Vedantu - JEE Main Simulator: 1. in A Circuit Consisting of A Capacitance and A Generator With Alternating Emf E
Vedantu - JEE Main Simulator: 1. in A Circuit Consisting of A Capacitance and A Generator With Alternating Emf E
Vedantu - JEE Main Simulator: 1. in A Circuit Consisting of A Capacitance and A Generator With Alternating Emf E
Questions
1. In a circuit consisting of a capacitance and a generator with alternating emf E g = E g0 sinωt, V C and I Care
the voltage and current. Correct phasor diagram for such circuit is:
(a)
(b)
(c)
(d)
2. A Copper (Cu) rod of length 25 cm and cross-sectional area 3 mm 2 is joined with a similar Aluminium
(Al) rod as shown in figure. Find the resistance of the combination between the ends A and B.
(Take Resistivity of Copper = 1.7 × 10 − 8 ΩmResistivity of Aluminium = 2.6 × 10 − 8 Ωm)
(a) 2.170 mΩ
(b) 1.420 mΩ
(c) 0.0858 mΩ
(d) 0.858 mΩ
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3. → →
What will be the projection of vector A = î + ĵ + k̂ on vector B = î + ĵ ?
(a) √2 (î + ĵ + k̂ )
(
(b) 2 î + ĵ + k̂ )
(c) √2 (î + ĵ )
(d) (î + ĵ )
4. A porter lifts a heavy suitcase of mass 80 kg and at the destination lowers it down by a distance of 80 cm
with a constant velocity. Calculate the work done by the porter in lowering the suitcase.
(take g = 9.8 ms ) −2
(a) – 62720.0 J
(b) – 627.2 J
(c) + 627.2 J
(d) 784.0 J
5. 1
T 0 is the time period of a simple pendulum at a place. If the length of the pendulum is reduced to 16 times
of its initial value, the modified time period is:
(a) T 0
(b) 8πT 0
(c) 4T 0
1
(d) T
4 0
7. A bullet of ′ 4g ′ mass is fired from a gun of mass 4 kg. if the bullet moves with the muzzle speed of
50 ms − 1, the impulse imparted to the gun and velocity of recoil of gun are:
(a) 0.4 kg ms − 1, 0.1 ms − 1
(b) 0.2 kg ms − 1, 0.05 ms − 1
(c) 0.2 kg ms − 1, 0.1 ms − 1
(d) 0.4 kg ms − 1, 0.05 ms − 1
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9. Consider a situation in which a ring, a solid cylinder and a solid sphere roll down on the same inclined
plane without slipping. Assume that they start rolling from rest and having identical diameter.
The correct statement for this situation is:-
The sphere has the greatest and the ring has the least velocity of the centre of mass at the bottom of
(a)
the inclined plane.
The ring has the greatest and the cylinder has the least velocity of the centre of mass at the bottom of
(b)
the inclined plane.
(c) All of them will have same velocity
The cylinder has the greatest and the sphere has the least velocity of the centre of mass at the bottom
(d)
of the inclined plane.
10. Consider a situation in which reverse biased current of a particular P – N junction increases when it is
exposed to a light of wavelength ⩽ 621 nm. During this process, enhancement in carrier concentration
takes place due to generation of hole – electron pairs. The value of band gap is nearly.
(a) 2 eV
(b) 4 eV
(c) 1 eV
(d) 0.5 eV
11. A nucleus with mass number 184 initially at rest emits an α − particle. If the Q value of the reaction is
5.5 MeV, calculate the kinetic energy of the α − particle.
(a) 5.0 MeV
(b) 5.5 MeV
(c) 0.12 MeV
(d) 5.38 MeV
12. An electron of mass m e and a proton of mass m P are accelerated through the same potential difference.
The ratio of the de – Broglie wavelength associated with the electron to that with the proton is:-
mp
(a)
me
(b) 1
mp
(c)
√
me
me
(d)
mp
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List – I List – II
1
(a) ωL > (i) Current is in phase with emf
ωC
1
(b) ωL = (ii) Current lags behind the applied emf
ωC
1
(c) ωL < (iii) Maximum current occurs
ωC
(d) Resonant frequency (iv) Current leads the emf
14. What will be the average value of energy for a monoatomic gas in thermal equilibrium at temperature T?
2
(a) k T
3 B
(b) k BT
3
(c) k T
2 B
1
(d) k T
2 B
15. Intensity of sunlight is observed as 0.092 Wm − 2 at a point in free space. What will be the peak value of
(
magnetic field at that point? ε 0 = 8.85 × 10 − 12C 2N − 1m − 2 )
(a) 2.77 × 10 − 8T
(b) 1.96 × 10 − 8T
(c) 8.31 T
(d) 5.88 T
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16. The motion of a mass on a spring, with spring constant K is as shown in figure.
K
The equation of motion is given by x(t) = Asinωt + Bcosωt with ω =
√ m
Suppose that at time t = 0, the position of mass is x(0) and velocity v (0), then its displacement can also
be represented as x(t) = Ccos(ωt − ϕ), where C and ϕ are :
(a) C =
√
2v ( 0 ) 2
ω2 ( )
v(0)
+ x(0) 2, ϕ = tan − 1 x ( 0 ) ω
(b) C =
√
2v ( 0 ) 2
ω2 ( )
v(0)ω
+ x(0) 2, ϕ = tan − 1 2v ( 0 )
(c) C =
√
v(0) 2
ω2
+ x(0) 2, ϕ = tan − 1 ( )
x(0)ω
v(0)
(d) C =
√
v(0) 2
ω2 ( )
v(0)
+ x(0) 2, ϕ = tan − 1 x ( 0 ) ω
17. An electric dipole is placed on x – axis in proximity to a line charge of linear charge density
3.0 × 10 − 6C / m. Line charge is placed on z – axis and positive and negative charge of dipole is at a
distance of 10 mm and 12 mm from the origin respectively. If total force of 4 N is exerted on the dipole,
find out the amount of positive or negative charge of the dipole.
(a) 815.1 nC
(b) 8.8 μC
(c) 0.485, mC
(d) 4.44 μC
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18. A body is projected vertically upwards from the surface of earth with a velocity sufficient enough to
carry it to infinity. The time taken by it to reach height h is ______ S.
√ [( ) ]
Re h 3/2
(a) 2g
1+ R −1
e
√ [( ) ]
2R e h 3/2
(b) g
1+ R −1
e
√ [( ) ]
1 Re h 3/2
(c) 3 2g
1+ R −1
e
√ [( ) ]
1 2R e h 3/2
(d) 3 g
1+ R −1
e
19. A ray of light from a denser medium strikes a rarer medium at an angle of incidence i (see figure). The
reflected and refracted rays make an angle of 90o with each other. The angles of reflection and refraction
are r and r'. The critical angle is
20.
