1) 2-Butanona(1)/n-Heptano(2) Takeo et al Fluid Phase Equilibria 3 (1979) 123-131, evaluado por Eubank et al, J. Chem. Eng.

T = 45 C = 318.15 K 1 Pa = 7.5*10-3 mmHg; 1 mmHg = 133.2 Pa = 0.1332 kPa

x1 y1 P/kPa P/torr
0 0.0000 15.329988 115.09
0.0151 0.0951 16.741908 125.69
0.038 0.1999 18.552096 139.28
0.0738 0.3130 20.96568 157.4
0.1008 0.3712 22.446864 168.52
0.1416 0.4348 24.24906 182.05
0.2 0.4950 26.145828 196.29
0.2764 0.5542 28.006632 210.26
0.3617 0.5971 29.334636 220.23
0.4962 0.6513 30.76254 230.95
0.5791 0.6807 31.296672 234.96
0.7008 0.7289 31.825476 238.93
0.753 0.7547 31.889412 239.41
0.8027 0.7819 31.832136 238.98
0.9048 0.8608 31.130172 233.71
0.9528 0.9185 30.350952 227.86
0.9817 0.9649 29.658312 222.66
1 1.0000 29.072232 218.26

2) Acetone(1)/Ethanol(2)_at 50 deg C. Experimental data from Chaudhry, Van Ness, and Abbott data
T = 50 C
x1 y1 P/kPa
0 0 29.484
0.0532 0.23061 36.484
0.1009 0.35644 41.62
0.1759 0.48343 48.173
0.338 0.63726 58.577
0.4072 0.68162 62.032
0.488 0.7263 65.612
0.5062 0.73569 66.347
0.5853 0.77485 69.426
0.6526 0.80718 71.842
0.7318 0.84559 74.467
0.8146 0.88782 77.019
0.8873 0.92809 79.16
0.9422 0.96138 80.62
1 1 82.029

3) VLE for Acetone(1)/Methanol(2) at 372.8 K. Experimental data of Walsh, M.E. Thesis, 1974
T = 372.8 K
x1 y1 P/kPa x1 y1 P/kPa
1 1 365.1 0 0 349.9
0.943 0.927 375.8 0.042 0.068 359.9
 0.896 0.858 384 0.096 0.137 372
0.805 0.76 393.7 0.194 0.25 386.8
0.699 0.655 399.9 0.256 0.301 392.7
0.579 0.569 403.7 0.338 0.372 399.9
0.501 0.509 405.4 0.407 0.428 403.7
0.407 0.428 403.7 0.501 0.509 405.4
0.338 0.372 399.9 0.579 0.569 403.7
0.256 0.301 392.7 0.699 0.655 399.9
0.194 0.25 386.8 0.805 0.76 393.7
0.096 0.137 372 0.896 0.858 384
0.042 0.068 359.9 0.943 0.927 375.8
0 0 349.9 1 1 365.1

4) VLE for Acetone(1)/Methanol(2) at 422.6 K. Data of Wilsak, Campbell, & Thodos: FPE, 28, 13-37 (1986)
x1 y1 P/kPa x1 y1 P/kPa
1 1 1121.4 0 0 1366.5
0.889 0.855 1196.6 0.04 0.046 1382
0.853 0.8 1224.5 0.105 0.116 1394.1
0.796 0.745 1253.1 0.196 0.195 1399.3
0.673 0.618 1311.4 0.288 0.284 1396.5
0.571 0.521 1349.3 0.432 0.416 1380.7
0.432 0.416 1380.7 0.571 0.521 1349.3
0.288 0.284 1396.5 0.673 0.618 1311.4
0.196 0.195 1399.3 0.796 0.745 1253.1
0.105 0.116 1394.1 0.853 0.8 1224.5
0.04 0.046 1382 0.889 0.855 1196.6
0 0 1366.5 1 1 1121.4

