PFR100 PFR100 United Kingdom English OIC-EH Oilfield 1024269

Conforms to Regulation (EC) No.
1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI

2019/758
SAFETY DATA SHEET

Version
6
PFR100
SECTION 1: Identification of the substance/mixture and of the company/

undertaking
1.1 Product identifier
Product name : PFR100
EC number : Not available.
CAS number : Not available.
Product code : PFR100
Product type : Liquid.
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended use : Solvent

Identified uses
EC 203-625-9 Distribution of substance - Industrial
EC 203-625-9 Use in laboratories - Industrial
EC 203-625-9 Use in oil and gas field drilling and production operations - Industrial
Uses advised against Reason

It is recommended that this material is not used for any other Baker Hughes cannot confirm compliance with
purposes than those referenced under "Identified Uses". the REACH regulations for non-identified uses.
1.3 Details of the supplier of the safety data sheet

Baker Hughes
Kirkby Bank Road,
Knowsley Industrial Park,
Liverpool,
L33 7SY, UK
Tel: +44 (0)151 545 3899

Fax: +44 (0)151 547 3590
e-mail address of person : [email protected]

responsible for this SDS
1.4 Emergency telephone number

Supplier
Telephone number : CHEMTREC Emergency Telephone within UK: 0870 820 0418
CHEMTREC Emergency Telephone outside UK: +44 870 820 0418
Date of issue/Date of revision : 19 October 2022 Date of previous issue : 29 July 2020 Version :6 1/33
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 830/2015 -
United Kingdom (UK)
PFR100
SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Product definition : Mono-constituent substance
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Flam. Liq. 2, H225
Skin Irrit. 2, H315
Repr. 2, H361d
STOT SE 3, H336
STOT RE 2, H373
Asp. Tox. 1, H304
2.2 Label elements

Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms :
GHS02 GHS08 GHS07

Signal word : Danger
Hazard statements : Highly flammable liquid and vapour.
May be fatal if swallowed and enters airways.
Causes skin irritation.
May cause drowsiness or dizziness.
Suspected of damaging the unborn child.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Prevention : Obtain special instructions before use. Wear protective gloves, protective clothing,
eye protection, face protection, or hearing protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Do not
breathe vapour. Wash thoroughly after handling.
Response : IF exposed or concerned: Get medical advice or attention. IF INHALED: Call a
POISON CENTER or doctor if you feel unwell. IF SWALLOWED: Immediately call a
POISON CENTER or doctor. Do NOT induce vomiting. Take off contaminated
clothing and wash it before reuse. IF ON SKIN: Wash with plenty of water.
Storage : Store in a well-ventilated place. Keep container tightly closed.
Disposal : Dispose of contents and container in accordance with all local, regional, national
and international regulations.
Hazardous ingredients : PFR100
Hazard statements : H225, H304, H315, H336, H361d, H373
(Code)
Precautionary statements : P201, P280, P210, P260, P264, P308 + P313, P304 + P312, P301 + P310, P331,
(Code) P362 + P364, P302 + P352, P403 + P233, P501
Annex XVII - Restrictions : Shall not be placed on the market, or used, as a substance or in mixtures in a
on the manufacture, concentration equal to or greater than 0,1 % by weight where the substance or
placing on the market and mixture is used in adhesives or spray paints intended for supply to the general
use of certain dangerous public.
substances, mixtures and
articles
2.3 Other hazards
United Kingdom (UK)
PFR100
SECTION 2: Hazards identification

Product meets the criteria : PBT P B T vPvB vP vB
for PBT or vPvB according
to Regulation (EC) No. N/A N/A N/A Yes N/A N/A N/A
1907/2006, Annex XIII
Other hazards which do : None known.

not result in classification
SECTION 3: Composition/information on ingredients

3.1 Substances : Mono-constituent substance
Product/ingredient name Identifiers % by weight Regulation (EC) No. Type
1272/2008 [CLP]
toluene REACH #: 60 - 100 Flam. Liq. 2, H225 [A]
01-2119471310-51 Skin Irrit. 2, H315
EC: 203-625-9 Repr. 2, H361d
CAS: 108-88-3 (inhalation)
Index: 601-021-00-3 STOT SE 3, H336
STOT RE 2, H373
(central nervous
system (CNS))
(inhalation)
Asp. Tox. 1, H304
See Section 16 for
the full text of the H
statements declared
above.
There are no additional ingredients present which, within the current knowledge of the supplier, are classified and
contribute to the classification of the substance and hence require reporting in this section.
Type
[A] Constituent
[B] Impurity
[C] Stabilising additive
Occupational exposure limits, if available, are listed in Section 8.
SECTION 4: First aid measures