A parallel plate capacitor with plate area A and separation between the plates d, is charged by a constant
current I. Consider a plane surface of area A/2 parallel to the plates and drawn between the plates. The
displacement current through the area is
(a) I
I
(b)
2
I
(c) 4
I
(d)
8
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21. In a given circuit diagram, a 5 V Zener diode along with a series resistance is connected across a 50 V
power supply. The minimum value of the resistance required, if the maximum Zener current is 90 mA
will be ______ Ω
22. The position of the centre of mass of a uniform semi – circular wire of radius ′ R ′ placed in x – y plane
( ) xR
with its centre at the origin and the line joining its ends as x – axis is given by 0, π , Find x.
23. In an electric circuit, a cell of certain emf provides a potential difference of 1.25 V across a load
resistance of 5 Ω . However, it provides a potential difference of 1 V across a load resistance of 2 Ω .
x
The emf of the cell is given by 10 V. Then the value of x is ______.
24. The total charge enclosed in an incremental volume of 2 × 10 − 9 m 3 located at the origin is ______ nC, if
electric flux density of its field is found as D = e − x siny î − e − xcosy ĵ + 2zk̂ C / m 2.
25. → → →
Three particles P, Q and R are moving along the vectors A = î + ĵ, B = ĵ + k̂ and C = − î + ĵ
respectively. They strike on a point simultaneously and start to move in different directions. Now
→ →
particle P is moving normal to the plane which contains vector A and B. Similarly particle Q is moving
→ →
normal to the plane which contains vector A and C. The angle between the direction of motion of P and
Q is cos − 1
()
1
√x
. Then the value of x is _______.
26. The centre of a wheel rolling on a plane surface moves with a speed ν 0. A particle on the rim of the
wheel at the same level as the centre will be moving at a speed √x ν 0. Then the value of x is _______.
27.
A ray of light passing through a prism μ = ( √3 ) suffers minimum deviation. It is found that the angle of
incidence is double the angle of refraction within the prism. Then, the angle of prism is _______ (in
degrees)
28. The area of cross – section of a railway track is 0.01 m 2. The temperature variation is 10 oC .
Coefficient of linear expansion of material of track is 10 − 5 / oC . The energy stored per meter in the
track is ______ J/m.
(Young’s modulus of material of track is 10 11 Nm − 2)
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29. Three students S 1, S 2 and S 3 perform an experiment for determining the acceleration due to gravity (g)
using a simple pendulum. They use different lengths of pendulum and record time for different numbers
of oscillations. The observations are as shown in the table.
Student Length of pendulum No. of oscillations Total time for n Time period
No. (cm) (n) oscillations (s)
1. 64.0 8 128.0 16.0
2. 64.0 4 64.0 16.0
3. 20.0 4 36.0 9.0
30. In 5 minutes, a body cools from 75 oC to 65 oC at room temperature of 25 oC. The temperature of body
at the end of next 5 minutes is _______ oC.
{
4
− 3 x 3 + 2x 2 + 3x, x>0
f(x) =
3xe x, x⩽0
(a)
( )
− 1, 2
3
(b)
( ) −1
2
,2
(c) (0, 2)
(d) (− 3, − 1)
32. Let [x] denote the greatest integer less than or equal to x. Then, the values of
x ∈ R satisfying the equation e x [ ] + [e + 1 ] − 3 = 0 lie in the interval:
2 x
(b)
[ )
0, e
1
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33. Let n denote the number of solutions of the equation z 2 + 3ˉz = 0, z is a complex
∞ 1
number. Then the value of ∑ k is equal to:
k=0n
(a) 1
(b) 2
4
(c)
3
3
(d)
2
34.
[ ]
Let A = a ij be a real matrix of order 3 × 3, such that a i1 + a i2 + a i3 = 1, for i = 1, 2, 3. Then, the
sum of all the entries of the matrix A 3 is equal to:
(a) 1
(b) 3
(c) 2
(d) 9
35. The number of ways to distribute 30 identical candies among four children C 1, C 2, C 3 and C 4 so that
C 2 receives atleast 4 and atmost 7 candies, C 3 receives atleast 2 and atmost 6 candies, is equal to
(a) 205
(b) 615
(c) 510
(d) 430
where [x] is the greatest integer less than or equal to x, then the value of α is:
(a) 100(1 − e)
(
(b) 200 1 − e − 1 )
(c) 150 (e −1 − 1)
(d) 50(e − 1)
37. Four dice are thrown simultaneously and the numbers shown on these dice are recorded in 2 × 2
matrices. The probability that such formed matrices have all different entries and are non-singular, is:
23
(a)
81
22
(b)
81
45
(c)
162
43
(d)
162
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38. The area (in sq. units) of the parallelogram whose diagonals are along the vectors 8î − 6ĵ and
3î + 4ĵ − 12k̂, then is:
(a) 20
(b) 65
(c) 52
(d) 26
39. Let S n denote the sum of first n-terms of an arithmetic progression. If S 10 = 530, S 5 = 140, then
S 20 − S 6 is equal to:
(a) 1852
(b) 1842
(c) 1872
(d) 1862
40. Out of 11 consecutive natural numbers if three numbers are selected at random (without repetition), then
the probability that they are in A.P. with positive common difference, is:
10
(a)
99
5
(b) 33
15
(c)
101
5
(d) 101
41. Let the circle 36x 2 + 36y 2 − 108x + 120y + C = 0 be such that it neither intersects nor touches the co-
ordinate axes. If the point of intersection of the lines, x − 2y = 4 and 2x − y = 5 lies inside the circle S,
then :
(a) 100 < C < 156
25 13
(b) <C< 3
9
(c) 81 < C < 156
(d) 100 < C < 165
(d) √ ( √ )
3 1− 5
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43. x2 y2
Let E 1 : + = 1, a > b. Let E 2be another ellipse such that it touches the end points of major axis of
a2 b2
E 1 and the foci E 2 are the end points of minor axis of E 1. If E 1 and E 2 have same eccentricities, then its
value is :
− 1 + √3
(a)
2
− 1 + √6
(b)
2
− 1 + √5
(c)
2
− 1 + √8
(d)
2
44. If the vector bˉ = 3ĵ + 4k̂ is written as the sum of a vector bˉ , parallel to aˉ = î + ĵ and a vector bˉ ,
1 2
perpendicular to aˉ , then bˉ 1 × bˉ 2 is equal to:
9
(a) 6î − 6ĵ + k̂
2
(b) − 3î + 3ĵ − 9k̂
9
(c) − 6î + 6ĵ − k̂
2
(d) 3î − 3ĵ + 9k̂
45.
