringent, mouth-
must use water as it is received, whether it comes from a
puckering flavour. Tannins are oxidized polyphenols that
well or a municipal supply. In the winter, water
give beer similar flavours. Leaching these components from
temperatures may be as low as 5C and require as long as
the husks requires large amounts of water—up to four total
56 hours for a normal steep cycle.
water changes are needed per steep tank; and the tanks
may be overflowed during most of the immersion periods.
Grain temperature is only a factor for the first immersion.
Leaching during the steep does not remove all the
Grain is stored outdoors in large metal bins, so its
polyphenols from the malt.
temperature depends on the outside air temperature. In
the winter, grain temperatures can be close to freezing and,
Dry Air Rest Phase
in the summer, as high as 28C. After the barley is received Each immersion phase is followed by a dry air rest phase.
at the plant, its temperature rises a bit from indoor cleaning The water is drained from the tanks. Room air is drawn in
and handling. The maltster must adjust either the steep from the top of the tank, through the wetted barley, and
water temperature or the immersion time to compensate exhausted out the tank bottom by a CO2 suction fan.
for the grain temperature.
Steep Tank in Dry Air Rest Phase
Steep Pattern Layout As the embryo respires, it absorbs oxygen and releases CO 2
Moisture content alone does not determine the effect of and heat. If the CO2 were not drawn off the tank it would
the steeping process or germination characteristics of the accumulate and eventually displace the oxygen. CO 2 build-
barley. By making minor adjustments to the temperature up has two undesirable effects, listed below.
and time settings of the steep pattern layout, the maltster
CO2 buildup causes respiration to slow and
can influence when the majority of water take up will occur
eventually stop, resulting in anaerobic glycolysis.
in the process (whether water take up will occur early or
-Amylase enzyme production slows dramatically.
late in the steeping process). If a significantly, large amount
-Amylase enzymes are needed to convert
of water take up occurs early in the steeping process, the
starches to fermentable sugars during mashing. If
barley will ultimately solubilize more protein. In this case,
the malt does not contain enough -amylase, the
you are essentially starting the germination process earlier
wort will contain unconverted starches.
(in the steep tank). By the same measure, barley that
experiences late water take up will solubilize less protein.
During the rest period, air is drawn in from the top of the Extract
tank and out the bottom. To help keep the barley at the top The more fully grown or further developed green malt
of the tank from drying out, cool, humidified air may be becomes, the more potential extract it uses up. Limiting
supplied to the tank room. Each dry air rest phase except overgrowing of green malt will increase extract readings, or
the last is followed by another immersion phase. at least will not lower them.
Analysis of Steeping-Related Malting Specifications Lowering steep moistures can increase extract readings.
There are many variables that affect the final product in the Limiting the speed of modification or limiting germination
malting process. One of the most difficult jobs of the time also has the potential to increase the extract available
maltster is determining the cause of undesirable at the end of malting. Starting out slow in germination has
Summary of factors governing water uptake shown promise also in saving extract.
Temperature Initial water uptake is a purely physical
process, but if germination is initiated, the Overly skinned product will show a higher reading for
rate of water uptake increases. The higher
the temperature of the steep water the extract by increasing the usable volume of the sample (less
faster the rate of uptake, especially after chaff and husk - more usable product). This is not a
germination is initiated desirable scenario, since other areas, are adversely affected
Grain size Above approx 2.3mm the variation in by skinned kernels.
water uptake is less pronounced and
hence barley for steeping is often Viscosity
screened to remove grains much smaller
than this so that more even modification is The viscosity (consistency/thickness) affects lautering time
achieved. The larger the grain size, the in the brewing process. The lower the viscosity reading is,
slower the rate of uptake increases. the better the run off times. If viscosity readings are high, it
Protein content Mealiness and steeliness have an effect is generally an indication of poor modification. An increase
on water uptake steelier grains will have a in modification, increase in steep moisture, and/or more
lower rate of water uptake. Lower protein time in germination can lower viscosity readings.
endosperm (tendency towards mealiness)
enhances water uptake.
Grain viability Once germination starts the rate of water Factors Influencing Water Uptake
uptake increases significantly. A moisture content of 45% - 47% is desired because this is
Variety and Crop Varieties that are loose husked or tend to the point at which rapid and even germination can be
Year split in wet seasons tend to take up water
more rapidly. sustained. Achievement of this depends upon the rate and
the quantity of water uptake by the grains. The following
characteristics that may appear in malt and establishing a factors governing water uptake are critical to the process.
controlled approach for correcting problems. Often the
cause and effect relationship of certain process variables is
very subtle and complex. This is truly the “art” of the
maltster. 50
Kernel Growth 45
A proper steep moisture should be found and maintained
40
Moisture (%)
Other Technology
The purpose of washing the barley is to remove loose
insoluble material and soluble material from the barley.
Traditionally, barley washing is performed, by overflowing
the steep tank, a process that is less than ideal. Less than Area of abrasion damage shows up as blue spot due
to binding of iodine with amylose and amylopectin
50% of the water that is consumed during steeping
contributes to the moisture uptake of the barley – Figure 5. Abraded and damaged barley shown by staining
sometimes much less. A significant portion of the with an iodine solution.
remaining water is used for washing.
BARLEY GERMINATION – THE PHYSIOLOGICAL AND During malting the barley grain swells by a third, replacing
BIOCHEMICAL CHANGES. the water lost as it dried in the field, prior to storage.
Water uptake occurs rapidly at first and slows as steeping
Grain Hydration proceeds. A critical grain moisture level of around 44%
The process of steeping determines final malt quality. The must be achieved. Below 44% moisture there is insufficient
purpose of steeping (soaking of the grain in tanks) is to water to support the grain during germination and
initiate grain growth through hydration. Hydration of the modification may be incomplete. Above 47% moisture the
grain facilitates even endosperm modification. Steep water endosperm can become over-modified as the grains “bolt”
must be of potable quality and free of taints. If not, the through germination, and can create poor quality malt.
impurities may be passed on through the malt to the final
beer, affecting its quality and stability. Traditionally, barley was continuously immersed under
water for a period of up to three days in order to achieve
Why does grain hydration initiate germination? Before the desired moisture content. The rapid depletion of
hydration the barley grain lies in a state of suspended oxygen in this process plus the accumulation of carbon
animation, its growth has been halted in the field through dioxide (CO2) allowed little growth to take place. Multiple
desiccation. On re-hydration of the embryo, aleurone and steeping, in which each immersion is followed by an air
endosperm, the revived aqueous condition provides a rest, is now standard practice. In this process, germination
suitable environment in which the enzymes can regain can be enhanced and higher moisture achieved than with a
functional activity. single immersion. The duration of the air rest is dictated by
the volume of air available to keep the grain cool and
prevent CO2 build up in the steep. The effects of
continuous and multiple (broken) steeping are shown in
below:
50
40
30
Figure 1. Water uptake in barley.
20
GA3 4 granules
5 6
Outer wall
Protein (-Glucan and
pentosan)
middle
lamella
Figure 3. Asymmetric grain modification. Area of greatest Inner cell wall
modification (1) through to the least modified (7). (-Glucan)
The ventral furrow that runs along the lower side of the
grain impedes water and gibberellin distribution. This Figure 4. Endosperm cell structure
causes slower and reduced enzyme release and therefore, The location of starch
granules (stained black)
diminished endosperm modification in the ventral grain within the endosperm cells
region. of barley grain surrounded
by the protein matrix
(stained green) and
The scutellar epithelial cells are stimulated to produce protected by the aleurone
approximately 10% of total grain -amylase (dependent on layer and seed coat.
Source: FeedXL
variety). As such, this additional input of -amylase may
affect the distribution of endosperm modification,
reinforcing the proximal-distal pattern of grain modification
in relation to starch degradation only.
The abundance of enzymes noted above is necessary for
Within the endosperm, areas of localised steeliness will the release and conversion of the endosperm starch. In
hinder the distribution of water and impede enzyme sequence, the outer cell walls must be degraded (by
dispersal. In these regions of the starchy endosperm, proteases) before carboxypeptidases, glucanases and
under-modification will occur. The opposite is true for pentosanases can attack the inner cell walls. Only after
grains with localised areas of increased mealiness, creating sufficient cell wall degradation can the proteases hydrolyse
regions of over-modified endosperm. the storage protein matrix to expose the starch granules.
The - and -amylases can then liquefy and saccharify the
Increasing germination temperature facilitates quicker starch, respectively. This allows transport of the sugars,
enzyme dispersal and therefore, improved modification. along with the amino acids derived from the protein matrix,
However, excessive temperatures may dehydrate the grain through the scutellum to the embryo. The scutellum
and restrict modification. epithelial cells elongate to aid absorption of the nutrients
into the embryo.
Learning Material 2015 39
-Glucans and Pentosans Nitrogen (FAN) for grain embryo and yeast nutrition. If
The walls of the endosperm cells comprise a mixture of sufficient proteolysis does not occur during malting, a loss
hemicelluloses and gums. Hemicelluloses and gums are of potential extract will ensue in the brewhouse, along with
mixtures of polysaccharides with similar chemical other associated problems.
structures. The relatively insoluble hemicelluloses are alkali
extractable and are degraded to gums (warm water- The proteins contained within the endosperm matrix are
soluble) probably through proteolysis. The hemicelluloses defined by their solubility characteristics.
are less soluble due to their increased molecular weights
and/or their increased degree of internal cross-linking. Albumins and Globulins: dissolve in water or dilute
salt solutions.
The major components of the hemicellulose and gum
fractions of the barley cell wall are: Hordeins and Glutelins: dissolve in alkaline or hot
alcohol solutions, in association with reducing
-D-Glucan (70-75%) agents.
Pentosans (20-23%) e.g. arabinoxylan.
Approximately 5% of the cell wall is made up of protein as a The less soluble storage proteins, hordeins and glutelins
middle lamella, but the -glucans and pentosans are the predominate in the endosperm matrix. Hordein and
most important in brewing. glutelin contain large amounts of the amino acids proline
and glutamine. Notably, these protein fractions contain
β glucan is a linear polymer of glucose comprising 70% β 1-4 disulphide bonds. These bonds have the ability to be
links and 30% β 1-3 links. broken and reform creating different molecules. This
formation of new bonds is thought to play a role in the
70% of cell wall material is β Glucan. (Note that approx. 5% production of viscous worts that are difficult to separate
of the cell wall is protein as a middle lamella) during mashing. As grain Total Nitrogen (TN) increases
during grain development hordein becomes incorporated
into the storage protein matrix in a disproportionate
2 step breakdown of β Glucan: fashion.
Grain size also affects grain hydration. Large grains If hydrolysis does not occur during malting, there will be a
proportionately take up water slower than smaller grains. deficit of necessary enzymes during mashing to cleave and
The small grains will therefore “bolt” through germination. release amino acids. This FAN is essential for yeast growth
The malt produced will be non-homogeneous, with and if deficient will cause problematic fermentations. If the
proportions of over and under-modified grains generating protein is not broken down or solubilised, the large protein
brewhouse problems. molecules will undoubtedly contribute to the formation of
haze (colloidal instability) and related problems.
(b) Proteolysis of Endosperm Protein
The enzymes responsible for proteolysis include: Excessive proteolysis can lead to:
Limit dextrinase, existing in both bound and free forms, The surface moisture of the grain with better levels
degrades branched dextrin (partially degraded starch of uptake achieved by applications made to dry-
granules) to glucose. -Glucosidase degrades maltose to cast than wet-cast grains.
glucose providing immediate metabolic substrates for the
embryo. Limit dextrinase and -glucosidase are easily de- Temperature and maturity of the grain with
activated by heat and rarely survive kilning to be of benefit improved uptake on well chitted and warmer
in the mash. -Amylase and -amylase are to some extent grains.
easily de-activated by heat, with a proportion lost during
kilning. -Amylase is affected by heat more than α- The concentration of the aqueous GA solution
Amylase. applied – if this is too dilute much of the solution
will flow to waste, as the grain is unable to adsorb
Gibberellic acid in Malting the relatively high quantities of liquid involved.