4.1 Description of first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Continue to rinse for at least 15 minutes. Check for and remove any
contact lenses. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
If not breathing, if breathing is irregular or if respiratory arrest occurs, provide
artificial respiration or oxygen by trained personnel. If unconscious, place in
recovery position and get medical attention immediately. Maintain an open airway.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash
clothing before reuse. Clean shoes thoroughly before reuse.
United Kingdom (UK)
PFR100
SECTION 4: First aid measures

Ingestion : Wash out mouth with water. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Aspiration hazard if
swallowed. Can enter lungs and cause damage. Do not induce vomiting. If
vomiting occurs, the head should be kept low so that vomit does not enter the lungs.
Never give anything by mouth to an unconscious person. If unconscious, place in
recovery position and get medical attention immediately. Maintain an open airway.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it
is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation.
4.2 Most important symptoms and effects, both acute and delayed
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:,pain or irritation,watering,redness
Inhalation : nausea or vomiting,headache,drowsiness/fatigue,dizziness/vertigo,
unconsciousness,reduced foetal weight,increase in foetal deaths,skeletal
malformations
Skin contact : irritation,redness,reduced foetal weight,increase in foetal deaths,skeletal
malformations
Ingestion : Adverse symptoms may include the following:,nausea or vomiting,reduced foetal
weight,increase in foetal deaths,skeletal malformations
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable : Use dry chemical, CO₂, alcohol-resistant foam or water spray (fog).
Not suitable : Do not use water jet.
5.2 Special hazards arising from the substance or mixture
Special exposure hazards : Highly flammable liquid and vapour. Runoff to sewer may create fire or explosion
hazard. In a fire or if heated, a pressure increase will occur and the container may
burst, with the risk of a subsequent explosion.
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Hazardous thermal : carbon dioxide,carbon monoxide
decomposition products
5.3 Advice for fire-fighters
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves)
conforming to European standard EN 469 will provide a basic level of protection for
chemical incidents.
Additional information : Not available.
United Kingdom (UK)
PFR100
SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapour or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".
6.2 Environmental : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
precautions and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
6.3 Methods and material for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach the release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations. Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilt product.
6.4 Reference to other : See Section 1 for emergency contact information.

sections See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.
SECTION 7: Handling and storage

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
7.1 Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Avoid exposure during pregnancy. Do not
handle until all safety precautions have been read and understood. Do not get in
eyes or on skin or clothing. Do not breathe vapour or mist. Do not swallow. Use
only with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Do not enter storage areas and confined spaces unless adequately
ventilated. Keep in the original container or an approved alternative made from a
compatible material, kept tightly closed when not in use. Store and use away from
heat, sparks, open flame or any other ignition source. Use explosion-proof electrical
(ventilating, lighting and material handling) equipment. Use only non-sparking tools.
Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.
United Kingdom (UK)
PFR100
SECTION 7: Handling and storage

Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.
7.2 Conditions for safe storage, including any incompatibilities

Storage : Store in accordance with local regulations. Store in a segregated and approved
area. Store in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10). Store in original container, protected from direct sunlight. Store
locked up. Eliminate all ignition sources. Separate from oxidising materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not
store in unlabelled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.
Recommended Packaging : Use original container.
materials
Seveso Directive - Reporting thresholds
Danger criteria
Category Notification and MAPP Safety report threshold
threshold
P5c 5000 tonne 50000 tonne
7.3 Specific end use(s) : Solvent
SECTION 8: Exposure controls/personal protection

The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the
Exposure Scenario(s).
8.1 Control parameters
Occupational exposure limits
Product/ingredient name Exposure limit values
toluene EH40/2005 WELs (United Kingdom (UK), 1/2020). Absorbed
through skin.
STEL: 384 mg/m³ 15 minutes.
TWA: 191 mg/m³ 8 hours.
TWA: 50 ppm 8 hours.
STEL: 100 ppm 15 minutes.
Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace
procedures atmosphere or biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to European Standard EN 689 for
methods for the assessment of exposure by inhalation to chemical agents and
national guidance documents for methods for the determination of hazardous
substances.
DNELs/DMELs
United Kingdom (UK)
PFR100