α
( 1 + 2xe − 2x
( 1 − xe − x ) 2 ) x≠0
x=0
(a) 1
(b) 0
(c) 3
(d) 2
46. If the position vectors of the vertices A, B and C of a ΔABC are respectively
4î + 7ĵ + 8k̂, 2î + 3ĵ + 4k̂ and 2î + 5ĵ + 7k̂, then the position vector of the point, where the
bisector of ∠A meets BC is :
1
(
(a) 2 4î + 8ĵ + 11k̂ )
1
(b) 3 (6î + 11ĵ + 15k̂ )
1
(c) 3 (6î + 13ĵ + 18k̂ )
1
(d) 4 (8î + 14ĵ + 19k̂ )
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47. Let y = y(x) be the solution of the differential equation cosec 2x dy + 2dx = (1 + ycos2x)cosec 2x dx, with
()
y 4
π
1
= 0. Then, the value of (y(0) + 1) 2 is equal to :
(a) e 2
1
(b) e − 2
(c) e − 1
(d) e
48. The value of λ and μ such that the system of equations x + y + z = 6, 3x + 5y + 5z = 26, x + 2y + λz = μ
has no solution, are :
(a) λ = 3, μ ≠ 10
(b) λ ≠ 2, μ = 10
(c) λ = 3, μ = 5
(d) λ = 2, μ ≠ 10
49. √
cos − 1 x 2 − x + 1
If the domain of the function f(x) = is the interval (α, β], then α + β is equal to :
√ ( )sin − 1
2x − 1
2
(a) 2
3
(b)
2
1
(c)
2
(d) 1
50. If the shortest distance between the straight lines 3(x − 1) = 6(y − 2) = 2(z − 1) and
1
4(x − 2) = 2(y − λ) = (z − 3), λ ∈ R is , then the integral value of λ is equal to :
√38
(a) –1
(b) 2
(c) 3
(d) 5
51.
{ |
The number of elements in the set n ∈ {1, 2, 3, . . . . . , 100} (11) n > (10) n + (9) n is ______. is }
52. Let y = y(x) be the solution of the differential equation
53. Let A = {0, 1, 2, 3, 4, 5, 6, 7}. Then the number of bijective functions f : A → A such that
f(1) + f(2) = 3 − f(3) is equal to ______.
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54.
( )
If the constant term, in binomial expansion of 2x r +
1
x2
10
is 180, then r is equal to _____.
55.
{ ( )
|x|
3 1− 2 if |x| ⩽ 2
Let f : R → R be function defined as f(x) =
0 if |x| > 2
Let g : R → R be given by g(x) = f(x + 2) − f(x − 2). If n and m denote the number of points in R where
g is not continuous and not differentiable, respectively, then n + m is equal to
56.
[ ]
0 1 0
Let A = 1 0 0 . Then the number of 3 × 3 matrices B with entries from the set {1, 2, 3, 4, 5} and
0 0 1
satisfying AB = BA is _______.
309
If mean = 22 and median = 14, then value (a − b) 2 is equal to ________.
58. If the digits are not allowed to repeat in any number formed by using the digits 0, 2, 4, 6, 8, then the
number of all numbers greater than 10,000 is equal to _______.
59. The sum of all the elements in the set {n ∈ {1, 2, . . . . . , 100} | H. F. C of n and 2040 is 1} is equal to
_______.
60. The area (in sq. units) of the region bounded by the curves x 2 + 2y − 1 = 0, y 2 + 4x − 4 = 0 and
y 2 − 4x − 4 = 0, in the upper half plane is ____.
62. Which one of the following statements for D.I. Mendeleev, is incorrect?
(a) He authored the textbook – Principles of Chemistry.
(b) At the time, he proposed Periodic Table of elements structure of atom was known.
(c) Element with atomic number 101 is named after him.
(d) He invented accurate barometer.
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63.
Which purification technique is used for the organic compound that decomposes near its boiling point?
64. Which of the following compounds will provide a tertiary alcohol on reaction with excess of CH 3MgBr
followed by hydrolysis?
(a)
(b)
(c)
(d)
(b)
67.
68. What is the final product (major) ‘A’ in the given reaction?
(a)
(b)
(c)
(d)
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72. Consider the reversible isothermal expansion of an ideal gas in a closed system at two different
temperatures T1 and T2 (T1 < T2). The correct graphical depiction of the dependence of work done (w)
on the final volume (V) is:
(a)
(b)
(c)
(d)
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75. The set having ions which are coloured and paramagnetic both is -
(a) Cu 2 + , Cr 3 + , Sc +
(b) Cu 2 + , Zn 2 + , Mn 4 +
(c) Sc 3 + , V 5 + , Ti 4 +
(d) Ni 2 + , Mn 7 + , Hg 2 +
76.
For emission line of atomic hydrogen from n i = 8 to n f = n, the plot of wave number (vˉ ) against
()
1
n2
77. The following results were obtained during kinetic studies of the reaction;
2A + B → Products
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78.
( )
An organic compound A C 6H 6O gives dark green coloration with ferric chloride. On treatment with
CHC l 3 and KOH, followed by acidification gives compound B. Compound B can also be obtained from
compound C on reaction with pyridinium chlorochromate (PCC). Identify A, B and C.
(a)
(b)
(c)
(d)
(a)
(b)
(c)
(d)
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80. Which one of the following 0.06 M aqueous solutions has lowest freezing point?
( )
(a) Al 2 SO 4
3
C H
(b) 6 12 6O
(c) KI
(d) K 2SO 4
81.
[
The total number of unpaired electrons present in Co NH 3 ( )]
6
C l 2 and Co NH 3
6 [ ( )
C l 3 is ]
82. Methylation of 10 g of benzene gave 9.2 g of toluene. Calculate the percentage yield of toluene
___________. (Nearest integer)
83. The number of acyclic structural isomers (including geometrical isomers) for pentene are ______
84.
( )
Assume a cell with the following reaction Cu ( s ) + 2Ag + 1 × 10 − 3M → Cu 2 + (0.250 M) + 2Ag ( s )
EΘ
cell = 2.97 V
E cell for the above reaction is ___________V.