5) Acetona (1) / Ethylene Glycol (2) at 50 deg C. Experimental data from Loehe, Van Ness & Abbott, J. Chem. Eng. Data, Vol. 2
x1 y1 P/kPa
0 0 0.114 OJO: Excess thermodynamic functions for ternary systems. 7. Tota
0.02 0.9861 7.692 Joseph R. Loehe, Hendrick C. Van Ness, Michael M. Abbott, J. Che
0.0242 0.9884 8.894
0.0293 0.9903 10.852
0.0357 0.9919 12.703
0.0388 0.9925 13.795
0.0494 0.9939 17.165
0.0678 0.9953 22.38
0.0729 0.9956 23.837
0.0988 0.9966 30.255
0.1485 0.9975 39.91
0.1987 0.9979 47.007
0.249 0.9982 52.232
0.2986 0.9983 56.083
0.29861 0.9983 56.067
0.2991 0.9983 56.134
0.3484 0.9985 58.968
 0.3983 0.9986 61.245
0.4485 0.9986 63.064
0.4984 0.9987 64.55
0.4987 0.9987 64.586
0.4991 0.9987 64.548
0.5478 0.9988 65.822
0.5485 0.9988 65.837
0.5985 0.9988 67.023
0.5991 0.9988 67.01
0.6486 0.9989 68.157
0.6492 0.9989 68.161
0.6987 0.9989 69.31
0.6993 0.9989 69.312
0.6995 0.9989 69.317
0.7491 0.999 70.538
0.7494 0.999 70.534
0.7986 0.9991 71.911
0.7994 0.9991 71.909
0.8485 0.9992 73.533
0.8495 0.9992 73.543
0.8993 0.9993 75.558
0.8996 0.9993 75.597
0.9495 0.9996 78.197
0.9501 0.9996 78.291
0.9795 0.9998 80.209
0.9799 0.9998 80.277
1 1 81.83

6) Acetone(1)/Water(2)__at 50 deg C. Experimental data from Loehe, Van Ness & Abbott, J. Chem. Eng. Data, Vol. 26, p. 178-
x1 y1 P/kPa
0 0 12.313
0.0347 0.6381 32.624
0.0598 0.7204 41.78
0.1024 0.7771 51.632
0.1518 0.8056 58.041
0.2025 0.8211 61.897
0.2531 0.831 64.422
0.3028 0.8381 66.184
0.3522 0.8438 67.606
0.4018 0.8488 68.803
0.4519 0.8537 69.9
0.4637 0.8548 70.147
0.5017 0.8586 70.932
0.5169 0.8601 71.216
0.5706 0.8659 72.298
0.6248 0.8725 73.408
0.6796 0.8804 74.575
 0.7371 0.8904 75.862
0.793 0.9027 77.178
0.8497 0.919 78.576
0.9003 0.9382 79.798
0.9505 0.9641 80.919
1 1 81.822

7) Acetonitrile (1) / Ethylene Glycol (2)_at 50 deg C. Experimental data from M.A. Villamanan, A.J. Allawi, H.C. Van Ness, Int. D
x1 y1 P/kPa

0 0 0.104
0.0206 0.9716 3.358
0.0303 0.98 4.806
0.0403 0.9845 6.184
0.0506 0.9873 7.543
0.0735 0.9908 10.359
0.099 0.9928 12.994
0.1485 0.9946 17.208
0.1985 0.9956 20.324
0.2487 0.9962 22.678
0.295 0.9965 24.318
0.3485 0.9968 25.728
0.3984 0.997 26.709
0.4505 0.9972 27.499
0.4984 0.9973 28.051
0.4985 0.9973 28.071
0.5484 0.9974 28.528
0.5985 0.9975 28.944
0.6486 0.9976 29.32
0.6986 0.9977 29.67
0.7489 0.9978 30.034
0.799 0.9979 30.451
0.8494 0.9981 30.939
0.8992 0.9984 31.567
0.9498 0.9989 32.495
0.98 0.9994 33.255
1 1 33.9