The list of Identified Uses in Section
Product/ingredient name 1 should
Typebe consulted for any available
Exposure use-specific
Value information provided
Population in the
Effects
toluene DNEL Short term 226 mg/m³ Workers Systemic
Inhalation
DNEL Short term 226 mg/m³ Workers Local
Inhalation
DNEL Long term 56.5 mg/m³ Workers Systemic
Inhalation
DNEL Long term 226 mg/m³ Workers Local
Inhalation
DNEL Long term Dermal 226 mg/kg Workers Systemic
bw/day
DNEL Long term Oral 8.13 mg/ Workers Systemic
kg bw/day
DNEL Long term Oral 8.13 mg/ General Systemic
kg bw/day population
DNEL Long term 56.5 mg/m³ General Local
Inhalation population
DNEL Long term 56.5 mg/m³ General Systemic
DNEL Long term 192 mg/m³ Workers Local
Inhalation
DNEL Long term 192 mg/m³ Workers Systemic
Inhalation
DNEL Long term Dermal 226 mg/kg General Systemic
bw/day population
DNEL Short term 226 mg/m³ General Local
DNEL Short term 226 mg/m³ General Systemic
DNEL Long term Dermal 384 mg/kg Workers Systemic
bw/day
DNEL Short term 384 mg/m³ Workers Local
Inhalation
DNEL Short term 384 mg/m³ Workers Systemic
Inhalation
PNECs
Product/ingredient name Compartment Detail Value Method Detail
toluene Fresh water sediment 0.68 mg/l Assessment Factors
Marine water sediment 0.68 mg/l Assessment Factors
Sewage Treatment 13.61 mg/l Assessment Factors
Plant
Soil 2.89 mg/kg Assessment Factors
8.2 Exposure controls

Occupational exposure : Use only with adequate ventilation. Use process enclosures, local exhaust
controls ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. The engineering
controls also need to keep gas, vapour or dust concentrations below any lower
explosive limits. Use explosion-proof ventilation equipment.
Individual protection measures
United Kingdom (UK)
PFR100

The list of Identified
Hygiene measures Uses in Section 1 should
: Wash be consulted
hands, for any
forearms and faceavailable use-specific
thoroughly information
after handling provided
chemical in the
products,
before eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Considering the parameters specified by the glove manufacturer,
check during use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material may be
different for different glove manufacturers.
Eye protection : Wear chemical safety goggles. When transferring material wear face-shield in
addition to chemical safety goggles.
Skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to
controls ensure they comply with the requirements of environmental protection legislation.
In some cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.
SECTION 9: Physical and chemical properties

The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.
9.1 Information on basic physical and chemical properties

Appearance
Physical state : Liquid.
Colour : Colourless.
Odour : Characteristic. Aromatic.
Odour threshold : Not available.
Melting point/freezing point : Not available.
Initial boiling point and : >88°C
boiling range
Flammability (solid, gas) : May be combustible at high temperature.
Upper/lower flammability : Not available.
or explosive limits
Flash point : Closed cup: 4°C (39.2°F) [Pensky-Martens]
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
pH : Not available.
Viscosity : Kinematic (40°C): 1 to 7 cSt
Solubility : Insoluble in the following materials: cold water.
Partition coefficient: n- : Not applicable.
octanol/water
Vapour pressure : Not available.
United Kingdom (UK)
PFR100
SECTION 9: Physical and chemical properties

Evaporation rate : Not available.
Evaporation rate (butyl : Not available.
acetate = 1)
Relative density : 0.867 (20°C)
Vapour density : Not available.
Explosive properties : Not available.
Oxidising properties : Not available.
9.2 Other information

Pour point : Not available.
SECTION 10: Stability and reactivity

10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.
10.2 Chemical stability : The product is stable.
10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions
10.4 Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
10.5 Incompatible : Reactive or incompatible with the following materials: oxidising materials
materials
10.6 Hazardous : Under normal conditions of storage and use, hazardous decomposition products
decomposition products should not be produced.
SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
toluene LD50 Oral Rat 636 mg/kg -
Conclusion/Summary : No known significant effects or critical hazards.
Acute toxicity estimates
N/A
Irritation/Corrosion
Skin : May cause skin irritation.
Eyes : No known significant effects or critical hazards.
Respiratory : No known significant effects or critical hazards.
Sensitisation
Skin : No known significant effects or critical hazards.
Respiratory : No known significant effects or critical hazards.
Mutagenicity
Carcinogenicity
United Kingdom (UK)
PFR100

Reproductive toxicity
Conclusion/Summary : Suspected of damaging the unborn child.
Teratogenicity
Conclusion/Summary : Not available.
Specific target organ toxicity (single exposure)
Product/ingredient name Category Route of Target organs
exposure
toluene Category 3 - Narcotic effects
Specific target organ toxicity (repeated exposure)
Product/ingredient name Category Route of Target organs
exposure
toluene Category 2 inhalation central nervous
system (CNS)
Aspiration hazard
Product/ingredient name Result
toluene ASPIRATION HAZARD - Category 1
Information on likely routes : Not available.

of exposure
Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness.
Skin contact : Causes skin irritation.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed
and enters airways.
Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:,pain or irritation,watering,redness
Inhalation : nausea or vomiting,headache,drowsiness/fatigue,dizziness/vertigo,unconsciousness,
reduced foetal weight,increase in foetal deaths,skeletal malformations
Skin contact : irritation,redness,reduced foetal weight,increase in foetal deaths,skeletal
malformations
Ingestion : Adverse symptoms may include the following:,nausea or vomiting,reduced foetal
weight,increase in foetal deaths,skeletal malformations
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
United Kingdom (UK)
PFR100