(Nearest integer)
[Given: log 2.5 = 0.3979, T = 298 K]
85. Value of K p for the equilibrium reaction N 2O 4 ( g ) ⇌ 2NO 2 ( g ) at 288 K is 47.9. The K c for this reaction
at same temperature is ___________. (Nearest integer)
(R = 0.083 L bar K − 1 mol − 1)
86. If the standard molar enthalpy change for combustion of graphite powder is − 2.48 × 10 2 kJ mol − 1, the
amount of heat generated on combustion of 1 g of graphite powder is ______ kJ. (Nearest integer)
87. T
Consider the reaction N 2O 4(g) ⇌ 2NO 2(g). The temperature 60 at which K C = 20.4 and K P = 600.1,
is ............. K. (Round off to the Nearest Integer).
[Assume all gases are ideal and R = 0.0831 L bar K–1 mol–1]
88. Number of electrons that Vanadium (Z = 23) has in p-orbitals is equal to _______
89. 1
N 2O 5 ( g ) → 2NO 2 ( g ) + 2 O 2 ( g )
In the above first order reaction the initial concentration of N 2O 5 is 2.40 × 10 − 2 mol L − 1 at 318 K. The
concentration of N 2O 5 after 1 hour was 1.60 × 10 − 2 mol L − 1. The rate constant of the reaction at 318 K
is _______ × 10 − 3 min − 1. (Nearest integer)
[Given: log 3 = 0.477, log 2 = 0.3010]
90.
( )
If the concentration of glucose C 6H 12O 6 in blood is 0.72 g L − 1, the molarity of glucose in blood is
_____ × 10 − 3 M. (Nearest integer)
[Given: Atomic mass of C = 12, H = 1, O = 16 u]
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Answer Key
1. B 2. D 3. D 4. B 5. D 6. A
7. B 8. B 9. A 10. A 11. D 12. C
13. A 14. C 15. A 16. D 17. D 18. D
19. A 20. B 21. 500.00 22. 2.00 23. 15.00 24. 4.00
25. 3.00 26. 2.00 27. 60.00 28. 5.00 29. 1.00 30. 57.00
31. A 32. C 33. C 34. B 35. D 36. B
37. D 38. B 39. D 40. B 41. A 42. D
43. C 44. A 45. A 46. C 47. C 48. D
49. B 50. C 51. 96.00 52. 4.00 53. 720.00 54. 8.00
55. 4.00 56. 3125.00 57. 4.00 58. 96.00 59. 1251.00 60. 2.00
61. D 62. B 63. D 64. A 65. D 66. D
67. A 68. D 69. C 70. C 71. C 72. B
73. B 74. B 75. A 76. D 77. A 78. A
79. C 80. A 81. 1.00 82. 78.00 83. 6.00 84. 3.00
85. 2.00 86. 21.00 87. 6.00 88. 12.00 89. 7.00 90. 4.00
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Solutions
1. (B)
2. (D)
ρ Cu × ℓ
R Cu = A
ρ Al × ℓ
R Al = A
()
ρ Cu × ρ Al ℓ
R Eq = ρ + ρ × A
Cu Al
= 0.858 mΩ
3. (D)
→ →
A⋅B
Projection = →
(B̂)
|B|
( î + ĵ + k̂ ) ⋅ ( î + ĵ ) ( î + ĵ )
=
√2 √2
2 ( î + ĵ )
=
√2 √2
= (î + ĵ)
4. (B)
W = − N × Δx
80
= − 80 × 9.8 × 100
= − 627.2J
5. (D)
l
T = 2π
√ g
T0
′
T = 4
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6. (A)
With increase in temperature domain volume decreases.
Statement 1 true
Statement 2 false
7. (B)
m Bullet = 4 g, M Gun = 4 kg
v Bullet = 50 m / s
Now P B = P g
P g = m × v Bullet
4
= 1000 × 50
= 0.2 kg m / s
So impulse = 0.2 kg m / s
0.2 0.2
vG = M = 4 = 0.05 m / s
Gun
8. (B)
tan ( θT )
( )
tan θ a = cos ϕ
⇒ θa ⩾ θT
∴ True dip is less than apparent dip.
9. (A)
KT MR 2
KR
= I
CM
I CM is maximum for ring.
⇒ v is least for ring.
10. (A)
hc
Band gap = λ = 2 eV
11. (D)
k α + k N = 5.5
p2
k = 2m
kα 180 45
⇒ k = 4 = 45 ⇒ k α = 46 × 5.5MeV
N
= 5.38MeV
12. (C)
h h
λ= p =
√2km
λe k pm p mp
λp
=
√ √ k em e
= me
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13. (A)
1
ωL = ωC , X L = X C
So current in phase with EMF
At resonance, current have maximum value,
14. (C)
3
E = 2 K BT
15. (A)
I 1
C
= 2 ε 0 ⋅ E 20
2I
⇒ E0 =
E0
√ Cε 0
E0
B0
= C ⇒ B0 = C
2I 2 × 0.092
⇒ B0 =
√ √ ε 0C 3
=
8.85 × 10 − 12 × 27 × 10 + 24
= 2.77 × 10 − 8 T
16. (D)
Ccosϕ = x(0)
tCωsinϕ = v(0)
[ ] v(0) 2
ω
+ [x(0)] 2 = C 2
v(0)
tanϕ = x ( 0 ) ω
17. (D)
| F | = q E1 − E2 ( )
= (q)2kλ
[ 2
10 × 12 × 10 − 3 ]
4 = (q) × 2 × 9 × 10 9 × 3 × 10 − 6 ( ) [ 2
120 × 10 − 3 ]
⇒ q = 4.44μC
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18. (D)
1 GMm 2GM
2
mv 2 − r
=0⇒v=
√ r
dr 2GM
dt
=
√ r
t
⇒ ∫ ( R e + h ) √rdr = ∫ 0√2GMdt
R e
[ (R + h ) ]
2
⇒ 3 e
3/2 − R 3e / 2 = (t)√2GM
√ [( ) ]
1 2R e h 3/2
⇒t= 3 g
1+ R −1
e
19. (A)
r + r ′ + 90 0 = 180 0
∴ r ′ = 90 0 − r
Further, i = r
Applying Snell’s law, μ Dsini = μ Rsinr ′
20. (B)
Charge on capacitor plates at time t is, q = I t. Electric field between the plates as this instant is
q It
E = Aε = Aε - - - - - - (i)
0 0
Electric flux through the given area A/2 is
ϕE =
() A
2
It
E = 2ε - - - - - - (ii) [from (i)]
0
21. (500.00)
50 − V z 5
I= R
= R + 90 × 10 − 3
L
For R L → ∞
R = 500Ω
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22. (2.00)
2R
Centre of mass of half ring is located at a distance π from centre of the ring on its axis of symmetry so
( )
position of centre of mass in the given question will be 0, π
2R
⇒ |x| = 2
23. (15.00)
1.25
In case (a), ε = 5 (5 + r)
⇒ 4ε = 5 + r
1
In case (b), ε = 2 (2 + r)
⇒ 2ε = 2 + r
From equation (1) & (2)
2ε = 3 ⇒ ε = 1.5
or x = 15
24. (4.00)
ˉ = ε Eˉ
D 0
ρ
Div. Eˉ = ε
0
⇒ div. D ˉ =ρ
( ) ( )
∂ ∂ ∂
⇒ ∂x e − xsiny + ∂y − e − xcosy + ∂z (2z) = ρ
⇒ ρ = 2 (a constant)
V = 2 × 10 − 9 m 3
q = 2 × 2 × 10 − 9 = 4nC
25. (3.00)
→ →
A×B iˆ − jˆ + k̂
n̂ 1 = =
→ →
|A×B| √3
→ →
A×C
n̂ 2 = → →
= k̂
|A×C|
1
cosθ = n̂ 1 ⋅ n̂ 2 =
√3
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26. (2.00)
v0
|ω| = R
→
V p = v 0î + ωR( − ĵ) = v 0î − v 0ĵ
|v P | = √2v0
→
x = 02
27. (60.00)
For minimum deviation r 1 = r 2 = A / 2
Given i = 2r
sin i sin 2r
μ = sin r = sin r
μ
⇒ cosr = 2
⇒ r = 30 ∘
⇒ A = 60 ∘
28. (5.00)
As the tracks won't be allowed to expand linearly, the rise in temperature would lead to developing thermal
stress in track.
