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Table 1 (Order of Preference) and Table 2 (No Preference)

The document presents two tables that outline different functional groups in order of decreasing priority: 1. Table 1 lists common functional groups from highest to lowest priority, including carboxylic acids, sulphonic acids, acid anhydrides, esters, acid halides, acid amides, cyanides, iso-cyanides, aldehydes, ketones, alcohols, thioalcohols, amines, imines, alkenes, and alkynes. 2. Table 2 lists functional groups that do not have a priority order and are used only as prefixes, such as N-alkyl amino, N-alkyl/N,N-di alkyl amino, nitro, nitro

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0% found this document useful (0 votes)
69 views1 page

Table 1 (Order of Preference) and Table 2 (No Preference)

The document presents two tables that outline different functional groups in order of decreasing priority: 1. Table 1 lists common functional groups from highest to lowest priority, including carboxylic acids, sulphonic acids, acid anhydrides, esters, acid halides, acid amides, cyanides, iso-cyanides, aldehydes, ketones, alcohols, thioalcohols, amines, imines, alkenes, and alkynes. 2. Table 2 lists functional groups that do not have a priority order and are used only as prefixes, such as N-alkyl amino, N-alkyl/N,N-di alkyl amino, nitro, nitro

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Table-1

Different Functional group & their periority order:(decreasing from TOP to BOTTOM)

Functional Group Structure Prefix Suffix


Carboxylic acid – COOH Carboxy oic acid
Sulphonic acid –SO3H sulpho sulphonic acid
Acid anhydride –OC–O–CO– -anhydride oic anhydride
Esters –COOR alkoxy carbonyl alkyl alkanoate

Acid halides –COX halo formyl oyl halide


Acid amides –CONH2 carbamoyl amide
Cyanides – C{N cyano nitrile
Iso-Cynide –N{C Iso-cyno isonitrile(Carbil amine)

Aldehydes –CH=O formyl / aldo al


Ketones C=O oxo / keto one
Alcohols –OH hydroxy ol
Thioalcohols –SH mercapto thiol

Amines –NH 2 amino amine


Imine C=NH imino imine
Alkenes C=C Alkenyl ene
Alkynes –C{C– Alkynyl yne

Table-2
Groups which do not have any periority order ( Used ONLY as PREFIX)

-NHR N-alkyl amino


-NR2 N-Alkyl, N-Alkyl amino or N,N-di Alkyl amino
–NO2 nitro
–N=O nitroso
–X (F,Cl,Br,I) halo
–R alkyl
–O R Alkoxy ( Smaller alkyl group will be considered with ‘O’ alkoxy)
O
/ \ epoxy or Oxirane
! C  C 
-N=N- azo
=N diazo
or –Ph or Phenyl
C6H5- or I -

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