Potential chronic health effects
Not available.
Conclusion/Summary : Not available.
General : May cause damage to organs through prolonged or repeated exposure.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Reproductive toxicity : Suspected of damaging the unborn child.
Other information : Not available.
SECTION 12: Ecological information

12.1 Toxicity : No known significant effects or critical hazards.
Product/ingredient name Result Species Exposure
toluene Acute EC50 433 ppm Marine water Algae - Skeletonema costatum 96 hours
Acute EC50 11600 μg/l Fresh water Crustaceans - Gammarus 48 hours
pseudolimnaeus - Adult
Chronic NOEC 500000 μg/l Fresh Algae - Pseudokirchneriella 96 hours
water subcapitata
12.2 Persistence and degradability

Product/ingredient name Aquatic half-life Photolysis Biodegradability
toluene - - Readily
12.3 Bioaccumulative potential

Product/ingredient name LogPow BCF Potential
toluene 2.73 90 low
12.4 Mobility in soil : Not available.
12.5 Results of PBT and vPvB assessment

Product/ingredient name PBT P B T vPvB vP vB
PFR100 N/A N/A N/A Yes N/A N/A N/A
12.6 Other adverse effects : No known significant effects or critical hazards.
SECTION 13: Disposal considerations

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
13.1 Waste treatment methods
Product
United Kingdom (UK)
PFR100
SECTION 13: Disposal considerations

Methods of disposal : The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of
all authorities with jurisdiction.
Hazardous waste : The classification of the product may meet the criteria for a hazardous waste.
Packaging
Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
Special precautions : This material and its container must be disposed of in a safe way. Care should be
taken when handling emptied containers that have not been cleaned or rinsed out.
Empty containers or liners may retain some product residues. Vapour from product
residues may create a highly flammable or explosive atmosphere inside the
container. Do not cut, weld or grind used containers unless they have been cleaned
thoroughly internally. Avoid dispersal of spilt material and runoff and contact with
soil, waterways, drains and sewers.
SECTION 14: Transport information

International transport regulations
Regulatory 14.1 UN 14.2 Proper shipping name 14.3 Transport 14.4 PG* Label
information number hazard class(es)
ADR/RID Class UN1294 Toluene 3 II
ADN Class UN1294 Toluene 3 II
IMDG Class UN1294 Toluene 3 II
IATA Class UN1294 Toluene 3 II
PG* : Packing group

Regulatory 14.5 Additional information
information Environmental
hazards
ADR/RID Class No. Hazchem code
3YE
ADN Class Yes. The product is only regulated as an environmentally hazardous substance
when transported in tank vessels.
United Kingdom (UK)
PFR100
SECTION 14: Transport information

IMDG Class No. -
IATA Class No. -
14.6 Special precautions for : Transport within user’s premises: always transport in closed containers that are
user upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
14.7 Transport in bulk : Not available.

according to IMO
instruments
SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorisation
Annex XIV
None of the components are listed.
Substances of very high concern
None of the components are listed.
Annex XVII - Restrictions : Shall not be placed on the market, or used, as a substance or in mixtures in a
on the manufacture, concentration equal to or greater than 0,1 % by weight where the substance or
placing on the market mixture is used in adhesives or spray paints intended for supply to the general
and use of certain public.
dangerous substances,
mixtures and articles
Other EU regulations
Ozone depleting substances (1005/2009/EU)
Not listed.
Prior Informed Consent (PIC) (649/2012/EU)

Not listed.
Persistent Organic Pollutants
Not listed.
Seveso Directive (2012/18/EU)
This product is controlled under the Seveso Directive.
Danger criteria
Category Notification and MAPP Safety report threshold
threshold
P5c 5000 tonne 50000 tonne
Germany water class : 3
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol
United Kingdom (UK)
PFR100
SECTION 15: Regulatory information

Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
15.2 Chemical safety : This product contains substances for which Chemical Safety Assessments are still
assessment required.
SECTION 16: Other information

Indicates information that has changed from previously issued version.
Abbreviations and : ATE = Acute Toxicity Estimate
acronyms CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
N/A = Not available
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
SGG = Segregation Group
vPvB = Very Persistent and Very Bioaccumulative
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification Justification
Flam. Liq. 2, H225 On basis of test data
Skin Irrit. 2, H315 Calculation method
Repr. 2, H361d Calculation method
STOT SE 3, H336 Calculation method
STOT RE 2, H373 Calculation method
Asp. Tox. 1, H304 Calculation method

Full text of abbreviated H statements
H225 Highly flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H336 May cause drowsiness or dizziness.
H361d Suspected of damaging the unborn child.
H373 May cause damage to organs through prolonged or repeated
exposure.
Full text of classifications [CLP/GHS]
United Kingdom (UK)
PFR100
SECTION 16: Other information

