Polymer Science & Technology: Syllabus & Guidelines OF Chemistry SRI Jayewardenepura

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B.Sc.

(GENERAL) DEGREE

POLYMER SCIENCE & TECHNOLOGY

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SYLLABUS & GUIDELINES


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REVISED IN JANUARY 2014


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DEPARTMENT OF CHEMISTRY
FACULTY OF APPLIED SCIENCES
UNIVERSITY OF SRI JAYEWARDENEPURA
Polymer Science and Technology Course Units
Page
st st
1 Year – 1 Semester
1. PST 101 2.0 Introduction to Polymer# 2
2. PST 102 1.0 Inorganic Polymers# 4
3. PST 108 1.0 Statistics for Polymer Science# 5
4. PST 111 1.0 Polymer with Special Functionalities# 6

1st Year – 2nd Semester

1. PST 105 2.0 Basic Chemical Engineering and Polymer Industry# 7


2. PST 107 1.0 Degradation and Stability of Polymers# 9
3. PST 109 1.0 Fundamental of Polymer Physics# 10
4. PST 112 1.0 Dry Rubber Technology# 11

2nd Year – 1st Semester

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PST 206 1.0 Analytical Method and Testing of Polymers#

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1. 13

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2. PST 207 1.0 Solution Properties and Thermodynamics of Polymers# 15

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3. PST 214 1.0 Rubber Based Industries# AR IS 16
4. PST 216 1.0 Latex Technology# 18
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5. PST 217 1.0 Plastic Materials# 19


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2nd Year – 2nd Semester


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1. PST 205 1.0 Plastic Technology# 20


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PST 213 1.0 Kinetics of Polymerization#


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2. 21
3. PST 218 1.0 Engineering Plastics# 22
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4. PST 219 1.0 Polymer Rheology, Viscosity and Rubber Elasticity# 24


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5. PST 212 1.0 Laboratory Practicala 25


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3rd Year – 1st Semester


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1. PST 301 1.0 Polymer Blends and Composite* 27


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PST 307 1.0 Introduction to Die and Mould Designing*


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2. 29
3. PST 303 1.0 Polymer Coating and Paint Industry* 30
4. PST 305 1.0 Laboratory Practicala 32

3rd Year – 2nd Semester

1. PST 314 2.0 Industrial Management and Marketing* 34


2. PST 310 1.0 Environment and Polymer Industry * 36
3. PST 313 1.0 Introduction to Engineering Materials* 37
4. PST 314 1.0 Rubber Materials* 38
5. PST 309 3.0 Industrial Projecta 39
# * a
- Core Courses - Optional Courses - Compulsory Courses

Page 1 of 41
Course Title : PST 101 2.0 Introduction to Polymers
Number of lecture hours : 30
Number of Tutorial hours : 6
Lecturer in Charge : Prof. L. Karunanayake

Objectives:
 Introduction to the subject of polymer chemistry.
 Introduction to concept of average molar masses and molar mass distributions
 Study conformations, thermal properties and thermal transitions of polymers
 Elastomers, plastics and fibers
 Fundamentals of Step-growth polymerization
 Introduction to Chain/addition polymerization- ionic and free radical polymerization

Course Content:
1. Monomers and Polymers. Prerequisite to qualify as a monomer

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(1h)

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2. Differentiation of Polymers from simple molecules

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(1h)
3. Basic concepts of joining monomer molecules to form dimers, trimmers, oligomers
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and polymers
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(1h)
4. Classifications of polymers. Different approaches of categorizing polymers
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(1h)
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5. Monomers, homo-polymers, co-polymers and ter-polymers, graft polymers and


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IUPAC Nomenclature
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(2h)
6. Different average molar masses, their definitions and molar mass distributions, and
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polydispersity
(4h)
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7. Introduction to polymer conformations, amorphous and semi-crystalline polymers and


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their molecular structures, relation between chemical structure and morophology


(4h)
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8. Thermal behavior of polymers and thermal transitions.Graphical depiction of thermal


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behavior of polymers.Glass transition temperature (Tg), Melting temperature (Tm),


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Crystallization temperature (Tc),Differences in the thermal behavior of crystalline,


amorphous and semi crystalline polymers, Significant of the knowledge of Tg, Tm, Tc
of polymers in choosing the correct material for polymer industry
(6h)
9. Examples of Elastomers, plastics and fibers and their properties
(2h)
10. Step-growth polymerization and examples, Carother’s equation and mechanisms of
polymerization. Control of molar mass, Schotten-Baumann reaction, Salt dehydration
reaction, ester interchange reaction and step polyaddition. Stoichiometric control of
molar mass and the extended Carother’s equation. Examples, linear (thermoplastic)
and non-linear (thermosettings)
(4h)

Page 2 of 41
11. Chain/addition polymerization- ionic and free radical polymerization. Initiation,
propagation and termination.
(4h)

Learning outcomes:
 Students would be comprehended of basics of polymer chemistry.
 Students would learn concept of average molar masses and molar mass distributions
 Students would learn conformations, thermal properties and thermal transitions of
polymers
 Students would be introduced elastomers, plastics and fibers that are used in the
industry
 Students would learn fundamentals of Step-growth polymerization
 Students would learn fundamentals of Chain/addition polymerization- ionic and free
radical polymerization

Method of assessment:

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End of semester 2 h theory paper

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References:

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1. Textbook of polymer science, 3rd ed., Fred W. Billmeyer, Jr., Wiley-Interscience,
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New York
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2. Polymers: Chemistry and Physics of Modern Materials, Third Edition , J.M.G.


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Cowie, Valeria Arrighi, CRC Press


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3. Principles of Polymerization, 4th Edition, George Odian, Wiley


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Page 3 of 41
Course Title : PST 102 1.0 Inorganic Polymers
Number of lecture hours : 15
Number of Tutorial hours : 3
Lecturer in Charge : Prof. Sudantha Liyanage

Objectives:
 Overview the area of inorganic polymers.
 Familiarize the nomenclature, structure and properties, preparation and industrial
applications of commonly used inorganic polymers.

Course content:
1. Categories of Inorganic Polymers
Graphite, Diamond, Fullerene, Glass, Ceramics, Silica, Silicates, Silicones,
Aluminum Silicates and Related Compounds
Disadvantages in inorganic polymers over organic polymers
Structure and the Physical, Chemical properties of Graphite, Diamond and Fullerene

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(4h)

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2. Silica and silica based products

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Structure, properties and industrial applications of Quartz (Eg:-Granite), Glass;
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Properties, Manufacturing processes and techniques, Types of glass, Uses of
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different kinds of glass, Cement and Asbestos
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(4h)
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3. Aluminosilicates
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Classification and structures of Aluminosilicates, Examples of natural


Aluminosilicates and their utilization in industry.
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(3h)
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4. Chemistry of Silicone
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Nomenclature and the classes of silicone polymers, Structure and properties,


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Preparation of silicones, Industrial applications of silicone polymers


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(4h)
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Learning outcome:
 Students should be able to select the inorganic polymers for the suitable application.
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 Students should be able to relate the chemical structures of inorganic polymers to the
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properties.

References:
1. Inorganic Chemistry by J. D. Lee
2. Inorganic Chemistry by Cotton &Willinson

Page 4 of 41
Course Title : PST 108 1.0 Statistics for Polymer Science
Number of lecture hours : 15
Number of Tutorial hours : 3
Lecturer in Charge : Dr. Dilru Ratnaweera

Objectives:
 Overview of the basic statistic concepts
 Introduce probability distribution functions
 Describe basic hypothesis testing methods for data analysis

Course content:
1. Basic introduction
Population, sample, accuracy, precession, repeatability, reproducibility, significant
figures
(1h)
2. Location statistics

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Mean, median and mode

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(1/2 h)

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3. Measure of dispersion/variabilityAR IS
Range, inter quartile range, variance, coefficient of variance, slandered deviation,
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standard error
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(1 ½ h)
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4. Probability
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Properties/rules of probability, elementary and composite events, relative


frequencies, permutations of ordered sequences, expectation value, probability
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distribution functions and their applications (mainly focuses on the normal


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distribution function and provide brief introduction to uniform distribution,


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binomial distribution, Poisson distribution and log normal distribution)


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(4h)
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5. Hypothesis testing
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Basic steps, one tailed and two tailed tests, z-test, t-test, Chi-square test
(4h)
6. Error propagation
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(1 ½ h)
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7. Sampling techniques
Ways to chose samples to represent the whole population, non probability
sampling and bias, random sampling, cluster sampling, systematic sampling
(1 ½ h)
8. Statistical analysis software and graphical data representation:
(1h)