8) Acetone(1)/Chloroform(2)__at 50 deg C. Experimental data from Walsh, M.E. Thesis, 1974

x1 y1 P/kPa P/torr
0 0 69.269368 520.0403
0.0081 0.0038 68.981616 517.88
0.016 0.0077 68.71122 515.85
0.0281 0.014 68.272992 512.56
0.0412 0.0214 67.824108 509.19
0.0532 0.0286 67.269996 505.03
0.0726 0.0413 66.725208 500.94
 0.093 0.0559 66.04722 495.85
0.1338 0.0892 64.785816 486.38
0.1818 0.1353 63.347256 475.58
0.2483 0.2105 61.722216 463.38
0.3094 0.289 60.83244 456.7
0.3545 0.3509 60.600672 454.96
0.3982 0.4127 60.637968 455.24
0.4346 0.4645 60.920352 457.36
0.467 0.5102 61.361244 460.67
0.4968 0.5516 61.914024 464.82
0.5215 0.5852 62.28432 467.6
0.55 0.6228 63.024912 473.16
0.5806 0.6617 63.937332 480.01
0.6121 0.6999 64.984284 487.87
0.652 0.7454 66.436164 498.77
0.6886 0.784 67.869396 509.53
0.7318 0.8258 69.68358 523.15
0.7937 0.8784 72.146448 541.64
0.8532 0.9215 74.952972 562.71
0.8982 0.9494 77.057532 578.51
0.9305 0.9673 78.540048 589.64
0.9546 0.9795 79.66692 598.1
0.972 0.9877 80.471448 604.14
0.985 0.9935 81.021564 608.27
0.9934 0.9972 81.443808 611.44
0.9981 0.9992 81.670248 613.14
1 1 81.8128386 614.2105

9) Acetone(1) /1,4-Dioxane(2)__a 50.Experimental data from Loehe, Van Ness & Abbott, J. Chem. Eng. Data, Vol. 26, p. 178-1
x1 y1 P/kPa
0 0 15.682
0.0293 0.1752 18.451
0.0515 0.2722 20.543
0.0552 0.2862 20.762
0.101 0.4251 24.634
0.1043 0.4331 24.907
0.1452 0.5184 28.087
0.1547 0.5351 28.768
0.1917 0.5917 31.53
0.2074 0.6124 32.607
0.2399 0.6505 34.916
0.2566 0.668 36
0.2878 0.6976 38.137
0.306 0.7133 39.328
0.3365 0.7374 41.31
0.355 0.7509 42.485
0.3852 0.7713 44.419
 0.4046 0.7834 45.615
0.4343 0.8009 47.48
0.4506 0.8099 48.467
0.4546 0.8121 48.637
0.4533 0.8114 48.65
0.4844 0.8275 50.546
0.5005 0.8355 51.509
0.503 0.8367 51.677
0.5051 0.8377 51.708
0.546 0.8565 54.294
0.5504 0.8584 54.528
0.5556 0.8606 54.765
0.6009 0.8794 57.536
0.6062 0.8815 57.799
0.6507 0.8984 60.517
0.6564 0.9005 60.795
0.7007 0.916 63.499
0.7065 0.9179 63.809
0.7487 0.9317 66.358
0.7502 0.9322 66.472
0.7985 0.9469 69.374
0.8 0.9474 69.466
0.8481 0.9611 72.405
0.8496 0.9616 72.498
0.8984 0.9747 75.495
0.8998 0.9751 75.558
0.9488 0.9876 78.658
0.9493 0.9877 78.631
0.975 0.994 80.254
1 1 81.827

10) Acetonitrile(1)/Ethanol(2)_at 50 deg C. Experimental data from Wilson, Patel, Abbott, and Van Ness
x1 y1 P/kPa
0 0 29.496
0.0518 0.16221 33.343
0.1418 0.30879 38
0.2169 0.3786 39.878
0.3163 0.44131 41.203
0.4065 0.48517 41.952
0.4864 0.5203 42.313
0.5642 0.55476 42.395
0.6391 0.59105 42.239
0.7063 0.62886 41.851
0.7923 0.68999 40.854
0.8724 0.76953 39.204
0.95 0.8861 36.499
1 1 33.864
11) Benceno(1)/n-Heptano(2) at 80 C.Experimental data from Barker J. A., Austral. J. Chem., 1953, 6, 207-210