(a) Discovery of Gibberellic Acid GA has also been applied in steeping and during early
The discovery of the gibberellins, a group of naturally germination. Generally applications in steeping are less
occurring plant growth regulators, dates from work of efficient because of the volume of steep water which must
Kurosawa in the 1920's. He was studying the 'bakanae' be treated and the fact that the grains are at a more
disease of rice and showed that excessive elongation of the immature stage. It is possible to improve the efficiency if
stems was due to an infection with the fungus Gibberella in-steep grain development is encouraged but the more
fujikuroi. In 1939, the active compound was isolated and mature grains that result are more prone to physical
given the name 'gibberellin A'. It was not until 1954 that damage on subsequent transfer to the germination vessel.
further progress was made when the pure compound was
isolated and characterised. By the 1990's over 80 Similarly, for treatment of grain in the germination box, it is
gibberellins had been identified, over half of which were difficult to achieve an even application of GA across the
found in developing seeds. In barley the key gibberellin has depth of the grain bed. In those situations where the
been shown to be GA 1. The first application of exogenous design of plant necessitates GA application in the
gibberellic acid to malting took place in 1959 (Sandegren germination box the usual approach is to incorporate a
and Beling). spray bar on the grain turner. This allows the application to
be made at the instant of turning when the bed is most
(b) Use of Gibberellic Acid in Malting open and the chance of penetration to the lower grain is at
There is no legislative restriction on the use of gibberellic an optimum.
acid (GA) in malting although customers who wish to
preserve the image of malt as a substance entirely The responsive of barley to GA can be enhanced by physical
produced by a natural process may choose to prohibit its treatments. At the experimental stage, these physical
use. This is particularly the case for the Scotch Whisky treatments have included 'squeezing' steeped barley
industry which, because of the long periods of storage of between mill rollers with the aim of disrupting the internal
raw spirit (which are fundamental to the process of whisky endosperm structure and enhancing hydration and physical
production) has to anticipate future restrictive legislation or transport pathways within the grain. However, the only
changes that may occur in consumer sensitivities and technique to be commercially adopted was that of abrasion
preferences. developed by Palmer in 1969.
Where the customer approves its use, GA application can In this technique, barley from store (at a nominal 11-12%
offer a number of opportunities including: moisture is passed through an abrading machine where the
grains rub or are 'abraded' against wire brushes or abrasive
reduction or breaking of dormancy; surfaces lining the machine. Subsequently the grain is
accelerated malt production; processed in the normal manner. Commercial operations
enhanced enzyme production; showed that abraded barley required a considerably
reduced malting loss via embryo substitution. reduced steeping time for satisfactory malting. This is in
Table 1 where there is an increase in the rate of water
The response to GA application is both dose and variety uptake that allowed a reduction in the overall steeping
dependent. Typically in the maltings GA is applied in time.
aqueous solution at a rate of up to 0.4 mg/kg of original
barley. The preferred method of application is at the
300
Appearance – malt made from abraded barley can
have a poor appearance and be prone to breakage. 200
Grain
Figure 2 A) Schematic representation of a
fully perforated drum. The drum rotates
mixing the germinating grain whilst air
from
emerges from the perforated central pipe. B)
Schematic representations of a Galland drum. 1 2 3 4
Air from perforated ducts, situated around
the circumference of the drum, is exhausted
through a central pipe.
CONTROL PARAMETERS Both proteases and amylases are formed within the grain
during germination. Their rates of development, however,
(a) Moisture Control are affected differently by temperature at the start of
Once the steeped grain has been cast samples are normally germination.
withdrawn and analysed by the laboratory for moisture
content and growth counts. If the moisture content is too high temperature start suppresses protease
low the batch can be sprayed inside the vessel. It should be activity and
noted that this technique of moisture adjustment does not low temperature start enhances protease activity
necessarily get the moisture into the centre of the
endosperm where it is really needed and can also bring
about excessive rootlet growth resulting in increased (e) Effect of Temperature on Rate of Modification
malting losses. Conversely, if the moisture content of the As both these enzyme systems are so important in malting,
cast grain is excessively high the bed can be turned with the a compromise situation has to be found depending on the
germination fan at maximum speed and air conditioning customer's malt specification. For example, a distiller
system off to remove some of the excess moisture. If either requires high levels of soluble nitrogen in the wort,
spraying or water removal is necessary then the steeping indicating that the protein matrix in the endosperm has
cycle is wrong and must be adjusted for subsequent been sufficiently broken down, whereas there is usually an
batches. excess of amylase. For this reason, moderate-low
germination temperatures should be used to enhance
Once the initial moisture content is at the correct level (44 - protease activity.
47%) it is important that this moisture is maintained.
Humidified air is therefore blown through the growing (f) Air-on and Air-off Temperatures
green malt. Even so, the grain moisture will fall by roughly In practice, the air-on temperature (air temperature below
0.5% per day of germination due to the heat generated by grain bed) is controlled. It is important, however, that the
the growing malt itself. air-off temperature (air temperature above grain bed) is
monitored and reacted to. When malting vigorous grain it
is important to keep the growth under control. If the
At the end of germination, the modified barley, now (a) Free Drying
termed “green malt” (un-kilned malt) has been Initially, water can be easily removed from the moist grain
manipulated to achieve the maltster’s and brewer’s using low temperatures (50 – 65°C) if combined with high
specifications. These grain characteristics must now be volume airflow which reaches a Relative Humidity [RH] of
fixed to avoid any deleterious changes that may occur >95% during drying in this phase. During free drying, water
before the brewery can take delivery of their malt. Kilning diffuses through the grain to its surface and is absorbed by
effectively serves two purposes: the warm air passing through the bed. The action of water
removal from the grain cools the malt (due to the latent
1. To halt and capture the biological activity of the heat of evaporation). Often the internal grain temperature
germinating grain at a point of optimum enzyme will be 30°C lower than that of the air-on temperature. This
yield and endosperm modification. removal of moisture at low temperatures ensures the
maximal survival of enzymes, whilst encouraging the
2. To reduce the moisture content of the green malt development of colour and flavour compounds.
to a level at which it can be safely stored to avoid
deterioration and microbial infection.
KEYPOINT: In addition to the removal of water from the
THE PHYSICAL PROCESS OF KILNING grain, kilning evaporates undesirable flavour volatiles that
impart grainy or grassy aromas.
Kilning reduces the moisture content of the grain, which, at
the end of germination is usually between 42% and 45%. A
final grain moisture level of approximately 3 – 5% is
achieved by the end of kilning. Kilning of the grain is also Caution is taken during free drying to prevent the
responsible for the characteristic colour and flavour of malt. occurrence of “drip back” or stewing of the grain, which
This requires intense heating, which conflicts with the need prolongs and enhances colour/flavour production and
to preserve essential enzymatic activity in the grain. enzyme destruction. Drip back occurs when the air-off
reaches saturation (RH = 100%) which on cooling releases
Enzymes are considerably more heat stable when the malt excess moisture. For instance, as the saturated air leaving
is dry. Kilning objectives can therefore be accomplished the grain bed meets the colder interior of the kiln; the
with a drying regime that first removes the majority of excess water condenses and drips back down into the malt.
moisture at relatively subdued temperatures. Secondly, Stewing arises when the saturated air passing through the
more intense heating is used to obtain final moisture bed prevents evaporation and therefore cooling of the malt
removal, and colour/flavour production. – in effect stewing it. Such conditions are avoided by
increasing the water carrying capacity of the air by
Kilning consumes some 75% of the total energy utilised in increasing its temperature and/or preferably flow volume.
malting and must therefore be operated at maximum
efficiency. This would dictate that the warm air (used to Typically the “air-on” temperature is raised a few degrees
dry the grain) leaves the kiln satisfying its maximum each hour for the first 12 hours. Free drying produces malt
moisture carrying capacity. This may not always be with moistures in the region 15-20%.
accomplished or even desired.
The inherent nature of malt kilning, maintaining “air-off”
Kilns can be similar in design to germination chambers and relative humidity at above 95% makes it an inefficient and
in fact some maltings utilise vessels in which the two wasteful process.
process steps are carried out in the one vessel -
Germination and Kilning Vessels (GKVs). Other inevitably sources of energy loss are:
Within the kiln, the green malt is loaded onto one or more Imperfect fuel combustion;
perforated floors, through which heated air can be driven Losses associated with heating the kiln structure;
(by fan) upwards through the grain bed to effect drying. If or
there is more than one floor, the heated air from the lower Heat losses directly to the atmosphere through
level is rejuvenated with additional flow to heat the bed limitations in the kiln structure.
above, resulting in economic savings. In dedicated kilns,
the bed is not usually turned, but in GKVs it may be. There KEYPOINT: Malt enzymes are damaged when moist malt is
are three stages incorporated in the drying process. exposed to high temperatures. To protect the enzymes and
also to minimise energy costs, drying starts with the air
o
1. Free Drying (or pre-break). temperature at about 55 C and then raised at later stages.
2. Forced drying. The design of the cycle varies according to the type of malt.
3. Curing (or the equilibrium phase).
10 Relative
6
CH3
CH3SCH2CH2CHNH2COOH
CH3S+CH2CH2CHNH2COOH (c) The Maillard Reaction
Methionine Some of the most important chemical reactions occurring
SMM
throughout malting are the production of melanoidins.
H3C H3C Melanoidins give the malt its characteristic flavour and
colour. Melanoidins are produced from the interaction of
S SO reducing sugars with amino acids (from the malt) via the
H3C H3C Maillard reaction. The intensities of these reactions are
dependent on both moisture and heat. Ale malts require
high curing temperatures at the end of kilning unlike
DMS DMSO
distilling or lager malts.
MELANOIDINS R
O
Amadori re-arrangements
(pigments) Furans
-H2O
. Reducing
sugars. +NH3
REDUCTONES
+ Amino
+ R
(-Diketones)
Amino acid N
acids.
Pyrroles
H
-Amino ketones +H2S
O2
R
S
N Thiophenes
R
N
Pyrazines
The process of moving malt, either into or out of silo, is Malt has been dried during kilning to somewhere typically
usually achieved by some form of conveyor, having between 4% and 5% during kilning; this low moisture
replaced manual handling in most medium and large sized content means it is brittle and easily damaged by poor
brewing or distilling operations. Many forms of conveying mechanical handling. Higher moisture levels and there is
systems are available, and are used according to the various danger of mould infection as well as increased
needs of the materials being moved. Generally speaking, a transportation costs (more water, less available extract)
conveyor can be classified as either mechanical or whereas lower malt moisture levels have higher extracts,
pneumatic and both types can commonly be used for malt tend to have higher colours (due to extended kilning) but an
handling. Chain conveyors are used for the horizontal increased risk of damage. Equipment must therefore be
transportation of malt over longer distances, and can also chosen carefully and the malt handled in as gentle a
overcome a slight angle of inclination minor differences in manner as possible. It must not be allowed to come into
height levels. Screw conveyors are used when malt has to contact with damp equipment or moist air, nor be allowed
be transported over relatively short distances, but can be to become cracked, crushed or de-husked in advance of the
used horizontally, vertically or at any angle of inclination. milling process. Additionally,
Most malt storage silos are constructed from steel but they
can be made from concrete. Silos have smooth walls with the malt silo and mill tower is a hazardous place, and
hopper bottoms to ensure easy grain withdrawal. Malt is consideration must be given to good hygiene and
stored at low moisture levels to discourage the growth of housekeeping with respect to dust avoidance. When
pests such as insects, moulds, fungi and bacteria, and also considering a new brewhouse project, or an upgrade of an
to prevent alteration to the biochemical structure of existing one to add bulk malt handling, there is a lot of
malt/adjunct prior to use due to an increase in moisture equipment than needs to be considered.
level).
The process of moving malt, either into or out of silo, is
Kiln Malt Cleaning usually achieved by some form of conveyor, having
Kiln Malt Cleaning is the first major step after the finished replaced manual handling in most medium and large sized
malt piece comes back from the malt house. The primary brewing or distilling operations. Many forms of conveying
54 General Certificate in Malting
systems are available, and are used according to the various Dust Removal
needs of the materials being moved. Generally speaking, a Dust is a dangerous substance because of the risk of
conveyor can be classified as either mechanical or explosion and also irritation to the lungs. It is now covered
pneumatic and both types will commonly be used for malt by COSHH (Control of Substances Hazardous to Health Act
handling. A typical intake system might comprise of a UK) regulations and it is extremely important that dust is
discharge ‘pit’ or hopper into which the malt is ‘tipped’ not allowed to accumulate. If a film of dust appears,
during offloading from the bulk transport. Some form of measures must be taken to eliminate the source of dust and
vertical elevator, such as a bucket elevator, would be used vacuum any deposits – the presence of dust would indicate
to raise the malt to the top of the silos and then conveyor a failure in the dust extraction system or leak in the plant.
would transport it horizontally towards the silo. Chain
conveyors are used for the horizontal transportation of An electrically driven fan sucks the dust through metal
malt over longer distances, and can also overcome a slight ducts or pipes from various points such as the elevator,
angle of inclination minor differences in height levels. Screw dresser and weighing machine. There are several ways of
conveyors are used when malt has to be transported over dealing with the dust collected; it may be blown into a
relatively short distances, but can be used horizontally, cyclone from which it drops down into a bagging point. In
vertically or at any angle of inclination. Discharge from some installations dust is blown into sleeves mounted
conveyor is by gravity into the top of the silo. inside a metal unit, on a frame that can be vibrated at the
end of the grinding or malt intake operation to shake off
Most malt storage silos are constructed from steel but they the dust. The dust then falls into a container at the bottom.
can be made from concrete. Silos have smooth walls with A regular system of emptying the dust sacks or containers is
hopper bottoms to ensure easy grain withdrawal. Malt and necessary to allow the plant to work at maximum
also cereal adjuncts are stored at their delivery moisture efficiency, and a periodical examination must be made of
levels to discourage the growth of pests such as insects, the pipe ducts to and from the fan to avoid build up and
moulds, fungi and bacteria, and also to prevent alteration blockage by dust.
to the biochemical structure of malt/adjunct prior to use
due to an increase in moisture level). Even if there is good housekeeping, it may not be possible
to completely eliminate the risk of explosions in hoppers
Screening/Grading and Dressing and conveying equipment. For this reason, explosion vents
Prior to dispatch from the maltings the malt is screened and are provided to allow an explosion to pass harmlessly into
dressed. To ensure uniformity of milling, it is necessary to the atmosphere without damage to equipment and people.
have a reasonable consistency in the size of corns. To For hazards associated with dust, see section 13.
obtain such consistency, bulks of malt are often graded.