Learning outcomes:
 Be able to describe basic statistical concepts
 Be able to utilize statistical tools to validate experimental data
 Be able to utilize the statistics knowledge to maintain the accuracy in laboratory
practicals and research projects
 Be able to utilize the statistics knowledge in advanced courses in polymer science and
technology program

Page 5 of 41
Method of assessment:

End of semester 1h theory paper

References:
1. Introductory Statistics, Neil A. Weis, Pearson; 9 edition (January 6, 2011),ISBN-10:
0321691229, ISBN-13: 978-0321691224
2. An Introduction to Statistics, George Woodbury , Publication Date: August 29, 2001
, ISBN-10: 0534377556 , ISBN-13: 978-0534377557 , Edition: 1
3. Introductory Statistics, Prem S. Mann, Publication Date: February 17, 2006 , ISBN-
10: 0471755303 , ISBN-13: 978-0471755302 , Edition: 6

Course Title : PST 111 1.0 Polymers with Special Functionalities


Number of lecture hours : 15

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Number of Tutorial hours : 3

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Lecturer in Charge : Dr. K. M. Thilini D. Gunasekara

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Objectives:
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 To present innovation, invention, imagination and creativity in modern Polymer


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Science and Technology


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 To introduce different types of functional polymer


 To elaborate the structure and property relationship of polymers
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Course content:
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1. Introduction: revolution in materials science


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(1/2 h)
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2. Smart Polymers
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Introduction: Can a piece of plastic think? Definition, applications, external


triggers, Photo-responsive materials, Thermo-responsive material, chemical
responsive materials, electro-responsive materials
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(3½ h)
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3. Liquid crystal polymers


Introduction to Low Molar Mass Liquid Crystals and Definitions, Liquid
Crystalline Polymers, Properties of liquid crystal polymers, Liquid crystalline
phases, Applications and limitations
(3h)
4. Multi block polymers
Advantages of having multi blocks, Factors controlling the self-assembly of multi-
block polymers, Phase diagram of multi block polymers (copolymers),
Applications of multi-block polymers, Reversible Addition-Fragmentation chain
Transfer
(3h)
5. Conducting polymers
Electron conducting polymers, Proton conducting polymers, Ion conducting
polymers, Application of conducting polymers
(4h)
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6. Self healing polymers
Introduction to self-healing phenomenon, Self-healing mechanisms, Applications
(1h)

Learning outcomes:
 Students will learn characteristics of various functional polymers
 Students will be able to correlate the specific properties with the polymeric structure
 Identified the latest advances and applications in Polymer science and technology

Method of assessment:

End of course 1h theory paper

References:
1. Smart polymers- applications in biotechnology and biomedicine by Igor Galaev and
Bo Mattiasson, CRC press, 2008
2. Liquid Crystalline Polymers By A. M. Donald, A. H. Windle, S. Hanna, Cambridge

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university press, 2005

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Course Title : PST 105 2.0 Basic Chemical Engineering and


Polymer Industry
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Number of lecture hours : 30


Number of Tutorial hours : 6
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Lecturer in Charge : Visiting Lecturer


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Objectives:
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 To introduce technologies related to polymer industry


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 To provide knowledge on raw materials and energy sources used in the polymer
industry
 To provide understanding on the basic concepts of unit operations, process
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development, flow sheeting, material and energy balances


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 To provide knowledge on ancillary services and related instruments required to the


process industry

Course content:
1. Introduction to polymer industry
Technologies, processes
(2h)
2. Natural resources
Materials from geosphere, biosphere, hydrosphere and atmosphere, sources of
energy
(3h)
3. Concepts of unit operations

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Anatomy of a process, introduction to unit operations, reactor systems, product
separation processes (chemical, physical and mechanical), purification and product
storage
(4h)
4. Process development
Objectives, process development procedure (laboratory scale, mini plant, pilot
plant, industrial scale), design constraints
(4h)
5. Process Flow sheeting
Block diagram, process flow diagram, material and energy balance sheets and pipe
and instrumentation diagram
(4h)
6. Material and energy balances
Calculations relating to reactive and non- reactive systems with single and multiple
inputs and outputs
(10h)
7. Utilities
Ancillary services, related instruments (boilers, steam distribution and traps,

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chillers, compressors, pumps, valves)

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(3h)

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Learning outcomes:
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 Be able to indentify various chemical, physical and biological operations involved in
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the polymer industry


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 Be able to develop a process from laboratory scale to industrial scale


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 Be able to generate process flow sheets based on basic design criteria


 Be able to identify the ancillary services required for the polymer industry and select
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instruments accordingly
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Method of Assessment:
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End of semester 2h theory paper


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References:
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1. Basic principles of and calculations in Chemical Engineering by David M


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Himmelblau
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2. Chemical Engineering Volume 1-6, by JM Coulson and JF Richardson


3. Introduction to materials and energy balances by GV Reklaitis
4. Transport processes and unit operations by CJ Geankoplis

Page 8 of 41
Course Title : PST 107 1.0 Degradation and Stability of Polymers
Number of lecture hours : 15
Number of Tutorial hours : 3
Lecturer in Charge : Dr. K. M. Thilini D. Gunasekara

Objectives:
 To provide a general understanding of polymer degradation and stability.
 Understand the structure relationship with degradation processes
 Explore current stabilization techniques

Course Content:
1. Introduction
General aspects of polymer degradation and stability, Advantages and
disadvantages of polymer degradation, General factors of polymer degradation,
Introduction to common degradation processes, Miscellaneous types of degradation
processes: Degradation by, Ionizing radiation, mechano-degradation,

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biodegradation, chemical agents

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(2h)

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2. Thermal Oxidation and DegradationAR IS
Thermal oxidation; thermal autoxidation, Mechanism, structure stability
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relationship, Stabilizers: free radical traps, electron donors, H-donors, metal ion
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deactivators, peroxide decomposers, combination of stabilizers: additive effect,


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antagonistic effect, synergistic effect


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Thermal Degradation; Mechanism: random scission and sequential elimination


(5h)
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3. Ozone Degradation
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Introduction, general observation, stabilization: waxes, other physical methods,


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antiozonernts
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(2h)
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4. Photodegradation
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Mechanism of oxidative photodegradation, primary/secondary photochemical


initiation, dark reactions, methods of stabilization: light screeners, UV stabilizers
and quenchers
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(5h)
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5. Importance of degradation
Environmental pollution, precautions: reduce, recycle, reuse, greener plastics
(1h)

Learning outcomes:
 Be able to understand the fundamentals of polymer degradation and stability
 Indentify structure relationship with degradation processes
 Be able to understand current stabilization techniques

Method of assessment:
End of semester 1h theory paper

References:
1. Polymer Degradation and Stabilization by By Norman Grassie, Gerald Scot
2. Polymer Stabilization by W. Lincolin Hawains
Page 9 of 41
3. Fundamentals of Polymer Degradation and Stabilization by N.S. Allen, M. Edge

Course Title : PST 109 1.0 Fundamental of Polymer Physics


Number of lecture hours : 15
Number of Tutorial hours : 3
Lecturer in Charge : Dr. K. M. Thilini D. Gunasekara

Objectives:
 To introduce the physical properties of polymers and their applications
 To identify the correlation of physical properties of polymers with their structure
 To provide basic concepts, theories/models and tools of analysis of viscoelastic
materials

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Course content:

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1. Introduction to physical properties of polymers

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Mechanical and rheological properties, Deformation of polymers (types and forces
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that can make deformations), tensile strength, stress-strain diagrams, elastic
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deformation/plastic deformation, young’s modulus, yield strength, ultimate
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strength, strain hardening, necking, brittle/ductile materials, static testing, poisons


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ratio, change of modulus with temperature, compressed deformation, shear


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deformation
(5h)
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2. Structure/property relationship
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Roles of polymer architecture, intermolecular forces and physical entanglements


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on polymer packing and physical properties


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(1h)
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3. Mechanical models describing viscoelastic material


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Ideal solids/ideal liquids and their governing equations, Newtonian/ non


Newtonian fluids, viscoelastic materials, introduction to shear thinning/ shear
thickening and thixotropic and rheopectic fluids, spring and dashpot model,
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Maxwell model, Kelvin model, multi-element models


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(2½ h)
4. Hysteresis effect
Definition, types of hysteresis, Creep, Stress relaxation, explaining the hysteresis
effect using mathematical models (Maxwell model, Kelvin model, multi-element
models)
(2½ h)
5. Intermittent loading
Introduction to Superposition principle, Boltzman superposition principle, time –
temperature superposition
(2 h)
6. Dynamic response
Dynamic response on ideal solid/ideal liquids/viscoelastic materials, governing
equations, storage modulus/los modulus/damping, major methods employed to
analyze the dynamic behavior of polymeric materials (Dynamic Mechanical
Thermal Analysis (DMTA/DMA), Dielectric Thermal Analysis (DTA))
Page 10 of 41
(2 h)

Learning outcomes:
Students should:
 be able to describe mechanical and rheological properties of polymers and factor
controlling such properties
 be able to express concepts and mechanism behind viscoelastic nature, creep, stress
relaxation, dynamic response of polymers
 be able to introduce major analytical tools that can be used to analyze dynamic
behavior of polymers

Method of assessment:

End of semester 1h theory paper

Reference:
1. Physical Properties of Polymers Handbook by James E. Mark, Springer, 2007

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2. Rubinstein, M., Colby, R.H., Polymer Physics, Oxford University Press, 2003.

