EC Physical Science Grade 12 SEPT 2022 P2 and Memo

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NATIONAL
SENIOR CERTIFICATE
GRADE 12
SEPTEMBER 2022
PHYSICAL SCIENCES P2 (CHEMISTRY)
MARKS: 150
TIME: 3 hours
This question paper consists of 21 pages, including 4 data sheets.

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PHYSICAL SCIENCES P2 com (EC/SEPTEMBER 2022)
INSTRUCTIONS AND INFORMATION
1. Write your full NAME and SURNAME in the appropriate spaces on the
ANSWER BOOK.
2. This question paper consists of NINE questions. Answer ALL the questions
in the ANSWER BOOK.
3. Start EACH question on a NEW page in the ANSWER BOOK.
4. Number the answers correctly according to the numbering system used in

this question paper.
5. Leave ONE line between two sub questions, for example between
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QUESTION 2.1 and QUESTION 2.2.
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6. You may use a non-programmable calculator.
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7. You may use appropriate mathematical instruments.
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8. Show ALL formulae and substitutions in ALL calculations.
9.
ep
Round off your FINAL numerical answers to a minimum of TWO decimal
or
places.
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10. Give brief motivations, discussions, et cetera where required.

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11. You are advised to use the attached DATA SHEETS.

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12. Write neatly and legibly.

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Copyright reserved Please turn over

(EC/SEPTEMBER 2022) com
PHYSICAL SCIENCES P2 3
QUESTION 1: MULTIPLE-CHOICE QUESTIONS
Various options are provided as possible answers to the following questions. Choose
the answer and write only the letter (A–D) next to the question numbers (1.1 to 1.10)
in the ANSWER BOOK, for example 1.11 D.
1.1 The name of the functional group of propanoic acid is ...
A formyl.
B carboxyl.
C carbonyl.
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D hydroxyl. (2)
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1.2 Which ONE of the following is the CORRECT name for the addition reaction
s.
of water to an alkene?
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A hydration
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B hydrolysis ep
or
C dehydration
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D hydrohalogenation (2)
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1.3 Consider the compound shown below:

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H CH3 CH3 H H
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H C C C C C H
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H H H Br H
oa
The CORRECT IUPAC name of the above compound is:

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A 4-bromo-2,3-dimethylpentane
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B 2-bromo-3,4-dimethylpentane
C 2,3-dimethyl-4-bromopentane
D 3,4-dimethyl-2-bromopentane (2)

1.4 Which ONE of the following organic molecules will react rapidly with bromine
water?
A CH3CH2OH
B CH3CH3
C CH2CH2
D CH3CH2CH3 (2)
1.5 Consider the potential energy profile below for the following hypothetical
reaction:
P ⇌ Q
Potential energy (kJ·mol-1)
Q
b
P
c
Reaction progress
Which ONE of the following combinations correctly indicates both the

activation energy and the heat of reaction (ΔH) for the REVERSE
REACTION?
Activation energy (kJ·mol-1) Heat of reaction (ΔH)
A a–b b–c
B b–a a–c
C a–b c–b
D b–c a–b (2)

1.6 H2S (g) decomposes according to the following balanced equation:
H2S (g) ⇌ H2 (g) + S (s)
In each of four separate experiments, A to D, H2S of initial concentration ci is

placed in identical empty flasks which are then sealed and heated. The graphs
below display the results of the experiments A to D.
Which experiment has the largest Kc value?
A B
Concentration
Concentration
ci ci
0 time 0 time
C D Concentration
Concentration
ci ci
0 time 0 time
(2)
1.7 The reaction below represents the general equation for the reaction of an
acid-base indicator.
HIn (aq) + H2O (ℓ) ⇌ H3O+ (aq) + In – (aq)

yellow blue
In which ONE of the following salt solutions will this indicator turn yellow?
A KCℓ(aq)
B NH4Cℓ(aq)
C NaHCO3(aq)
D CH3COONa(aq) (2)

1.8 The function of a salt bridge in a galvanic cell is to …
A allow for the movements of protons.
B allow for the movements of electrons.
C provide a site for reduction to occur.
D ensure electrical neutrality of solutions. (2)
1.9 Which ONE the substances can act as an ampholyte in some reactions?
A CH3COO–
B HSO4 –
C H3O+
D NH4+ (2)
1.10 The electrolytic cell below is used during the electroplating of an iron ring with
copper.
Power
Cu
Iron ring
Which ONE of the following combinations is CORRECT about the ions in the
electrolyte when the cell is operating?
Concentration Positive ions
A Remain constant Cu2+
B Remain constant Fe2+
C Increases Fe3+
D Increases Cu2+ (2)

[20]

QUESTION 2 (Start on a new page.)
The letters A to D in the table below represent four organic compounds that belong
to different homologous series.
A B
CH3
2-methylpropanal H H CH2 H O
H C C C C C O H
H H H CH3
C D
CH3C ≡ CCH2CH3 Pentane
2.1 Define the term homologous series. (2)
2.2 Write down the:
2.2.1 Letter that represents a saturated hydrocarbon (1)
2.2.2 General formula of the homologous series to which compound C

belongs (1)
2.2.3 Structural formula of compound A (2)
2.3 Write down the IUPAC name of compound B. (3)
2.4 Compound D has three structural isomers.
Write down the:
2.4.1 Structural formula of the isomer with the shortest chain (3)
2.4.2 Balanced equation for the combustion reaction of compound D in

EXCESS oxygen using molecular formulae (3)
[15]

3.1 The graphs below show the boiling points of straight chain primary alcohols
and straight chain ketones with different number of carbon atoms.
160
Alcohols
140
Boiling point (oC)
Ketones
120
100
80
60
40
5 7
Number of carbon atoms
3.1.1 Define the term boiling point. (2)
3.1.2 Explain why the boiling points of alcohols increase as the number of
carbon atoms increase by referring to TYPE and STRENGTH of
intermolecular forces only. (2)
3.1.3 Explain why the curve of the alcohols is higher than that of the
ketones.
Refer to the TYPE and STRENGTH of intermolecular forces involved. (3)
The vapour pressure of the alcohol is compared to that of a ketone at the

same temperature.
3.1.4 Why must the alcohol and ketone which are used for the comparison
have the same number of carbon atoms? (1)
3.1.5 Which ONE will have a higher vapour pressure: ALCOHOL or

KETONE?
Give a reason for the answer by referring to the data in the graph. (2)

3.2 The boiling points of propanoic acid and propan-1-ol are compared.
3.2.1 Which compound has the higher boiling point? (1)
3.2.2 Explain the answer to QUESTION 3.2.1 by referring to TYPE,

STRENGTH of intermolecular forces and ENERGY. (3)
[14]

4.1 Compound P can be used to prepare organic compounds R and Q as shown

in the flow diagram below.
Alcohol P HCℓ
Haloalkane Q
II
I Concentrated H2SO4
Compound R: CH3CH2CH2OCCH3
In reaction I, alcohol P reacts with another organic compound in the presence

of concentrated sulphuric acid.
4.1.1 Name the type of reaction represented by I. (1)
4.1.2 Besides the presence of a catalyst write down another reaction condition
for reaction I. (1)
Write down the:
4.1.3 Structural formula of alcohol P (2)
4.1.4 IUPAC name of compound R (2)
4.1.5 IUPAC name of a straight chain FUNCTIONAL isomer of compound R (2)
For reaction II write down the:
4.1.6 Type of reaction taking place (1)
4.1.7 Formula of the inorganic product (1)
4.1.8 Condensed structural formula of compound Q (2)