x1 y1 P/kPa T= 353.15
0 0 57.077
0.0464 0.0988 60.6110151
0.0861 0.1729 63.494778
0.2004 0.3473 71.2448072
0.2792 0.4412 75.9257556
0.3842 0.5464 81.7972727
0.4857 0.6304 86.6808711
0.5824 0.7009 90.6245467
0.6904 0.7759 94.4962283
0.7842 0.8384 97.2946648
0.8972 0.9149 99.7864599
1 1 101.008

12) Benzene_Propylene at 25 deg C.Experimental data from Yamamoto et al, Fluid Phase Equilibria 46 (1989) 53-58

(OJO: El compuesto 1, mas volatil es el propileno ==> Favor invertir el orden!!)

x1 y1 P/bar x(prop) y(prop) P/bar

0 0 11,566 1 1 11566
0.0491 0.0019 10,948 0.9509 0.9981 10948
0.0927 0.0034 10,428 0.9073 0.9966 10428
0.1735 0.006 9,523 0.8265 0.994 9523
0.2556 0.0083 8.83 0.7444 0.9917 8.83
0.3568 0.011 7.87 0.6432 0.989 7.87
0.4621 0.0148 6,827 0.5379 0.9852 6827
0.5748 0.0199 5.69 0.4252 0.9801 5.69
0.6839 0.0254 4.66 0.3161 0.9746 4.66
0.7769 0.0368 3,538 0.2231 0.9632 3538
0.8633 0.0565 2,321 0.1367 0.9435 2321
0.9227 0.0899 1,477 0.0773 0.9101 1477
1 1 0.1269 0 0 0.1269

13) Piridina(1)/Tetracloroetileno(2) a 60 C.Fried V., P. Gallant y G.B. Schneier (1967) J. of Chem. & Eng. Data, 12: 504-508

x1 y1 P/kPa P/torr
0 0 12.81 96.09
0.0652 0.1354 13.95 104.65
0.0837 0.1654 14.16 106.21
0.1628 0.2727 15.07 113.06
0.2115 0.3225 15.55 116.6
0.2465 0.3507 15.75 118.11
0.35 0.4307 16.29 122.14
0.4462 0.4985 16.60 124.52
 0.5035 0.5348 16.75 125.66
0.5546 0.5655 16.81 126.08
0.6209 0.6113 16.82 126.16
0.6578 0.6357 16.80 125.98
0.6912 0.66 16.73 125.48
0.7357 0.6957 16.63 124.76
0.782 0.7362 16.49 123.64
0.8567 0.8092 16.12 120.92
0.92 0.8815 15.74 118.04
0.9525 0.9248 15.41 115.61
1 1 14.84 111.31

14) CHCl3(1)/n-Heptano(2) @ 50 C. Experimental data from Walsh, M.E. Thesis, 1974.