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3. Gedde, U.W., Polymer Physics, Kluwer Academic Publishers, 1995.

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Course Title : PST 112 1.0 Dry Rubber Technology


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Number of lecture hours : 15


Number of Tutorial hours : 3
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Lecturer in Charge : Dr. Susantha Siriwardena (Visiting)


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Objectives:
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 To explore the available raw materials to be used in rubber based product


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manufacture
 To understand the functions of different rubber ingredients
 To select and use of different rubber ingredients in rubber product manufacture
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 To develop skills to achieve desired curing characteristics


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 To understand the basic rubber compounding principles and compounding process


 To develop confidence on rubber compound design and manufacturing methods of
rubber products

Course content:
1. Brief introduction to dry rubber technology
Including Brief introduction to compounding and compounding principles:
definition of compounding, compounding principles
(1h)
2. Introduction
Raw materials available-NR (local Crepe/Scrap Crepe, TSR) & Synthetic rubbers
(3h)
3. Brief overview on quality testing of raw materials
(1h)

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4. Mastication
Importance of mastication and its effect on processing and performance of final
product, factors affecting the efficiency of mastication
(1h)
5. Dry rubber other ingredients used in dry rubber industry
Types and classes of ingredients (for latex based and dry rubber based industries)
such as fillers, accelerators, activators, anti-degradents, processing aids,
miscellaneous ingredients and special additives, dry rubber compounding.
(4h)
6. Assessment of rubber compounds
Quality, economics aspects of compounding
(1h)
7. Vulcanization
Rheograph, study of curing characteristics, vulcanization techniques, vulcanization
systems, effect of vulcanization on the performance
(2h)
8. Brief introduction to shaping methods used for making rubber based product
Moulding, calendaring extrusion, injection moulding

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(2h)

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Learning Outcomes: AR IS
 Be able to select types and grades of rubber and other ingredients for the manufacture
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of different types of rubber products
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 Be able to understand the functions of various rubber ingredients


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 Be able to analyze the cure characteristics of a rubber compound and interpret cure
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curves
 Be able to predict the product performance of a given rubber compound and supervise
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a rubber manufacturing production flow line under guidance of a technical expert


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Method of assessment:
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End of course 1h theory paper 80% and 20% class tests and assignments
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References:
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1. Polymer industry in Sri Lanka, edt. Sudantha Liyanage, published by the University
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of Sri Jayewardenepura of Sri Lanka.


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2. Basic Chemistry and Technology of Industrial Polymers, Kanthappu Subramaniam,


2012.
3. Handbook of Rubber Technology: Volume 1, Natural and synthetic rubber and
technology of vulcanization by J. M. Martin, W. K. Smith; edited by S. C. Bhatia, CB
Publishers, 2007
4. Handbook of Fillers, George Wypych. Chem. Tech Publishing, 2000; Polymer
Lattices, Science and Technology, D. C. Blackley, CHAPMAN & Hall, London, 1997

Page 12 of 41
Course Title : PST 206 1.0 Analytical Methods and Testing of
Polymers
Number of lecture hours : 15
Number of Tutorial hours : 3
Lecturer in Charge : Dr. K. M. Thilini D. Gunasekara

Objectives:
 Provide a general understanding of analytical methods of polymers
 Understand the basic theory behind the instrumentation
 Explore standard testing methods of plastics

Course content:
1. General overview
Review of key concept in polymer analysis and testing
(1/2 h)
2. Absorption Spectroscopy:

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a) IR spectroscopy

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Theory behind IR, Instrumentation, characteristic group absorption,

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interpretation of spectra, attenuated total reflectance (ATR) method, FTIR
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method. Application of IR: Analyze structure of monomers/polymers,
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tacticity/ crystallinity, extent of chemical reactions, investigation of unknown
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compounds, quality control, IR as semi-quantitative/ quantitative analysis,


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Polymer Degradation, reaction mechanism, Rate of chemical reactions,


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Additives Analysis
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(3h)
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b) NMR Spectroscopy
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Theory behind NMR, Applications: Copolymer composition analysis,


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sterioisomerization, tacticity, monomer/polymer characterization, solid state


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NMR
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(2h)
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c) UV visible Spectroscopy
Theory of UV visible spectroscopy, Applications, Identification and analysis
(Oxidation, Discoloration) of polymer by UV spectroscopy, Analysis of
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oxidative degradation of polymers (In PVC, Polyethylene), staining techniques


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to identify polymer
(1/2 h)
3. Thermal analysis:
a) Thermogravimetric Analysis (TGA)
Theory behind TGA, Instrumentation, typical TGS curves, applications:
thermal stability, material characterization, compositional analysis, simulation
of industrial processes, kinetic studies
(2h)
b) Differential Scanning Calorimetry (DSC)
Theory behind DSC, Instrumentation, typical DSC curves, applications:
melting process, enthalpy of fusion, purity, transition processes
(2h)
c) Dynamic Mechanical Analysis (DMA)
Instrumentation, Common clamping geometries, DMA curves, Time-
Temperature Correspondence, The Crankshaft Model, applications
Page 13 of 41
(1h)
4. Gel Permeation Chromatography (GPC)
Theory behind GPC, Instrumentation, applications
(1h)
5. Plastic testing
Impact strength, Flexural strength, Fatigue and flexing, Abrasion resistance, mold
shrinking, density, viscosity, thermal conductivity, Deflection temperature,
flammability, melt index, UV resistance, permeability, secular gloss, index of
refraction, arc resistance, resistivity, dialectic constant
(2h)
6. Scanning electron microscope, Transmission electron microscopy, X-ray Diffraction
Methods
(1h)

Learning outcomes:
 Understand the principles of characterization techniques of polymers
 Be able to interpret spectrums, plots and curves
 Be able to select appropriate techniques to provide specific information on polymer

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 Aware about the current testing approaches

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Method of assessment: AR IS
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End of semester 1h theory paper


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References:
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1. Composition and failure analysis of polymers (a practical approach) by John Scheirs


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2. Campbell, C., Polymer Characterization: Physical Technique, Chapman and Hall,


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1989.
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3. Industrial plastics – theory and applications by Richardson and Loensgard


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4. Spectrometic Identification of organic compounds by Robert Silverstein


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Page 14 of 41
Course Title : PST 207 1.0 Solution Properties and Thermodynamics
of Polymers
Number of lecture hours : 15
Number of Tutorial hours : 3
Lecturer in Charge : Dr. M. A. B. Prashantha

Objectives:
 To improve visualization skill of conceptual approach to the model development of
dissolution process of small molecular substances and very long chain molecular
substance.
 To understand the fascinating art of model development for polymer solutions using
basics of thermodynamics.
 To familiarize the theory of solubility parameter, Flory-Huggins theory and
interaction parameter.
 To understand the behavior of linear polymer molecule in diluted solution.
 To select suitable solvent for the given polymer to make a polymer solution.

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Course content:

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1. Introduction to the thermodynamic approach for mixing of two components
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,
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Statistical thermodynamics approach for the entropy of mixing.


(3h)
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2. Interpretation of dissolution process of polymer


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Effect of chemical structure, Chain length, Morphology, Fickian and non-Fickian


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diffusion of solvent, hydrodynamic volume and its equilibrium


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(2h)
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3. Quantitative interpretation of the effect of thermodynamics functions to the


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dissolution process of polymer


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Good solvent and non-solvent, solubility of polydispersed system, solubility of


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crystalline and amorphous polymer, fractional precipitation


(3h)
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4. Mathematical models for solubility of polymers parameter (Scachard-Hilderbrad and


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Hansen)
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(4h)
5. Flory-Huggins theory of polymer solution and interaction parameter
(3h)
6. Chain size and chain statistics of linear polymer in solution, end-to-end distance,
unperturbed dimension and radius of gyration
(1h)

Learning outcomes:
 Students should be able to understand the fascinating art of model development using
basics of thermodynamics to get a simplified equation based on measurable quantities.
 Students should be able to read literature to understand current developments in the
subject are.

