Complete NEET

Chemistry-
handwritten notes

By Mayur
By Mayur Pawar
Pawar [1st
[1st
year MBBS
year MBBS ~MGIMS]
~MGIMS]

Mayur Pawar Neet

https://t.me/mayurpawarnotes
Complete
physical
CSD@Sarvesh Dixit Sir
Solid
state
@Mayur Pawar
 Solid state

.ua/. . . .
Close packing

pF=Z✗ʰsa%
i>

=
2D 3D
body diagonal ☒ ☆ (4)
☆ 2D
=

' "1=2

-Ga☆i v

Unitceygqy.gg CN=4
① Simple / Primitive V. C. : -
PF= 78% cN=6

FF 91%
2=1
=

☆ 28=9 ☆

PE
¥
☆ - = 52.4%

Body centered Urc 3- D

② : -

☆ 4z=✓3a CN=SÉhf ✓ ①← ②
SCP ( SCC)
→

BCP
✓ ② ✓④
CCP
⑥v
HCP

☆ 2=2 ④q ( BCC) pf .
( Fcc)
6
/ 8 12 12

Fs 68 % 52.4% 68% 74% 74%

PE
=

☆ =
AAA . . . ABAB . . . ABC ABC .. .
ABAB ..

In CCP / HCP
Voids. }
: -

HCP
③
→
3-2 FCC
-_

.
.

.
¥dy
+
④ → NO of particles / +"

☆ 48 = Fda . .

Diagonal
④ Tetrahedral void
→
.

☆ 2=4 ④ → Octaid .

☆ 1
Body Diagonal 2 TV ⑨ Attach =
.

☆ DE = JI = 74% : . 1 Cube ( Fcc) = 41313=8 TV .

wit "
atom
""

3rd
☆ Octahedral :-(surrounded by spheres)
-
: [ ontoibutioi) : _
6 .

Centre & point of

nt
Body Mid
Edge length
• +
on
-

Face
Cooner
Body .
• Total Oct . Voids =

1×1+12×14=4
¥
.

1 ↳
¥ { Body Centre
Edge Centre .

* Attack

Total = 8 6 1 with one

atom .
 Defects

Stoichiometric Impurity Non -

stoichiometric .

Defects .
Defects .
defects .

eg ④ So"= ④ Nat ( d- block)

:
leave
-

④ 502-1 =
④ Cationic
vacancy .

&
① Cdclz Agcl
/ Donojaate Koi bh
;
/ Metal excess Metal
Thai SE g ② Sock & NaCl
.
.

⑨[nÑF@g
defect
deficiency
defect defect "
"
" ""
" defect .

.gg??y,age9:-Fe0
I

[yy) (g)
☆ A+ and due to due to ↓
on
apni
Feo .gr to
B- Anionic
apni jagan se
Vacancy .
,
Feo .g6O
cation
Jagah bicb Mein
'

se ① Anion Absent

soV0id# ☆
Excess cation is
Bahar Scotch Chale
jate
-

created which + at in interstitial

hair
pine Chale is
space .

occupied by
]
☆ To Maintain Electrical
Jaate hai ! [ A hole "
E-
.

Neutrality an e-

[ A
pair of holes ] %
: -

Schottky -
is also
stitiae
+ nt

space
in

.
inter

defect .

Frenkel
Nacl Yellow eg : -
-
.

Ka → Violet .
defect .

ZnO →
Yellow .

Study of ionic
crystal
⑥ Radio
Limiting Radio : -

0.155 0.225 3 Plane

Trigonal .

0.225 0^414 4 Tetrahedral .

0.414 0.732 6 Octahedral .

0.732 1 .
8 Cubical .
÷
:

0
0 &
*
☆
Redox
reactions
@Mayur Pawar
 ⚡
Electrochemical series:- ·
NHxNO3 > NH4
I
+

NO5

+ 35 +
I
S
OA
SRPA Bleaching
Powder

· (o!
·
[aOCl2
F

⑧ ⑧
⑧
Il

--
11
-
·
BU, 08 t 6 +
4 6 I
: -
B8 -
By -
B8 - ⑧
-/ -

0 0

·
Feo g4O
.
: - Fe : - +
2 0 : --2 .

·
[Fe(MO)sN] s : -
Brown
Ring Complex .

Fe : - +
1

Steps for balancing the

redox reaction:-
Oxidation No:- 1 For
Assign o N .
. each element

Oxide -62- Peroxide : -O? Jaha Jaha Wake waka

2
change
·
·
:

O
Superoxide : connection
· -
.

·
Marshall Acid : - ·
Carose Acid :
-
3) Jaisa connection waisa likhneka .