Asp. Tox. 1 ASPIRATION HAZARD - Category 1
Flam. Liq. 2 FLAMMABLE LIQUIDS - Category 2
Repr. 2 REPRODUCTIVE TOXICITY - Category 2
Skin Irrit. 2 SKIN CORROSION/IRRITATION - Category 2
STOT RE 2 SPECIFIC TARGET ORGAN TOXICITY - REPEATED
EXPOSURE - Category 2
STOT SE 3 SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE -
Category 3
Date of issue/ Date of : 19 October 2022
revision
Date of previous issue : 29 July 2020
Version : 6
Disclaimer
This information relates only to the specific material designated and may not be valid for such material used
in combination with any other materials or in any process. Such information is, to the best of the company's
knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or
representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy
himself as to the suitability of such information for his own particular use.
Annex to the extended Safety Data Sheet (eSDS)
Identification of the substance or mixture

Code : PFR100
Section 1 - Title
Short title of the exposure : EC 203-625-9 (1)
scenario
List of use descriptors : Identified use name: EC 203-625-9 Distribution of substance - Industrial
Process Category: PROC01, PROC02, PROC03, PROC04, PROC08a, PROC08b,
PROC09, PROC15
Substance supplied to that use in form of: As such
Sector of end use: SU03, SU08, SU09
Subsequent service life relevant for that use: No.
Environmental Release Category: ERC01, ERC02
Market sector by type of chemical product: Not applicable.
Environmental :
contributing scenarios
Health Contributing : General exposures (closed systems) - PROC02
scenarios Use in contained batch processes - PROC01
General exposures (open systems) - PROC08a
Batch process - PROC03, PROC04
Process sampling - PROC02
Laboratory activities - PROC15
Bulk transfers - PROC08b
Drum and small package filling - PROC09
Equipment cleaning and maintenance - PROC15
Storage - PROC02
Industry Association : LOA [Low Olefins & Aromatics]
Processes and activities : Bulk loading (including marine vessel/barge, rail/road car and IBC loading) of
covered by the exposure substance within closed or contained systems, including incidental exposures during
scenario its sampling, storage, unloading, maintenance and associated laboratory activities.
Section 2 - Exposure controls

2.1.0 Contributing scenario :
controlling environmental
exposure for
Product characteristics : Liquid, vapour pressure 0.5 - 10 kPa at Standard Temperature and Pressure
Concentration of substance : Covers percentage substance in the product up to 100 %.
in mixture or article
Amounts used : Fraction of EU tonnage used in region 0.1
Regional use tonnage 7.8e4
Fraction of Regional tonnage used locally 2.0e-3
Annual site tonnage 1.6e2
Maximum daily site tonnage 7.8e3
Frequency and duration of : Emission days 300
use
Date of issue/Date of revision : *** 16/33

PFR100 EC 203-625-9 (1)
Environment factors not : Local freshwater dilution factor 10
influenced by risk Local marine water dilution factor 100
management
Other conditions affecting : Release fraction to air from process (initial release prior to RMM) 1.0e-4
environmental exposure Release fraction to wastewater from process (initial release prior to RMM) 1.0e-7
Release fraction to soil from process (initial release prior to RMM) 0.00001
Technical conditions and : Common practices vary across sites thus conservative process release estimates
measures at process level used.
(source) to prevent release
Technical on-site : Risk from environmental exposure is driven by freshwater sediment. Prevent
conditions and measures to discharge of undissolved substance to or recover from onsite wastewater. No
reduce or limit discharges, wastewater treatment required.
air emissions and releases Treat air emission to provide a typical removal efficiency of 90
to soil Treat on-site wastewater (prior to receiving water discharge) to provide the required
removal efficiency of 0
If discharging to municipal sewage treatment plant, provide the required on-site
wastewater removal efficiency of 0
Organisational measures to : Do not apply industrial sludge to natural soils. Sludge should be incinerated,
prevent/limit release from contained or reclaimed.
site
Conditions and measures : Estimated substance removal from wastewater via on-site sewage treatment 81.1
related to sewage treatment Total efficiency of removal from wastewater after on-site and off-site (municipal
plant treatment plant) RMMs 81.1
Maximum allowable site tonnage (MSafe) based on release following total wastewater
treatment removal 1.2e7
Assumed on-site sewage treatment plant flow 2000
Conditions and measures : External recovery and recycling of waste should comply with applicable local and/or
related to external national regulations.
treatment of waste for
disposal
related to external recovery national regulations.
of waste
2.2 Contributing scenario : General exposures (closed systems)

controlling worker
exposure for
Product characteristics : Liquid, vapour pressure 0.5 - 10 kPa at Standard Temperature and Pressure Readily
biodegradable
Amounts used : Not applicable.
Frequency and duration of : Covers daily exposures up to 8 hours
use
Human factors not : Not applicable.
influenced by risk
management
Area of use: : Assumes use at not more than 20°C above ambient temperature.
Engineering controls : No specific measures identified.
Ventilation control : Provide a good standard of general ventilation (not less than 3 to 5 air changes per
measures hour).
Conditions and measures related to personal protection and hygiene
Personal protection : Wear suitable gloves tested to EN374.