The malt is carried by pneumatic or mechanical means past
magnetic separators to rotating, cylindrical, oscillating or
MALT EVALUATION AND DISPATCH
flat-bed screens. Not only are corns of unwanted size
rejected (these are sold for animal feed wherever possible), Blending
but foreign matter such as straw, stones, string, sacking and After aging is completed, the malt varieties are blended to
metal particles are removed. specification. Blending is accomplished by mixing malt from
various combinations of bins. By adjusting slide gates at the
Dressing bin discharge (either automatically or by manual
The malt dresser was usually a cylindrical screen revolving adjustment) the grain flow rate can be adjusted to provide
inside a wooden casing that has detachable doors on either the desired ratios of varieties.
side for easy access. The last part of the screen consists of
a mesh large enough to let malt pass through to a small Shipping Malt Cleaning
hopper feeding the weigher or the mill. Any foreign matter After blending, the shipping malt is often cleaned again
such as pieces of wood, metal, or stone, which are too large through further malt cleaning. This cleaning removes any
to pass through this mesh, is carried forward to the end of sprouts not taken out during kiln malt cleaning. Thin
the screen where it is rejected via a spout into a bag. When kernels, husk, hull, and broken kernels are also removed.
the culms were separated from the malt during screening, Malt is transferred to a pre-delivery storage bin, from which
circular brushes revolved against the exterior of the screens it is loaded directly for delivery.
thereby ensuring that the apertures were kept clear.
Speciality malts, or malt for small brewing operations, are Samples are collected either from a specialised sampling
also bagged and available for delivery in batches as small as device, which automatically takes a small, continuous
25kg. sample of malt from a conveyor during transfer to a
delivery bin or malt truck, or can be sampled directly from
Malt Analysis and Specification. the delivery truck/railcar by use of a sampling spear.
It is essential that all malt leaving the malthouse is
accompanied by a laboratory analysis and delivery Delivery bins, holding malt for a number of bulk deliveries,
certificate. are often analysed in advance of loading and delivery so
that the completed laboratory analysis and delivery
Brewers and distillers purchase malt against a certificate can accompany the delivery to the brewery or
specification. A certificate of analysis / compliance distillery.
to specification is normally required as part of the
purchasing contract. For detailed information on malt specifications, refer to
Each malt delivery must contain a batch number section 10.4 malt Specifications.
(or blend ratio, when multiple batches have been
BARLEY
GREEN MALT
High
Low Drum roasted
Normal Temperature Drum roasted
Temperature 220-230°C
Temperature Kilning 120-160°C
Kilning
60-75°C Kilning Drum roasted
85-115°C
85-115°C
Pilsner Malt Pale Ale Malt Black Malt Crystal Malt Roasted
Barley
Enzymatic Malt Vienna Malt Chocolate Malt
Barley and hence the malt are derived from living materials Errors can be made in sampling, especially when a small
and so are subject to the variations that can occur as a sample is taken from a large batch as it may not be
result of genetic and environmental conditions. This means representative of the whole.
that no two batches of malt are identical. Malt analysis
provides guidance on the effectiveness of the malting Therefore it is usual to give specifications a ‘range’ to
process and suitability of the malt for brewing. reflect the normal expected variation in values.
Notes.
PRODUCT CONSISTENCY Write down the specifications for a raw material, product
and a process that you are familiar with.
The people who use our malt expect and deserve a
consistently high quality product. METHODS FOR RECORDING, REPORTING AND THE
INTERPRETATION OF DATA.
The key factors in maintaining consistent quality are the
establishment of, and the measurement for comparison to, (a) Sampling Schedules.
a set of process and product specifications. A sampling schedule is a plan specifying where, how and
how frequently samples of the product in process and at
There are a number of measurements that are taken during the end of process are taken.
the process and at the completion of the process which
indicate whether the process is in control and whether the A routine sampling schedule is required so that:-
malt is of the right quality.
Key measurements are taken without exception and the
Examples of the most important of these measurements whole of the process is covered. It is too late if the first
are given below. warning of a quality problem comes from the customer.
The principle of controlling quality is based on setting The quality picture can be seen from statistically
specifications for each of these measurements, measuring presented data. A very useful quality control method is
the process and taking corrective action if the product or to look at historical trends. Using this method, current
process is ‘out of specification’. results are compared to those obtained in previous
months/years. A sampling schedule makes sure that
Having said that, there are some factors to be taken into there are enough data to make these comparisons.
consideration:-
The work of the people who are sampling and
All measuring instruments have a degree of tolerance. measuring can be organised effectively.
The raw materials used in the malting process are
naturally grown and therefore cannot be expected An example of a sampling schedule is detailed in the table
always to behave in exactly the same way. below:-
Stage. Frequency. Notes.
Raw materials (Barley) Each delivery. Frequency depends on supplier reliability and
performance.
Steeping Operations Each batch Process control to monitor water uptake and the
steeping process
Kilned malt Each Batch To monitor post-kiln analysis, potential for blending
Malt for dispatch Each Silo To confirm conformance to specification and therefore
suitability for delivery
Delivery sample Each delivery. Analysis of conformance to customer specification
(b) Collation and presentation of data. Control charts can be in different formats and can show:-
It is likely that there will be a large number of results from a Individual results plotted on a graph. The
sampling schedule like the one illustrated, especially in a specifications can be drawn in as well.
large plant. The results must then be presented in a way Average results or ‘rolling’ average results plotted on
that highlights the information as effectively as possible. a graph.
The range of results obtained.
There are two main ways of presenting data so that The cumulative effect of deviation from the target
problems are highlighted and action can be taken:- and the effect of any action taken.
Defect highlighting. This is a graph plotting the malt moistures that were shown
Control charts. above as individual results:-
15
It can be seen very quickly that sample number 8 is out of
specification. 14
13
This type of presentation is useful, if for example, a simple 12
decision is required as to whether the malt is passed as 11
suitable for delivery. 10
9
It does not however, assist in analysing results so that some
clue as to the cause of the problem result can be 8
discovered. 1 2 3 4 5 6 7 8 9 10
It would be useful to know the average moisture of This method of presenting data evens out the highs and
these malts. If that was high, then an adjustment to the lows and illustrates the rising trend very well. From this
process upstream could be made. graph, it can be seen that the moistures have been
increasing steadily and that, unless something is done
It would be useful to know the range or spread of about it, they will likely continue to increase.
moisture of these malts. If the range is very wide, then
the process may be out of control and action may be The next graph below is called a ‘cumulative sum’ or
required to resolve the situation. ‘cusum’. It is designed to exaggerate very graphically, how a
trend is going and the effect of any action taken to correct a
In order to resolve these problems, statistical analysis in the problem. It is plotted by taking as a starting point the target
form of control charts is required. Pictures in the form of value which would normally be the middle of the
graphs have much more impact than simple tables. specification.
Many malt houses enter the results of analyses into Investigation and action:-
computer databases. This gives a number of benefits:-
What else was happening at the Check process activities that could affect malt moisture at the time that sample 5 was kilned
time? - An air-on temperature during curing was below specification.
What are the possible or likely It is likely that the curing temperature is causing the high moistures.
causes?
What can be done about it? For the current problem:-
Blend the batch with a lower moisture malt. The malt is acceptable and blending will not
cause any further problems.
(a) Hot Water Extract (HWE) For all-malt beers, malt protein values exceeding 12% (1.9%
This is probably the most important of all malt analyses. It TN) indicate that the beer may be prone to haze formation
gives a measure of likely yield in the brewhouse. As such, it or present mash run-off problems. European lager and
reflects the extent to which the endosperm is solubilised British ale malts usually contain around 11% protein (1.75%
during germination of the barley and also the portion that is TN). One of the major reasons brewers prefer these malts
released by the enzymes during mashing. The higher the for all-malt beers is because their protein levels are
value, then potentially the more alcohol that can be derived adequate for head-formation, body, and healthy
by the brewer or distiller per unit of malt and the more fermentation – yet low enough to present less chill haze
valuable the malt (especially if other parameters are met). potential than high-protein North American malts.
These factors are also influenced by environmental Cold water extract measures the amount of sugars
conditions, e.g. weather, soil type and fertiliser. The barley broken down and released during the malting
variety is also important not only because of its brewing process – a greater value for the cold water extract
characteristics, but because of special characters it gives to means a higher modification
the finished beers.
It is important to use malt that has been correctly modified.
(b) Extract Yield Under-modified malts will give brewhouse problems, for
The extract yield is a measure of the amount of sugar example, poor extract recovery and hinder wort filtration.
potentially recoverable from the grain during the brewing With over-modified grains the extract is easier to recover
process. There are a number of recognised methods for but some of the extract will have been lost to growth.
measuring extract potential. Briefly, the % extract is Over-modified malts also give wort separation problems,
measured by preparing a dilute mash in distilled water with lend a thin character to the beer, and produce weak head
very finely ground grist. After a set stand time at a retention; losses can also be incurred as over-modified
particular temperature the solids are separated by filtration malts break-up easily when handled. If slightly less well-
and the gravity of the extract is measured using a specific modified malts are used head retention is favoured.
gravity bottle. The two standard methods are the IOB and
the EBC methods: (d) Visual/ Sensory Evaluation
Lot analysis specifications are really best for making
In the IOB method the mash stands for 60 minutes comparisons between lots and between products. You can
o o
at 65 C. The extract is expressed as L / kg. draw your own conclusion by putting the malt through a
few simple tests.
The EBC method there are two mash stands at
o o
45 C and 70 C. The extract is expressed as % sugar Malt needs vary depending on the style of beer to be
(sucrose) over the total weight of malt. brewed and the mashing profile to be used. Experienced
brewers can often tell just by looking at and handling the
(c) Modification malt how it will perform in the mash. Take some time to
This is probably the most important measurement the compare samples of different malts to give you a reference
brewer has to gauge and this measurement demonstrates point. Any sample should include a handful of at least 50
how well the maltster has done his job! Modification gives kernels for a reasonable analysis. The main rules of thumb
an indication of how evenly the cell structure has broken are that the majority of the kernels should be of similar size,
down in the endosperm during the malting process. The modification, and colour for good milling and mashing, and
degree of modification can be measured in a number of should show no visible signs of disease (that is, discoloured
ways: or seriously misshapen kernels). The plumper and larger
the kernel, the better! In base malt, the ends should not be
Soluble nitrogen/ total nitrogen expressed as a % vitreous, or glassy. You should be able to easily crush the
(Kolbach index) that measures how much of the malt with your fingers. Chewing the malt will also tell you
nitrogen wall structure has been broken down. about its friability, or softness, as well as its flavour and
The higher the value, the greater the modification aromatics.
of the protein matrix surrounding the cells in the
endosperm. If you are very concerned about degree of modification, you
could also cut into a handful of malt to expose the
Difference in extract between a coarse and fine acrospire, the embryonic barley plant inside the husk. The
grind. When malt is ground the cells are crushed length of the acrospire should be three-quarters or greater
up and the extract can be recovered for analysis. of the kernel in well-modified malt. Well-modified malt will
In brewing, it is necessary to have a relatively also float in water.
coarse grind so that the residues can form a filter
bed for wort separation. The difference in extract Contribution of Malt to Wort Quality
between the coarse and fine grind shows how
much of the structure of the endosperm has Malt supplies the sugars required for alcohol production
broken down. The smaller the difference, the and the main nutrients for satisfactory yeast growth. The
better the modification. typical components supplied by the malt for yeast
fermentation include:
The mouth feel and texture of the beer mostly Specifications for Brewing and Distilling Malts
comes from the residual unfermented sugars
(dextrins) derived from the malt. The essential property of any brewing or distilling malt is its
extract potential. This is indicated by the Hot Water Extract
The pH of wort and beer is regulated through the (HWE) parameter, which determines how much sugar is
interaction of malt components and ions in the available for alcohol production. Friability and
brewing liquor. homogeneity values, based on a physical crushing
technique, are an indication of how well the maltster has
Beer foam is made up from hydrophobic proteins modified the malt. The Soluble Nitrogen Ratio (SNR) or
that originate from malt. Kolbach Index both measure the degree of modification
based on the amount of protein breakdown during malting.