( Stress )
y
= αΔT or σ = YαΔT
1 σ2
Energy stored per unit volume = 2 Y
Aσ 2
⇒ Energy stored per unit length = 2Y
A
= 2 × Yα 2ΔT 2
10 − 2 × 10 11 × 10 − 10 × 100
= 2
= 5 J/m
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29. (1.00)
t l
T = n = 2π
√ g
4π 2l
⇒g=
T2
Δg Δl ΔT
⇒ g × 100 = l × 100 + 2 T × 100
=
( Δl
l
+ nT 100%
20
2Δt
)
E 1 = 64 %
30
E 2 = 64 %
19
E 3 = 18 %
30. (57.00)
75 − 65
5
=k
2
( 75 + 65
2
− 25
)
⇒ k = 45
65 − T
5
=k
( 65 + T
2
− 25
)
⇒ T = 57 ∘ C
31. (A)
For x > 0, f ′ (x) = − 4x 2 + 4x + 3
f(x) is increasing in − 2 , 2
( )1 3
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32. (C)
[e ] + [e + 1 ] − 3 = 0
x 2 x
⇒ [e ] + [e ] + 1 − 3 = 0
x 2 x
Let [e ] = t x
⇒ t2 + t − 2 = 0
⇒ t = − 2, 1
[e ] = − 2 (Not possible)
x
or [e ] = 1 x
∴1⩽e <2 x
33. (C)
z 2 + 3zˉ = 0
Put z = x + iy
⇒ x 2 − y 2 + 2ixy + 3(x − iy) = 0
(
⇒ x 2 − y 2 + 3x + i(2xy − 3y) = 0 + i0 )
x2 y2
∴ − + 3x = 0 . . . (1)
2xy − 3y = 0....
3
x = 2, y = 0
3
Put x = 2 in equation (1)
9 9
4
− y2 + 2 = 0
27 3√ 3
y2 = 4 ⇒ y = ± 2
( )(3 3√ 3
)
3 − 3√ 3
∴ (x, y) = 2
, 2 , 2, 2
Put y = 0 ⇒ x 2 − 0 + 3x = 0
x = 0, − 3
∴ (x, y) = (0, 0), (− 3, 0)
∴ No of solutions = n = 4
() ()
∞ 1 ∞ 1
∑ k = ∑ k
k=0 n k=0 4
1 1 1 1
= 1 + 4 + 16 + 64 + . . .
1 4
= 1 = 3
1− 4
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34. (B)
[ ]
a 11 a 12 a 13
A= a 21 a 22 a 23
a 31 a 32 a 33
[]
1
Let x = 1
1
[ ] []
a 11 a 12 a 13
1
AX = a 21 a 22 a 23 = 1
a 31 a 32 a 33 1
⇒ AX = X
Replace X by AX
A 2X = AX = X
Replace X by AX
A 3X = AX = X
[ ]
x1 x2 x3
Let A 3 = y1 y2 y3
z1 z2 z3
[] [ ] []
x1 + x2 + x3
1 1
A3 1 = y1 + y2 + y3 = 1
1 z1 + z2 + z3 1
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35. (D)
t 1 + t 2 + t 3 + t 4 = 30
Coefficient of x 30 in (1 + x + x 2 + . . . . . . + x 30) 2
(x 4 + x 5 + x 6 + x 7) (x 2 + x 3 + x 4 + x 5 + x 6)
x 6
( )
1 − x 31
1−x
(1 + x + x 2 + x 3) (1 + x + x 2 + x 3 + x 4)
x 6 (1 − x 31) 2 (1 − x 4) (1 − x 5) (1 − x) − 4
x 6 (1 − x 4 − x 5 + x 9) (1 + x 62 − 2x 31 (1 − x) − 4)
x 6 (1 − x 4 − x 5 + x 9) (1 − x) − 4
Coefficient of x nin (1 − x) − r is n + r − 1C r − 1
⇒ 27C 3 − 23C 3 − 22C 3 + 18C 3
2925 − 1771 − 1540 + 816
= 430
OR
x 2 ∈ [4. 7], x 3 ∈ [2, 6]
⇒ t 1 + t 2 + t 3 + t 4 = 24
total ways =
24 + 4 − 1
C 4 − 1 − 20 + 4 − 1C 4 − 1 − 19 + 4 − 1C 4 − 1 + 15 + 4 − 1C 4 − 1
= 27C 3 − 23C 3 − 22C 3 + 18C 3 = 430
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36. (B)
100π sin 2x π sin 2x
I= ∫ dx = 100∫ x dx
0
e {} x
π
0 eπ
π x ( 1 − cos 2x )
100∫ e − π 2
dx
0
{ }
π x π x
−π −π
= 50 ∫ e dx − ∫ e cos2x dx
0 0
[ ]
π x x π
I1 = ∫ e − π dx
0
= − πe − π 0
= π 1 − e −1( )
π x
I 2 = ∫ e − π cos2xdx
0
x π x
π
= − πe − π cos2x] 0 − ∫ − πe − π (− 2sin2x)dx
0
π x
(
= π 1 − e − 1 − 2π∫ e − π sin2xdx) 0
{[ ] }
x π π x
=π 1− ( e −1 ) − 2π − πe − π sin2x 0
− ∫ πe − π 2cos2x dx
0
(
= π 1 − e − 1 − 4π 2I 2 )
(
π 1−e −1 )
⇒ I2 =
1 + 4π 2
{( ( )
}
π 1−e −1
∴ I = 50 π 1 − e −1
)− 1 + 4π 2
(
200 1 − e − 1 π 3 )
=
1 + 4π 2
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37. (D)
A=
| | a
c
b
d
|A| = ad − bc
Total case = 6 4