Page 15 of 41
 Students should be able to use the thermodynamics approach to select a suitable
solvent or solvent system to form a polymer solution using the given the given
polymer

Method of Assessment:

End of semester 1h theory paper

References:
1. Text book of polymer science, Fred W. Billmeyer, A Wiley International Publication
2. Polymers: Chemistry and Physics of Modern Materials, Third Edition , J.M.G. Cowie,
Valeria Arrighi, CRC Press
3. Physical chemistry, P. W. Atkins, Oxford University Press

A
R
Course Title : PST 214 1.0 Rubber Based Industries

U
EN Y
EP
D TR
Number of lecture hours : 15
Number of Tutorial hours : 3 AR IS
M
Lecturer in Charge : Dr. L. M. K. Tilekeratne (VL)
EW HE
AY C
I J OF

Objectives:
 Present an overview of the economic importance of the rubber industry to Sri Lanka
SR T
F N

 Provide a knowledge on Raw Rubber Industry


O ME

 Provide a knowledge on all aspects of rubber products manufacture


TY T

 Provide a basic knowledge on machinery used in the rubber processing industry


SI AR

 Provide a knowledge on cost cutting in products manufacture, and on costing and


ER EP

marketing a product
 Provide knowledge sufficient to manufacture good quality raw rubber if they have a
D

rubber property
IV
N

Course content:
U

1. National and International rubber statistics


World demands and demand variation for natural and synthetic rubber and leading
produces, numerous applications of natural and synthetic rubber, the challenges of
local rubber industry, master plan of local rubber industry and its sustainability.
Economic importance of the rubber industry to Sri Lanka
(3h)
2. Dry rubber industry and manufacturing processes
Deferent categories of tyres, main components of Solid tyres and pneumatic tyres
and the principle steps in the manufacture of them, Extruded products
(3h)
3. Latex industry and manufacturing processes
Dipped Products, Foam rubber, Rubberized Coir and moulded toys
(4h)
4. Reclaim rubber manufacturing process

Page 16 of 41
Advantages of reclaim rubber, applications of reclaimed rubber and manufacturing
process, Tyreretrading
(3h)
5. Rubber plantation
Tapping technology and latex yield, factors affecting to the quality of field latex
(2h)

Learning outcomes:
 Be able to understand the economic importance of converting raw rubber to end
products for export.
 Be able to improve the quality of raw rubber produced to gain a higher price
 Be able to start a rubber based industry at a low investment after graduation.

Method of assessment:

End of semester 1h theory paper

A
References:

R
1. Chemistry of Rubber like elements. Editor Bateman

U
EN Y
EP
D TR
2. Polymer Chemistry Editor- Morris Morten
3. Hand Book of Rubber Processing and Culture. RRISl publication Editor L. M. K.
AR IS
Tillekeratne
M
EW HE

4. International Rubber Study Group Bulletins.


5. Rubber Technology and Manufacture C M Blow, CRC Press, Division of the
AY C

Chemical Rubber Co. Cleveland, Ohio, US


I J OF
SR T
F N
O ME
TY T
SI AR
ER EP
IV D
N
U

Page 17 of 41
Course Title : PST 216 1.0 Latex Technology
Number of lecture hours : 15
Number of Tutorial hours : 3
Lecturer in Charge : Visiting Lecturer

Objectives:
 Provide a general understanding of natural and synthetic rubber latex and its
industrial applications
 Provide different processing techniques used in Latex industry

Course content:
1. Introduction to Natural rubber latex
Composition of Natural Rubber (NR) Latex, Non-rubber substances in the NR
latex and importance, Architecture of the rubber particle in NR latex
(2h)
2. Preservation of NR latex

A
R
Spontaneous coagulation, Preservation by ammonia (HA Latex, LA Latex, LA-TZ

U
EN Y
Latex), Factors affecting on the stability of preserved natural rubber latex

EP
D TR
AR IS (2h)
3. Concentrating methods of NR latex
M
Centrifugation and different fractions of latex, Creaming, Evaporation, ISO
EW HE

standard for concentrated NR latex


AY C

(2h)
I J OF

4. Stabilization of NR latex
Stabilizers (Fixed alkali, Surface active materials, protective colloids)
SR T
F N

(1h)
O ME

5. Synthetic lattices
TY T

Different types of synthetic latices (Styrene butadiene latex, nitrile butadiene latex,
SI AR

Polychloroprene latex)
ER EP

(2h)
6. Latex Compounding
D

Latex compounding ingredients (vulcanizing agents, Accelerators, Activators,


Antioxidants, Fillers, special additives based on the application), Preparation of
IV

dispersions and emulsions, Machinery and equipment used for preparing


N
U

dispersions and emulsions of compounding ingredients


(2h)
7. Prevulcanized and postvulcanized NR Latex
Preaparation of prevulcanization latex, Comparison of prevulcanized and post
vulcanized latex
(1h)
8. Techniques used in Latex industry and latex allergy
Dipping (Straight dipping process, Coagulant dipping process, Heat sensitive
dipping), Forming (Dunlop process and Talalay process), Casting, Extrusion for
elastic threads, Adhesives and surface coating, Latex allergy
(3h)

Learning outcomes:
 Student should be able to understand the chemical and physical changes during
storage and processing of latex.
Page 18 of 41
 Student should be able to use the basic knowledge to understand the manufacturing
process in latex industry.

Method of assessment:

End of semester 1h theory paper

References:
1. Polymer lattices science and technology, D. C. Blackley, Wiley interscience, 1997
2. Basic chemistry and technology of industrial polymer, Andra Digital printer,
Kanthappu Subramaniam, 2012

Course Title : PST 217 1.0 – Plastic Materials


Number of lecture hours : 15

A
Number of Tutorial hours : 3

R
U
EN Y
Lecturer in Charge : Prof. L. Karunanayake

EP
D TR
AR IS
M
Objectives:
EW HE

 To introduce the commodity plastics.


AY C

 To provide basic knowledge on common polymerization techniques used for


I J OF

commodity plastics commercially.


 To demonstrate relationship between structure and properties of commodity plastics.
SR T
F N

 To provide students with the knowledge on application of commodity plastics.


O ME
TY T

Course content:
SI AR

1. Introduction
ER EP

(2h)
D

2. Common polymerization techniques used for commodity plastics commercially


Polymerization techniques and their relationship to properties will be discussed.
(5h)
IV
N

3. Structure and properties of commodity plastics


U

Effect of conformational changes and other factors effecting properties will be


discussed
(5h)
4. Applications
Commercial applications and formulations used for them with reasons will be
discussed
(3h)

Learning outcomes:
The students should have knowledge on types and grades of commodity plastics available in
the market, on polymerization techniques used and their effects on properties, on structure
and property relationship. Finally, they should have a basic idea of selecting materials for
common plastic products

Page 19 of 41
Method of assessment:

End of semester 1 h theory paper

References:
1. Industrial polymers handbook: Products, Processes, Applications (V1,2& 3)Edited
by E. S. Wilks, Wiley-VCH Verlag GmbH, Weinheim
2. Processes, Applications Industrial Polymers, Monograph No.24, L.
Karunanayake, Institute of Chemistry Ceylon
3. Brydson, J.A. - Plastics Materials 7th Ed. (Butterworth 1999)

Course Title : PST 205 1.0 Plastic Technology


Number of lecture hours : 15
Number of Tutorial hours : 3

A
Lecturer in Charge : Prof. L. Karunanayake

R
U
EN Y
EP
D TR
Objectives:
AR IS
M
 Fundamentals of polymer compounding, mixing and blending
EW HE

 Introduction to polymer processing


AY C
I J OF

Course content:
1. What is polymer compounding? Why it is necessary to mix polymers with other
SR T
F N

ingredients. How do you compound polymers and instruments used in compounding?


O ME

Factors effecting mixing.


TY T

(5h)
SI AR

2. Choice of a blender, mixing techniques and mixers, master-batches.


ER EP

(3h)
3. Plastic processing techniques and equipment. Extrusion, injection moulding,
D

calendaring, blow moulding, film forming, fiber spinning and coatings.


(7h)
IV
N
U

Learning outcomes:
 Fundamentals of mixing, compounding and blending would be learnt
 Compounding and mixing techniques would be learnt.
 Plastic processing techniques would be learnt.

Method of assessment:

End of semester 1h theory paper

References:
1. Outlines of Polymer Technology: Processing Polymers, R. Sinha, Prentice-Hall
India.
2. Polymer Processing Fundamentals, Tim A. Osswald, Hanser.

Page 20 of 41
Course Title : PST 213 1.0 Kinetics of Polymerization
Number of lecture hours : 15
Number of Tutorial hours : 3
Lecturer in Charge : Dr. M. A. B. Prashantha

Objectives:
 To impart the knowledge of historical development of chemical kinetics of
polymerization.
 To understand the distribution of weight fractions with the number average degree of
polymerization.
 To impart the knowledge of reactivity ratio of copolymerization.
 To impart the knowledge of reaction mechanism of polymerization and electronic
environment of monomers.