H2Sc08 H2SOS 4 Balance the element

2 2
undergoing
5-2 8-
-

change
g
11
.

-
· 1 -1 I 11 -1- 1
H-0-s-0-0
I
-
S -0 -H H -
S -0 -0 -
H 5) Balance all other elements except
! !
-

6
- 2 - 2

I6
! 6
Oxygen
Balance
&
hydrogen
with
.

water
Oxygen
+

Ht
·
Blue Chromate : -
7) Balance
hydrogen by
980s .
KCw08 8) Balance
charge by e
-
2
0 3 Add both the sides

cr
9) Or &
-

8
I
o We

[1
Il
~

in
balanced Basic Med."
I- get eg" in

s
-o

·
- I
0 · C8
0
I
- ->

-
O
V I
-
I -

+
G

+
S
Acidic medium
1
hydrides
- +
covalent
=

· H

↳-1= Ionic
hydrides .
 Acidic medium

Basic medium

Basic medium
Types of redox reactions: -
1) Intermolecular Redox Rx : -

a) Combination R R . : -

4
+
2
c 0
-

+
- CO2

2) Displacement Redox Rx" :-

a) Metal R R .:
Displacement
-
.

2n +
CUSO4 ↑ InS04 +
Cr @Mayur Pawar

b) Non-Metal R R .:
Displacement .
-

F2 +
2kI > 2KF +
Iz

3)
Intramolecular Redox Rx" : -

(NMx)2Cr207 >N2+CW20b +4/20

Neet
4) Disproportionation
3 BU2 +GNaOH NaBrOs+SNaBr +

same element 3 H20

undergo oxidation &

Reduction .

5)
Comproportionation Redox Rx" : -

-
3 + 5 0

NH4 NO3 >

N2 + 2 H20

Jee
Cuz FezS4 ~ CrFeS2
CULS FezSs CuS FeS
1 +3 + 2 +2
+
Atomic
structure
 Canal
Rays
Anode Rays [+ve]
.

Cathode says .

Ma> Mn > Mp>Me

M Me
Shortes
, ne

Limiting Line
 /atom
.

2 .
176
TE
=
 -
0 81
.

ev/atom
hai
Mr- Jahase Kudhra

Kudhra hai
Jahaps
.

=
Jim P
.

- 1 5x18 V 2
18 x 108/s
T
= .

= .

22
⑧

R =
0 .

529A
E =
-
13 6.
ev
x
2
/atom
E - 2
=
.
16x188/atom .
at +

ot
- + (E- v .
 Graphical Representation
:
* P-orbital :
-

RN =
D
2P

P
1S RN = 0 Always
+
ve
↑ ↑

l S S
S+-
↑ O 4 OP
P
4JTEd x

Y
↑ P

M
2 z z

3p RN = 1

T
↑ P

~ el e
8 3

=0
N P 0
RN 1 4 0
=

2S
= =

⑧
⑧
2 ↳ z

p Electronic Configuration
:

P
-

L hi ④
S pdf
I 234
Trick
-
1S 35
- ⑧
25
24
3 2

live hai 34453d 44

35 RN =
2 J- Dok bar zero .

6S
55 4d Sp
↑

..
T

L m
4F 5d op 75

i⑧ & o &

-
⑧ ⑧

j
5f6d =P 85
Mole Concept
 I
-
Redox Redox reaction

reaction
Redox reaction
Ionic
equilibrium
t
 V, +
V2

V, V2
+
1 = n-factor hai !
~
↑

-
.
E
-
s
8
.
1
uchbirlbonjugate
e
 Exce -

Acid
- -
=

>
Agai toh I S
o
pok I
Loga
Bane
again
rong
weak-Strong
-
>

I
excess .

-
Chemical
equilibrium
 -
Kitne Tutgaye
Kitte pahile the

initial
· VP Marg
2

Siix=
Marg
 B
*
Solution
 H-bond>P-P > P-NP > NP-ND

*
~ Mwt .

change by changing : -

not
(d) V P
.
.
will
of container
is
stape
.

2) Amt - of Liquid .

3) S A
. .
of Containes
 > Non Reactive
hone
2) Attrac equal
chahiye .

Piam
b) Piyada > P+ > .

usi
Frack jyada koga VP

3
* Kole Total
.

Tiska
v P Ke pass
Ke
.

liquid
.

nogi
.

value
P
+
=

(P1t -

PB) XE +

PB of
sol" Ki
mole hai :
-

PAY) Xi +PA & Liq-B

=

equal
P+ =

(B -

>
A Lig-A
Pr = PA PB+

i
Ka V P
solution
.

Frack"1"
.