For non-singular matrix |A| ≠ 0 ⇒ ad − bc ≠ 0
⇒ ad ≠ bc
And a, b, c, dare all different numbers in the set {1, 2, 3, 4, 5, 6}
Now for ad = bc
(i) 6 × 1 = 2 × 3
⇒ a = 6, b = 2, c = 3, d = 1
or a = 1, b = 2, c = 3, d = 6 } 8 such cases
(ii) 6 × 2 = 3 × 4
⇒ a = 6, b = 2, c = 3, d = 2
or a = 1, b = 3, c = 4, d = 6 } 8 such cases
favourable cases
= 6C 4(4 !) − 16
required probability
6C
4(4! ) − 16 43
= = 162
64
38. (B)
1
Area of parallelogram = 2 dˉ 1 × dˉ 2 | |
| |
î ĵ k̂
dˉ 1 × dˉ 2 = 8 −6 0
3 4 − 12
1
=
2
√16900
1
= (130)
2
= 65 sq.units
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39. (D)
10
S 10 = 530 ⇒ 2 {2a + 9d} = 530
⇒ 2a + 9d = 106...(1)
5
and S 5 = 140 ⇒ 2 {2a + 4d} = 140
⇒ 2a + 4d = 56...(2)
⇒ 5d = 50 ⇒ d = 10 ⇒ a = 8
20 6
Now, S 20 − S 6 = 2 {2a + 19d} − 2 {2a + 5d}
= 14a + 175d
= (14 × 8) + (175 × 10)
= 1862
40. (B)
Case-1
E, O, E, O, E, O, E, O, E, O, E
2b = a + c → Even
⇒ Both a and c should be either even or odd.
6C 5C
2+ 2 5
P= 11C = 33
3
Case-2
O, E, O, E, O, E, O, E, O, E, O
5C 6C
2+ 2 5
P= 11C = 33
3
1 5 1 5 5
Total probability = 2 × 33 + 2 × 33 = 33
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41. (A)
S : 36x 2 + 36y 2 − 108x + 120y + C = 0
10 C
⇒ x 2 + y 2 − 3x + 3 y + 36 = 0
Centre ≡ (− g, − f) ≡
( ) 3
2
, 6
− 10
9 100 C
radius = r =
√ 4
+ 36 − 36
Now,
3
⇒r< 2
9 100 C 9
⇒ 4 + 36 − 36 < 4
Now point of intersection of x − 2y = 4 and 2x − y = 5 is (2, − 1), which lies inside the circle S.
∴ S(2, − 1) < 0
10 C
⇒ (2) 2 + (− 1) 2 − 3(2) + 3 (− 1) + 36 < 0
10 C
⇒ 4 + 1 − 6 − 3 + 36 < 0
C < 156
From (1) & (2)
100 < C < 156
42. (D)
sin12 o + sin12 o − sin72 o
= sin12 o − 2cos42 osin30 o
= sin12 o − sin48 o
= − 2cos30 osin18 o
√3 √5 − 1
= −2× 2 × 4
√3
(
= 4 1 − √5 )
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43. (C)
b2
e2 = 1 − . . . (1)
a2
a2
e2 = 1 − . . . (2)
c2
b2 a2
⇒ =
a2 c2
a4 a2
⇒ c2 = ⇒c= b
b2
Also b = ce
b a2 b2
∴ e = b ⇒ 2 =e
a
b2
e2 = 1 − ⇒ e2 + e − 1 = 0
a2
− 1 + √5
e= 2
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44. (A)
bˉ 1 is parallel to aˉ
⇒ bˉ 1 = λˉa
bˉ 2 is perpendicular to aˉ
⇒ bˉ 2. aˉ = 0
also,
bˉ = bˉ 1 + bˉ 2
bˉ = λˉa + bˉ 2
Take dot with aˉ
ˉ aˉ = λaˉ . aˉ + bˉ . aˉ
b. 2
⇒ 0 + 3 + 0 = λ |aˉ |2 + 0
3 = 2λ
3
λ= 2
3
∴ bˉ 1 = 2 (aˉ )
3
( )
bˉ 1 = 2 î + ĵ
3 3
bˉ 1 = 2 î + 2 ĵ
∴ bˉ = b − b
2 1
(
bˉ 2 = 3ĵ + 4k̂ −
−3 3
) ( 3
2
3
î + 2 ĵ
)
bˉ 2 = 2 î + 2 ĵ + 4k̂
| |
i j k
3 3
0
bˉ 1 × bˉ 2 = 2 2
−3 3
2 2
4
= î(6 − 0) − ĵ(6) + k̂ 4 + 4
9
( )
9 9
= 6î − 6ĵ + 2 k̂
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45. (A)
For continuity
x3
lim 4
x → 0 4sin x
(ln (1 + 2x e ) − 2ln (1 − xe ))
− 2x −x
=α
[ ]
1
lim 4x 2xe − 2x + 2xe − x = α
x→0
1
= 4 (4) = α = 1
46. (C)
⇒ P(x, y, z) =
( mx 2 + nx 1 my 2 + ny 1 mz 2 + nz 1
m+n
⇒ P(x, y, z) =
( (2) (2) + (1) (2)
2+1
,
(2) (5) + (1) (3)
2+1
,
(2) (7) + (1) (4)
2+1 )
⇒ P(x, y, z) =
( 6 13 18
3
, 3, 3
) 1
∴ Position vector of point P = 3 6î + 13ĵ + 18k̂ ( )
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47. (C)
dy
dx
+ 2sin 2x = 1 + ycos2x
dy
⇒ dx + (− cos2x)y = cos2x
sin 2x
I. F. = e ∫ − cos 2xdx = e − 2
Solution of D.E.