x1 y1 P/kPa
0 0 18.9300 323.15
0.0181 0.0842 20.3450
0.0359 0.1557 21.6689
0.0542 0.2197 23.0048
0.0785 0.2929 24.7407
0.1091 0.3701 26.8458
0.1698 0.4883 30.9855
0.2576 0.6077 36.4170
0.3402 0.6873 41.1433
0.407 0.7374 44.7044
0.4621 0.7721 47.4481
0.5082 0.7977 49.6413
0.548 0.8178 51.4811
0.5811 0.8333 52.9557
0.6097 0.8461 54.1929
0.6324 0.8558 55.1662
0.6532 0.8645 56.0394
0.6757 0.8736 57.0954
0.7016 0.8838 58.1353
0.7318 0.8954 59.3032
0.7612 0.9064 60.4604
0.7961 0.9194 61.8016
0.8338 0.9334 63.2229
0.8712 0.9474 64.6374
0.9172 0.9651 66.3426
0.9591 0.9822 67.8998
0.9722 0.9877 68.3878
0.9806 0.9913 68.7037
0.9872 0.9943 68.9424
0.9924 0.9966 69.1264
0.9967 0.9985 69.3224
0.9986 0.9994 69.3397
1 1 69.3880
15) CHLOROFORM / METHANOL at 50 deg C. Experimental data from Walsh, M.E. Thesis, 1974
x1 y1 P/kPa
0 0 55.62
0.0038 0.01316 56.0221
0.0092 0.03123 56.5527
0.0166 0.05483 57.3753
0.0247 0.07924 58.2366
0.036 0.11106 59.4672
0.0493 0.1455 60.9124
0.086 0.22675 64.7481
0.1297 0.30345 69.0557
0.1696 0.35983 72.6888
0.2047 0.40142 75.5965
0.2407 0.43805 78.255
0.2708 0.46489 80.2281
0.3 0.4882 81.9213
0.3355 0.51352 83.6359
0.3079 0.4941 82.356
0.3354 0.51346 83.6425
0.3709 0.53602 85.0971
0.4101 0.55827 86.3823
0.4571 0.58193 87.5315
0.508 0.60462 88.4568
0.574 0.63059 89.1567
0.655 0.65898 89.4474
0.7564 0.69309 89.1021
0.862 0.73817 86.9329
0.9495 0.8234 80.2241
0.9656 0.85722 77.5884
0.9749 0.88326 75.7152
1 1 69.31

16) Ciclohexano(1)/Benceno(2) @ 313.15 K. Experimental data from Lozano et al Fluid Phase Equilibria 110 (1995) 219-230
x1 y1 P/kPa
0 0 24.4
0.0504 0.0727 25.272
0.0822 0.114 25.605
0.157 0.2006 26.276
0.1998 0.2449 26.584
0.2656 0.3076 26.954
0.3213 0.3567 27.195
0.3736 0.4004 27.355
0.4232 0.4403 27.459
0.4504 0.4618 27.498
0.5005 0.5009 27.524
0.5242 0.5193 27.515
 0.5503 0.5395 27.502
0.6008 0.5791 27.427
0.651 0.6193 27.303
0.7014 0.6612 27.122
0.7517 0.7054 26.88
0.7989 0.7498 26.579
0.8489 0.8009 26.199
0.8981 0.8569 25.723
0.9519 0.9269 25.08
1 1 24.6

17) CO2(1)/Propane(2) at 277.59 K.Experimental data from Reamer, Sage, & Lacey, I&EC, Vol. 43, 2515-2520 (1951)
x1 y1 P/bar

0 0 5.447
0.0247 0.2056 6.895
0.0884 0.4676 10.342
0.1602 0.6036 13.79
0.2402 0.6864 17.237
0.3316 0.7431 20.684
0.4361 0.7876 24.132
0.5532 0.8309 27.579
0.6714 0.8688 31.026
0.7956 0.9102 34.474
0.9401 0.9702 37.921
1 1 39.059

18) Dietilcetona(1)/n-Hexano(2) ) a 65C.Experimental data from Smith et al (2003) p. 462

(OJO: El compuesto 1, mas volátil es el n-Hexano ==> Favor invertir el orden!!)
x1 y1 P/kPa xC6 yC6 P/kPa

0 0 90.2 1 1 90.2
0.063 0.049 91.78 0.937 0.951 91.78
0.248 0.131 88.01 0.752 0.869 88.01
0.372 0.182 81.67 0.628 0.818 81.67
0.443 0.215 78.89 0.557 0.785 78.89
0.508 0.248 76.82 0.492 0.752 76.82
0.561 0.268 73.39 0.439 0.732 73.39
0.64 0.316 66.45 0.36 0.684 66.45
0.702 0.368 62.95 0.298 0.632 62.95
0.763 0.412 57.7 0.237 0.588 57.7
0.834 0.49 50.16 0.166 0.51 50.16
0.874 0.57 45.7 0.126 0.43 45.7
1 1 29 0 0 29