4.2 A primary alcohol that contains 3 carbon atoms is converted to a secondary

alcohol in a TWO step process as shown in the flow diagram below:
STEP 1 STEP 2
Primary alcohol Compound Q Secondary alcohol
P
P is an inorganic reagent while compound Q is an organic compound.
Write down the:
4.2.1 Formula of reagent P (2)
4.2.2 One reaction condition for the reaction in STEP 2 (1)
4.2.3 A balanced equation for the reaction in STEP 2 by using structural

formulae for the organic compounds. (5)
[20]

The reaction between sodium thiosulphate (Na2S2O3) and EXCESS hydrochloric

acid (HCℓ) is used to investigate the effect of concentration and temperature on the
rate of reaction.
The balanced equation for this reaction is:
Na2S2O3 (aq) + 2 HCℓ → 2 NaCℓ (aq) + S (s) + SO2 (g) + H2O (ℓ)
An Erlenmeyer flask is placed on a white paper marked with a light cross on it. The
time taken for the visibility of the cross (X) to disappear is measured. See the
diagram below.
Na2S2O3 solution
with HCℓ
White paper
NOTE: The same volume of Na2S2O3 solution was used for all three
reactions.
The table below shows the reaction conditions.
Exp Concentration Concentration Temperature Volume of

of Na2S2O3 of HCℓ (°C) HCℓ
(mol·dm-3) (cm3)
1 0,05 2 25 25
2 0,05 1 25 25
3 0,05 2 40 25
5.1 Define the term reaction rate. (2)
5.2 Write down the name of the independent variable for the comparison of
experiment 1 and 2. (1)
5.3 How will the amount of sulphur (S) formed in experiment 1 compare to the
amount of sulphur (S) produced in experiment 2 at the completion of the
reaction?
Choose from HIGHER THAN, LOWER THAN or EQUAL TO.
Give a reason for the answer. (2)

5.4 Experiments 1 and 3 are now compared.
The Maxwell-Boltzmann energy distribution curves for Experiments 1 and 3

are shown below.
T1
Number of particles
T2
Kinetic energy Ea
5.4.1 Which experiment 1 or 3 is represented by curve T2? (1)
5.4.2 Explain the answer to QUESTION 5.4.1 by referring to the collision

theory. (3)
5.4.3 Sketch the curve of T2 ONLY in the answer book and indicate the
effect that a catalyst would have on Ea.
Indicate the new activation energy as X on the graph. (2)
5.5 0,7118 g of Na2S2O3 reacted completely with HCℓ in experiment 1 in 34 s.
Calculate the rate at which HCℓ reacted in experiment 1 in mol·s-1. (5)
The volume of HCℓ used in experiment 1 is now doubled. All other reaction
conditions remain the same.
5.6 How would the reaction rate be affected by the change in volume?
Choose from INCREASES, DECREASES or REMAIN THE SAME. (1)

[17]

6.1 The following reversible reaction can be used to demonstrate how certain
factors influence chemical equilibrium:
CoCℓ42– (aq) + 6 H2O (ℓ) ⇌ Co(H2O)62+ (aq) + 4 Cℓ – (aq)

Blue Pink
6.1.1 Define the term reversible reaction. (2)
Initially, the solution is BLUE.
Write down either TURNS MORE BLUE or TURNS MORE PINK to describe
what happens to the reaction mixture if some:
6.1.2 CoCℓ42- is added (1)
6.1.3 Concentrated HCℓ is added (1)
The test tube containing the reaction mixture is placed in a hot water bath. It is
observed that the solution becomes more blue.
6.1.4 Is the forward reaction EXOTHERMIC or ENDOTHERMIC? (1)
6.1.5 Explain the answer to QUESTION 6.1.4 by referring to Le Chatelier’s

principle. (2)
6.2 3,01 x 10 23 molecules of N2O4 are sealed into a 4 dm3 container and then
heated to 400 K.
The following balanced equation represents the reaction that reaches

equilibrium in the container at 400 K.
N2O4 (g) ⇌ 2 NO2 (g)
At equilibrium, it is found that 0,4 mol of N2O4 have decomposed to NO2
Calculate the equilibrium constant (Kc) at 400 K. (8)

[15]

7.1 The equations below show the reactions occurring in hydrochloric acid (HCℓ)
and ethanoic acid (CH3COOH) solutions. Both acids have a concentration of
1 mol·dm-3, and are kept at a temperature of 25° C.
I: HCℓ (aq) + H2O (ℓ) ⇌ Cℓ – (aq) + H3O+ (aq) Ka = 1,3 × 106
II: CH3COOH (aq) + H2O (ℓ) ⇌ CH3COO– (aq) + H3O+ (aq) Ka = 1,8 × 10-5
7.1.1 Define an acid according to the Lowry-Brønsted theory. (2)
7.1.2 Write down ONE conjugate acid pair-base pair in reaction I. (2)
7.1.3 Which solution, I or II, will have the lower pH value?
Explain the answer. (3)
7.2 10 cm3 of a 1 mol·dm-3 sodium hydroxide (NaOH) solution is diluted with water
until its pH is 13.
7.2.1 Calculate the number of moles of NaOH in the 10 cm 3 of the initial

solution. (3)
7.2.2 Calculate the volume of the diluted solution in dm3. (5)
All of the diluted sodium hydroxide solution is poured into a burette.

During a titration, 15 cm3 of oxalic acid of concentration 0,09 mol·dm-3
is exactly neutralised by a certain volume of the diluted sodium
hydroxide solution.
The balanced equation for the reaction is:
2 NaOH (aq) + H2C2O4 (aq) → Na2C2O4 (aq) + 2 H2O (ℓ)
7.2.3 Calculate the volume of the diluted sodium hydroxide that is left in the
burette after the titration. (5)
[20]

A galvanic cell is set up under standard conditions using half-cells A and B shown
below.
Half-cell A: Cu(s)/Cu2+(aq) Half-cell B: H2O(ℓ) /O2(g)/ H+(aq)
8.1 Define oxidation in terms of electron transfer. (2)
8.2 Write down the:
8.2.1 Initial concentration of the H+(aq) solution in half-cell B (1)
8.2.2 Name of the metal used as the electrode in half-cell B (1)
8.2.3 Formula of the reducing agent (1)
8.2.4 Reduction half reaction (2)
8.2.5 Balanced ionic equation for the overall cell reaction (3)
8.3 The graph below shows the EMF of this cell against time.
x
EMF (V)
0
Time (s) t1
8.3.1 Calculate the value of x on the graph. (4)
8.3.2 Explain the decrease in the EMF of the cell as time proceeds. (2)
8.3.3 What has happened to the reaction in the cell at time t1? (1)
[17]