Other proteins derived from malt cause non- Lager malt does not have to be so well modified as an ale
biological haze. Non-biological hazes are (or distilling) malt – as the "head" on a glass of lager
composed of colloidal particles that give beer a depends essentially on the protein content.
cloudy appearance. Most non-biological hazes are
comprised of particles brought about from the Yields in both distilling and brewing are important.
interaction of protein and polyphenols, derived Distillers are interested in how much spirit can be obtained
from the malt, to produce protein-polyphenol from the malt, hence the requirement for Fermentability,
complexes. Carbohydrate hazes consist of Fermentable Extract (FE) and Predicted Spirit Yield (PSY)
ungelatinised starch, pentosans, and -glucan. specifications, whereas yields in Breweries are measured in
These “invisible” hazes are produced due to the terms of extract before fermentation.
incomplete degradation of the carbohydrates
during malting and mashing. Brewers are particularly concerned about the final colour of
their beers and specify malt colour in order to control this
Malt also has an effect on beer flavour due to the action of characteristic. Lager beers, being very pale use malt with
certain flavour active compounds, including: low colour values – compared with the higher colour values
for ale malt that produces very much darker beers. The
Dimethyl sulphide (H2S) is derived from malt and it maltster controls the development of malt colour during
has a flavour of ‘uncooked sweet corn’ and is often kilning.
associated with lagers. Off-flavours can develop
68 General Certificate in Malting
Some brewers and grain distillers make use of other cereals
as well as malt and so require a high enzyme malt to assist
in the conversion of the non-malted cereals during Table 3. Typical list of analytical parameters used in
mashing. A minimum -amylase activity (also known as
specifications for distilling malts.
Dextrinising Units) and Diastatic Power (DP) are specified
to achieve this. Diastatic power is the measurement of the
combined activities of the α- and β-amylase enzymes. Analytical Abbrev Typical Distilling Range (Dist.
These enzymes are heat sensitive and so can also be used Parameter iation Malt Malt only)
as a means of confirming that the kilning regime has not
Moisture (%) 5.0 4.5 – 5.0
been too severe.
Hot Water Extract HWE 76.5 76 - 78
Individual customers also specify certain flavour (%)
characteristics in their malt. Some distillers have Fine Coarse F/C Diff 1.5 1.0 – 2.0
requirements for peat smoke flavour and the distilling malts Difference (%)
are peated to varying degrees. Some lager beers are
Fermentability (%) 86.8 86.5 – 87.5
identifiable by particular flavours and odours, so lager malts
may often have a DMS specification. The maltster is able to Predicted Spirit PSY 402 400 - 416
achieve this wide range of flavour characteristics by Yield (litres of
adjusting the germination and kilning processes. alcohol/ tonne)
A Definition of Beer:-
Ales come from:-
In its basic sense, beer is an alcoholic beverage produced by The use of a well modified malt and specialty malts
the fermentation of sugars derived from malted barley and which is sometimes highly coloured.
flavoured with hops. They use of a top fermenting yeast.
There are some minor differences where malt is Ales come in various forms, bitters, pale ales and mild
supplemented with adjuncts or where the hops are beers.
replaced by other flavours, but this definition would be
recognised by the majority of people round the world.
Wheat beers are beers produced from the use of a
The manufacture of all alcoholic beverages utilises the proportion of malted wheat, often around 50%, replacing
ability of yeast to ferment sugar into alcohol. some of the "malted barley.
Stouts are very dark in colour and richly flavoured from the
use of highly coloured malts or roasted barley.
'GREEN
BEER Low-carbohydrate beers are brewed by producing wort that
SUGAR YEAST FOR
BEER'
SALE is more fermentable than in “standard beers” by several
techniques, but usually by adding additional enzymes to
convert more of the non-fermentable sugars into
CARBON fermentable sugars. These enzymes may be produced from
DIOXIDE
unboiled wort and added to conventional wort, or from
commercial suppliers derived from fungal and/or bacterial
BEER TYPES sources and added during wort production or during
fermentation. The overall objective by making the wort
Different types of beer.
Different areas around the world have developed their own more fermentable than standard (or “super-attenuated”) is
types of beer. The variations have come about through a to brew products that have lower carbohydrate content in
combination of the materials available for its manufacture the finished beer.
and the tastes of the consumers.
Sucrose is mostly used in liquid form, it is highly Brew kettle – sugars are typically added directly to wort
fermentable and is usually added to the boiling vessel (wort kettle where they are readily dissolved and sterilised.
kettle). It is used to supplement the malt where malt
processing plant (storage, mills, mash tuns etc.) is a limiting As well as un-malted cereals such as corn, rice, and wheat
factor. Sucrose can be added to the beer after fermentation being used by brewers as adjuncts, the use of un-malted
as ‘primings’ to provide sugar to encourage conditioning or barley is also common as it gives a rich and grainy flavour to
increase sweetness. the beer (as well as being typically cheaper than the malted
equivalent). It will help improve foam retention at the
Invert is produced by hydrolysing sucrose and it can be detriment to physical stability due to the higher level of
liquid or solid. It is added to the wort kettle and is used for nitrogen and proteins.
the same reasons as sucrose although it has a more
distinctive flavour. MALT HANDLING IN THE BREWERY
Glucose is produced from starch and is used in liquid form Raw Material Intake
in the same way that sucrose is used. Its fermentation The responsibilities of the brewer start as soon as their raw
characteristics are very similar to sucrose. materials are delivered. It is important to routinely check
the raw material consignment to ensure that what the
Maltose and Maltotriose etc. are produced from starch and brewery has ordered has been delivered.
are used in liquid form in the same way that sucrose is
used. Their fermentation characteristics depend on the (a) Sampling
sugar type so that they can be used to modify the When the consignment of material arrives at the brewery,
fermentability of the wort and therefore the character or the delivery vehicle is weighed in and then again before it
alcohol content of the beer. leaves the brewery; this is to measure and record the
quantity delivered. At this point the materials are randomly
Lactose is produced from milk whey and is used to sampled and checked for quality and specification. For
contribute a milk character to milk stout. It is added to example, malt will be checked for moisture content – the
the wort kettle. brewer wants to pay for extract not water.
Caramel is extremely dark and has a burned toffee flavour. The sampling of malt can be carried out using spears. These
It is produced from sugars and is used to contribute colour are hollow spikes that are pushed into the grain bed and
and flavour to beers like stouts and dark milds. when withdrawn retrieve a sample of the grain. Many
designs are available to the brewer, but to avoid bias results
Un-malted cereal adjuncts are typically used in the brewery samples must be taken from randomly defined points
or distillery in one of three ways. throughout the grain bed. The main priority for the brewer
is to obtain a homogeneous batch of malt; this helps avoid
Cereal cooker – in a cereal cooker the adjuncts generally production problems. For example, a delivery of malt may
contain starch in their unrefined forms, such as grits, flour, be composed of two different batches. This batch may
dry grain or starches. These adjuncts need to be gelatinised contain 95% Malt A and 5% Malt B, but if malt B is not high
(to allow the starch molecule to be enzymatically converted quality (i.e. it is undermodified or has a high -glucan
to fermentable sugars) and liquefied to allow solubilisation content) this 5% may cause production problems.
and pumping to the main malt mash in a second vessel
where the malt enzymes can now be used to modify the These problems include:
starch from the adjunct and create fermentable sugar.
Poor extract recovery
Not all cereal starches gelatinise at the same temperature. Sticky spent grains
Barley starch gelatinises at around 61 – 62°C, whereas rice Viscous wort
and maize starch gelatinise at temperatures between 70 – Poor wort separation
80°C. If the adjuncts are not pre-gelatinised they must be Potential carbohydrate haze
cooked in a separate vessel before addition to the main Poor clarification performance
mash.
Magnets
(b) Storage
We are already familiar with the concerns of barley storage It is essential that pieces of metal that may be in the malt
and these are no different for cereals entering the brewery. should be removed before they reach the mill, because
such metal can cause a spark and start a fire or explosion.
The different types of materials (grains, flakes, grits, flours,
Separation is effected by placing permanent magnets either
starches and syrups) are all stored separately until required
for processing. Most storage silos are constructed from in the malt chute to the dressing machine or across the feed
to the mill.
stainless steel but they can be made from concrete. Silos
have smooth walls with hopper bottoms to ensure easy
Malt should flow over the magnet in a thin layer and at the
grain withdrawal. The malt and cereal adjuncts are stored
at their delivery moisture levels to: same rate as it is being ground, thus allowing the magnet to
extract any metal that may be in the malt.
Discourage the growth of pests such as insects,
moulds, fungi and bacteria. Dressing
Prevent alteration to the biochemical structure of The malt dresser was usually a cylindrical screen revolving
inside a wooden casing that has detachable doors on either
malt/adjunct prior to use (for example increasing
side for easy access. The last part of the screen consists of
in moisture or “turning slack” and losing enzyme
activity). a mesh large enough to let malt pass through to a small
hopper feeding the weigher or the mill. Any foreign matter
such as pieces of wood, metal, or stone, which are too large
Storage and handling of syrups is unique. Syrups are stored
to pass through this mesh, is carried forward to the end of
in insulated tanks and held at elevated temperatures
(glucose syrups 45°C and sucrose/invert syrups 25°C). the screen where it is rejected via a spout into a bag. When
the culms were separated from the malt during screening,
Warm storage is essential to prevent the syrup from
circular brushes revolved against the exterior of the screens
crystallising, whilst the viscosity of the syrup will hinder, if
not halt, transfer between vessels. Microbial infection can thereby ensuring that the apertures were kept clear.
be avoided by ensuring that glucose syrups contain at least
80% solids and sucrose syrups 67% solids. It is extremely
important to avoid condensation within the vessel which
can drip onto the liquid surface and dilute locally the syrup. In modern installations there is a separator/dresser to
remove foreign material based on size, and in addition a
Maintaining the syrups at such solids loadings or
de-stoner that separates material according to density. In
concentrations produces osmotic pressures within the
this way small stones of the same size as the malt grains can
syrup at which few microbial contaminants can survive.
The use of sterile air filters will also help maintain sterility. be removed and it has been found that the amount of
stones can vary considerably according to the source of the
Of course all storage silos should be cleaned at regular
barley. Stones can damage mill rolls and can also create
intervals to prevent the build up of soil and contaminants.
sparks in the mill.
During milling, the malt grain is crushed so that the highest MASH CONVERSION.
possible yield of soluble nutrients can be extracted during
mashing. This physical degradation of the malt into an Mashing is the process where the crushed malt or grist is
array of small particles is called comminution. The greater mixed with water under specified conditions so that
the degree of comminution (i.e. the finer the flour enzymic action can take place to convert the starch into
produced) the larger the surface area available for fermentable sugar and in certain cases break down proteins
enzymatic attack – this means there will be a better extract into more soluble forms.
efficiency. As a comparison it takes longer for a sugar lump
to dissolve in your coffee than a spoonful of granulated Milling, Mashing and Conversion:-
sugar.
Beer production starts in the brewhouse where the malt is
processed to release fermentable sugars.
Friability
The action of comminution is influenced by malt friability.
MILLING MASHING CONVER-
What is friability? The friability (extent of modification) of
malt is a measure of the amount of energy required to SION
“crush” the grain. Crushed malt The starch is
The malt is is mixed with converted into
During malting of barley the endosperm is modified to crushed Water to start sugar by the
differing extents with particular areas prone to under- the conversion malt enzymes
process
modification (high nitrogen, steely areas) and over-
modification (the low nitrogen, mealy areas). The internal
structure of well-modified malts fully degraded by diastatic First the malt is milled to grind the starch into flour while
malt enzymes are said to be friable – they are easily protecting the malt husk because undamaged husk is
crushable and therefore require only a small input of required later.
mechanical energy (milling) to break them up. In the case Milling
of poorly modified malt, the internal structure of the grain
remains fairly intact (they are less friable) and requires a
high input of energy via milling to comminute the grain. Malt
pH. Acidic conditions kill the enzymes. 5.4 High pHs slow enzyme action, but it does
Enzyme action is stopped at pHs below continue at pHs of 7 or above.
5.0
Water. Enzymes are more sensitive to heat in a Between 2.5 Enzymes are less sensitive to heat in a
(Mash thickness) thin mash. and 3.5 litres of thick mash. There is a higher
water per concentration of enzyme and starch in a
There is a lower concentration of kilogram of dry thick mash.
enzyme and starch in a thin mash. grist.
Time. Enzymes take time to attack the starch. 30 minutes Conversion will be virtually complete
Conversion will be incomplete in less after 30 minutes. A longer time will not
than 30 minutes. increase the yield of sugar but may make
it more fermentable.
The production of fermentable sugars from starch is a When the malt has been
complex biochemical reaction starting with ‘gelatinisation’ mashed with water,
enzymes are released which
of the starch by heat. This is where the spiral configuration attack the links in the starch
of the starch molecule is unwound so the enzymes can chain at the points shown by
attack. the arrows.
Conversion follows and the diagrams below illustrate how amylase attacks at random
the enzymes in the malt attack the long chains of sugar points in the chain. There is a high
level of activity during mashing.
units that make up the starch molecule and convert them
into fermentable wort:-
T h e re a re s o m e b ra n c h e s
in th e c h a in .