− sin 2x − sin 2x
y. e 2 = ∫ (cos2x)e 2 dx + c
Given
y 4
()
π
=0
1 1
⇒ 0 = − e−2 + c ⇒ c = e−2
at x = 0
1
y= −1+ e−2
1
−2
⇒ y(0) = − 1 + e
⇒ (y(0) + 1) 2 = e − 1
48. (D)
| |
1 1 1
D= 3 5 5 =0
1 2 λ
(5λ − 10) − 1(3λ − 5) + (6 − 5) = 0
2λ − 10 + + 5 + 1 = 0
λ = 2 only one option satisfy
Atleast one IF D 1, D 2, D 3 ≠ 0
49. (B)
0 ⩽ x2 − x + 1 ⩽ 1
⇒ x2 − x ⩽ 0
⇒ x[0, 1]
⇒0< 2
⩽1
⇒ 0 < 2x − 1 ⩽ 2
1 < 2x ⩽ 3
1 3
2
<x⩽ 2
Taking intersection
x∈
( ] 1
2
,1
1
⇒ α = 2, β = 1
1
⇒ α = 2, β = 1
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50. (C)
(x−1) (y−2) (z−1) → ∧ ∧ ∧
L1 : 2
= 1
= 3
, r 1 = 2 i + j + 3k
(x−2) → ∧
y−λ ∧z−3 ∧
L2 : 1
= 2 = 4 , r 2 = i + 2 j + 4k
→ →
→
Shortest distance = Projection of a on r 1 × r 2
| a . ( r1 × r2 ) |
→ → →
=
| r1 × r2 |
→ →
| |
1 λ−2 2
|a. ( r 1 × r 2 )| =
→ → →
2 1 3 = |14 − 5λ|
1 2 4
| |
→ →
r1 × r2 = √38
∴ |14 − 5λ| = 1
⇒ 14 − 5λ = 1 or 14 − 5λ = − 1
13
⇒ λ = 5 or 3
∴ Integral value of λ = 3
51. (96.00)
11 n > 10 n + 9 n
⇒ 11 n − 9 n > 10 n
⇒ (10 + 1) n − (10 − 1) n > 10 n
⇒ { C . 10
n
1
n−1 + nC 310 n − 0 + nC 510 n − 5 + . . . . } > 10 n
{
⇒ 2n.10 n − 1 + 2 nC 310 n − 3 + nC 510 n − 5 + . . . . } > 10 n . . . (1)
For n = 6, 7, 8, . . . . .100
⇒ 2n10 n − 1 + { C 10
n
3
n−3 + nC 510 n − 5 + . . . . } > 10 n
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52. (4.00)
y + 1 = Y ⇒ dy = dY
x + 2 = X ⇒ dx = dX
( Y
⇒ Xe X + Y dX = XdY
)
⇒ XdY − YdX = Xe Y / XdX
() Y Y dX
⇒ d X e−X = X
Y
− e − X = ln|X| + c
2
(3, 2) → − e−3 = ln|3| + c
Y 2
− e − X = ln|X| − e − 3 − ln3
Y 2
e − X = e 3 + ln3 − ln|X| > 0
2
ln|X| < e 3 + ln3 → λ
|x + 2| < e λ ; | x + 2 | ≠ 0
− eλ < x + 2 < eλ ; x + 2 ≠ 0
− eλ − 2 < x < eλ − 2 ; x ≠ − 2
α + β = − 4 ⇒ |α + β| = 4
53. (720.00)
f(1) + f(2) = 3 − f(3)
⇒ f(1) + f(2) + f(3) = 3
The only possibility is: 0 + 1 + 2 = 3
⇒ Elements 1, 2, 3 in the domain can be mapped with 0, 1, 2 only.
So number of bijective functions.
= 3 ! × 5 ! = 720
54. (8.00)
( )
2x r +
x2
1 10
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55. (4.00)
{
3x
2
−4 ⩽ x ⩽ − 2
f(x − 2) = 3x
− 2 −2 < x ⩽ 0
0 x ∈ (− ∞, − 4) ∪ (0, ∞)
{
3x
2
+6 0⩽x⩽2
f(x + 2) = 3x
− 2 +6 2<x⩽4
0 x ∈ (− ∞, 0) ∪ (4, ∞)
{
3x
2
+6 −4 ⩽ x ⩽ − 2
3x
− 2 −2 < x < 2
g(x) = f(x + 2) − f(x − 2) =
3x
2
−6 2⩽x⩽4
0 x ∈ (− ∞, − 4) ∪ (4, + ∞)
n=0
m = 4 ⇒ (n + m = 4)
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56. (3125.00)
[ ]
a b c
Let Matrix B = d e f
g h i
∴ AB = BA
[ ][ ] [ ][ ]
0 1 0 a b c a b c 0 1 0
1 0 0 d e f = d e f 1 0 0
0 0 1 g h i g h i 0 0 1
[ ][ ]
d e f b a c
a b c = e d f
g h i h g i
⇒ d = b, e = a, f = c, g = h
[ ]
a b c
∴ Matrix B = b a c
g g i
No. of ways of selecting a, b, c, g,
i=5×5×5×5× ×5
= 5 5 = 3125
∴ No. of Matrices B = 3125
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57. (4.00)
Class: Frequency Xi F ix i
0-6 a 3 3a
6-12 b 9 9b
12-18 12 15 180
18-24 9 21 189
24-30 5 27 135
N = (26 + a + b) (504 + 3a + 9b)
⇒ 2 −
13
a+b
( ) a+b
9
4
=2
⇒ 4
= 2
⇒ a + b = 18 → (2)
From equation (1) & (2)
a = 8, b = 10
∴ (a − b) 2 = (8 − 10) 2
58. (96.00)
⇒ 4 × 4 × 3 × 2 = 96
59. (1251.00)
2040 = 2 3 × 3 × 5 × 17
n should not be multiple of 2, 3, 5 and 17.
Sum of all n = (1 + 3 + 5... + 99) − (3 + 9 + 15 + 21 + . . . + 99) − (5 + 25 + 35 + 55 + 65 + 85 + 95) − (17)
17
= 2500 − 2 (3 + 99) − 365 − 17
= 2500 − 867 − 365 − 17 = 1251
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60. (2.00)
Required Area (shaded)
[( ) ( ) ]
2 4 − y2 1 1 − x2
=2 ∫ 4
dy − ∫ 2
dx
0 0
[ ]
=2 3−3
4 1
= (2)
61. (D)
As the temperature increases, the solubility of gases in the liquid decreases. Thus, water at 4 oCwill have
maximum dissolved oxygen.
Polluted water has less oxygen concentration than normal water as a large population of bacteria decomposes
organic matter present in water. They consume oxygen dissolved in water.