9.1 The diagram represents the apparatus used in the electrolysis of a

concentrated NaCℓ solution. A and B are two carbon electrodes.
A B
NaCℓ (aq)
9.1.1 Define an electrolytic cell. (2)
9.1.2 Write down the half reaction that occurs at electrode B. (2)
Gas bubbles are observed at the cathode of the cell.
9.1.3 Write down the NAME or FORMULA of the gas formed at the cathode. (1)
9.1.4 Refer to the relative strengths of the oxidising agents to explain why
the gas in QUESTION 9.1.3 and not Na, is formed at the cathode. (2)
9.2 An electrolytic cell is using an impure copper electrode consisting of 95% Cu

and a pure copper electrode. Copper (II) chloride (CuCℓ2) solution is used as
the electrolyte.
9.2.1 Is the pure copper the ANODE or CATHODE? (1)
9.2.2 When all the copper in the impure copper electrode has been
deposited on the copper electrode, it is found that 6 mol of electrons
were transferred.
Calculate the initial mass of the IMPURE copper electrode. (4)

[12]
TOTAL: 150

NATIONAL SENIOR CERTIFICATE

NASIONALE SENIOR SERTIFIKAAT
DATA FOR PHYSICAL SCIENCES GRADE 12

PAPER 2 (CHEMISTRY)
GEGEWENS VIR FISIESE WETENSKAPPE GRAAD 12

VRAESTEL 2 (CHEMIE)
TABLE 1: PHYSICAL CONSTANTS/TABEL 1: FISIESE KONSTANTES
NAAM/NAME SIMBOOL/SYMBOL WAARDE/VALUE

Standard pressure
p 1,013 × 105 Pa
Standaarddruk
Molar gas volume at STP
Vm 22,4 dm3∙mol-1
Molêre gasvolume teen STD
Standard temperature
Tθ 273 K
Standaardtemperatuur
Charge on electron
e -1,6 × 10-19 C
Lading op elektron
Avogadro’s constant
NA 6,02 × 1023 mol-1
Avogadro se konstante
TABLE 2: FORMULAE/TABEL 2: FORMULES
m n m
n= or/of c= or/of c = pH= -log[H3O+]
M V MV
Kw = [H3O+][OH-] = 1x10-14
N ca Va na at /by 298K
n= or/of =
NA
cb Vb nb
V
n=
Vm
Eθcell = Eθcathode–Eθanode / Eθsel = Eθkatode–Eθanode
Eθcell = Eθreduction–Eθoxidation / Eθsel = Eθreduksie–Eθoksidasie
Eθcell = Eθoxidising agent – Eθreducing agent / Eθsel = Eθoksideermiddel–Eθreduseermiddel

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(EC/SEPTEMBER 2022) PHYSICAL SCIENCES P2 19
TABLE 3: THE PERIODIC TABLE OF ELEMENTS/TABEL 3: DIE PERIODIEKE TABEL VAN ELEMENTE
1 2 3 4 5 67 8 9 10 11 12 13 14 15 16 17 18
(I) (II) Atoomgetal (III) (IV) (V) (VI) (VII) (VIII)
KEY/ SLEUTEL Atomic number
1 2
H He
2,1
1 29 4
Elektronegatiwiteit Simbool
3 4 Cu 5 6 7 8 9 10
1,9
Electronegativity Symbol
Li Be B C N O F Ne
1,0
1,5
2,0
2,5
3,0
3,5
4,0
63,5
7 9 11 12 14 16 19 20
11 12 13 14 15 16 17 18
Na Mg Benaderde relatiewe atoommassa Aℓ Si P S Cℓ Ar
0,9
1,2
1,5
1,8
2,1
2,5
3,0
Approximate relative atomic mass
23 24 27 28 31 32 35,5 40
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
0,8
1,0
1,3
1,5
1,6
1,6
1,5
1,8
1,8
1,8
1,9
1,6
1,6
1,8
2,0
2,4
2,8
39 40 45 48 51 52 55 56 59 59 63,5 65 70 73 75 79 80 84
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
0,8
1,0
1,2
1,4
1,8
1,9
2,2
2,2
2,2
1,9
1,7
1,7
1,8
1,9
2,1
2,5
86 88 89 91 92 96 101 103 106 108 112 115 119 122 128 127 131
55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tℓ Pb Bi Po At Rn
0,7
0,9
1,6
1,8
1,8
1,9
2,0
2,5
133 137 139 179 181 184 186 190 192 195 197 201 204 207 209
87 88 89
Fr Ra Ac
0,7
0,9
226 58 59 60 61 62 63 64 65 66 67 68 69 70 71
Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
140 141 144 150 152 157 159 163 165 167 169 173 175
90 91 92 93 94 95 96 97 98 99 100 101 102 103
Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
232 238

PHYSICAL SCIENCEScom
P2 (EC/SEPTEMBER 2022)
TABLE 4A: STANDARD REDUCTION POTENTIALS

TABEL 4A: STANDAARD REDUKSIEPOTENSIALE
Half-reactions/Halfreaksies E θ (V)
F2(g) + 2e− ⇌ 2F− + 2,87
Co 3+
+e − ⇌ Co 2+
+ 1,81
H2O2 + 2H+ +2e− ⇌ 2H2O +1,77
−
MnO 4 + 8H+ + 5e− ⇌ Mn 2+
+ 4H2O + 1,51
Cℓ2(g) + 2e − ⇌ 2Cℓ −
+ 1,36
2−
Cr2O 7 + 14H+ + 6e− ⇌ 2Cr3+ + 7H2O + 1,33
O2(g) + 4H+ + 4e− ⇌ 2H2O + 1,23
MnO2 + 4H+ + 2e− ⇌ Mn2+ + 2H2O + 1,23
Pt2+ + 2e− ⇌ Pt + 1,20
Br2(ℓ) + 2e− ⇌ 2Br− + 1,07
−
NO 3 + 4H+ + 3e− ⇌
Increasing reducing ability/Toenemende reduserende vermoë

NO(g) + 2H2O + 0,96
Increasing oxidising ability/Toenemende oksiderende vermoë
Hg 2+
+ 2e − ⇌ Hg(ℓ) + 0,85
Ag+ + e− ⇌ Ag + 0,80
−
NO 3 + 2H+ + e− ⇌ NO2(g) + H2O + 0,80
Fe3+ + e− ⇌ Fe2+ + 0,77

O2(g) + 2H + 2e + − ⇌ H2O2 + 0,68
I2 + 2e− ⇌ 2I− + 0,54
Cu+ + e− ⇌ Cu + 0,52
SO2 + 4H + 4e + − ⇌ S + 2H2O + 0,45
2H2O + O2 + 4e− ⇌ 4OH− + 0,40
Cu2+ + 2e− ⇌ Cu + 0,34
2−
SO 4 + 4H+ + 2e− ⇌ SO2(g) + 2H2O + 0,17
Cu2+ + e− ⇌ Cu+ + 0,16

