1.1 - Structure of Water & Hydrogen Bonding

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1.

1 - Structure of Water & Hydrogen Bonding

Structure of Water:
● Density Anomaly: Water reaches its maximum density at around 4°C, unlike
most substances which become denser as they cool.
● Hydrogen Bonding in Ice: In the solid state (ice), water molecules form a crystal
lattice held together by hydrogen bonds, causing ice to be less dense than liquid
water.
● Cohesion and Adhesion: Cohesion refers to the attraction between molecules
of the same substance, while adhesion refers to the attraction between
molecules of different substances. Water's polarity and hydrogen bonding
contribute to its high cohesion and adhesion properties.

Hydrogen Bonding:
● Examples: Besides water, hydrogen bonding is important in biological molecules
like DNA and proteins, as well as in determining the properties of many organic
compounds.
● Boiling and Freezing Points: The presence of hydrogen bonding in water leads
to higher boiling and melting points compared to similar molecules that lack
hydrogen bonding, like methane (CH4).
● Surface Tension: Hydrogen bonding contributes to the high surface tension of
water, allowing some insects to walk on water.
● Solvent Properties: Water's ability to dissolve many substances is due in part to
its hydrogen bonding with solute molecules, which helps to pull them apart and
surround them with water molecules.

Biological Significance:
● Biological Solvent: Water's ability to dissolve a wide range of substances
makes it a universal solvent in biological systems.
● Temperature Regulation: Water's high specific heat capacity, a result of
hydrogen bonding, helps regulate temperature in organisms and ecosystems.
● Cohesion and Adhesion in Plants: Water's cohesion and adhesion properties
are crucial for the transport of water and nutrients in plants through capillary
action.

Environmental Impact:
● Ice Formation: The expansion of water upon freezing due to hydrogen bonding
is important in shaping Earth's landscape through processes like frost action and
the formation of ice wedges.
● Climate Regulation: Water's high heat capacity and ability to store and release
heat slowly due to hydrogen bonding play a role in moderating Earth's climate.
Water's Role in Biological Systems:
● Universal Solvent: Water is often called the "universal solvent" because it can
dissolve a wide range of substances, including polar and ionic compounds. This
property is crucial for biological processes such as digestion, metabolism, and
the transport of nutrients and waste products in organisms.
● Hydration of Biomolecules: Water molecules surround and interact with
biomolecules like proteins, nucleic acids, and carbohydrates through hydrogen
bonding. This hydration layer helps maintain the structure and function of these
molecules.
● Regulation of Body Temperature: Water's high specific heat capacity allows it
to absorb and release large amounts of heat with minimal temperature change.
In organisms, this property helps regulate body temperature, preventing rapid
fluctuations that could be harmful.
Biology AP
Unit 1
Chapter 1

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