Course content:
1. Introduction to the classification systems of polymers based on polymerization

A
R
Carother classification system based on polymerization reactions, Flory

U
EN Y
classification system based on reaction mechanism, Lenze classification system for

EP
D TR
the step- growth polymerization.
AR IS
(2h)
M
2. Introduction to the polymerization systems
EW HE

Bulk polymerization, Solution polymerization, suspension polymerization and


AY C

emulsion polymerization.
I J OF

(4h)
3. Determination of copolymer composition using rate constants
SR T
F N

Monomer reactivity ratio, homo-propagation, cross propagation, composition of


O ME

co-monomer feed and copolymer


TY T

(2h)
SI AR

4. Reaction Kinetics of Step-growth polymerization


ER EP

Historical development of the equal reactivity of functional groups,


D

Polyesterification as a typical example for the step-growth polymerization, Second


order reaction kinetics, concentration of monomers and ithmers at a given moment,
Polyesterification under non-equilibrium condition (presence of weak acid and
IV

strong acid as catalyst, self catalysed polyesterification), Agreements and


N
U

disagreements 3rd order reaction kinetics, Reaction kinetics of polyesterification


and experimental determination using acid value, Gel point calculations., Shultz-
Flory distribution for linear step-growth polymerization
(3h)
5. Reaction kinetics of chain polymerization
Initiation, propagation, termination and chain transfer stages, Introduction to ionic
polymerization, free radical polymerization and coordination polymerization,
Electronic environment of monomers, typical examples for cationic and anionic
polymerization mechanisms, Reaction kinetics of vinyl radical polymerization and
kinetic chain length.
(4h)

Learning outcomes:
 Students should be able to understand the practical importance of the knowledge of
kinetics of polymerization.
Page 21 of 41
 Students should be able to read literature to understand current developments in the
subject are.
 Students should be able to use the basics of chemical kinetics with suitable
modifications to develop mathematical relation in order to quantitatively describe the
polymerization systems.

Method of assessment:

End of semester 1h theory paper

References:
1. Text book of polymer science, Fred W. Billmeyer, Wiley Interscience Publication
2. Polymer science and technology, Joel R. Fried, Prentice-Hall of india
3. Fundamental of Polymer science, Paul.C. Painter, Michel M. Coleman, Technomic
publication.

A
R
U
EN Y
EP
Course Title : PST 218 1.0 Engineering Plastics

D TR
Number of lecture hours : 15 AR IS
M
Number of Tutorial hours : 3
EW HE

Lecturer in Charge : Dr. Olga Gunapala


AY C
I J OF

Objectives:
SR T
F N

 To teach the specialties of engineering plastics.


O ME

 To provide basic knowledge on common manufacturing methods of engineering plastics


TY T

employed in commercial industry.


SI AR

 To give general knowledge on structure and properties of industrially important grades


ER EP

of engineering plastics.
 To provide students with the best and most current knowledge of processes and
D

technologies related to engineering plastics.


 To build the capability of understanding the area of applications of engineering plastics,
IV
N

product and components design


U

Course content:
1. Introduction
Explaining the similarities and differences of the engineering plastics when
compared to thermosets and general-purpose thermoplastics, Understanding the
unicity of engineering plastics leading to superior performance in terms of
transparency, heat resistance, dimensional stability and mechanics.
(2h)
2. Common Manufacturing methods of engineering plastics employed in commercial
industry.
(2h)
3. Structure and properties of amorphous engineering plastics
Polycarbonate (PC), Polyphenylene Oxide (Modified PPO), Polyphenylene Ether
(Modified PPE), Thermoplastic Urethane (TPU)
(3h)
Page 22 of 41
4. Structure and properties of semi crystalline engineering plastics
High performance processable PolyAcetal (PA), Polyethylene Terepthalate (PET)
as a material for manufacture of precision mechanical parts, sustaining high loads
and enduring wear, PolybutyleneTerepthalate (PBT), Ultra High Molecular Weight
Polyethylene (UHMW-PE)
(3h)
5. Processing and application of engineering plastics
Handling and Processing characteristics of engineering plastics, Manufacturing
methods: Reactive casting and non reactive casting, Semi-product Extrusion and
injection molding, Machining, Annealing, Welding, Bonding, Cleaning;
Techniques employed for manufacture of products made of glass reinforced
engineering plastics.
(5h)

Learning outcomes:
 Be able to understand the properties of commercial grades of engineering plastics
available at market
 Be able to select correct materials, and processing methods for a given plastics

A
R
product

U
EN Y
 Be able to apply principles of polymer technology to the solution of problems related

EP
D TR
to plastic product manufacturing, design and optimization of plastic process
AR IS
parameters, plastics mold design and optimization, die design and plastic product
M
EW HE

design
AY C

Method of Assessment:
I J OF
SR T

End of course 01 h theory paper-70%


F N

Assignment-30%
O ME
TY T

References:
SI AR

1. Brydson, J. A. (John Andrew), Plastics materials British Library Cataloguing in


ER EP

Publication Data, 1997-7th ed.668.4


D

2. Advanced polymer processing operations Edited by Nicholas P. Cheremisinoff, Ph.D.


Wesiwood, New Jersey, U.S.A.1998
IV
N
U

Page 23 of 41
Course Title : PST 219 1.0 Polymer Rheology, Viscosity and Rubber
Elasticity
Number of lecture hours : 15
Number of Tutorial hours : 3
Lecturer in Charge : Dr. Dilru Ratnaweera

Objectives:
 Overview of basic concepts of rheology and their applications in polymer processing
 Introduction to molecular origin of flow behavior
 Introduce methods used for rheological measurements

Course content:
1. Introduction to basics in rheology
Overview of the scope of rheology as it applies to polymer science, rheology in
engineering context, rheology of polymer melt, factors affecting rheological
properties of polymers, stress (organization of stress components in the polymer

A
R
melt, typical stress tensors), flow velocity (velocity gradient, rate of deformation),

U
EN Y
relationship between stress and rate of deformation

EP
D TR
AR IS (2 ½ h)
2. Flow regimes
M
Laminar vs. turbulent flows, Reynolds number
EW HE

(½ h)
AY C

3. Viscoelastic models
I J OF

Brief overview of the Kelvin and Maxwell models and explain creep, relaxation
SR T

and recovery stages of viscoelastic materials, 3 element model, burger model and
F N

viscoelastic models with higher number of spring and dashpot elements


O ME

(2h)
TY T

4. Rheological flow behaviors


SI AR

Ideal solid and fluid, non-Newtonian fluids, time-independent fluids, time


ER EP

dependent fluids, viscoelastic fluids, Bingham fluids and yield point, power law
D

model for time-independent fluids (Herschel & Bulkley model, Ellis model,
Casson model), temperature dependent flow behaviors
(3h)
IV
N

5. Molecular origin of flow behavior


U

Overlap parameter, dealing with entanglements, repetition of polymer chains, tube


model, explaining rheological phenomenon using tube model
(2h)
6. Rheological challenges during polymer processing
Die swelling, shark skin, die lip build up, challenges in co-extrusion, pressure drop
and effect of melt elasticity on melt processing
(2h)
7. Rheological measurements: (Rheometry)
Capillary rheometer, concentric cylinder rheometer, cone and plate rheometer, melt
flow indexer, Mooney viscometer
(3h)

Learning outcomes:
 Be able to understand the importance of polymer rheological properties.
 Student will be able to understand responses of a polymers under applied stress
Page 24 of 41
 Be able to describe major methods used to measure polymer melt rheology
 Student will be able to identify the rheological challenges in polymer melt processing

Method of assessment:

End of semester 1h theory paper

References:
1. Introduction to polymer rheology, Montgomery T. Shaw, ISBN: 978-0-470-38844-0
2. Applied Polymer Rheology: Polymeric Fluids with Industrial Applications, Marianna
Kontopoulou , ISBN: 978-0-470-41670-9
3. Polymer Rheology, R. S. Lenk, ISBN 978-94-010-9668-3, ISBN 978-94-010-9666-9

Course Title : PST 212 1.0 Laboratory Practical

A
Number of practical hours : 45

R
U
Lecturer in Charge : Dr. M. A. B. Prashantha

EN Y
EP
D TR
AR IS
M
Each practical class is limited to 3 hours and hence each practical is designed to carry out
EW HE

within the time frame to gain the basic understand.


AY C

1. Synthesis of glyptal / Glycerylpthalate


I J OF

Objectives
 Provide hands on experience on synthesis of branched polyester polymer
SR T
F N

through condensation polymerization.


O ME

 Provide hands on experience on fluidity changes during the polymerization.