Tiske near
uska Mole

"zero
.
Maxed Max- O
dusreka
"

Min =
0 Mik - 1
Chemical
kinetics
#
Sin
Kuckta wai
no
At Ar-kt -(e)
i
=

c xx
y
-
=
·
 zero or del
x =

kt

tyz =

A/2K
First order .

1
+
0
=

=
 -

In +
kt
093
=
=

At

+ 2
30310g,
=
.

109 Ar-logA
=
1 +
,
2 303
.

mx
logAloA Kt/2 303
-

- .
.
.
 Zero order .
First Order . Second Order .
nth order : -

*
( ]"n+(jt
2+yz =
e
=

k =

x = Ar-At
2k
tyz =

142 +y = (i)
B
.T

Thermodynamics
E
↳ Ele
 S= - W

-
-

=
--
stat?
Thermochemistry .

of Formation
:

1 Heat
-

* E
Imoe form" molecule
by their natural
-

form of autom

AME
3
-> 0
Natural Form
=

AHF O

CCs) -
graphite .

AMF =

(Mf)p-(AHf)R
↓h A +
R2B - h3C+MD- balance hai

-(AHf)R

[Nx(AMf)c (AMr) ,]- (n (Anfx+

=
+
14 .

12 (aMf)is]
is state Fi
Enthalpy
* a .

↳ math
15 do
Chemical
Eg" Ko se Solve

2) Heat ofneutralization :
-
HON =
(Hflno
hai
/mole
⑯
>
-
Water Ke Form" Ki
Energy .

SA+SB= salt+Hex E7 SK5 . .

->
some amount of heat is used for
ionis" of WA or WB .

AH <-57 5KJ
A/B Weak *B
3
:Weak + .

08

Strung A/B
3) Heat of ionisation (101) : -

Meat
req
for ionisation of Imole WA/WB .

Earne-IHON
↳
WA/WBI Of
Kcal
Acidic
Strength /HON
.

&

HON= exothermic .

pail * al
Tempr
-> Wise

independent upon amt .

or Acid & Base .

4) Heat of Combustion :
-
(AHd)
Heat in combustion of
1mole molecule .
exchange

Ene(Arc - (And --
Pc
>
enava .

Eme(AMf)p-(AMf)R
Standard Heat of Combustion . (AM)
nee
↳ i
T 298K"
=

Ene Calorific
value
- Heat

COMIsound
released

.
in combust" of
Igin of

"Fuel "
Measure
Efficiency
~
.

Ernes Att of Molecule Mwt AHc

->
Calorific =
.

Jatue M Wt -
.

1gx
Mwt
5) Heat of Atomisation :
-

Heat for form" of 1 mole of

reg
form of dement
gal
atom
by nature .

Ed Ed
Natural / mole
I
Fowk Gra
Atok

Bond
Enthalpy Feat :

to break /mole
reg
covalent bond of molecule & form
gaseous
gas atoms

E
.

-
Ga
↳ Ga
Molecule A TOMS
 Heat of Atomis Heat of Sublimation
# =
of Metal -
of Metal .

↳ M(s) ->
M(g) 1
E
* Average Bond
Enthalpy :
-
H
I
CH4 = 2 +

41 =
x( , +
x2 +

x3 +
34 C
n ↳n
4 molec -
1 =
-
H
Imole (-1 =
x[1 +
32 +

33 +
34

&
- (3p3- P3 :"re
6) Heat of Fusion :
-

solid -Liquid AM ve] at Mpt .

- . = +
,
(Imole) (1mole) .

7) Heat of
vapourisation : -

Liquid
(Imoe)
>
Vapour
(I mole .
Aniap =
+
relat B .
pt .

8) Heat of Sublimation :
-

solid
(Imoe)
>Japore
(Imole) Eme
Alsub= Atrapt AHfus
↓
.

E
i
State Fo" Enthalpy
3
Al sub

Awa
⑤
.

-G
Alfu, Attrap .
 of Dilution & Solution
9) Heat Hydration , .

CuS04(s) + SH2D >

CUSO4 SH20.
+
20120

White AHryd Blue SO1" Andil

- -

AMsol" CUSOp
AMdil
AMmyd
> > . 2SH20

2000H20
-

AHsol"
W

CUSO4 . 202SH20

Heat of Al=-ve
Hydrogenation
10) :
-

always .

Heat release in add" of Imple He in

unsaturated compound .

* Effect of
Temp in Heat of Rx : -

(Kirckoff's Law) .
AH , = Heat of Rx" & Ti
Alz =
Heat of Rx" & To

AH
AMa= At
cp .