Sn 4+
+ 2e − ⇌ Sn 2+
+ 0,15
S + 2H+ + 2e− ⇌ H2S(g) + 0,14
2H+ + 2e− ⇌ H2(g) 0,00
Fe 3+
+ 3e − ⇌ Fe − 0,06
Pb2+ + 2e− ⇌ Pb − 0,13
Sn2+ + 2e− ⇌ Sn − 0,14
Ni2+ + 2e− ⇌ Ni − 0,27
Co 2+
+ 2e − ⇌ Co − 0,28
Cd2+ + 2e− ⇌ Cd − 0,40
Cr3+ + e− ⇌ Cr2+ − 0,41
Fe2+ + 2e− ⇌ Fe − 0,44
Cr 3+
+ 3e − ⇌ Cr − 0,74
Zn2+ + 2e− ⇌ Zn − 0,76
2H2O + 2e− ⇌ H2(g) + 2OH− − 0,83
Cr2+ + 2e− ⇌ Cr − 0,91
Mn 2+
+ 2e − ⇌ Mn − 1,18
Aℓ3+ + 3e− ⇌ Aℓ − 1,66
Mg2+ + 2e− ⇌ Mg − 2,36
+
Na + e − ⇌ Na − 2,71
Ca2+ + 2e− ⇌ Ca − 2,87
Sr2+ + 2e− ⇌ Sr − 2,89
Ba2+ + 2e− ⇌ Ba − 2,90
+
Cs + e - ⇌ Cs - 2,92
K+ + e− ⇌ K − 2,93
Li+ + e− ⇌ Li − 3,05

TABLE 4B: STANDARD REDUCTION POTENTIALS

TABEL 4B: STANDAARD REDUKSIEPOTENSIALE
Half-reactions/Halfreaksies E θ (V)
Li+ + e− ⇌ Li − 3,05
+
K +e − ⇌ K − 2,93
Cs+ + e− ⇌ Cs − 2,92
Ba2+ + 2e− ⇌ Ba − 2,90
Sr2+ + 2e− ⇌ Sr − 2,89
Ca2+ + 2e− ⇌ Ca − 2,87
Na+ + e− ⇌ Na − 2,71
Mg2+ + 2e− ⇌ Mg − 2,36
Aℓ + 3e
3+ − ⇌ Aℓ − 1,66
Mn2+ + 2e− ⇌ Mn − 1,18
⇌
Increasing reducing ability/Toenemende reduserende vermoë

Cr2+ + 2e− Cr − 0,91
2H2O + 2e− ⇌ H2(g) + 2OH− − 0,83
Increasing oxidising ability/Toenemende oksiderende vermoë
Zn2+ + 2e− ⇌ Zn − 0,76

Cr3+ + 3e− ⇌ Cr − 0,74
Fe2+ + 2e− ⇌ Fe − 0,44
3+
Cr + e − ⇌ Cr 2+
− 0,41
Cd2+ + 2e− ⇌ Cd − 0,40
Co2+ + 2e− ⇌ Co − 0,28
Ni2+ + 2e− ⇌ Ni − 0,27
Sn2+ + 2e− ⇌ Sn − 0,14
2+
Pb + 2e − ⇌ Pb − 0,13
Fe3+ + 3e− ⇌ Fe − 0,06
2H+ + 2e− ⇌ H2(g) 0,00
S + 2H+ + 2e− ⇌ H2S(g) + 0,14
Sn4+ + 2e− ⇌ Sn2+ + 0,15
2+
Cu + e −
⇌ Cu +
+ 0,16
2−
SO 4 + 4H+ + 2e− ⇌ SO2(g) + 2H2O + 0,17
Cu2+ + 2e− ⇌ Cu + 0,34

2H2O + O2 + 4e− ⇌ 4OH− + 0,40
SO2 + 4H+ + 4e− ⇌ S + 2H2O + 0,45
+
Cu + e − ⇌ Cu + 0,52
I2 + 2e − ⇌ 2I −
+ 0,54
O2(g) + 2H+ + 2e− ⇌ H2O2 + 0,68
Fe3+ + e− ⇌ Fe2+ + 0,77
−
NO 3 + 2H+ + e− ⇌ NO2(g) + H2O + 0,80
Ag+ + e− ⇌ Ag + 0,80
2+
Hg + 2e − ⇌ Hg(ℓ) + 0,85
−
NO 3 + 4H+ + 3e− ⇌ NO(g) + 2H2O + 0,96
Br2(ℓ) + 2e − ⇌ 2Br −
+ 1,07
Pt2+ + 2 e− ⇌ Pt + 1,20
MnO2 + 4H+ + 2e− ⇌ Mn2+ + 2H2O + 1,23
O2(g) + 4H+ + 4e− ⇌ 2H2O + 1,23
2−
Cr2O 7 + 14H+ + 6e− ⇌ 2Cr3+ + 7H2O + 1,33
Cℓ2(g) + 2e− ⇌ 2Cℓ −

+ 1,36
−
MnO 4 + 8H+ + 5e− ⇌ Mn + 4H2O2+
+ 1,51
H2O2 + 2H +2 e + −
⇌ 2H2O +1,77
Co3+ + e− ⇌ Co2+ + 1,81
F2(g) + 2e − ⇌ 2F −
+ 2,87
Copyright reserved
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MRS F. NTSANGANI
SUBJECT: ERRATA – PHYSICAL SCIENCES P2

GRADE 12 PREPARATORY EXAMS
DATE: 22 SEPTEMBER 2022
Physical Sciences P2 was written on 19 September 2022. We were made aware of

certain errors, amendments and omissions that were discovered during the marking
process.
In order to address this and to ensure that the learners are not disadvantaged, the
following standardised approach to marking must be adopted across the Province.
The following guidelines with regard to marking was prepared in conjunction with the
examiner and moderator.
ERRATA: PHYSICAL SCIENCES P2 (MARKING GUIDELINE)
QUESTION CORRECTION
2.3 Correct answer:
3-ethyl-2-methyl pentanoic acid√√√
3.2.1 and No NEGATIVE Marking
3.2.2
3.2.2 Correction
• Both have hydrogen bonds√
• Intermolecular forces are stronger in propanoic acid are

stronger√( than in propan-1-ol)
• More energy is needed to overcome intermolecular forces
in propanoic acid√ (than in propan-1-ol)
(Note: Do not penalize for “breaking bonds” in place of overcoming
intermolecular forces since these are hydrogen bonds )
OR
• Both have hydrogen bonds
• Intermolecular forces in propan-1-ol are weaker than in
propanoic acid
• Less energy is needed to overcome intermolecular forces in
propan-1-ol (than in propanoic acid)
4.1.5 Afrikaans version should read: Pentanoesuur

4.2.1 Add a second tick on Memo
4.2.3 Remove the extra bond and hydrogen in the organic reactant
5.4.2 Third bullet
Accept Frequency of effective collision increases
OR Frequency of effective collisions decreases ( in Option 2)
5.4.3 Both X and Ea must be on graph for marks to be awarded
6.1.4 and No NEGATIVE Marking
6.1.5
We request that this must be brought to the attention of all educators marking this
paper and sincerely apologise for the inconvenience.
Yours in quality education.
22 SEPTEMBER 2022
Mrs F. Ntsangani DATE
NATIONAL
SENIOR CERTIFICATE/
NASIONALE SENIOR
SERTIFIKAAT
GRADE/GRAAD 12
SEPTEMBER 2022
PHYSICAL SCIENCES P2
MARKING GUIDELINE/
FISIESE WETENSKAPPE V2
NASIENRIGLYN
MARKS/ PUNTE: 150
This marking guideline consists of 19 pages./