PFR100 EC 203-625-9 (1)
Respiratory protection : Wear suitable respiratory protection (conforming to EN140 with type A filter or better)
and gloves (type EN374) if regular skin contact likely.
2.3 Contributing scenario : Use in contained batch processes

controlling worker
exposure for
biodegradable
use
influenced by risk
management
measures hour).
2.4 Contributing scenario : General exposures (open systems)

controlling worker
exposure for
biodegradable
use
influenced by risk
management
measures hour).

PFR100 EC 203-625-9 (1)
2.5 Contributing scenario : Batch process
controlling worker
exposure for
biodegradable
use
influenced by risk
management
measures hour).
2.6 Contributing scenario : Process sampling

controlling worker
exposure for
biodegradable
use
influenced by risk
management
measures hour).

PFR100 EC 203-625-9 (1)
2.7 Contributing scenario : Laboratory activities
controlling worker
exposure for
biodegradable
use
influenced by risk
management
measures hour).
2.8 Contributing scenario : Bulk transfers

controlling worker
exposure for
biodegradable
use
influenced by risk
management
measures hour).

PFR100 EC 203-625-9 (1)
2.9 Contributing scenario : Drum and small package filling
controlling worker
exposure for
biodegradable
use
influenced by risk
management
measures hour).
2.10 Contributing scenario : Equipment cleaning and maintenance

controlling worker
exposure for
biodegradable
use
influenced by risk
management
measures hour).

PFR100 EC 203-625-9 (1)
2.11 Contributing scenario : Storage
controlling worker
exposure for
biodegradable
use
influenced by risk
management
measures hour).
Section 3 - Exposure estimation and reference to its source

Website: : Not applicable.
3.1 Exposure estimation :

and reference to its source -
Environment
Exposure assessment : EUSES 2.1.1
(environment):
Exposure estimation and : Predicted exposures are not expected to exceed the PNEC's when the Risk
reference to its source Management Measures/Operational Conditions outlined in Section 2 are
implemented.
3.2 Exposure estimation : General exposures (closed systems)

Workers
Exposure assessment : The ECETOC TRA tool has been used to estimate workplace exposures unless
(human): otherwise indicated.
Exposure estimation and : Not available.
reference to its source
3.3 Exposure estimation : Use in contained batch processes
Workers

PFR100 EC 203-625-9 (1)
3.4 Exposure estimation : General exposures (open systems)
Workers
3.5 Exposure estimation : Batch process
Workers
3.6 Exposure estimation : Process sampling
Workers
3.7 Exposure estimation : Laboratory activities
Workers
3.8 Exposure estimation : Bulk transfers
Workers
3.9 Exposure estimation : Drum and small package filling
Workers
3.10 Exposure estimation : Equipment cleaning and maintenance
Workers

PFR100 EC 203-625-9 (1)
3.11 Exposure estimation : Storage
Workers
Section 4 - Guidance to DU to evaluate whether he works inside the boundaries set by the ES
Environment : Predicted exposures are not expected to exceed the DN(M)EL when the risk
management measures/operational conditions outlined in section 2 are implemented.
Where other risk management measures/operational conditions are adopted, then
users should ensure that risks are managed to at least equivalent levels.
Health : Guidance is based on assumed operating conditions which may not be applicable to
all sites; thus, scaling may be necessary to define appropriate site-specific risk
management measures. Required removal efficiency for wastewater can be
achieved using onsite/offsite technologies, either alone or in combination. Required
removal efficiency for air can be achieved using on-site technologies, either alone or
in combination. Further details on scaling and control technologies are provided in
SPERC factsheet.
Additional good practice advice beyond the REACH CSA

Health : Bulk transfers
Wear suitable gloves tested to EN374. Avoid splashing. Clear transfer lines prior to
de-coupling.
Equipment cleaning and maintenance

Wear suitable coveralls to prevent exposure to the skin.
Laboratory activities
Wear suitable gloves tested to EN374.