The result of the
enzyme attack is shown
here.
These units are sugars
and they dissolve in the
water used in the mash.
The liquid is called
'wort'.
Most of these sugars
are fermentable but
some are not.
85 120
This sugar is called glucose and it Lager Ale
80 mash mash
ferments very quickly.
100
75
70
80
65
60
60
fermentable.
Enzymes are sensitive to the conditions that they work in, The temperature rise to 80C in the lager mash is to
they are affected by how much water is present, improve filterability in the wort separation system.
temperature and pH or mash acidity. They take time to
work, so the length of time that is allowed for mash
conversion will affect the degree of conversion. Starch Test
The colour reaction between iodine and large-chain glucose
There are optimum conditions for mashing and these are (dextrins and starch) is used to detect their presence in
illustrated in the table below:- wort. Aside from producing a wort of desired fermentability
it is the goal of mashing to reduce the maximum length of
dextrins in the sweet wort to less than 9 glucose molecules
The most important enzymes are the amylases. They for unbranched and less than 60 for branches chains. At this
point they don't show a reaction with iodine anymore and
convert the remaining unmodified starch granules in the
the wort or mash is said to be iodine negative and mash
mash into fermentable sugars. Fundamentally, however, conversion is complete.
the two amylases have distinct temperature optima:
In an incomplete conversion dextrins are carried over, and
Optimal Temperature Inactivation Temperature the beer may develop a so called "starch haze". Despite its
Enzyme name in most cases this haze is not caused by starch but by
(°C) (°C)
long dextrins which become less soluble and precipitate in
-Amylase 70 – 75 75 – 80
the presence of alcohol. Those dextrins give a red to purple
-amylase 63 – 65 68 – 70 colour reaction with iodine
IoB Method: Example - 10,000 kgs of wort at a S.G. of 15 Plato are
collected from 2000 kilograms of malt. The extract is:-
Volume collected X specific gravity = litre degrees / kg
Weight of malt + adjuncts 10,000 X 15 = 75%.
2,000
Example - 10,000 litres of wort at a S.G. of 60 are collected 75 % of the weight of the malt has been converted
from 2000 kilograms of malt. The extract is:- to extract.
Both of these calculations are based upon the total weight
10,000 X 60 = 300 litre degrees / kg. of raw material being used, and represent the brewhouse
2,000 yield. Malt is an expensive raw material and achieving good
extract levels is therefore very important.
Mash Conversion
This recipe is used around the world for making malt C le a r W o r t
whiskies. Malt whiskies have a distinct flavour that is due in
part to the type of malt mashed . Mashing is carried out in the following way. The grist is
mixed with water that is called the first water because
The conversion of starch to sugars has already started more water will be used later in the process. This mixing of
during the malting process, following the breakdown of the the first water and the grist is called ‘mashing-in’. Mashing-
cell walls and protein matrix surrounding the granules. This in is a critical step because the water must be at a precisely
conversion was stopped by drying the grains. It is restarted controlled temperature.
by adding back the water but there is no point in doing this
with whole grains because the distiller must extract from
the mash
In some grain distilleries the entire mash, including residues This final water or “sparge” is not cooled and pumped to
from the wheat or maize and malt is carried forward to the the wash-back but is retained as mashing water for the next
fermenter (to achieve higher alcohol yields), but in some mash.
the wort is separated from the spent grains in a mash tun or
on filters of various types. When all the wort has been run off, spent grain is removed
through a port in the base either manually or by discharge
However, in every malt distillery, wort is always separated gear rotating arms.
from the spent malt grains.
Learning Material 2015 81
N.B. All types of mash tun act both as a conversion vessel
and as a wort separation vessel.
Mash tun
Sparge water
supply to rotating Preparation of wort from unmalted source of starch (80-
sprinkler.
85%) and (15 - 20%) malted barley
it is used to control its run-off rate. It is important that the as quickly as possible.
malt bed is not pulled down on to the mash tun plates,
when it would impair drainage. Most malt distilleries are Variations to this process include:
equipped with a balanced underback, in which the wort hammer milling the grain to a flour to
level in the mash tun and underback are equalised, allowing help mixing and gelatinisation and
close control of the run-off rate. the addition of backset (stillage from the
beer column of the continuous still) to the
Unlike the brewing industry where mash filtration is now water, reducing the water usage rate.
quite a common practice, there is presently only one
distillery in Scotland which operates a mash filter.
MALT AND MALT ENZYMES Key analytical parameters for malt distilling malt and
examples of typical values are:
Malt and its Uses
(a) Moisture < 5%
The distiller buying malt from a malting company must In the last 20 years, the moisture content has been raised
agree a specification because of the potentially variable from 4 to 5% or slightly higher for two main reasons. Firstly,
nature of malt. gentler kilning helps preserve the activities of the more
heat-sensitive enzymes, which can continue to work during
A basic specification for distilling malt is: the mashing and fermentation, releasing more fermentable
carbohydrate. Second, there is a saving in energy. Malt is
1. moisture of less than 5% (to preserve the enzyme hygroscopic (attracts water) and there may be a moisture
content) pickup of up to 0.5% between maltings and distillery. So, if
2. the predicted spirit yield that can be calculated the malt is required to be 5% moisture, the off-kiln
from how much material can be extracted from moisture should be 4.5%.
the grain (soluble extract) and how much of the
material extracted can be fermented by yeast Where there are adjacent maltings and distillery, it can be
(fermentabilty), both of which are laboratory dried to 5%. Malt with moisture content of 6% or more is
measurements, difficult to mill, and there is the possibility that ‘green-malt’
3. diastatic enzyme levels (i.e. the enzymes which sensory notes may enter the spirit from lightly kilned malt.
break down starch); alpha and beta-amylase are However, grain distilling malt moisture content can be up to
the two main diastatic enzymes involved in the 6%, the lighter kilning preserving enzymes.
breakdown of starch to fermentable sugars.
4. the malt should be easy to process through the
stages of milling and mashing and there are
various tests, such as friability, which can be used
(d) Soluble Extract (SE): > 80% of malt materials made (Where lpa/t = litres of pure alcohol per tonne, and dwb =
soluble dry weight basis).
o
The units used to describe SE are ‘litre /kilogram’ or ‘%
extract’ (%). The two units are related by a factor. Both In a grain distillery, the calculation is a little more
units are in use, depending on distiller’s preference. complicated due to the use of both malt and wheat (or
maize). The first step is to calculate separately the PSY of
The SE2 figure is the maximum extract that is obtainable the malt and the PSY of the other cereal. Then it is an easy
from the malt, as milling at this 0.2mm setting (fine grind) matter to calculate the PSY of the particular mash recipe in
mechanically breaks up any residual cell wall material, use at the time.
releasing the starch granules. This figure varies little with
the degree of modification of the malt. Milling at the For instance, in a distillery using 10% malt with a PSY of 420
0.7mm setting (coarse grind) (SE7) releases only the starch lpa/t and 90% wheat with a PSY of 370 lpa/t, the calculation
granules that have been made available because of matrix and result is:
breakdown during malting, so it is a measure of the degree 420 x (10/100) + 370 x (90/100) =375 lpa/t
of modification of the malt. The fine/coarse difference is
normally about 1%. Some distillers prefer to use a coarse SE (h) Total Soluble Nitrogen (TSN) and Free amino-nitrogen
figure obtained by milling the malt sample with a mill gap (FAN)
setting of 1.0mm, but the vast majority use 0.2 and 0.7mm Free α-amino nitrogen in the wort is required for the yeast
SE’s. growth that occurs at the start of fermentation. If wort is
deficient in this respect, the performance of the yeast
The SE7 figure was chosen when the Miag laboratory mill fermentation will be affected. FAN measurement gives a
became standard because its values were closest to the direct analysis for this parameter. TSN measurement is a
distillery’s mash tun extract (mte), when the traditional measure of protein modification, and may be expressed as
mash tun was the norm. In the last about 30 years, there a ratio to the total nitrogen – soluble nitrogen ratio (SNR). It
has been a gradual change in Scottish malt distilleries to is unlikely that there will be a shortage of FAN in malt
lauter-type mash tuns, which have higher extraction whisky production. Some distillers specify high TSN values,
efficiency. These tuns can achieve SE2 levels of extract, but which tend to depress laboratory fermentability values.
the SE7 figure that is the most reliable figure for predicting Grain distillery wort can be FAN-deficient particularly if the
spirit yield. proportion of malt in the mash is lower than 9% (w/w).
Health and Safety (H&S), also known as Occupational Safety confined space before entry, for tracing leaks or to give an
and Health (OSH) is a cross-disciplinary area concerned with early warning of the presence of gas, flammable gas or
protecting the safety, health and welfare of people engaged vapour when work is being carried out in a hazardous area.
in work or employment. The goals of occupational safety
and health programs include fostering a safe and healthy Whichever type of detection is in use, people must be
work environment. OSH may also protect co-workers, trained in the use of the detector and how to respond to
family members, employers, customers, and many others any alarm situation.
who might be affected by the workplace environment.
Regular maintenance and calibration of the carbon dioxide
This section will illustrate typical H&S legislation by monitors and alarm system are essential, as well as the
referring to UK legislation. maintenance of mechanical ventilation systems
Additionally Disposable Masks can be used, they are easy to Chemicals, such as detergents (designed to dissolve organic
use and offer protection for short term applications. Both matter) and sterilants (designed to kill organisms) may be
types require the filter or mask to be offering at least P3 hazardous materials for people to handle.
protection.
In the most countries, under Control of Substances
Full face masks can also be supplied as battery powered Hazardous to Health (C.O.S.H.H.) legislation, manufacturers
masks that filter the contaminants out via disposable filters are required to issue technical information on any cleaning
and force clean air into the mask (or hood). These are materials they supply. This information covers
particularly useful in very dusty atmospheres. recommended usage concentrations and actions to be
taken in case of accidents.
Air supplying respirators are generally used in more
hazardous environments like chemicals, smoke etc. and An analysis of the risks indicates the following methods of
they would include airline systems and self-contained reducing the hazards:-
breathing apparatus (SCBA). Anybody using this type of
equipment must be fully trained and competent. If a detergent or sterilant is considered too hazardous
then choose an alternative which is safer.
All RPE should be comfortable, fit the wearer and meet the
requirements for protection from the contaminant. Face-Fit
testing should be carried out to ensure this criteria is met,
in fact is it a legal requirement if the RPE is used as a control Isolate people from the hazard, for example in CIP
measure. (Cleaning in Place) systems, detergents and sterilants
are kept in automatically topped up tanks and away
The UK COSHH Approved Code of Practice says that from the staff. They are also stored in suitably sized
“Employers should ensure that the selected face piece is of bunds and kept away from other materials that would
the right size and can correctly fit each wearer. For a tight- react together.
fitting face piece, the initial selection should include fit
testing to ensure the wearer has the correct device. Also, Implement control measures like ‘safe systems of work’
employers must ensure that whoever carries out the fit that when followed, eliminate risks to the staff. An
testing is competent to do so.” example would be a ‘permit to work’ procedure for the
maintenance of CIP equipment.
Health Surveillance
The UK Control of Substances Hazardous to Health Ensure that people in the proximity of detergents and
Regulations 2002 (COSHH) require health surveillance to be sterilants use protective equipment especially eye
mandatory where risk assessment has shown individuals protection (goggles), gloves, boots and overalls.
are likely to be exposed to harmful substances.
Install safety showers in areas where risks are highest
The purpose of health surveillance is to, protect the health like detergent and sterilant delivery points.
of employees by early detection of adverse changes or
disease, collect data for detecting or evaluating health Inform people who work with detergents and sterilants
hazards and evaluate control measures. of the potential hazards.
It is important that documents are ‘controlled’ so that The control of quality through a ‘Quality System’ gives the
people are confident that the document they are working following advantages over a ‘Final Inspection’ approach:-
to is current and valid. The use of documented procedures and specifications
ensures that everybody knows what they are supposed
to be doing.
Document change is controlled by: HAZARD ANALYSIS AND CRITICAL CONTROL POINTS
- approval of changes before issue (HACCP)
- issue of an amendment sheet so that changes are
identified When applied to the food and beverage industries, a HACCP
- keeping a master list of document numbers to procedure involves the systematic analysis of production
ensure all staff use up-to-date copies and handling processes from the purchasing of the raw
- retrieval of obsolete copies as replacements materials through to the end use of the product by the
issued consumer. A HACCP audit seeks to identify the source and
- archiving one copy. severity of potential hazards that may threaten the safety
or integrity of the product. It involves the identification of
The Maintenance of Conformity critical control points (CCPs), i.e. locations, stages,
Adherence to a well-established quality system will ensure operations or raw materials that if not properly controlled,
that conformity of product quality and company operation provide a threat to product acceptability and consumer
is maintained. safety.
However, all quality standards strive for improvement and (A) Role in Food and Beverage Production
this is often best achieved by regular management reviews One of the main difficulties faced by the food and beverage
of the quality system and appropriate communication to all industry in controlling the hygiene status of products is the
staff, especially for changes to systems and Regulations. time taken for conventional laboratory methods to produce
useful results.