 Provide hands on experience on gelation and importance of controlling the
TY T
SI AR

gelation.
ER EP

 Provide the hands on experience to physical properties of highly cross-linked


D

thermoset plastic material.


 Provide the hands on experience to use the FTIR technique to identify the
development of new functional group.
IV
N
U

2. Synthesis of linear polyester


Objectives
 Provide hands on experience on synthesis of linear polyester polymer through
condensation polymerization.
 Provide hands on experience on fluidity changes during the polymerization.
 Provide hands on experience for comparing the fluidity changes during the
polyesterification process to synthesis linear polyester and branched polyester.

3. Controlling the functionality to overcome gelation


Objectives
 Provide hands on experience to understand the effect of functionality to the gel
point.
 Provide hands on experience to understand the effect of functionality to the
properties of polymers.

Page 25 of 41
 Provide the hands on experience to use the FTIR technique to identify the
development of new functional group.

4. Synthesis of unsaturated polyester.


 Provide hands on experience on synthesis of unsaturated thermoset polyester
polymer through condensation polymerization.
 Provide hands on experience on crosslinking of unsaturated polyesters using
crosslinking agent.
 Provide the hands on experience to use the FTIR technique to identify the
development of new functional group.

5. Synthesis of PVA polymer slime


Objectives
 Provide the hands on experience on synthesis of network polymer using
organic polymer and inorganic compound.
 Provide hands on experience to understand the importance of hydrogen
bonding to form polymer having gel behavior.

A
R
U
6. Study the influence of PET to the concentration of NaOH.

EN Y
EP
D TR
Objectives
 Provide the hands on experience on studying the reaction kinetics of
AR IS
M
depolymerization of PET.
EW HE

 Provide the hands on experience to understand the importance of planning and


AY C

controlling of the laboratory conditions to conduct kinetic study.


I J OF

7. A Rapid, Economical, and Eco-Friendly Method to Recycle Terephthalic Acid from


SR T

Waste PET Bottles (Depolymerization of PET)


F N
O ME

Objectives
 Provide the hands on experience on depolymerization of PET and separation
TY T
SI AR

of products.
 Provide hands on experience to understand the effect of strong alkali medium
ER EP

to PET.
D

8. Synthesis of Polysulfide rubber


IV

Objectives
N

 Provide the hands on experience on synthesis of polysulphide rubber


U

 Provide hands on experience to understand the importance polysulphide to


impart rubbery behavior.
 Provide hands on experience to understand the application of sulpher as
inorganic substance to synthesis polymers.

9. Emulsion Polymerization of Styrene


Objectives
 Provide the hands on experience on Emulsion Polymerization of Styrene
 Provide hands on experience to understand the importance of additives used in
formula.
 Provide hands on experience to make a film using the emulsion.

10. Glycolysis of PET to BHET


Objectives
Page 26 of 41
 To provide opportunity to familiarize the glycolysis of PET
 To provide opportunity to isolate BHET and evaluate the purity.

11. Rubber compounding using two roll mill and determination of properties
Objectives
 To provide opportunity to familiarize the two roller mill operations.
 To provide opportunity to experience the effect of mastication to the physical
properties of natural rubber and make rubber compound.

12. Factory visits and report writing.


Objectives
 To provide opportunity to observe unit operations, manufacturing techniques
and quality management systems in rubber and plastics based industries.
 To provide opportunity to observe unit operations, manufacturing techniques
and quality management systems in paint manufacturing industries.

A
R
U
EN Y
EP
D TR
Course Title : PST 301 1.0 Polymer Blends & Composites
Number of lecture hours : 15 AR IS
M
Number of Tutorial hours : 3
EW HE

Lecturer in Charge : Visiting Lecturer


AY C
I J OF
SR T

Objectives:
F N

 To teach basic phase separation concept in polymer blends and composites


O ME

 Learn ways of improving the compatibility of the components in polymer


TY T

blends/composites
SI AR

 To deliver the structure – property relationship of polymer composites/blends


ER EP

 To explore various types of polymer blend/composites available in the polymer filed


D

Course content:
IV

1. Introduction to polymer blends and composites


N

Definitions, benefits and problems of blends/composites over conventional


U

polymers, phase behavior and phase separation in polymer blends (also briefly
review the thermodynamics of mixing), phase diagrams, rheology and morphology
of polymer blends
(3h)
2. Ways of overcoming phase separation
Theoretical aspects of interfaces (surface energies and interfacial tension),
determination of interfacial parameters, compatibilization by addition of a
compatibilizer, reactive compatibilization of polymer blends (direct covalent
crosslinking, graft copolymer formation, covalent crosslinking mediated by an
activating agent, covalent crosslinking mediated by a coupling agent, and ionic
interactions)
(4h)

Page 27 of 41
3. Properties and performances of polymer blends
Mechanical properties (tensile strength, tensile modulus, elongation, toughness,
compressive strength, rigidity, fracture mechanics), thermal properties,
flammability, electrical and optical properties
(2h)
4. Natural polymer blends and composites
Blends and composites based on starch, cellulose and natural polymers
(1h)
5. Fiber reinforced composites
Reinforcing mechanism, types of fiber reinforces composites and their preparation
methods.
(1h)
6. Biodegradable composites
Starch-based, polylactide -based, natural rubber/clay based
(1h)
7. Polymer nanocomposites
Advantages over micro and macro scale composites, effect of particle size on

A
R
properties, preparation and advantages of commercially available polymer

U
EN Y
nanocomposites, future trends

EP
D TR
AR IS (2h)
8. Role of polymer blends’ technology in polymer recycling
M
(1h)
EW HE
AY C

Learning outcomes:
I J OF

Students will be able to understand


 challenges in making polymer blends/composite
SR T
F N

 ways to overcome above challenges


O ME

 why composites/blends have superior properties compared to their individual


TY T

counterparts and how they contribute to property improvement


SI AR

 advantages of nanocomposites over conventional composites


ER EP
D

Method of assessment:
IV

End of semester 1h theory paper


N
U

References:
1. Polymer blends handbook, Volume1, L. A. Utracki, ISBN-10: 1402011105, ISBN-
13: 978-1402011108
2. Biodegradable polymer blends and composites from renewable resources, Long
Yu, ISBN: 978-0-470-14683-5

Page 28 of 41
Course Title : PST 307 1.0 Introduction to Die and Mold Designing
Number of lecture hours : 15
Number of Tutorial hours : 3
Lecturer in Charge : Visiting Lecturer

Objectives:
 To identify basic concepts in designing dies and moulds for polymer processing.
 To relate material properties and product requirements to the design features in dies
and moulds.
 To identify and product defects related to die and mould design.

Course content:
1. Product designing and process selection
Basic requirements in process selection based on type and grade of polymer, shape,
size and design features of the product and production scale. Identification of main
requirements in products conducive to each processing technique.

A
R
(3h)

U
EN Y
2. Injection Mould designing

EP
D TR
Basic design procedure to satisfy product and material requirements. Function and
AR IS
essential design features in injection mould components such as sprue, runners and
M
gates, Standard mould set with guide bars, guide sleeves and other guiding
EW HE

elements, Ejector pins and special components for ejection, Ejector set guiding
AY C

elements, Core pins, Core moving elements, Cold runner system components, Hot
I J OF

runner system components, Fastening and closing elements, elements for lifting the
mould.
SR T
F N

(4h)
O ME

3. Types of extruder dies


TY T

Sheet extrusion dies, flat-film and blown-film dies, pipe and tubing dies, profile
SI AR

extrusion dies; and co-extrusion dies


ER EP

(2h)
D

4. Extrusion Die designing


Basic design procedure to satisfy product and material requirements. Function and
essential design features in extrusion die components such as the manifold, die
IV

land, choke bar, dekle rods, die lips, and mandrels.