Code : PFR100
Section 1 - Title
scenario
List of use descriptors : Identified use name: EC 203-625-9 Use in laboratories - Industrial
Process Category: PROC10, PROC15
Sector of end use: SU03, SU10
Environmental Release Category: ERC02, ERC04
Environmental :
Health Contributing : Laboratory activities - PROC15
scenarios Equipment cleaning and maintenance - PROC10
Processes and activities : Use of small quantities within laboratory settings, including material transfers and
covered by the exposure equipment cleaning
scenario

exposure for
Amounts used : Fraction of EU tonnage used in region 15000
Regional use tonnage 1500
Fraction of Regional tonnage used locally 1
Annual site tonnage 1500
Frequency and duration of : Emission days 300
use
Environment factors not : Local freshwater dilution factor 10
influenced by risk Local marine water dilution factor 100
management
Other conditions affecting : Release fraction to air from process (initial release prior to RMM) 0.025
environmental exposure Release fraction to wastewater from process (initial release prior to RMM) 0.02
Release fraction to soil from process (initial release prior to RMM) 0.0001
Technical on-site : Treat air emissions. 0
conditions and measures to Treat on-site wastewater (prior to receiving water discharge) to provide the required
reduce or limit discharges, removal efficiency of 93.3
air emissions and releases If discharging to municipal sewage treatment plant, provide the required on-site
to soil wastewater removal efficiency of 0

PFR100 EC 203-625-9 (2)
Organisational measures to : Do not apply industrial sludge to natural soils.
prevent/limit release from
site
Conditions and measures : Estimated substance removal from wastewater via on-site sewage treatment 93.3
related to sewage treatment Total efficiency of removal from wastewater after on-site and off-site (municipal
plant treatment plant) RMMs 93.3
Maximum allowable site tonnage (MSafe) based on release following total wastewater
treatment removal 7020
Assumed on-site sewage treatment plant flow 2000
Conditions and measures : External treatment and disposal of waste should comply with applicable local and/or
disposal
of waste
2.2 Contributing scenario : Laboratory activities

controlling worker
exposure for
use
influenced by risk
management
Other conditions affecting : Assumes use at not more than 20°C above ambient temperature. Assumes a good
workers exposure basic standard of occupational hygiene is implemented
Technical conditions and : No specific measures identified.
measures to control
dispersion from source
towards the worker
2.3 Contributing scenario : Equipment cleaning and maintenance

controlling worker
exposure for
use
influenced by risk
management
Ventilation control : Provide a good standard of controlled ventilation (10 to 15 air changes per hour).
measures

PFR100 EC 203-625-9 (2)


Environment
Exposure assessment : Not available.
(environment):
Exposure estimation and : Predicted exposures are not expected to exceed the PNEC's when the Risk
reference to its source Management Measures/Operational Conditions outlined in Section 2 are
implemented.
3.2 Exposure estimation : Laboratory activities

Workers
(human):
Exposure estimation and : Predicted exposures are not expected to exceed the DN(M)EL when the risk
reference to its source management measures/operational conditions outlined in section 2 are
implemented.
3.3 Exposure estimation : Equipment cleaning and maintenance
Workers
(human):
implemented.
Environment : Not available.
Health : Not available.


Code : PFR100
Section 1 - Title
scenario
List of use descriptors : Identified use name: EC 203-625-9 Use in oil and gas field drilling and production
operations - Industrial
Process Category: PROC01, PROC02, PROC03, PROC04, PROC08a, PROC08b
Sector of end use: SU03, SU10
Environmental Release Category: ERC04
Environmental :
Health Contributing : Bulk transfers - PROC01
scenarios Filling of equipment from drums or containers - PROC08a, PROC08b
Drill floor operations - PROC04
Operation of solids filtering equipment - vapour exposures - PROC04
Operation of solids filtering equipment - aerosol exposures - PROC04
Operation of solids filtering equipment - PROC04
Pouring from small containers - PROC08a
General exposures (open systems) - PROC04
Processes and activities : Oil field well drilling and production operations (including drilling muds and well
covered by the exposure cleaning) including material transfers, on-site formulation, well head operations,
scenario shaker room activities and related maintenance.

exposure for
Amounts used : Fraction of EU tonnage used in region 30000
Regional use tonnage 3000
Fraction of Regional tonnage used locally 1
Annual site tonnage Not applicable.
Frequency and duration of : Emission days Not applicable.
use
Environment factors not : Local marine water dilution factor Not applicable.
influenced by risk
management

PFR100 EC 203-625-9 (4)
Other conditions affecting : Release fraction to air from process (initial release prior to RMM) Not applicable.
environmental exposure Release fraction to wastewater from process (initial release prior to RMM) Not
applicable.
Technical conditions and : Discharge to aquatic environment is restricted (see section 4.2).
measures at process level
(source) to prevent release
Technical on-site : Discharge to aquatic environment is restricted (see section 4.2).
conditions and measures to
reduce or limit discharges,
air emissions and releases
to soil
Organisational measures to : Prevent environmental discharge consistent with regulatory requirements.
prevent/limit release from
site
Conditions and measures : Total efficiency of removal from wastewater after on-site and off-site (municipal
related to sewage treatment treatment plant) RMMs Not applicable.
plant Maximum allowable site tonnage (MSafe) based on release following total wastewater
treatment removal Not applicable.
Assumed on-site sewage treatment plant flow Not applicable.
Conditions and measures : External treatment and disposal of waste should comply with applicable local and/or
disposal
of waste
2.2 Contributing scenario : Bulk transfers

controlling worker
exposure for
use
influenced by risk
management
measures hour).
Organisational measures to : Operate activity away from sources of substance emission or release.
prevent/limit releases,
dispersion and exposure