19) 1,4 Dioxane (1) / Water (2)__at 50 deg C. Experimental data from Loehe, Van Ness; and Abbott . J. Chem. Eng. Data 1981
 x1 y1 P/kPa
0 0 12.337
0.0508 0.2823 16.266
0.1013 0.3884 18.543
0.1518 0.4432 19.906
0.1519 0.4433 19.911
0.2014 0.476 20.721
0.2021 0.4764 20.719
0.2517 0.4986 21.229
0.2522 0.4988 21.223
0.3019 0.515 21.54
0.302 0.5151 21.547
0.3519 0.5278 21.735
0.3522 0.5279 21.747
0.4021 0.5386 21.864
0.4022 0.5387 21.866
0.4519 0.5481 21.954
0.4523 0.5482 21.968
0.4761 0.5525 22.01
0.4995 0.5568 22.035
0.5015 0.5571 21.977
0.5022 0.5572 22.001
0.5344 0.5631 22.045
0.5488 0.5658 22.054
0.5918 0.5741 22.049
0.5984 0.5755 22.049
0.6483 0.5866 22.005
0.6501 0.587 22.007
0.6984 0.5999 21.908
0.7006 0.6005 21.895
0.7312 0.6104 21.781
0.7789 0.6296 21.509
0.859 0.6802 20.663
0.9495 0.811 18.304
1 1 15.678

20) Ethanol(1)/Chloroform (2)__at 50 deg C. Experimental data from Gonzalez, Van Ness, J. Chem. Eng. Data, Vol. 28, p. 407-
x1 y1 P/kPa
0 0 69.356
0.0208 0.0441 70.783
0.1017 0.1168 72.808
0.1523 0.139 72.883
0.2029 0.1564 72.639
0.2532 0.1722 72.152
0.3036 0.1878 71.485
0.3536 0.2039 70.653
0.4032 0.2211 69.627
 0.4532 0.2401 68.367
0.4998 0.2599 66.978
0.5026 0.2612 66.856
0.5505 0.2843 65.106
0.6004 0.312 62.858
0.6508 0.3448 60.115
0.701 0.3839 56.862
0.7512 0.4313 52.985
0.7984 0.4863 48.888
0.8517 0.5659 43.829
0.9014 0.6648 38.849
0.9481 0.792 34.254
0.9805 0.9108 31.237
1 1 29.51

21) Etanol (1) /1,4-Dioxano (2)__a 50 C. Experimental data from Gonzalez and Van Ness J. Chem. Eng. Data 1983, Vol. 28 Nº
x1 y1 P/kPa
0 0 15.697
0.0218 0.0863 16.826
0.0517 0.181 18.244
0.1023 0.2998 20.305
0.1522 0.3848 22.019
0.2022 0.4499 23.476
0.2655 0.5137 25.025
0.3016 0.5437 25.764
0.3532 0.5808 26.698
0.4024 0.6116 27.452
0.4518 0.6392 28.103
0.4986 0.6633 28.677
0.5003 0.6641 28.664
0.5972 0.7103 29.55
0.6472 0.7336 29.892
0.6969 0.7574 30.162
0.7466 0.7828 30.371
0.7968 0.8111 30.505
0.8449 0.8421 30.535
0.8999 0.8849 30.425
0.9496 0.9339 30.108
0.9794 0.9704 29.804
1 1 29.51

18) CO2(1)/Propane(2) at 310.93 K.Experimental data from Reamer, Sage, & Lacey, I&EC, Vol. 43, 2515-2520 (1951)
x1 y1 P/kPa
0 0 1301.04
0.0081 0.0472 1378.95
0.0495 0.2281 1723.69
0.0926 0.3511 2068.42
0.1361 0.437 2413.16
0.1799 0.4994 2757.9
0.2248 0.5481 3102.64
0.2709 0.5876 3447.37
0.3191 0.6213 3792.11
0.3693 0.6514 4136.85
0.4212 0.6781 4481.58
0.4735 0.7013 4826.32
0.5272 0.7238 5171.06
0.5814 0.7448 5515.8
0.6346 0.7647 5860.53
0.6861 0.7801 6205.27
0.7363 0.7908 6550.01