Hierdie nasienriglyn bestaan uit 19 bladsye.
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P2/FISIESE WETENSKAPPE V2 (EC/SEPTEMBER 2022)
QUESTION/VRAAG 1
1.1 B ✓✓ (2)
1.2 A ✓✓ (2)
1.3 B ✓✓ (2)
1.4 C ✓✓ (2)
1.5 C ✓✓ (2)
1.6 A ✓✓ (2)
1.7 B ✓✓ (2)
1.8 D ✓✓ (2)
1.9 B ✓✓ (2)
1.10 A ✓✓ (2)
[20]
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SCIENCES P2/FISIESE WETENSKAPPE V2 3
QUESTION/VRAAG 2
2.1 It is a series of organic compounds that can be described by the same

general formula. ✓✓ (2 or 0)
ŉ Reeks organiese verbindings wat deur dieselfde algemene formule

beskryf kan word. (2 of 0)
OR/OF
A series/group of organic compounds in which one member differs from the

next with -CH2- group. ✓✓ (2 or 0)
ŉ Reeks organiese verbindings waarin die een lid van die volgende verskil
met ŉ CH2-groep. (2)
2.2.1 D ✓ (1)
2.2.2 CnH2n-2 ✓ (1)
2.2.3 O Marking criteria/ Nasienkriteria

H H
✓ • Only functional group correct /
H C C C H ✓ Slegs funksionele groep korrek:
H Max/ Maks ½
H C H
• Whole structure correct/
H Hele struktuur korrek: 2/2
(2)
2.3 3-ethyl-2-methylhexanoic acid / 3-etiel-2-metielheksanoësuur
Marking criteria
• Correct stem i.e hexanoic acid ✓
• All substituents (ethyl and methyl) correctly identified ✓
• IUPAC name completely correct including numbering, sequence and
hyphens ✓
Nasienkriteria
• Korrekte stam d.i heksanoësuur
• Alle substituente (etiel en metiel) korrek geїdentifiseer
• IUPAC-naam heeltemal korrek insluitende nommering, volgorde en
koppeltekens
(3)
2.4.1 Marking criteria/Nasienkriteria

H • Longest chain contains 3 carbons /
H C H Langste koolstofketting bevat 3
koolstowwe ✓
H H
• Two methyl substituents on C2 /
H C C C H Twee metielsubstituente op C2 ✓
H • Whole structure is correct / Hele
H
struktuur korrek ✓
H C H
H (3)

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2.4.2 C5H12 + 8 O2 ✓→ 6 H2O + 5 CO2 ✓ (bal ✓) Marking criteria/ Nasienkriteria

• Reactants / Reaktanse
• Products / Produkte
• Balancing / Balansering (3)
[15]
QUESTION/VRAAG 3

If any of the underlined key words/phrases in the correct context are
omitted: - 1 mark per word/phrase.
Indien enige van die sleutelwoorde/frases in die korrekte konteks weggelaat
word: - 1 punt per woord/frase.
The temperature at which the vapour pressure of a liquid equals the

atmospheric pressure. ✓✓
Die temperatuur waarby die dampdruk van die vloeistof gelyk is aan die
atmosferiese druk. (2)
3.1.2 As the number of C atoms increases:
• The surface area/chain length/molecular mass of the alcohols

increases ✓
• The strength of London forces/induced dipole forces/dispersion forces
increase. ✓
Soos die aantal C-atome toeneem:
• Die oppervlak-area/kettinglengte/molekulêre massa van die alkohole

verhoog.
• Die sterkte van die Londonkragte/geїnduseerde dipoolkragte/
verspreidingskragte verhoog
OR/OF
As the number of C atoms decreases:
• The surface area/chain length/molecular mass of the alcohols

decreases ✓
• The strength of London forces/induced dipole forces/dispersion forces
decrease. ✓
Soos die aantal C-atome afneem:
• Die oppervlak-area/kettinglengte/molekulêre massa van die alkohole

verlaag.
• Die sterkte van die Londonkragte/geїnduseerde dipoolkragte/
verspreidingskragte verswak (2)

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3.1.3 Marking criteria

• Identify the intermolecular forces in both compounds. ✓✓
• Compare the strength of the intermolecular forces. ✓
Nasienkriteria
• Die intermolekulêre kragte korrek geїdentifiseer in beide verbindings
• Vergelyk die sterkte van die intermolekulêre kragte
• Alcohols have both (London forces) and hydrogen bonds ✓

• Ketones have both (London forces) and dipole-dipole forces ✓
• Hydrogen bonds in the alcohols are stronger than the dipole-dipole
forces in ketones ✓
• Alkohole het beide (Londonkragte) en waterstofbindings

• Ketone het beide (Londonkragte) en dipool-dipool kragte
• Waterstofbindings in die alkohole is sterker as die dipool-dipoolkragte
in ketone
OR/OF
• Alcohols have both (London forces) and hydrogen bonds ✓

• Ketones have both (London forces) and dipole-dipole forces ✓
• the dipole-dipole forces in Ketones are weaker than the hydrogen
bonds in the alcohols ✓
• Alkohole het beide (Londonkragte) en waterstofbindings

• Ketone het beide (Londonkragte) en dipool-dippol kragte
• Die dipool-dipoolkragte in ketone is swakker as die waterstofbindings
in die alkohole (3)
3.1.4 To have one independent variable✓ OR To have a fair test

Om slegs een onafhanklike veranderlike te het OF Om ŉ regverdige toets
te hê (1)
3.1.5 Ketone ✓
Lower boiling point / Laer kookpunt ✓ (2)
3.2.1 Propanoic acid / Propanoësuur ✓ (1)

SCIENCES com
3.2.2 Marking criteria

• Identify the intermolecular forces correctly in both compounds. ✓
• Compare the strength of the intermolecular forces. ✓
• Compare the energy required to overcome the intermolecular forces. ✓
Nasienkriteria
• Die intermolekulêre kragte is korrek in beide verbindings geїdentifiseer
• Vergelyk die sterkte van die intermolekulêre kragte.
• Vergelyk die energie wat benodig word om die intermolekulêre kragte te
oorkom.
• Both have hydrogen bonds

• Propan-1-ol has ONE site for hydrogen bonds
• Propanoic acid has TWO sites for hydrogen bonds ✓
• The intermolecular forces of propanoic acid are stronger than that of
propan-1-ol ✓
• More energy is needed to overcome the intermolecular forces of
propanoic acid. ✓
• Beide het waterstofbindings

• Propan-1-ol het EEN plek vir waterstofbindings
• Propanoësuur het TWEE plekke vir waterstofbindings
• Die intermolekulêrekragte in propanoësuur is sterker as dié in
propan-1-ol
• Meer energie word benodig om die intermolekulêre kragte te oorkom in
propanoësuur
OR/OF
• Both have hydrogen bonds.