PFR100 EC 203-625-9 (4)
2.3 Contributing scenario : Filling of equipment from drums or containers
controlling worker
exposure for
use
influenced by risk
management
measures hour).
2.4 Contributing scenario : Drill floor operations

controlling worker
exposure for
use
influenced by risk
management
Area of use: : Ensure operation is undertaken outdoors.
2.5 Contributing scenario : Operation of solids filtering equipment - vapour exposures

controlling worker
exposure for
use
influenced by risk
management
Engineering controls : Ensure material transfers are under containment or extract ventilation.

PFR100 EC 203-625-9 (4)
2.6 Contributing scenario : Operation of solids filtering equipment - aerosol exposures
controlling worker
exposure for
use
influenced by risk
management
Engineering controls : Ensure material transfers are under containment or extract ventilation.
2.7 Contributing scenario : Operation of solids filtering equipment

controlling worker
exposure for
use
influenced by risk
management
measures hour).
2.8 Contributing scenario : Pouring from small containers

controlling worker
exposure for
use
influenced by risk
management
measures hour).

PFR100 EC 203-625-9 (4)
2.9 Contributing scenario : General exposures (open systems)
controlling worker
exposure for
use
influenced by risk
management
Area of use: : Ensure operation is undertaken outdoors.


Environment
(environment):
3.2 Exposure estimation : Bulk transfers

Workers
(human):
implemented.
3.3 Exposure estimation : Filling of equipment from drums or containers
Workers
(human):
implemented.
3.4 Exposure estimation : Drill floor operations
Workers
(human):
implemented.

PFR100 EC 203-625-9 (4)
3.5 Exposure estimation : Operation of solids filtering equipment - vapour exposures
Workers
(human):
implemented.
3.6 Exposure estimation : Operation of solids filtering equipment - aerosol exposures
Workers
(human):
implemented.
3.7 Exposure estimation : Operation of solids filtering equipment
Workers
(human):
implemented.
3.8 Exposure estimation : Pouring from small containers
Workers
(human):
implemented.
3.9 Exposure estimation : General exposures (open systems)
Workers
(human):
implemented.
Environment : Not available.
Health : Not available.

PFR100 PFR100 United Kingdom English OIC-EH Oilfield 1024269

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Conforms to Regulation (EC) No.

1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI

SAFETY DATA SHEET

SECTION 1: Identification of the substance/mixture and of the company/

Recommended use : Solvent

Uses advised against Reason

1.3 Details of the supplier of the safety data sheet

Tel: +44 (0)151 545 3899

e-mail address of person : [email protected]

1.4 Emergency telephone number

SECTION 2: Hazards identification

2.2 Label elements

GHS02 GHS08 GHS07

2.3 Other hazards

SECTION 2: Hazards identification

Other hazards which do : None known.

SECTION 3: Composition/information on ingredients

SECTION 4: First aid measures

SECTION 4: First aid measures

SECTION 5: Firefighting measures

SECTION 6: Accidental release measures

6.3 Methods and material for containment and cleaning up

6.4 Reference to other : See Section 1 for emergency contact information.

SECTION 7: Handling and storage

SECTION 7: Handling and storage

7.2 Conditions for safe storage, including any incompatibilities

7.3 Specific end use(s) : Solvent

SECTION 8: Exposure controls/personal protection

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

SECTION 8: Exposure controls/personal protection

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

SECTION 9: Physical and chemical properties

9.2 Other information

SECTION 10: Stability and reactivity

SECTION 11: Toxicological information

SECTION 11: Toxicological information

Information on likely routes : Not available.

Symptoms related to the physical, chemical and toxicological characteristics

SECTION 11: Toxicological information

Other information : Not available.

SECTION 12: Ecological information

12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil : Not available.

12.5 Results of PBT and vPvB assessment

12.6 Other adverse effects : No known significant effects or critical hazards.

SECTION 13: Disposal considerations

SECTION 13: Disposal considerations

SECTION 14: Transport information

ADN Class UN1294 Toluene 3 II

IMDG Class UN1294 Toluene 3 II

IATA Class UN1294 Toluene 3 II

PG* : Packing group

SECTION 14: Transport information

IATA Class No. -

14.7 Transport in bulk : Not available.

SECTION 15: Regulatory information