Regular Quality Review meetings should:
review the Quality Policy and Quality System at defined Understanding the source of contamination and the way in
intervals (at least annually) which different microorganisms respond to processing and
be additional to departmental or section quality storage conditions enables prediction of their behaviour
meetings and the design of the processes and products to eliminate
be chaired by senior management them or prevent them from growing. This concept forms
include QA staff, production managers, auditors, the basis of HACCP approach to the control of
purchasing staff microbiological hazards.
review the operation of the quality system
ensure the policy and system are suitable and effective A properly designed and operated HACCP system is
recommend changes essential to food handlers or processors intent on ensuring
record actions and responsibilities the safety of their operation in the food supply chain.
meeting agenda should include:
- audits (internal and external) (B) Hazard Analysis
- process performance Consideration of HACCPs is essential for maintenance of
- complaints high quality standards. Hazard analysis is equally applicable
- preventative and corrective actions to non-microbiological problems, e.g. the prevention of
- changes glass fragments in malt is an engineering problem.
- training needs Therefore, the panel assessing hazards must be composed
- supplier performance of all relevant specialists. A multidisciplinary team that
- future developments. covers all aspects of the production should carry out the
HACCP programme.
3. Identify the CCPs for these hazards. 2. Identify all hazards and list the control measures.
Obvious sources of hazards are as follows:
4. Establish critical limits for each CCP. Processing stages: time, temperature,
recontamination.
5. Establish corrective action to be taken when Product shelf life: packaging, storage, and
monitoring indicates a fault at a CCP. temperature.
Raw materials: micro-organisms, trace
6. Establish record keeping for HACCP; for contaminants such as pesticides and heavy
documentation, and verification that HACCP metals.
analysis is effective.
3. Assess the risk of hazard occurring. Once the
potential hazards have been identified the
KEYPOINT: Different food processes are vulnerable to associated risk of each should be quantified, usually
different hazards. There is no single hazard analysis that into high, medium and low categories.
covers all cases, but the general principles of HACCP will still
apply. 4. Identify CCPs and prepare a ‘decision tree’ for
action. Control of hazards is exercised at CCPs.
If a safety hazard is identified that results from inadequate These can be locations, procedures, practices or
or, in some cases, no control measures in place at a CCP, processes, such as maintaining staff hygiene
then as far as the legislation is concerned food safety is standards, correct operation of thermal processes,
lacking and the situation must be rectified. control of product storage temperatures etc.
When considering quality hazards, however, a more- 5. Establish critical limits for each CCP. Once CCPs have
defined risk assessment can prove very useful indeed. A been identified, the means of testing to ensure that
popular method of assessment is a dual risk assessment the control is adequate must be established for
based on the risk of the hazard occurring with control each. This assessment may include microbiological,
measures in place at a specified process step compared chemical, physical, sensory or administrative
with the probability of that hazard getting through to the procedures.
final product with subsequent control measures in place.
6. Establish monitoring procedures for each CCP.
A score is given in each case based on a scale of 1 to 5: Once established, all controls must be implemented
and the CCPs monitored to ensure that adequate
1. Minimal or no risk control is being maintained. Monitoring should be
2. Possible risk on a continuous basis.
3. Likely risk
4. Very likely risk 7. Establish corrective action for each CCP.
5. Definite risk Procedures must be written detailing the course of
action to be taken when the CCP is found to be ‘out
For example, it could be considered a ‘likely (3)’ risk of of control’. These procedures detail the steps to be
weevils gaining access to the barley in the silo block. taken to bring the CCP back into control.
However, the risk of the insects being carried through to
the final pack is ‘possible (2)’. The final risk assessment is 8. Establish record keeping and documentation.
given as 3/2.
9. Establish and audit procedure for verification.
The scores help to prioritise action. This is especially useful More detailed tests should be used periodically to
when action requires capital expenditure, or significant ensure the effectiveness of the HACCP system in
changes in procedures or process. Priority issues can be relation to the stated protocols and any hazards not
addressed first and should be addressed in the current included in the initial hazard analysis.
financial year. Other issues can take a back seat, although a
clear action plan must be documented and held with the 10. Review the HACCP system each time there is any
HACCP plan. change to the process. Any changes in the
production or handling processes that may affect
the HACCP system must be identified and
The growth of these species during grain storage is A survey of beers showed that malt from certain maltings
dependent on the moisture content and temperature of the was responsible for higher levels of NDMA in the finished
grain, and it is practical to control this growth by ensuring product, and a rapid conclusion as to the common factor
that grain enters storage at appropriate moisture and that between these maltings was that they operated direct-fired
it is cooled promptly to a suitable temperature. gas kilns. Then the task of understanding the chemistry
started.
Once grain is safely in store, monitoring of temperature
must continue by a matrix of thermometers throughout the We are now able to benefit from those studies to
bulk. This will show whether heating is occurring through, understand that the nitrosylation of amines in the malt,
for example, insect infestation or water contamination particularly in the rootlets of the growing grain, was caused
leading to germination. Once an area of the bulk starts to by oxides of nitrogen in the gases which passed over the
heat, moisture rises from this area and can condense on grain in the kiln – styled NOx, as the important two gases
other grain, leading to further mould growth, insect or mite are NO and NO2.
proliferation and possible grain germination – a bulk can
quickly be spoilt from a quality viewpoint because of The maltings that did not produce high NDMA malt were
reduced Germinative Energy (GE) and from a food safety fired indirectly, or fired by oil or even coal. The difference
angle because of contamination with mycotoxin. A from the change of fuel was the pH on the surface of the
composite chart showing the safe zones of moisture and grain – more acid when the fuel contained sulphur which
temperature for insects, mould, mites and germination is burned to produce SO2 and created sulphurous acid in the
shown below. flue gases. The change for indirect-fired kilns was that the
flue gases did not pass through the grain, but instead the
drying air passed through a heat exchanger and was heated
Temperatures should be checked in store at least every by (typically) a thermal fluid – steam, hot water or thermal
week until they reach the safe zone, at which time the oil which itself had been heated in a boiler by the flue gases
frequency may be reduced to fortnightly. from the flame.
References:
Ethyl Carbamate
MAGB Implementation of HACCP for barley and malt.
Some barley varieties produce high levels of cyanogenic http://www.assuredukmalt.com/The%20MAGB%20HACCP
glucosides, commonly known as glycosidic nitriles and %20Protocol%20%20Version%203.0.pdf
abbreviated to GN, when malted. The use of these varieties
in the distilling industry, under certain conditions, can BBPA list of approved pesticides for barley.
produce significant levels of a potentially carcinogenic http://www.ukmalt.com/sites/default/files/files/TECH-
compound – ethyl carbamate, often abbreviated to EC. 456%20BARLEY%20Feb%202012.pdf
TYPES OF SYSTEMS AND CLEANING CYCLES. might as well as areas not suitable for automated cleaning.
Typical areas not suited to automated cleaning include:-
There are essentially two types of plant cleaning available, Kilns.
Manual Cleaning and Automatic Cleaning. For the purpose Storage facilities
of this learning material assume all automatic cleaning Dry product handling machinery
systems are of CIP type even if they have to be manually General cleaning (eg: vacuuming floors, cleaning
activated. Automatic cleaning / CIP has been adopted into walls, cleaning railings etc)
the malting industry from the brewing and distilling
industries and is suitable for a number of specific types of Manual cleaning has the following benefits:-
cleaning duties. As you might expect the brewing and No significant capital outlay.
distilling sector use a large number of enclosed systems Adaptable to changing cleaning requirements.
such as pipes, tanks, vats etc. As these elements are usually Can clean dry areas.
subject to filling with fluid it makes them particularly suited Plant is observed more closely and issues can be
to automatic / CIP cleaning. Likewise, the malting industry brought to light early.
has some similar areas suitable for the automated cleaning.
Such areas include:- Disadvantages include:-
Steep tanks Standard of cleaning is determined by the
Germination vessels individual and subject to variation.
Conveying equipment/pipework associated with Running costs are higher than automatic cleaning
both the above. due to the salary overheads in addition to the
cleaning materials.
Automatic / CIP cleaning in such systems has the following Workers may be subject to any dangerous effects
benefits:- from cleaning materials during the cleaning
Reduced downtime for cleaning procedures. process.
No requirement to dismantle for cleaning. Workers may be entering confined spaces.
Cleaning can be programmed to begin at set stages Cleaning can take longer to complete.
rather than wait for manual intervention.
Workers are not subject to any dangerous effects Cleaning in place has replaced older methods where plant
from cleaning materials during the cleaning was dismantled for manual cleaning. Modern plants do not
process. have the manpower or time for manual cleaning operations
Workers are not entering confined spaces. and they need the higher standards that an effective CIP
If the CIP system is suitable for task then the task system can deliver.
will be repeated to a very similar standard during
each use. CIP is the circulation of detergents, water rinses and
Chemical use can be optimised and evenly applied. sterilants through fixed plant without dismantling. In order
Running costs are lower due to negligible to achieve this, plant has to be fitted with spray balls/heads
manpower required. and pipework has to be linked into a ‘ring’ main.
Disadvantages include:-
High capital outlay.
If not correctly set up, may fail to clean evenly or
to a high enough standard.
Has a degree of burden for the plants engineering
department to maintain the extra equipment.
Choice of cleaning/sterilising materials (se Section 16). A final rinse if it is decided that no sterilant should
remain in the plant. This is similar to the initial rinse
Automation and monitoring. although the water that is used must be
uncontaminated. If it is considered, however, that
Running costs. residual traces of the sterilant will not harm the
product, the final rinse may be omitted. Water from the
final rinse can be collected and used as an initial rinse
Choice of System - Recovery or Total Loss.
when the next vessel is cleaned. The benefits of a final
rinse recovery being a reduction in water use, a
A recovery CIP system consists of tanks where supplies of
reduction in effluent and a more effective pre-rinse.
detergent and sterilant are held at the required
concentration for use. Cleaning fluids are delivered from
the tanks and returned to them. Detergent and sterilant Comparison of Recovery versus Total Loss Systems
strength is maintained in the tank.
The benefits and problems associated with ‘Recovery’ and
A total loss system doses concentrated detergent or ‘Total Loss’ systems are detained in the table below:-
sterilant into the delivery line and although they are re-
circulated, at the end of the clean the cleaning fluids are Recovery System Total Loss System
run to waste. Capital costs are higher Lower capital cost
because of the need for
large tanks
Spray balls are relatively cheap and they are easy to Delivery pump.
maintain although they can block up especially if the
cleaning liquid is unfiltered. Rinse water and drain valves.
Plant Design - Hygiene Considerations. - There should be adequate procedures in place to control
pests.
Effective cleaning is the result of a combination of four A site pest control system should be a pre-requisite of the
factors:- company HACCP (Hazard Analysis and Critical Control
Points) system and is a requirement to comply with Good
Time. How long is the cleaning agent/detergent in Manufacturing Practice and a number of standards
contact with the plant? including the Feed Material Assurance Scheme FEMAS.
Temperature. How hot is the cleaning agent/detergent? Good practice for pest control:
The company shall develop and implement a pest control
Chemical activity. How strong/effective is the cleaning program using a trained specialist that has been approved
in accordance with national legislation. The programme
agent/detergent?
shall ensure that all products, processes and other sensitive
areas are suitably protected from pest activity. The
Physical activity. How vigorously is the cleaning
company shall ensure that all storage, processing,
agent/detergent applied to the plant? packaging and dispatch areas are protected against the
ingress of pests. Waste materials shall be regularly cleared
If one of these factors is reduced, for example if the plant away so as to avoid attracting pests. Records of all
has to be cleaned quickly, then another factor must be treatments and inspections shall be kept. The program can
increased to compensate, for example hot instead of cold be developed and operated in-house or sub-contracted. If
detergent could be used. an employee carries out the pest control it must be in
accordance with legislation and DEFRA guidance.
Most buildings provide 3 main attractions for pests: 6) Adequate measures must be taken to prevent pests
from entering buildings.
- Food and water – Most pests require very small
amounts of food, an adult mouse for example can 7) Appropriate measures of insect control, such as fly
survive on as little as 3 grams a day. It follows that screens, electronic fly killers, rodent baits etc. must be
cleaning is a key requirement of pest control as is provided, properly placed and maintained.
removal of water sources.
- Warmth – A few degrees increase in temperature 8) A reputable pest control contractor must be employed
may be sufficient to encourage infestation unless the company has equivalent expertise and
particularly in winter months. With most species of resources. In the case of a company-based pest
pests an increase in temperature corresponds to control service, the operation must be managed by an
an increase in breeding frequency and numbers. appropriately experienced supervisor.
- Shelter – All buildings provide a degree of shelter
or harbourage whether old or new, if they include 9) The contractor must be provided with a contract
areas allowing internal movement of pests such as specification which requires the contractor to report
wall cavities, service ducts, panelling and to the responsible manager before and following visits
suspended ceilings for example. to the premises. An exit meeting should take place
within an agreed time schedule to review findings of
the visit.