• Propan-1-ol has ONE site for hydrogen bonds
✓
• Propanoic acid has two sites for hydrogen bonds
• The intermolecular forces of propan-1-ol are weaker than that of
propanoic acid ✓
• Less energy is needed to overcome the intermolecular forces of
propan-1-ol. ✓
• Beide het waterstofbindings

• Propan-1-ol het EEN plek vir waterstofbindings
• Propanoësuur het TWEE plekke vir waterstofbindings
• Die intermolekulêrekragte in propan-1-ol is swakker as dié in
propanoësuur.
• Minder energie word benodig om die intermolekulêre kragte te oorkom
in propan-1-ol. (3)
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QUESTION/VRAAG 4
4.1.1 Esterification / condensation / Esterifikasie / konsensasie✓ (1)
4.1.2 (Mild) heat / (Matige) hitte ✓ (1)
4.1.3 H H H Marking criteria/ Nasienkriteria

• Only functional group correct
H C C C O H✓ ✓ Slegs funksionele groep
korrek: Max/Maks ½
H H H
• Whole structure correct/
Hele struktuur korrek: 2/2
(2)
4.1.4 Propyl ✓ethanoate ✓ / Propiel etanoaat (2)
4.1.5 Pentanoic acid / Propanoësuur ✓✓ (2)
4.1.6 Substitution reaction / Substitusie-reaksie ✓ (1)
4.1.7 H2O ✓ (1)
4.1.8 CH3CH2CH2Cℓ ✓✓ Marking criteria/ Nasienkriteria

• Only functional group correct / Slegs
funksionele groep korrek: Max/Maks ½
• Whole structure correct / Hele struktuur

korrek: 2/2 (2)
4.2.1 (Concentrated / Gekonsentreerde) H2SO4 ✓ (2)
4.2.2 H2O in excess ✓ / catalyst/ (Add small amount of HCℓ/H3PO4) (1)
4.2.3 H H H H H H
H C C C H✓ + H2O ✓ → H C C C H✓
✓
✓
H H H O✓ H
Marking criteria/ Nasienkriteria

(Organic molecules / Organiese molekules)
• Only functional group correct / Slegs funksionele groep korrek: Max/Maks ½
• Whole structure correct/ Hele struktuur korrek: 2/2

(5)
[20]

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QUESTION/VRAAG 5
5.1 Marking criteria/ Nasienkriteria

Indien enige van die sleutelwoorde/frases in die korrekte konteks
weggelaat word: - 1 punt per woord/frase
ANY ONE
• Change in concentration ✓of reactant / product per (unit) time.✓
• Change in amount/number of moles/volume/mass of products or

reactants per (unit) time.
• Amount/number of moles/volume/mass of products formed/reactants

used reactants per (unit) time.
ENIGE EEN
• Verandering in konsentrasie van reaktanse/produkte per (eenheid)
tyd
• Verandering in hoeveelheid/getal mol/volume/massa van reaktanse of

produkte per (eenheid) tyd.
• Hoeveelheid/getal mol/volume/massa van produkte gevorm/

reaktanse gebruik per (eenheid) tyd
OR/OF
The rate of change in concentration / amount of moles / number of moles /

volume / mass. (2 or 0).
Die tempo van verandering in konsentrasie / hoeveelheid mol / getal

mol/volume/massa (2 of 0) (2)
5.2 Concentration / Konsentrasie (of/van HCℓ) ✓ (1)
5.3 Equal to / Gelyk aan ✓
The same amount of (the limiting reagent), Na2S2O3, is used. ✓

Dieselfde hoeveelheid (van beperkde reagens) Na2S2O3 was gebruik. (2)
5.4.1 Experiment 3 / Eksperiment 3 ✓ (1)

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5.4.2 For T2
• Higher temperature increases kinetic energy of particles ✓
• Greater number of particles have sufficient energy. ✓
• More effective collision per unit time ✓
Vir T2
• Hoër temperatuur verhoog die kinetiese energie van die deeltjies
• Groter aantal deeltjies het genoeg energie
• Meer effektiewe botsings per eenheidstyd
OR/OF
For T1
• Lower temperature decreases kinetic energy of particles
• Fewer particles have sufficient energy.
• Less effective collision per unit time
Vir T1
• Laer temperatuur verlaag die kinetiese energie van die deeltjies

• Minder aantal deeltjies het genoeg energie
• Minder effektiewe botsings per eenheidstyd (3)
Number of particles/

• X < Ea
Aantal deeltjies
✓✓
X Ea
Kinetic energy / Kinetiese energie (2)

SCIENCES com
5.5 Marking criteria
• Formula n = m/M
• Substitution into n = m/M
• Using ratio HCℓ: Na2S2O3 2 : 1
• Substitution into rate equation
• Final answer
Nasienkriteria
• Formule n = m/M
• Vervanging in n = m/M
• Gebruik van verhouding HCℓ: Na2S2O3 2 : 1
• Vervanging in tempo vergelyking
• Finale antwoord
m
n= ✓
M
0,7118
n= ✓
158
n (Na2S2O3) = 4,505 x 10-3 mol
n (HCℓ) = 2 (4,505 x 10-3) ✓
n (HCℓ) = 9,01 x 10-3 mol
Δn Accept / Aanvaar
rate/ tempo = -
Δt
Δn
0 - 9,01 x 10-3 rate/ tempo =
rate/ tempo = - ✓ Δt
34
- 9,01 x 10-3
rate/ tempo = 2,65 x 10-4 (mol·s-1) ✓ rate/tempo = 34
✓
rate / tempo = - 2,65 x 10-4

(mol·s-1) ✓ (5)
5.6 REMAINS THE SAME / BLY DIESELFDE ✓ (1)

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QUESTION/VRAAG 6
6.1.1 (A reaction in which) products can be converted back to its reactants ✓✓

(and vice versa)
(Is ŉ reaksie waar) produkte terug na reaktanse, en omgekeerd,

omgeskakel kan word. (2 or/ of 0) (2)
6.1.2 Turns more pink / Raak meer pienk ✓ (1)
6.1.3 Turns more blue / Raak meer blou ✓ (1)
6.1.4 Exothermic / Eksotermies ✓ (1)
6.1.5 • Increase in temperature shifted the equilibrium position left ✓/Reverse

reaction is favoured
• Increase in temperature favours the endothermic reaction ✓
• Toename in temperatuur verskuif die ewewigsposisie na links/

Terugwaartse reaksie word bevoordeel.
• Toename in temperatuur bevoordeel ŉ endotermiese reaksie. (2)

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6.2 OPTION 1: MOLE CALCULATIONS

OPSIE 1: MOL BEREKENINGE
Marking criteria:
N
a. Substitution into formula n = ✓
NA
b. Using ratio N2O4 : NO2 = 1 : 2 ✓
c. n(NO2) equilibrium = n initial + Δn ✓
d. n(N2O4) equilibrium = n initial - Δn ✓
e. Divide equilibrium amounts of N2O4 and NO2 by 4 dm3 ✓
f. Correct KC expression (formulae in square brackets) ✓
g. Substitution into equilibrium concentration into KC expression ✓
h. Final answer ✓
Nasienkriteria:
N
a. Vervanging in formule n =
NA
b. Gebruik verhouding N2O4 : NO2 = 1 : 2 ✓
c. n(NO2) ewewig = n initial + Δn ✓
d. Deel ewewighoeveelhede van N2O4 en NO2 deur 4 dm3
e. Korrekte Kc-uitdrukking (formules met vierkanthakies)
f. Vervanging in ewewigskonsentrasies in Kc-uitdrukking
g. Finale antwoord
N
n=
NA
3,01 × 1023
n= ✓ (a)
6,02×1023
n = 0,5 mol
N2O4 (g) 2 NO2 (g)