N
U

(3h)
5. Processing defects of injection moulded and extruded products
Short shots, flashing, shrinkage, sink marks and warping of injection moulded
products. Die swell, warping, melt fracture, shark skin, orange peel and
Bambooing of extruded products.
(3h)

Learning Outcomes:
 Be able to identify basic concepts in designing dies and moulds for polymer
processing.
 Be able to provide a description, rationalization of polymer processing techniques
 Be able to explain product designing process

Page 29 of 41
Method of assessment:

End of semester 1h theory paper

References:
1. How to make injection moulds – Menges / Michaeli / Mohren
2. Extrusion Dies for Plastics and Rubber: Design and Engineering Computations,
Walter Michaeli, Hanser Publishers, Jan 1, 2003 - Technology & Engineering

Course Title : PST 303 1.0: Polymer Coatings and Paint Industry
Number of lecture hours : 15
Number of Tutorial hours : 3
Lecturer in Charge : Dr. Dilru Ratnaweera

A
R
U
EN Y
Objectives:

EP
D TR
 Overview of the basic concepts of paints and polymer coatings
AR IS
 Describe the functions of different components in coatings/paints
M
 Introduce basics of formulation of paints/coatings
EW HE

 Recent advancements and future directions in polymer coatings/paints industry


AY C
I J OF

Course content:
1. Introduction to surface coatings and paints
SR T
F N

Types of coatings, classification, major ingredients of paints (pigments, resin,


O ME

solvent, additives, and driers) and their functions, solvent based and water based
TY T

paints
SI AR

(1h)
ER EP

2. Methods of making polymeric coatings


D

Applying with brush, dip coating, spin coating, doctor blading, spraying
(1h)
3. Pigments
IV

Different types of pigments (color pigments, hiding pigments, barrier pigments,


N
U

inhibitive pigments, reinforcing pigments, extender pigments, and sacrificial


pigments), physics behind the role of pigments
(1h)
4. Pigment dispersion
Wetting of pigments and wetting agents, dispersion of pigments and techniques
used in dispersion, stabilization of pigments (electrostatic and steric stabilization
methods), states of pigment dispersions, pigment dispersants (polymeric
dispersants (anchoring groups and polymer chains), surfactants, anchoring
mechanisms of dispersants to pigments), problems due to poor stabilization of
pigments (flooding and floating of pigments, poor color strength, syneresis, poor
gloss level)
(2h)
5. Resins
Different curing mechanisms for various resins, curing agents, alkyd resins and
their modifications, epoxy resins, polyurethane resins and their modifications,
Page 30 of 41
acrylic resins, silicon coatings, energy curable resins (free radical curing and
cationic curing)
(3h)
6. Other ingredients and their functions
Solvents, anti skimming agent, anti settling agents, anti floating and anti-flooding
agents, flow controlling and leveling agents, deforming agents, fungicides and
preservatives
(2h)
7. Formulation
Volume of solid, pigment volume concentration, critical pigment volume
concentration, formulating paints, dry film thickness, wet film thickness
(2h)
8. Coating and paints testing
Adhesion testing (cross cut test, tensile method, knife cutting method, blister
method), cohesion testing, impact effect on coating, pigment stability tests (rub
test, pour out test)
(2h)
9. Recent advancements and future directions in paints/coatings

A
R
Conjugated polymer coatings for light harvesting, structured coatings from block

U
EN Y
polymers, super hydrophobic and super oliophobic coatings, self healing and

EP
D TR
stimuli responsive coatings AR IS
(1h)
M
EW HE

Learning outcomes:
AY C

 Be able to describe important components of paints/surface coatings.


I J OF

 Be able to describe major testing methods used to check the quality of coatings.
 Be able to describe ways to overcome challenges during formulating paints
SR T
F N

 Be able to understand the novel trends in polymer coatings


O ME
TY T

Method of assessment:
SI AR
ER EP

End of semester 1h theory paper


D

References:
IV

1. Paint and surface coatings theory and practice (2nd edition), R. Lambourne and T. A.
N

Strivens, ISBN 1-8557-3348 x


U

2. Coating materials and surface coatings, Arthur A. Tracton, ISBN 1-4200-4404-4


3. Surface Coatings: Science and Technology (2nd edition), Swaraj Paul , ISBN: 978-0-
471-95818-5

Page 31 of 41
Course Title : PST 305 1.0 Laboratory Practical
Number of practical hours : 45 (15 days)
Lecturer in Charge : Dr. K. M. Thilini D. Gunasekara

Allocation of marks:

Item Marks
Attendance (80 % required) 10
Laboratory reports 20
Pre-lab / Post-lab questions 20
Assessments 20
Final exam 30
Total 100

List of Experiments:

A
R
U
EN Y
1. Experiment 1: The determination of zinc, calcium and magnesium in rubber

EP
D TR
compounds using EDTA AR IS
Objectives:
M
- To determine metal cations of a given NR sample
EW HE
AY C

2. Experiment 2: Experimental determination of latex properties -total solid content


I J OF

(TSC) and dry rubber content (DRC)


Objectives:
SR T
F N

- Understand how to determine the total solid content (TSC) of given NR latex
O ME

- Understand how to determine the dry rubber content (DRC) of given NR


TY T

latex
SI AR
ER EP

3. Experiment 3: Manufacture of surgical gloves using coagulant dipping method


D

Objectives:
- To get the basic knowledge about dipped products of NR latex
- To gain hands on experience of manufacturing a glove.
IV
N
U

4. Experiment 4: Determination of Mechanical stability (MST) of given NR latex


Objectives:
- Understand how to determine the Mechanical stability (MST) of given NR
latex

5. Experiment 5: Experimental determination of volatile fatty acid number (VFA)


Objectives:
- Learn how to determine volatile fatty acid number of given NR latex
- Understand the importance of VFA

6. Experiment 6: Experimental determination of KOH number and alkalinity of a given


NR sample
Objectives:
- Learn how to determine KOH number and alkalinity of a given NR sample

Page 32 of 41
7. Experiment 7: Study of Brookfield Digital Viscometer
Objectives:
- Measure the viscosity of a fluid using rotational viscometer,
- Determine the viscosity of different liquids.

8. Experiment 8: Determination of the molar mass of a polymer using viscosity


measurements
Objectives:
- Measure the viscosity of a fluid using Ubbelohde viscometer

9. Experiment 9: Determination of carboxylic acid and ester


Objectives:
- Learn how to determine the Acid number and the saponification value of a
given resin

10. Experiment 10: Universal Testing Machine


Objectives:
- To Identify the functions of Universal Testing Machine

A
R
U
EN Y
11. Experiment 11: The Condensation Polymerization of Phenol and Formaldehyde :

EP
D TR
Bakelite AR IS
Objectives:
M
- To gain an understanding of preparation of synthetic polymers
EW HE
AY C

12. Experiment 12: Polymer analysis by FTIR, UV-Vis


I J OF

Objectives:
SR T

- To gain experience with FTIR and UV-Vis instrumentation


F N
O ME

13. Experiment 13: A Silly Polymer


TY T

Objectives:
SI AR

- To cross-link a polymer and observe the changes in the physical properties as


ER EP

a result of this cross-linking


IV D
N
U

Page 33 of 41
Course Title : PST 314 2.0 Industrial Management and Marketing
Number of lecture hours : 30
Number of Tutorial hours : 2
Lecturer in Charge : Dr. Pahan Godakumbura

Objectives:
 Prepare and shape students to managerial post to cater current industrial needs.
 Enhance the practical, technical as well as the theoretical knowledge in managing
people with specialized skills.
 Enhance the problem solving skills in relation to the company survival, growth and
development.
 Increase the demand in graduates to the research and development field in industry

Course Content:
1. Introduction to Management
Managerial roles, managerial levels, Characteristics of a good manager, Evolution

A
R
of management theory: The Scientific approach, The Classical approach,

U
EN Y
Behavioral approach, Management functions, Planning, Organizing, Leading,

EP
D TR
Controlling, Organization behavior
AR IS
(8h)
M
2. Human Resources Management
EW HE

Staffing, Benefits of human resources planning, the process of staffing, Job


AY C

analysis, Job description, Job specification, Recruitment and Retention, Career


I J OF

planning, Performance appraisal, Employee training and development, Training


techniques
SR T
F N

(6h)
O ME

3. Principles of Marketing management


TY T

Marketing concept (7 Ps), Tools of marketing, Product life cycles, Market Search,
SI AR

Industry Analysis on Porters Five forces model, Boston matrix


ER EP

(8h)
D

4. Production / Operation and Lean Management


 Steps in operational management: Selecting, Designing, Operating,
Controlling, Updating, Competition, changes in organizational objectives and
IV
N

personnel
U

 Steps in Production Planning and Control: Routing, scheduling, dispatching,


Inspection and Follow up
 Functions of production operations management: Design and Development,
Capital equipment, Site selection, Facilities layout, Work design and
Measurement, Purchasing/Materials Management, Inventory control
(6h)
5. 5S concepts
(2h)

Method of assessment:
Assessments 1: 15%
1. Market search, documentation and Oral presentation (5 to 7 min)
Identify a product and does a Market search. Eg “Beverage: any product item, coca
cola”.

Page 34 of 41
 Market search is a process of gathering information and analyzing about the
market or customers to find out the needs, market size and competition.
 Documentation: Based on your findings, predict the future of the product. (How
will it go for next 3 years, demand and supply etc...)
 Assignment requirement: Minimum 5 pages (single side), single spaced, Font:
TNR 12, can include figures, tables and properly reference them.
 No copying with each other, or plagiarisms

Survey design
1. Identify and study about a market product thoroughly.
2. Collect information/data by consulting managers and consumers.
3. Process information and analyze the current situation.
4. Predict future trends based on collected data.
5. Provide outcomes, benefits and recommendation for the predicted product.