Molar heat
Ap =

Capacity
of Product -

AH2 = AH 1 +ACp(T2-T ) , Mular heat

capacity
of Reactant .

AW2 =
AU , + ACrCTa-T ,

Tz =
Final Tempo
T initial
Teiy3
.
=
* BOMB Calorimeter :
-

Experimental process to calculate Heat of

Rx" at const" P & V .

Heat
Capacity of Calorimeter x AT
Ar
Organic Compound
= x M Wt
.
of .

of
Mass
Organic Compound .

AM Ar+
ARgRT
=
.
States of
Matter
 C
B

P V A
i T

G
 (5> a ,)

* (1) a >
 in

Attract -
-
 micheleuska
jitna kam
Graph utna !
jayega ↓hoga
Tem
 critical
condition
*
2 =
Solid
state
⑳
Electrochemistry
 Constant
- Conductance x Cell

factor

A1z(50n) > =
2 (
+

3)16

3C , xm0x * but 14

x xY

Finite ↓ ↓
dilution infinite dilution.
 1 =
-
B .

Exi

dilution .
-
-
-
 Kuch nai bs M =
S

xm
=

Ha

in

-P V
· -I

⑨
CD 6

I
Am
=

= X
 Daniel Cell : -

->
Ed
mathode
-> PO de !

LR
-

R -

Extent
somehere -
-

D , R2 =
Total no
.
of mole of

e-exchange during red"

 Qc= ]
[R]

of Cell
Representat" .

Anode Salt Cathode

hauf t half
cell
bridget
cell
.

AG = - 2 .
303RTlogkeg
I To half cell of
get
Max . Ecell : -

Ecen (SRP),
(SRY
-

↓
Maximum Min
( + vel (- vaS

(SRP), ↑+ = cathode .

W
/
X
Kon Deposit hoga : -

->
Joh niche hoga
wor reduce
hoga .

-> Joh Metal E CS

.
.
.

mein sabse nicke

hoga
Woh Reduce Lokal

Mis) banayega mutlab

deposit hoga !
Oxidation : - Anion .

SO
-

> NO5 <

-

x <n

* ot
(2x) (404)
Reduction :
- Cathode .

SRPM :
-
Reduction -
Occul
-
-

ist
.

Joh niche
hoga .
 Sin

I
confusio Galvanic Cell
Electrolyte Cell.

Anode : - ⑦ ⑰

Cathode : - ⑦

AG =
0 -
ve AG =
+ Ve
,

nFE
nFEceY
AG = - A G =
-

(not applicable)
IF pan
Kiya tok
1gi Equivalent
deposit hoga !

Eit
W =
z it =

2 Ent
Ent= Ant - 96500
n factor .

Ent=
Mut
 10
Battery : -

2
0
Ecol = +2 . 041 V .

] dec
use
.

.
during

Anode Pbrod
non-rechargable Rechargable
.
. : -

Chemical - Elec E C E E
E. E Cathode of Pb
. . .
.
.
:
-grind .

Electrolyte : -
38 % (w/w) H2SO4 sol"
↑Battery : -

Lac-lanche cell :
a)
Dry cell
E E
or -

Discharge Rx" : - C E . .
-> . .

Pb +
Pb0c -> PbSO4 + PbSO4 .

Anode -[PIs) 2 2e -> +

-

Ry EE C E
Charge
: : -
.
.
- . .

MnOz +NA -> M +NMsY

4 + I

Cathode : -
PbSO4 + Pb50x -Pb
+
PbOz

-3 +
1 51V
.

Ewing
ene
FUEL CELL :
2 H2 0
-

= zH20 /H =- ve
+

Cathode : -

Graphite rod .
2 =
4 x100
G
= #4x100
-
F Eccl

Anode : - In .

CORROSION :
-

NMuCI, MnO2 InCl2

Electrolyte : -

,
eg
:-
Renting of iron .

3
+

b) Button cell Rut : Fe2O3

In-Hg cell : CH20
-
or -
. .

Fels) -> Fet + 2e Anode .

Anode 02 + 2e 2H20 -> 40H Cathode

In-Hg
: - +

Cathode : and Form Feo

Hg0 paste
-
. .

K01 FeO ais

FezDz C120
Electrolyte :
>
-
. .

2
+
3
. CRIT
0
+

+2 0
200
In-Hg+ HgO +Mg
->

Ecel=+1 . 31 . (Const .

Battery
2 : -

a) Lead
-Pb
Battery : -

Anode : +
H2SUn->PbSO4 +
H2

Cathode : -PbOz+H2SO4 -> PbSO4 + So,

+ 2420

2H2SO4 + Pb +
PbOz->PbSOx +PbSO4 .