Initial quantity (mol)
0,5 -
Aanvangshoeveelheid (mol)
Change (mol) ✓ (b)
0,4 0,8
Verandering (mol) ratio
Equilibrium (mol)
0,1 ✓ (d) 0,8 ✓ (c)
Ewewig (mol)
Concentration (mol·dm-3) ✓ (e)
0,025 0,2
Konsentrasie (mol·dm-3)

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[NO2]2 No Kc expression, correct substitution / Geen Kc-

Kc = ✓ (f) uitdrukking, korrekte, korrekte substitusie.
[N2O4]
Max / Maks 7/8
(0,2)2 Wrong Kc expression/Verkeerde Kc – uitdrukking.
Kc = ✓ (g)
(0,025) Max. Maks. 5/8
Kc = 1,6 ✓ (h)
OPTION 2: CONCENTRATION CALCULATIONS/

OPSIE 2: KONSENTRASIEBEREKENINGE
Marking criteria
N
a. Substitution into formula n = ✓
NA
b. Using ratio N2O4: NO2 = 1 : 2 ✓
c. c(NO2) equilibrium = c initial + Δc ✓
d. c(N2O4) equilibrium = c initial – Δc ✓
e. Divide n initial and Δn of N2O4 by 4 dm3 ✓
f. Correct KC expression (formulae in square brackets) ✓
g. Substitution into equilibrium concentration into KC expression ✓
h. Final answer ✓
Nasienkriteria:
N
a. Vervanging in formule n =
NA
b. Gebruik verhouding N2O4 : NO2 1 : 2
c. Ewewig c(NO2) = begin c + Δc
d. Ewewig c (N2O4) = begin c – Δc ✓(b)
e. Deel aanvangs en verandering hoeveelhede van N2O4 en NO2 deur 4
dm3
f. Korrekte Kc-uitdrukking (formules met vierkanthakies) ✓ (e)
g. Vervanging in ewewigskonsentrasies in Kc-uitdrukking
h. Finale antwoord

SCIENCES com
N
n= NA
3,01 × 1023
n= ✓ (a)
6,02 × 1023
n = 0,5 mol
N2O4 (g) 2 NO2 (g)

Initial concentration (mol·dm-3) 0,125 -
Aanvangs konsentrasie (mol·dm-3) ✓ (d)
Change in concentration (mol·dm-3)
0,1 0,2
Verandering in konsentrasie(mol·dm-3)
Equilibrium concentration (mol·dm-3)
0,025✓ (c) 0,2
Ewewig konsentrasie (mol·dm-3)
[NO2]2 No Kc expression, correct substitution / Geen Kc-

Kc = ✓ (f) uitdrukking, korrekte substitusie.
[N2O4]
Max / Maks 7/8
(0,2)2 Wrong Kc expression / Verkeerde Kc -uitdrukking.
Kc = ✓ (g)
(0,025) Max. Maks. 5/8
Kc = 1,6 ✓ (h) (8)

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QUESTION/VRAAG 7
7.1.1 An acid is a proton (H+ ion) donor / ŉ Suur is ‘n proton (H+-ioon) skenker ✓✓ (2)
7.1.2 HCℓ and/en Cℓ- ✓✓ OR/OF H3O+ and/en H2O ✓✓ (2)
7.1.3 Solution I. ✓
• HCℓ is a stronger acid than CH3COOH / HCℓ has a higher Ka ✓ (than
CH3COOH)
• HCℓ will produce a higher concentration of H3O+ ✓ (than CH3COOH)
OR
• CH3COOH is a weaker acid than HCℓ / CH3COOH has a lower Ka (than
HCℓ)
• CH3COOH will produce a lower concentration of H3O+ (than HCℓ)
Oplossing I.
• HCℓ is ŉ sterker suur as CH3COOH / HCℓ het ŉ hoër Ka-waarde as
CH3COOH
• HCℓ sal ŉ hoër konsentrasie van H3O+ produseer as CH3COOH
OF
• CH3COOH is ŉ swakker suur as HCℓ / CH3COOH het ŉ laer Ka-waarde
as HCℓ
• CH3COOH sal ŉ laer konsentrasie H3O+ produseer as HCℓ (3)
7.2.1 n = cV ✓
= 1 x10 / 1 000 ✓
= 0,01 mol ✓ (3)

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7.2.2 Marking criteria Marking criteria
• Formula pH = - log [H3O+] ✓ • Formula pOH + pH = 14 ✓

• pH value substituted into • pH value substituted into
formula ✓ formula ✓
• Substitution in Kw formula✓ • Substitution in pOH formula✓
• Substitution into n = cV✓ • Substitution into n = cV✓
• Final answer✓ • Final answer✓
Nasienkriteria
Nasienkriteria • Formule pOH + pH = 14
• Formule pH = - log [H3O+] • pH-waarde vervang in formule
• pH-waarde vervang in formule • Vervanging in pOH formule
• Vervanging in Kw formule • Vervanging in n = cV
• Vervanging in n = cV • Finale antwoord
• Finale antwoord
OPTION 1 / OPSIE 1 OPTION 2 / OPSIE 2
pH = - log [H3O+] ✓ pOH + pH = 14 ✓
13 ✓ = - log [H3O+] pOH + 13 ✓ = 14
[H3O+] = 1 × 10-13 mol·dm-3 pOH = 1
Kw = [OH-][H3O+] = 1 × 10-14 pOH = - log [OH-]
[OH-][H3O+] = 1 × 10-14 1 = - log [OH-] ✓
[OH-](1 × 10-13) = 1 × 10-14 ✓ [OH-] = 0,1 mol·dm-3
[OH-] = 0,1 mol·dm-3 [NaOH] = 0,1 mol·dm-3
[NaOH] = 0,1 mol·dm-3
n OR/OF
c
= V c1V1 = c2V2
From 7.2.1
0,01 Vanaf 7.2.1 (1)(10) = (0,1)V2 ✓
0,1 = ✓
V
V2 = 100 cm3
V = 0,1 (dm3)✓ V = 0,1 (dm3) ✓ (5)

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7.2.3 Marking criteria Marking criteria /

c V n
• Formula n = cV✓ • Formula ca Va = na ✓
b b b
• Substitution of acid values into n = cV c V
AND • Substitution LHS a a ✓
✓ cb Vb
n
Using ratio Acid : Base = 1 : 2 • Substitution RHS na ✓
• Substitution of V and c into b
n = cV for V base reacting ✓ • Subtracting