62. (B)
(a) Dmitri Ivanovich Mendeleev taught at the University of St. Petersburg where he was appointed Professor
of General Chemistry in 1867. Preliminary work for his great textbook “Principles of Chemistry” led
Mendeleev to propose the Periodic Law and to construct his Periodic Table of elements.
(b) At that time, the structure of atom was unknown and Mendeleev’s idea to consider that the properties of
the elements were in some way related to their atomic masses was a very imaginative one.
(c) Mendeleev’s name has been immortalized by naming the element with atomic number 101, as
Mendelevium.
(d) Mendeleev was a versatile genius. He worked on many problems connected with Russia’s natural
resources. He invented an accurate barometer.
63. (D)
Reduced pressure distillation or vacuum distillation is used for the purification of organic liquids which
decompose at or below their boiling point.
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64. (A)
65. (D)
CH 3CH 2CH = CHCH 2NH 2
No conjugation is present.
66. (D)
Fructose is an example of Ketohexose.
67. (A)
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68. (D)
69. (C)
70. (C)
( i ) AlH ( i − Bu ) 2
R−C≡N → R − CHO
( ii ) H 2O
The reduction of nitriles to aldehydes can be done using DIBAL-H[AlH(i-Bu)2].
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71. (C)
72. (B)
For reversible isothermal expansion,
V2
w = − nRTln ⇒
V1
V2
⇒ | w | = nRTln
V1
(
| w | = nRT lnV 2 − lnV 1 )
| w | = nRTlnV 2 − nRTV 1
y = mx + c
So, slope of curve 2 is more than curve 1 and intercept of curve 2 is more negative than curve l .
73. (B)
The stability of group-15 hydrides decreases from NH3 to BiH3 which can be observed from their bond
dissociation enthalpy.
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74. (B)
Compound, III
is most basic as the lone pair of nitrogen is easily available for the donation.
In case of compound (I)
lone pair is not involved in resonance but nitrogen atom is sp2 hybridised whereas in compound II the lone
pair of nitrogen is involved in aromaticity which makes it least basic.
75. (A)
The option (a) has all ions which are coloured and paramagnetic as well due to presence of unpaired
electrons.
Cu2+: [Ar] 3d9
Cr3+: [Ar] 3d3
Sc+: [Ar] 3d1 4s1
76. (D)
As we know,
( )1 1
vˉ = − R H 2 − 2 Z 2( where , Z = 1)
n2 n1
vˉ = − R H
( )1
n
1
− 2
82
RH RH
⇒ vˉ = − 2
64 n
Comparing to y = mx + c, we get
1
x= and m = − R H(slope)
n2
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77. (A)
From experiment l and II, it is observed that order of reaction w.r. t. (B) is zero.
From experiment II and III, a can be calculated as :
1.386 × 10 − 2
6.93 × 10 − 3
= ( )0.2 α
0.1
∴α=1
Now, Rate = K[A]1
or, 6.93 × 10–3 = K(0.1)
K = 6.93 × 10–2
For the reaction, 2A + B → Products
[A] 0
2Kt = ln [ A ]
0.693 0.693
∴ t 1 / 2 = 2K =
6.93 × 10 − 2 × 2
t1 / 2 = 5
78. (A)
79. (C)
Aniline does not undergo Friedel craft reaction.
Due to the lone pair of electrons on N, aniline is a strong lewis base. Also, the catalyst used (AlCl3 ) is a very
strong lewis acid.
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80. (A)
As the value of ∆Tf increases, the freezing point of the solution decreases. Since all the given solutions have
the same concentration, the one with maximum value of van’t hoff factor for the solute will have minimum
freezing point. The values are –
( )
Al 2 SO 4 - 5
3
C 6H 12O 6 - 1
KI - 2
K 2SO 4 - 3
( )
Thus, among given solutes, aq. solution of Al 2 SO 4 will have lowest freezing point.
3
81. (1.00)
[ ( )]
Co NH 3
6
C l 2: Co2+ = [Ar] 3d7. In presence of strong field ammine ligand, the electrons will be paired
and one unpaired electron will be excited to the 4d orbitals so that the hybridization is d2sp3 and thus the
number of unpaired electrons = 1.
[ ( )]
Co NH 3
6
C l 3: Co3+ = [Ar] 3d6. In presence of strong field ammine ligand, all the electrons will be
paired and thus the number of unpaired electrons = 0.
82. (78.00)
One mole of benzene will form one mole of toluene at 100% yield.
i.e., 78 g benzene will produce 92 g of toluene at 100% yield.
92
or 10 g benzene will produce 78 × 10 g of toluene at 100% yield.
actual amount formed
Thus, percentage yield = theoretical amount formed × 100
9.2
Therefore, %yield = 92 × 100 = 78%
78
× 10
83. (6.00)
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84. (3.00)
Using Nernst equation –
∘ 0.06 [ Cu ]
2+
0.25
⇒ E cell = 2.97 − 0.03 × log − 6
10
85. (2.00)
We know that K p = K c(RT) Δn g
Δn g = 2 − 1 = 1
⇒ 47.9 = K c(0.083 × 288) 1
⇒ 47.9 = K c × 23.904
47.9
⇒ K c = 23.904 ≈ 2
86. (21.00)
∆cH° (standard molar enthalpy change for combustion) is defined as the amount of heat liberated on
combustion of one mole of a substance.
12 g of graphite powder on combustion gives 2.48 × 102 kJ energy
2.48 × 100
Thus 1 g of graphite powder on combustion will give 12
= 20.67 kJ energy.
87. (6.00)
K P = K C(RT) Δn g, Δn g = 1(For given reaction)
600.1 = 20.4(RT) 1
⇒ T ≈ 354K
T 354
60
= 60 ≃ 6
88. (12.00)
The electronic configuration of Vanadium is 1s2, 2s2, 2p6, 3s2, 3p6, 4s2, 3d3.
Thus, the number of electrons in p-orbitals = 12.
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89. (7.00)
Using the integrated rate law for first order reaction –
[R] 0 kt
log [ R ] = 2.303
t
2.4 × 10 − 2 k × 60
⇒ log = 2.303
1.6 × 10 − 2
3 k × 60
⇒ log 2 = 2.303
k × 60
⇒ (0.4771 − 0.3010) = 2.303
0.1761 × 2.303
⇒k= 60
= 0.00676 min -1 or 6.76 × 10 -3 min -1
90. (4.00)
The mass of glucose present in 1 L of blood = 0.72 g
0.72
Thus, moles of glucose present in 1 L of blood = 180 = 0.004 = 4 × 10 − 3
Since molarity is defined as the moles of solute present in 1 L solution, molarity of the given solution =
4 × 10 − 3 M
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