Assessment 2: 10%
Present your market search (5 to 7 min)

A
R
Assessment 3:

U
EN Y
EP
D TR
Final exam: 75% with
Condition: Two Assessments must be completed to sit the final exam
AR IS
M
EW HE

References:
1. Management (sixth edition), James A. F. Stoner
AY C

2. Management Theory and Practice, J. S. Chandan


I J OF

3. Fundamentals of Management, (core concepts and applications) by Ricky W. Griffin


SR T
F N
O ME
TY T
SI AR
ER EP
IV D
N
U

Page 35 of 41
Course Title : PST 310 1.0 Environment and Polymer Industry
Number of lecture hours : 15
Number of Tutorial hours : 1
Lecturer in Charge : Dr. S.D.M. Chinthaka

Objectives:
 Understanding major environmental issues and their relationship with the polymer
industry.
 Provide the comprehensive understanding of the stability of polymeric materials in
the environment.
 Rationalize the energy as the major consideration for polymer recycling.
 Explore the significance of recycling of plastics for the waste reduction
 Understanding the various recycling options available for used plastic materials

Course contents:
1. Local and global environmental issues, contribution from polymer industry to the

A
R
global and local environmental issues.

U
EN Y
(1h)

EP
D TR
2. Common polymeric materials and the basic impact of their synthesis and usage on the
AR IS
environment.
M
(2h)
EW HE

3. Polymer and the energy, the unique relationship between polymer industry and the
AY C

energy, calorific value as the determining factor for polymer recycling.


I J OF

(2h)
SR T

4. Usage of plastics in packaging, agriculture, coating and in textile industry and their
F N

recycling potential.
O ME

(5h)
TY T

5. Effect of the environment factors on the stability of polymeric materials.


SI AR

(2h)
ER EP

6. Polymer recycling: potential, methods and options.


D

(3h)
Learning outcomes:
 Students will be able understand the global and local environmental issues and the
IV
N

degree of their relationship to polymer industry.


U

 Students will be able to understand the effect of environmental factors on the stability
of polymeric materials and how to stabilize plastics against environmental factors.
 Students will be able to determine whether recycling of polymers is economical over
the use of virgin polymers based on calorific values.
 Students will be able to understand the recycling potential of plastics used in various
industries.
 Students will be able to understand the techniques used to segregate various plastics
in consumer products.

Method of assessment:

End of semester 1h theory paper

Page 36 of 41
References:
1. Anthony L. Andrady, Plastics and the Environment, Wiley Interscience, Hoboken,
New Jersey.
2. Stanley E. Manahan, Environmental Chemistry, 7th Edition, CRC press, Boca Raton,
Florida.

Course Title : PST 313 1.0 Introduction to Engineering Materials


Number of lecture hours : 15
Number of Tutorial hours : 1
Lecturer in Charge : Dr. Nilwala Kottegoda

Course content:
Structure, properties and applications of

A
R
i. Ceramics

U
EN Y
ii. Metals

EP
D TR
iii. Modern functional polymers
AR IS
iv. Composites of ceramics, polymers and metals and their advanced derivatives
M
v. Smart materials
EW HE

vi. Liquid crystals


AY C

vii. Biomaterials and their composites and derivatives


I J OF

Learning Outcomes:
SR T
F N

By the end of the module, students will be able to:


O ME

 Discuss the structural characteristics of ceramics, metals, modern polymers,


TY T

composites of ceramics, polymers and metals and their advanced derivatives, smart
SI AR

materials, liquid crystals, biomaterials and their advanced derivatives.


 Explain the properties of ceramics, metals, modern polymers, composites of ceramics,
ER EP

polymers and metals and their advanced derivatives, smart materials, liquid crystals,
D

biomaterials and their advanced derivatives.


 Predict structure property relationships in ceramics, metals, modern polymers,
IV

composites of ceramics, polymers and metals and their advanced derivatives, smart
N
U

materials, liquid crystals, biomaterials and their advanced derivatives.


 Discuss the industrial applications of the ceramics, metals, modern polymers,
composites of ceramics, polymers and metals and their advanced derivatives, smart
materials, liquid crystals, biomaterials and their advanced derivatives.
 Gain fundamental understanding on how certain basic materials such as polymers,
ceramics, metals and biomaterials are combined together to produce advanced
functional materials.
 Design functional materials to achieve a given property or combined properties.

Method of Assessment:

End of semester 1h theory examination

Page 37 of 41
Course Title : PST 314 1.0 Rubber Materials
Number of lecture hours : 15
Number of Tutorial hours : 1
Lecturer in Charge : Dr. Susantha Siriwardena

Objectives:
 To provide basic knowledge on Natural rubber manufacturing processes, available
types, their properties and possible modifications
 To demonstrate relationship between structure and properties of natural rubber
and synthetic elastomers
 To provide basic knowledge on available rubbery materials for industrial applications

Course content:
1. Introduction:
Special features of rubbery materials, Rubber and elastomers
(1h)

A
R
2. Natural Rubber (NR) manufacturing process:

U
EN Y
Types and grades: Sheet rubber, Crepe rubber; Technically specified rubber;

EP
D TR
modified grades of NR, Different raw rubber properties between different types
AR IS
and grades of NR; special features of NR, effects of non-rubbers present on the
M
properties of NR
EW HE

(3h)
AY C

3. Quality parameters of NR:


I J OF

Dirt, ash, plasticity (Po); Plasticity Retention Index (PRI); Volatile Matter content
(VM), Nitrogen content
SR T
F N

(2h)
O ME

4. Properties of NR:
TY T

Chemical properties, physical properties, electrical properties, swelling index,


SI AR

crystallinity, Solubility parameters thermal properties viscoelastic properties


ER EP

(2h)
D

5. Synthetic rubber:
General purpose specialty elastomers, structure-property relationship, main
characteristics
IV

BR, SBR, IR, IIR, NBR, EPDM, EPR, silicone Rubber


N
U

(5h)
6. Industrial applications:
Selection of different rubbers and synthetic elastomers for different industrial
applications
(2h)
Learning outcomes:
 be able to explain characteristic features of rubber materials
 be able to explain the manufacturing processes of different types of rubber
 be able to compare the different properties of different grades of natural rubber
the importance of following the recommended procedures in the manufacturing
process
 be able to suggest the remedial measures to overcome day to day problems
found in the raw rubber manufacturing process

 be able to explain the special characteristics of natural rubber


Page 38 of 41
 be able to compare the different properties of different types of synthetic rubbers
 be able to suggest suitable rubber types for particular industrial applications

Method of assessment:

End of semester 1h theory paper (80%)


Two class tests (10%)
One assignment (10%)

References:
1. Basic chemistry and Technology of Industrial Polymers, Kanthappu Subramanium,
2012.
2. Handbook of rubber technology: volume 1, Natural and synthetic rubber and
technology of vulcanization by J.M. Martin,W. K. Smith; edited by S. C.
Bhatia, CB Publishers, 2007
3. Rubber Technology: Compounding and Testing for Performance, ed. John S.
Dick, Hanser publishers, 2001

A
4. Handbook of rubber technology: Volume 2, raw rubber processing, eds.

R
Tillkeratna, K. Nugawela, A and Seneviratne, G., Rubber Research Institute of

U
EN Y
EP
Sri Lanka, 2007

D TR
AR IS
M
EW HE
AY C
I J OF

Course Title : PST 309 3.0 Industrial Projects


SR T

Lecturer in Charge : Dr. M. A. B. Prashantha


F N
O ME
TY T
SI AR

Duration:
30 days
ER EP
D

Objectives:
 To expose students to industrial atmosphere to gain an insight and understanding of
IV

operations and management system of organization.


N

 To improve the ability to relate the lecture room knowledge to industrial practice.
U

 To get a feel of the work environment.


 To expose students to the industrial responsibilities and ethics.
 To develop skills in relation to:
i) interpersonal and problem solving.
ii) research and reporting.
iii) professional competence
 To prepare for employment after graduation.

Commencement:

At the beginning of second semester

Guidelines of training:

Page 39 of 41
Organization has to design the training schedule to achieve the objectives under following
topics.

Production process Operational techniques


Material Management system Quality assurance system
Quality controlling systems and type of testing Lean manufacturing practices
Waste controlling Fire protection
New challenges
Management practices and experience in management meeting

Evaluation:
Student should submit an approved report on training experience by the organization and
conduct a 15 minutes presentation on his training experience. Report and the presentation will
be evaluated.

**********

A
R
U
EN Y
EP
D TR
AR IS
M
EW HE
AY C
I J OF
SR T
F N
O ME
TY T
SI AR
ER EP
IV D
N
U

Page 40 of 41

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