Vremaining = Vinitial ‒ Vreacting ✓
• Subtracting
Vremaining = Vinitial ‒ Vreacting ✓ • Final answer ✓
• Final answer ✓
Nasienkriteria
Nasienkriteria ca Va n
• Formule n = cV • Formule cb Vb
= na
b
• Vervanging van suur waardes in ca Va
• Vervang LK c V
b b
formule n = cV n
EN • Vervang RK na
b
Gebruik verhouding Suur : Basis = 1 : 2 • Aftrekking
• Vervanging van V en c in n Voorbly = Vaanvangs – Vreageer
= cV vir V basis wat reageer • Finale antwoord
• Aftrekking
Voorbly = Vaanvangs - Vreageer
• Finale antwoord
OPTION 1/OPSIE 1 OPTION 2/OPSIE 2

n acid reacting = cV✓ ca V a na
= ✓
= 0,09 x 15/1 000 cb V b n b
= 1,35 x 10-3 mol ✓
-3
n base reacting= 2 x 1,35 x 10 mol (0,09)(15) 1
= 2,7 x 10 -3 mol ✓= ✓
(0,1)Vb 2
n = cV
Vb = 27 cm3
2,7 x 10 -3 = 0,1 Vbase reacting /basis reageer✓
Vb = 0,027 dm3
0,027 dm3 = Vbase reacting/ basis reageer
Vremaining/oorbly = 0,1 – 0,027 ✓

= 0,073 dm3 ✓ (5)
[20]

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QUESTION/VRAAG 8
8.1 Loss of electrons / Verlies aan elektrone ✓✓ (2 or/of 0) (2)
8.2.1 1 mol·dm-3 ✓ (1)
8.2.2 Platinum ✓ (1)
8.2.3 Cu ✓ (1)
8.2.4 O2 + 4H+ + 4e- → 2 H2O ✓✓

Marking criteria / Nasienkriteria
• O2 + 4H+ + 4e- ⇌ 2 H2O ½
• 2 H2O ← O2 + 4H + 4e
+ - 2/2
• 2 H2O ⇌ O2 + 4H + 4e
+ - 0/2
• 2 H2O → O2 + 4H+ + 4e- 0/2
• Ignore if the charge omitted on electron / Ignoreer indien lading op

elektron weggelaat is. (2)
8.2.5 2 Cu + O2 + 4 H+ ✓→ 2 Cu2+ + 2 H2O ✓ (✓ bal)

Marking criteria/Nasienkriteria
• Reactants/ Reaktanse
• Products / Produkte
• Balancing / Balansering
(3)
8.3.1 Eθcell = Eθcathode/reduction/oxidising agent – Eθanode/oxidation/reducing agent ✓

Notes/Aantekeninge
Eθcell = (1,23) ✓ – (0,34) ✓
• Any other formula using unconventional
abbreviation , e.g.
Eθcell = 0,89 V ✓
Eocell = EoOA – Eo RA followed by the correct
substitution : ¾
• Enige ander formule wat onkonvensionele
afkortings gebruik bv.
• Eosel = EoOM – Eo RM gevolg met korrekte
vervangings: ¾
(4)
8.3.2 Concentration of the reactants decreases ✓

Rate of the forward reaction decreases ✓
Konsentrasie van reaktanse verlaag

Tempo van voortwaartse reaksie verlaag (2)
8.3.3 Equilibrium / Ewewig ✓ (1)

[17]

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QUESTION/VRAAG 9
9.1.1 Marking criteria/ Nasienriglyne

Indien enige van die sleutelwoorde/frases in die korrekte konteks weggelaat
word: - 1 punt per woord/frase
(It is a cell in which) electrical energy ✓ is converted into chemical energy ✓
(Dit is ŉ sel waarin) elektriese energie omgeskakel word na chemiese

energie. (2)
9.1.2 2 Cℓ- → Cℓ2(g) + 2e− ✓✓
Ignore phases / Ignoreer fases (2)

Marking criteria / Nasienkriteria
• 2 Cℓ- ⇌ Cℓ2(g) + 2e− ½
• Cℓ2(g) + 2e− ← 2 Cℓ- 2/2
• Cℓ2(g) + 2e− ⇌ 2 Cℓ- 0/2
Ignore if the charge omitted on electron / Ignoreer indien lading weggelaat

is op elektron
9.1.3 H2 / Hydrogen gas / Waterstofgas (1)
9.1.4 H2O is a stronger oxidising agent than Na+ ✓

H2O is reduced to H2 ✓
H2O is ŉ sterker oksideermiddel as Na+

H2O word gereduseer na H2 (2)
9.2.1 Cathode / Katode ✓ (1)
9.2.2 nCu =½x6✓

Marking criteria
= 3 mol
• Use of ratio of electrons to Cu
mCu = nM = 3 x 63,5✓ • Subst. into n = m/M
• Division by 0,95
= 190,5 g • Final answer
0,95 ✓m IMPURE sample = 190,5 Nasienkriteria
• Gebruik van verhouding van
m IMPURE sample = 200,53 g ✓
elektrone tot Cu
• Vervanging in n = m/M
• Deel deur 0,95
• Finale antwoord
(4)
[12]
TOTAL/TOTAAL: 150

EC Physical Science Grade 12 SEPT 2022 P2 and Memo

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PHYSICAL SCIENCES P2 (CHEMISTRY)

This question paper consists of 21 pages, including 4 data sheets.

INSTRUCTIONS AND INFORMATION

3. Start EACH question on a NEW page in the ANSWER BOOK.

4. Number the answers correctly according to the numbering system used in

10. Give brief motivations, discussions, et cetera where required.

11. You are advised to use the attached DATA SHEETS.

12. Write neatly and legibly.

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QUESTION 1: MULTIPLE-CHOICE QUESTIONS

1.1 The name of the functional group of propanoic acid is ...

1.3 Consider the compound shown below:

The CORRECT IUPAC name of the above compound is:

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Which ONE of the following combinations correctly indicates both the

Activation energy (kJ·mol-1) Heat of reaction (ΔH)

D b–c a–b (2)

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1.6 H2S (g) decomposes according to the following balanced equation:

H2S (g) ⇌ H2 (g) + S (s)

In each of four separate experiments, A to D, H2S of initial concentration ci is

Which experiment has the largest Kc value?

HIn (aq) + H2O (ℓ) ⇌ H3O+ (aq) + In – (aq)

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1.8 The function of a salt bridge in a galvanic cell is to …

A allow for the movements of protons.

B allow for the movements of electrons.

C provide a site for reduction to occur.

D ensure electrical neutrality of solutions. (2)

Concentration Positive ions

A Remain constant Cu2+

B Remain constant Fe2+

D Increases Cu2+ (2)

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QUESTION 2 (Start on a new page.)

CH3C ≡ CCH2CH3 Pentane

2.1 Define the term homologous series. (2)

2.2 Write down the:

2.2.1 Letter that represents a saturated hydrocarbon (1)

2.2.2 General formula of the homologous series to which compound C

2.2.3 Structural formula of compound A (2)

2.3 Write down the IUPAC name of compound B. (3)

2.4 Compound D has three structural isomers.

Write down the:

2.4.2 Balanced equation for the combustion reaction of compound D in

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QUESTION 3 (Start on a new page.)

3.1.1 Define the term boiling point. (2)

Refer to the TYPE and STRENGTH of intermolecular forces involved. (3)

The vapour pressure of the alcohol is compared to that of a ketone at the

3.1.5 Which ONE will have a higher vapour pressure: ALCOHOL or

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3.2.1 Which compound has the higher boiling point? (1)

3.2.2 Explain the answer to QUESTION 3.2.1 by referring to TYPE,

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QUESTION 4 (Start on a new page.)

4.1 Compound P can be used to prepare organic compounds R and Q as shown

In reaction I, alcohol P reacts with another organic compound in the presence