Lecture - 6
Lecture - 6
Lecture - 6
Atmospheric Trace
Gases
• NO + HC + O2 + Sunlight ---->
Ozone
• Ozone + other air pollutants ----
> 100 different secondary
pollutants ( Peroxyacyl nitrates
(PANs for example)
Phenomenon of Thermal
Inversion
• Air near the ground is colder than the
air at higher levels.
• Pollutants are trapped.
• Usually persist only a few hours.
Some times, however, can last for
days.
• Cities located in valleys
(Kathmandu), near the coast, or on
the leeward side of the mountains.
London killer fog - 1952
• London was covered with fog
• failed to mix with air
• Four thousand people died in few
weeks
• More than 50% of the people got
affected.
• These were related to SO2
Controlling Air Pollutants
• Smaller more fuel efficient
automobiles release less emission
• Smoke stacks with electrostatic
precipitators, fabric filters, wet
scrubbers, or other technologies
remove particulate matter.
• Particulates can also be controlled
by sprinkling water
Controlling air pollutants
contd..
• Several methods exist for
removing SO2 but the best option
is to introduce low-sulfur fuel such
as natural gas or non-fossil fuel
energy options such as solar
energy
• Sulfur can also be removed from
coal as in Coal Gasification
Controlling Air Pollutants
Contd..
• Reduction of combustion temperatures
in automobiles reduces the formation
of nitrogen oxides.
• Modification of furnaces and engines to
provide more complete combustion
controls production of both CO & HCs.
( Catalytic afterburners used after the
emission or the catalytic converters to
treat auto-exhaust)
Taxing Polluters
• Sweden taxes on carbon monoxide
and sulfur dioxide emissions
• Since the amount of these
pollutants vary with the type of fuel
this encourages the users to go for
cleaner fuels.
Air Pollution in Developing
Countries
• Old vehicles with no pollution control devices
• Less priority on environment
• Dominance of very small number of cities
• Mexico city: The fourth largest city in the world
with the worst air quality. ( This is in an elevated
valley )
– 3 million motor vehicles and thousands of
businesses which spew 4.4 million tons of
pollutants
– In 1990, replacing old buses, taxis, delivery
trucks, and cars with cleaner vehicles and by
switching to unleaded gasoline.
– Businesses that violate laws were closed.
Indoor Air Pollution
• Some pollutants may be several times higher
inside the buildings
• Urban residents spent 90% of their time
indoor
• Health effects of indoor pollutants resemble
common cold, influenza, or upset of
stomachs, they are often not recognized. (Sick
Building Syndrome )
Indoor air pollution
• Sick building syndrome -- when occupants of a
building suffer persistant symptoms associated with
certain pollutants
• More dangerous problems: asbestos, carbon monoxide,
formaldehyde, radon, tobacco smoke.
• More common in newer buildings because of lower air
exchange, windows that don't open, and gases given off
by new carpeting and furniture
• Radon Colorless, tasteless radioactive gas. Threat of
dying is greater. Capable of seeping through the ground
and entering the buildings. This gets diluted in outdoors.
Harms only when ingested. Smoking increases risk. Radon
concentrations can be reduced by sealing concrete floors.
Air Quality and Health
• In developing countries 0.5 – 1.0 million
people die as a result of exposure to urban
air pollution
• 30 – 40 % of asthma
• 20 – 30 % all respiratory diseases
• Average compound growth rate of vehicles
is 12 % a year (0.8 million - 5 million in two
decades)
• Rickshaws - > two times, Motor cycles – 7
times
Sources of Air Pollution in Pakistan
Vehicles
Trans
boundary
Pollution
Natural Dust
Stone
Crushers
Brick Kilns
Industry
Garbage
Burning
Domestic
Burning
Trend in Population & Vehicle
Growth (Karachi)
Population Vehicles (million)
(million) • 0.88
• 1.006
• 1995 - 8.465
• 1.135
• 2000 10.032 • 1.432
• 2003 11.819
• 2005 12.10 • 72 % diesel (60 %
Trucks, 27 % Buses,
11 % Passenger
wagons)
• 28 % Petrol
TSP Load in Major Cities
City point TSP (ug/m3)
• Yateem Khana – Lhr • 996
• Satellite Town – Qta • 778
• Attock Refinary- Rwp • 500
• Kohat Adda – Pesh • 530
• I/9 – Islamabad • 490
• Civic Center - Kchi • 410
(WHO limit is 150 – 230
in 24 hrs)
PM10 (particles measuring 10
microns or less)
City point PM10 (ug/m3)
• Yateem Khana – Lhr • 368
• Satellite Town – Qta • 331
• Attock Refinary- Rwp • 276
• Kohat Adda – Pesh • 350
• I/9 – Islamabad • 280
• Civic Center - Kchi • 302
(WHO limit is 150 in 24
hrs)
Oxides of Nitrogen
City point NOx (ppb)
• Yateem Khana – Lhr • 60.7
• Meezan Chowk – Qta • 60
• Faizabad - Rwp • 40
• Bus Stand – Pesh • 47
• Polyclinic – • 39
Islamabad • 52
• Garden Road - Kchi (WHO/USEPA limit is
53 ppb in 24 hrs)
Sulfur di-Oxide
City point SO2 (ppb)
• Yateem Khana – Lhr • 53
• Meezan Chowk – Qta • 46
• Faizabad - Rwp • 31
• Bus Stand – Pesh • 43
• Polyclinic – • 35
Islamabad • 44
• Garden Road - Kchi (WHO/USEPA limit is
53 ppb in 24 hrs)
Surface Ozone
City point O3 (ppb)
• Yateem Khana – Lhr • 8.5 - 49
• Meezan Chowk – Qta • 11.7 - 44
• Faizabad - Rwp • 3.3 - 42
• Bus Stand – Pesh • 4 – 49.5
• Polyclinic – • 6.2 - 38
Islamabad • 6 - 48
• Garden Road - Kchi
Carbon Monoxide
City point CO (ppb)
• Yateem Khana – Lhr • 1.3 - 12
• Meezan Chowk – Qta • 3 - 14
• Faizabad - Rwp • 1.6 - 8
• Bus Stand – Pesh • 2 – 10
• Polyclinic – • 1.5 - 6
Islamabad • 1.6 - 13
• Garden Road - Kchi
Hydrocarbon (methane & non
methane)
City point CH (ppm)
• Yateem Khana – Lhr • 0.45 – 2.8
• Meezan Chowk – Qta • 0.2 – 1.6
• Faizabad - Rwp • 0.3 – 2.8
• Bus Stand – Pesh • 0.2 - 3
• Polyclinic – • 0.4 – 2.2
Islamabad • 0.25 – 3
• Garden Road - Kchi
Lead Level