A Typical Pest Control Service Contract:
10) The contractor must provide the company with a
This will contain the following.
written report of any pest control activities
undertaken on the premises and must provide, where
needed, written recommendations of action required
Premises Risk Assessment.
to solve pest related problems.
The number and type of routine visits will be based on risk
assessment. This will consider the past history of the site. Is
11) All instances, as seen by any employee, of pests within
there documented evidence that rodents have been active
buildings or, in the case of rodents, within the site
in the last two years?
perimeter must be immediately reported to the
responsible manager.
The site’s potential for infestation. Does the layout,
construction, manufacturing process, hygiene practices or 12) Hygiene auditing must encompass routine surveillance
product lend the site liable to infestation? Are there water of buildings and perimeter for pests.
courses, railways, amenity sites nearby? Is the site situated
within or adjacent to a high risk area? 13) A manual must be available which will contain all the
relevant information of the pest control programme,
What is the status of neighbouring properties? Are the including a site plan with the location of all pests traps
activities of adjacent properties or businesses liable to where necessary.
attract pests into the vicinity?
14) Pesticides and chemicals when used must be industry
The key points of a Pest Control Contract are as below: approved and have the relevant documentation
including COSHH data sheets. Usages of pesticides are
1) Responsibility must be allocated to a senior manager. to be kept.
2) Suppliers Health, Safety and Environmental Policy and
Risk Assessments in relation to the tasks to be Pest Diseases:
undertaken. The Insurance documents of the Supplier
should also be available at all times. The supplier must a) Weil’s Disease
also provide a Waste Carriers Licence for approved
disposal of pests and pesticides. Weil's disease is an infection that humans can catch from
animals, including domestic animals like dogs. Perhaps most
3) The contract will identify terms and conditions
commonly however, the disease is spread by rats. Rats
including costs, frequency of visits, key contact details,
carry and excrete an organism called Leptospira ictero-
reporting mechanism and contract length.
haemorrhagiae in their urine. Between 50 and 60% of all
c) Salmonella:
Pigeons/Birds
Mice and rats are both frequent carriers. Spreads to All doors and entrances must be kept shut
humans by contact with mouse droppings, especially All grain spillages must be cleaned and removed.
through consumption of contaminated food. Causes All windows are to be kept shut.
serious, sometimes fatal gastroenteritis. Household pets Cover openings of grain with netting.
are also frequently infected with Salmonella by this means Use imitation birds of prey to scare other birds
and often die as a result. away from the premises.
d) Pigeon Droppings:
8. CADELLE, Tenebroides mauritanicus. Both the adult and 1) Brush, sweep out and/or vacuum the combine, truck
larvae are large and easy to see. Both stages feed mainly on beds, transport wagons, grain dumps, augers, and elevator
the germ of stored grains, but may also attack milled cereal buckets to remove insect-infested grain and debris.
products. The larvae leave stored grain in the fall and
burrow into woodwork, such as wooden bins or boxcars, to 2) In empty bins, thoroughly sweep or brush down walls,
hibernate. They may also burrow into packaged cereal ceilings, ledges, rafters, braces, and handling equipment,
products, thus providing an entrance for other cereal pests. and remove debris from bins.
9. FLAT GRAIN BEETLE, Cryptolestes pusillus. This is a tiny 3) Remove all debris from fans, exhausts, and aeration
beetle that feeds primarily on the germ of stored grains, ducts (also from beneath slotted floors, when possible).
especially wheat. It is readily attracted to high-moisture
grain. In fact, under high-moisture conditions, the flat grain 4) Remove all debris from the storage site and dispose of it
beetle may also develop in many cereal products, but is not properly according to local / national guidelines (this debris
a common pest in kitchens. usually contains insect eggs, larvae, pupae, and/or adults,
all ready to infest the new grain).
Direct-feeding damage by insects reduces grain weight,
nutritional value, and germination of stored grain. 5) Remove all debris and vegetation growing within ten feet
Infestations also cause contamination, odour, mould, and of the bins (preferably the whole storage area).
heat-damage problems that reduce the quality of the grain
and may make it unfit for processing into food for humans 6) Examine area to determine if rodent bait stations are
or animals. Commercial grain buyers may refuse to accept required, and use if needed. Be sure to follow all label
delivery of insect contaminated grain, or may pay a reduced directions.
price.
7) Spray cleaned area around bins with a residual herbicide
Kinds of Stored Grain Insects to remove all undesirable weedy plants.
Several species of insects may infest grain in storage. The
principal pests that cause damage are the adult and larval 8) Inside bins, spray wall surfaces, ledges, braces, rafters,
stages of beetles, and the larval stage of moths. All may be and floors with an approved insecticides to the point of
a problem by their presence, either alive or dead, in grain runoff. Outside, spray the bases and walls up to 15 feet
that is to be processed for food. above the bases, plus the soil around the bins.
Stored-grain insects are known as “internal feeders” if they Preventative Measures During Binning
feed within the kernels, otherwise they are referred to as
“external feeders.” The granary weevil, rice weevil, lesser A grain protectant may be applied to grain that will be in
storage for one or more years. Grain protectants are
The most common stored grain insect pests may be Sawtoothed Grain Beetle, Red and Confused Flour Beetles,
grouped by their feeding habits. Listed below are Flat Grain Beetle, and Cadelle
appropriate management strategies for these groups. These secondary feeders infest bins because of the
availability of grain dusts, cracked kernels, and grain debris.
Internal Feeders These pests can be distributed and feeding throughout the
grain mass or localized because of a collection of fines, such
Weevils and Lesser Grain Borer as in the core of the bin where fines collect at binning. They
The only options with infested grain is to sell for animal will also feed on the dusts and damaged kernels created by
feed at a discounted rate, or fumigate it. All fumigants are internal feeders; if this is the case then the only control
classified as restricted use products. Fumigants are option is fumigation.
extremely hazardous for the user and must be applied by a
certified and licensed commercial fumigator. Fumigants for A grain bin of whole undamaged kernels is the key to
use in farm storage bins are registered as either “liquid preventing the secondary feeders. This may require running
under pressure” or “solid formulations.” Regardless of the the grain through a cleaner or aspirator while moving the
formulation, fumigants become effective when they change grain from one bin to another. This will not only remove the
to a gas form, and settle down through the grain mass. fines, but dead and live insects as well. Applying a grain
protectant) while moving this grain would be a sound
The grain bin should be air-tight and all openings sealed management practice. Refer to PREVENTIVE MEASURES
before fumigation. Best conditions for treatment are a calm BEFORE BINNING for proper preparation of the grain bin.
day with grain temperatures at or above 18°c. Success
a. Tradition - Kilns were traditionally heated by • Indirect heating provides a physical barrier
direct burning of fuels such as wood, between flame and drying air.
anthracite, peat, oil or gas. • Heat can be transferred from a boiler by
pressurised water, thermal fluid or steam. This
b. Gas - Natural gas is the cleanest burning fossil has the advantage of a remote heating plant.
fuel. Coal and oil, the other fossil fuels, are • Specially designed heaters, e.g. Air Frohlich
more chemically complicated than natural gas, ‘Anox’ or Flucorrex ‘Varinox’ contain
and when combusted, they release a variety of combustion in tubes with kilning air flowing
potentially harmful chemicals into the air. over the tubes.
Burning methane releases only carbon dioxide • Water of combustion does not affect the
and water. Since natural gas is mostly drying.
methane, the combustion of natural gas • No additional NOx is formed in the kilning air.
releases fewer by products than other fossil • Conducive to high degree of heat recovery
fuels. Water of combustion formed during the with flue gas cooled to <50°C and efficiencies
process of burning gas will reduce the drying >100% of Net Calorific Value.
effect slightly.
2. Fuel cost control:
c. Direct heating methods via a burner unit:
Nitrogen Oxides (NOx) formed in the flames There are a number of factors to take into consideration
(esp. Natural Gas) will produce NDMA (n- when trying to control the fuel costs in a maltings.
nitrosodimethylamine) with certain proteins in Importantly the business must have resource to provide a
the malt. To counteract the formation of purchasing strategy for fuel purchasing. There a number of
NDMA, sulphur would be burnt during the ways to purchase fuel including spot, forward buying and
early stages of the kilning process, reducing hedging. There are no perfect methods for purchasing fuel,
the pH level on the grain surface. Oil and coal but expertise is key to ensure it is undertaken correctly.
have sufficient sulphur content to prevent
NDMA formation. Below are a number of considerations to be undertaken to
control the cost of fuel use.
d. To minimise the formation of NDMA, low NOx
burners provide controlled combustion
o
temperatures at temperatures below 1250 C 1. Housekeeping
and therefore will reduce the formation of – Ensure no leaks in the drying units where
NOx products. hot air can escape.
– Kiln bed is evenly compacted & flat, this
Direct combustion is probably the cheapest in will enable the warm air to pass through
capital cost terms. the bed of malt with even distribution.
It should be remembered that there is a major – Kiln is stripped & loaded as quickly as
fire risk since cereal matter may be in direct possible. If the kilns cool down due to a
contact with flames from the fuel. slow process, it will require more fuel to
re heat the drying unit.
e. Low sulphur gas oil, fuel oil. – This fuel
medium would be used in conjunction with a 2. Insulation: the kilns must be insulated, so that the
direct fired burner, but due to the nature of heat will be contained within the building. also the
the product, the maintenance of the burner
kilns must contain no leaks, so all holes in the 3. Combined heat and power systems, CHP Technology
fabric should be filled and doors correctly sealed. A CHP plant consists essentially of an electrical generator
combined with equipment for recovering and using the
3. Process control: The system will ensure the correct heat produced by that generator. The generator may be a
sequence of kilning is followed and fuel costs are prime mover such as a gas turbine or a reciprocating
finely managed by correct use of heat, engine. Alternatively, it may consist of a steam turbine
recirculation and reuse of warm air. generating power from high-pressure steam produced in a
boiler. In some cases, a CHP scheme may be a combination
4. Moisture of final malt: It is essential that the of prime mover(s), boiler(s) and steam turbine(s) as shown
correct moisture is attained, but no lower, as in the image below.
energy may be wasted by lowering the moisture
beyond the necessary requirements. CHP plant can be broadly placed into three categories:
The two type GC 357 N5 CHP plants equipped with MTU Malt producers may draw their water from boreholes or
Series 400 engines deliver around one megawatt of thermal from domestic supplies. The latter is almost always the
and approx. 700 kilowatts of electrical energy more expensive choice.
Biogas is suitable for use in boilers, gas engines and gas It has long been recognized that by warming water and
turbines and it is common practise to utilise biogas in CHP steeping at slightly higher temperatures the duration of
units for simultaneous generation of heat and power. The steeping can be shortened.
heat generated by the CHP units is primarily utilised for
digester heating with surplus heat available for secondary However, there are physiological limits on how warm steep
uses such as greenhouse heating or for distribution to other liquor can be before germination is reduced and, at even
users via a district heating network. higher temperatures, grain is killed. Steep temperatures of
up to 18 °C are not unknown, and the temperatures are
closely controlled. To achieve this, the water is normally
Typical used steep water analysis The liquid percolates downward over the solid surfaces and
is in contact with an upward stream of air. The biology of
such beds is extremely complicated but, in principle, a
Sample BOD COD Organic pH Suspende 'zoogleal' bacterial slime forms on the solid support and it is
mg/l mg/l Nitroge d Solids here that oxidation occurs; suspended material is retained
n mg/l mg/l and the bacteria accumulate.
Steep 1 280 310 132 6.3 218
0 0 5
Steep 2 225 248 75 5.9 145 Sometimes it is necessary to add ammonium salts and
0 0 phosphates to the effluent to maintain the population of
Steep 3 190 214 64 5.6 112 microbes.
0 0 5
Steep 4 490 650 12 6.4 27.5
Composit 186 212 71 Dislodged solids are carried away in the liquid stream and
e 0 0 are collected in a separating tank. The bed must not be
allowed to dry and the effluent must not be too
concentrated, so some recirculation of treated effluent may
Waste steep water is yellow-brown, readily putrescible, be used.
contains microbes (but few or no pathogens), suspended
organic matter, colloidal materials and a range of low-
There can also be difficulties with offending odours and flies The disposal of sludge is potentially difficult and expensive.
breeding in the filter beds. Sometimes it is accumulated in holding tanks and may be
thickened to 4-5% solids by settling, and then is transported
More compact, high-filtration rate devices have been used, to be dumped or spread on fields as a soil conditioner and
for example as a preliminary treatment preceding activated fertilizer. In contrast to some others, sludges from maltings
sludge treatment. In these devices, a plastic material with a do not contain significant residues of toxic heavy metals.
high surface area, used to support a film of microbes, is
packed in a tower covering a relatively small ground area, In large treatment plants, the sludge may be 'dewatered',
and the effluent is sprayed in at the top. Such towers are often with the addition of lime, under vacuum, by pressure
able to tolerate higher BOD loads than trickling filters. filtration or by heat to reduce the volume.
In other devices, rotating biological contactors, supporting a Perhaps the most satisfactory arrangement is to biologically
mass of biological slime, are partly submerged in the digest the sludge anaerobically at 30-35 °C: the volume is
effluent to be treated. substantially reduced (e.g. by 50%), the sludge is stabilized
and swells less and carbon dioxide and methane is
The next objectives are to remove biologically oxidizable generated. This can be burned as a source of heat and may
materials and the suspended solids remaining after be used to keep the digester warm or to provide an energy
screening. This is achieved by a combination of biological source if the plant is large enough.
oxidative treatments and settling or precipitation. (In
Ref: Malts and Malting - Dennis E. Briggs
SUSTAINABILITY AND CLIMATE CHANGE. leading roles in their economies adhere to certain guiding
principles typified by the following:
The malting, brewing and distilling industry, in common
with other industries, impacts on the environment in many To comply with all relevant national and local
different ways. For example: legislation and regulations. To design, operate and
As a user of energy. maintain processes and plants to:
As a ‘consumer’ of water and other natural - optimise the use of all resources (materials,
resources. water, energy etc) whilst ensuring that
As a source, both directly and indirectly, of unavoidable wastes are recovered, reused or
atmospheric emissions, trade effluent and disposed of in an economically sustainable and
packaging waste. environmentally responsible manner.
- minimise the potential impact on the
Sustainable development environment from site emissions to air, water
and land.
The challenge of sustainable development is to achieve
economic, social and environmental objectives at the same To regularly assess the environmental impacts of
time. processes and plants and, based on the
assessments, set annual objectives and targets for
In the past economic activity and growth have often the continual improvement of environmental
resulted in pollution and wasted resources. A damaged performance.
environment impairs quality of life and at worst may
threaten long term economic growth, for example as a
To use and develop packaging and distribution
result of global climate change.
systems for which packaging/product
Climate change combinations will make fewer demands on non-
renewable and renewable natural resources.
Climate change is being caused by an increase in
greenhouse gases in the atmosphere. These gases come To minimise the use of substances which may
from both natural and man-made sources, but the increase cause potential harm to the environment and
is the result of human activity, mainly the release of carbon ensure they are used and disposed of safely.
dioxide from the use of fossil fuels such as coal, gas, oil,
petrol and diesel. To encourage a culture of awareness on
sustainability issues amongst employees through
All businesses and societies, to a greater or lesser extent, management commitment, appropriate
will feel the impact of climate change and the policies of communications, training and other initiatives.
governments around the world to address it. These may
include: To establish and maintain appropriate procedures
and management systems to implement these
restrictions on emission levels principles through policy commitment.
restrictions on water use
To work with suppliers and other business partners
changes in agricultural growth patterns in the supply chain to maintain high environmental
increases in energy prices standards.
changes in consumer habits
The role of carbon dioxide – the carbon cycle
Sustainability guiding principles
Carbon dioxide emission is seen as a key measure of
Companies committing to minimising the total impact of environmental damage. During germination the barley
their activities on the environment, to using natural respires, taking in oxygen and giving off carbon dioxide. The
resources wisely, to pursuing social progress and to playing impression may erroneously be given that this malting
process is a net generator of carbon dioxide as a result. In
Steeping – All steep tanks will have a fan linked to the unit
to enable air to be either pulled/pushed through the grain
to remove CO2 build up. A number of steeps will also have
an aeration system which will require a high volume of
compressed air to move the grain whilst under water.
Green malt that is transferred into the Germination process A barley washer can be used as a pre steep vessel and can
will normally have a moisture content between 43 – 46% be utilised to clean the barley and significantly raise the
moisture. During normal malting conditions, grain may dry moisture content of the steeped barley. It consists of two
out by > 0.5% each day it is germination. The germination pairs of washing screws each with a high throughput
unit will be humidified during this stage by passing moisture capacity per hour. The machine separates any floating
through the bed of malt which is introduced into the air barley as well as cleaning and pre-moistening the barley as
stream below the bed of malt. it transfers to the steeping vessel.
Types of units in the Germination are This process step gives optimal hygiene levels which
improve the effectiveness of the steeping process.
Sprays
Compressed air and water Ecosteep
Spinning Discs
• Developed by Buhler and various Dutch
Hygiene: universities.
• The system reduces water consumption
High levels of water are used during wash down of malting of the plant compared to other FBSTs by
plants with High Pressure Hoses. over 30%.
• The system has eliminated the clearance
area below the floor, which requires the
4. Typical water conservation strategies. use of lots of water and is very difficult to
clean.
Metering: • It also produces a more uniform malt
quality by using only a low depth of
Measure and monitor use of water and implement a plan to malted grain material during the
reduce consumption. Set targets, then measure and review production cycle.
on frequent basis. • Air and water for the process are
controlled carefully by being fed through
uniformly configured nozzles
Steep Programmes:
Reuse of water:
Steeping plant:
Lowering of the steep tank overflows to allow full and WASTE STORAGE AND SEGREGATION
robust steeping and overflows while reducing the amount
of water required. The malting industry gives rise to various waste streams
and co products; these are in general generated during
normal malting activities,(barley intake drying and storage,
the storage area is covered The duty of care responsibility ensures that waste
the storage area is fully enclosed (to contain management is audited throughout the process including
spillage) confirmation of the final location of the waste disposal or
there is protection against flood or fire-water recycling.
ingress
there is an air extraction system The pressure on landfill
drainage liquids are contained, treated and tested
prior to release Landfilling is increasingly discouraged for a number of key
there is fire protection reasons:
Examination Syllabus
The General Certificate in Malting gives international recognition of a basic, under-pinning knowledge and
understanding in the principles of malting operations. The qualification is offered by both the Institute of Brewing
and Distilling (IBD), as a stand-alone qualification, and the Maltsters’ Association of Great Britain (MAGB) as part of
their Certificate in Malting Competence (CMC) qualification.
The General Certificate in Malting has been designed for candidates who may have little or no formal academic or
technical qualification and will often be employed as a senior operator or technician in a malthouse, or will be
graduates or managers new to the malting business. The scope of these examinations will also enable those from
smaller malting operations to obtain this recognised qualification, and are open to anybody with interest in malt
production. They are a measure of basic knowledge (theoretical and practical) underpinning cereal growing, malt
production and associated operations.
- The General Certificate in Malting can be an end in itself, or the start of professional development leading
to further qualifications in malting.
- The General Certificate in Malting is accredited at Level 3 of the National Qualifications Framework in the
UK (or equivalent internationally recognised standards).
- The General Certificate in Malting takes the form of one multiple choice paper of two hours.
- The General Certificate in Malting is a module forming part of the MAGB’s Certificate of Malting
Competence.
Candidates can register to sit the exam on-line instead of using the traditional paper format. Candidates sitting
within malthouse or university centres will be encouraged to take the on-line version. The exam itself appears on
the screen very much like the paper version and with the same number of questions, but there are various different
ways of asking the questions which make the exam a more interesting experience. The marking is done
electronically and candidates will received a detailed feedback on how each section of the syllabus has been
answered.
The pass mark is set at 66% (40 correct answers from 60 questions) for all IBD General Certificate exams.
Candidates attaining 90% or more achieve a Distinction pass and between 80% and 89% achieve a Credit pass.
Ref. Topics Candidates should understand and be able to explain and describe in simple
terms, or demonstrate familiarity with:
(No. of questions to be
answered = 2)
3. Alternative cereals.
1.3 Malted cereals 1. Uses of malted cereals (including non-brewing/distilling uses) and malt
co-products.
Ref. Topics Candidates should understand and be able to explain and describe in simple
terms, or demonstrate familiarity with:
(No. of questions to be
answered =3)
3. The significant changes that occur when the barley grain is malted.
2.3 Requirements for 1. Costing – an awareness of the essential cost elements in the
malting manufacture of malt.
Ref. Topics Candidates should understand and be able to explain and describe in simple
terms, or demonstrate familiarity with:
(No. of questions to be
answered = 4)
3. Harvesting barley.
Ref. Topics Candidates should understand and be able to explain and describe in simple
terms, or demonstrate familiarity with:
(No. of questions to be
answered = 5)
4. Co-products.
2. Drying of barley
Ref. Topics Candidates should understand and be able to explain and describe in simple
terms, or demonstrate familiarity with:
(No. of questions to
be answered = 4)
Ref. Topics Candidates should understand and be able to explain and describe in simple
terms, or demonstrate familiarity with:
(No. of questions to be
answered = 4)
5. Hand evaluation
Ref. Topics Candidates should understand and be able to explain and describe in simple
terms, or demonstrate familiarity with:
(No. of questions to be
answered = 4)
Ref. Topics Candidates should understand and be able to explain and describe in simple
terms, or demonstrate familiarity with:
(No. of questions to
be answered = 2)
Ref. Topics Candidates should understand and be able to explain and describe in simple
terms, or demonstrate familiarity with:
(No. of questions to
be answered = 3)
9.1 Types of speciality 1. Different types of speciality malts, their characteristics and their
malts production.
9.2 Plant and processes 1. Principles and operation of malt roasting equipment.
9.3 Uses of speciality 1. Typical uses of roasted and ‘other’ speciality malts.
malts
Ref. Topics Candidates should understand and be able to explain and describe in simple
terms, or demonstrate familiarity with:
(No. of questions to
be answered = 5)
10.1 Process 1. Process adjustments to address the variable nature of the natural
Specifications ingredients of malt.
3. Effects of the malting process on the final product value of these key
parameters.
10.2 Process Control 1. The principles of monitoring and adjustment to achieve product
consistency.
10.3 Laboratory Analysis 1. Principles of the analytical methods for the key parameters.
Ref. Topics Candidates should understand and be able to explain and describe in simple
terms, or demonstrate familiarity with:
(No. of questions to be
answered = 3)
11.1 Definition of beer 1. A generic, non-legalistic definition of beer in terms of its typical
and types of beer ingredients and methods of production.
11.2 Barley and malt 1. The brewer’s key malt parameters of degree of modification, extract
content, moisture content, extract, and colour.
2. The selection of malt for beer type and mash conversion method.
11.4 Mash conversion 1. The respective roles of the amylases and protease, the effect of
temperature, pH and time on their activity.
Ref. Topics Candidates should understand and be able to explain and describe in simple
terms, or demonstrate familiarity with:
(No. of questions to
be answered = 2)
12.1 Definition of potable 1. Definitions of the main spirits derived from cereals.
spirits
12.2 Characteristics of 1. The range of spirit types and their respective styles and characters.
potable spirits
12.3 Malt and its uses, 1. The selection of malt for spirit type and mash conversion method.
including green malt
and peated malt. 2. Pre-acceptance checks at malt intake.
Ref. Topics Candidates should understand and be able to explain and describe in simple
terms, or demonstrate familiarity with:
(No. of questions to
be answered = 3)
13.1 Malting Plant 1. The evolution of carbon dioxide from steeping and germination
Safety
Considerations 2. The hazards associated with carbon dioxide.
13.3 Chemical Safety 1. The hazards associated with chemical cleaning and sterilizing agents.
Ref. Topics Candidates should understand and be able to explain and describe in simple
terms, or demonstrate familiarity with:
(No. of questions to
be answered = 4)
14.2 Roles 1. The impact of individual actions on product and service quality.
responsibilities and
benefits 2. The control of documentation.
14.4 Malt Related Food 1. Potential contaminants from outside the malting plant – field
Safety mycotoxins, agrochemicals, heavy metals
Ref. Topics Candidates should understand and be able to explain and describe in simple
terms, or demonstrate familiarity with:
(No. of questions to
be answered = 3)
3. The types of cleaning head used and reasons for their choice.
3. Legionella in cooling water and service water and the health risks
associated with the micro-organism.
Ref. Topics Candidates should understand and be able to explain and describe in simple
terms, or demonstrate familiarity with:
(No. of questions to
be answered = 3)
16.1 Objectives and 1. The key business reasons for an effective maintenance system.
approaches
2. The features, advantages, disadvantages and applications of:
- no maintenance
- breakdown maintenance
- preventive maintenance
- predictive maintenance
3. Autonomous maintenance.
16.3 Systems for 1. The key features of the following performance improvement systems
continuous
improvement - Reliability Centred Maintenance (RCM)
- Total Productive Maintenance (TPM)
- Workplace Organisation (5S)
Ref. Topics Candidates should understand and be able to explain and describe in simple
terms, or demonstrate familiarity with:
(No. of questions to
be answered = 3)
17.2 Water sources, 1. Characteristics and quality of an ideal malt house water supply
treatment and uses
in malting 2. Sources of water for a malt house.
17.3 Sources of effluent 1. The nature and characteristics of effluent from principal malt house
and its operations.
measurement
2. The components of effluent quality:
- volume
- suspended solids (SS)
- chemical oxygen demand (COD)
- biological oxygen demand (BOD)
- pH
- temperature
Ref. Topics Candidates should understand and be able to explain and describe in simple
terms, or demonstrate familiarity with:
(No. of questions to be
answered = 3)