Heat and Temperature
Heat and Temperature
Heat and Temperature
**Heat** is the total energy of all the molecular motion inside an object. It's
measured in **Joules** and is dependent on the number of particles in an
object as well as their speed and energy. Heat is an extensive property, which
means it depends on the amount of substance present.
To illustrate, imagine a tub of water and a cup of water at the same temperature.
The tub contains more water, so it has more heat energy overall, even though
each molecule of water in the tub and the cup has the same average energy¹².
In summary:
- **Heat** = Total molecular energy (Joules)
- **Temperature** = Average molecular energy (Kelvin)
Heat capacity is a physical property of matter that represents the amount of heat
required to change its temperature by one degree. It’s an extensive property,
meaning it depends on the amount of substance present. The unit of heat
capacity is joule per Kelvin (J/K) or joule per degree Celsius (J/°C)1.
Mathematically, heat capacity (( C )) is defined by the equation:
ΔQ=CΔT
where ( Q ) is the heat energy required to bring about a temperature change of ( \
Delta T ), and ( C ) is the heat capacity of the system under study 2.
In simpler terms, if you have a larger amount of a substance, it will have a higher
heat capacity because it can absorb more heat before its temperature rises by
one degree. This is why a large body of water, like a lake, takes longer to heat up
or cool down compared to a small pot of water.
If you need more detailed information or have any other questions, feel free to
ask!
Calculating the heat capacity of a substance involves measuring the amount of heat
energy supplied to the substance and the resulting change in its temperature. The
formula for calculating heat capacity (( C )) is:
�=�Δ�C=ΔTQ
where:
( Q ) is the heat energy supplied (in Joules),
( \Delta T ) is the change in temperature (in degrees Celsius or Kelvin).
For example, if you supply 2000 Joules of energy to a substance and its temperature
increases by 5 degrees Celsius, the heat capacity would be:
This means for every degree Celsius the temperature of the substance increases, it
requires 400 Joules of energy12.
If you know the specific heat capacity (( c )) of the substance and its mass (( m )), you
can also calculate the heat capacity using the formula:
�=��Δ�Q=mcΔT
where:
For instance, if you have a 70g piece of copper with a specific heat capacity of 0.385
J/g°C and you want to increase its temperature by 20°C, the heat energy required
would be:
The heat capacity in this case would be 539 Joules for a 20°C increase in
temperature1.
Heat capacity and specific heat capacity are related concepts, but they have distinct
differences:
Heat Capacity:
It is the amount of heat energy required to raise the temperature of one gram
of a substance by one degree Celsius (or one Kelvin).
Specific heat capacity is an intensive property, which means it does not
depend on the amount of the substance. It is a characteristic of the material
itself.
The unit of specific heat capacity is Joules per gram per degree Celsius (J/g°C)
or Joules per gram per Kelvin (J/gK)1.
In essence, heat capacity refers to the total heat needed for a temperature change in an
object, while specific heat capacity refers to the heat needed for the same temperature
change but per unit mass of the substance. This is why specific heat capacity is useful
for comparing the thermal properties of different materials, regardless of their size or
mass1.
Heat transfer is the process by which heat energy moves from one place to another. It
can occur through three main mechanisms: **conduction**, **convection**, and
**radiation**¹².
Each of these mechanisms plays a role in everyday phenomena, from cooking food to
heating homes and even in natural processes like the warming of the Earth's surface
by the Sun. If you're interested in more detailed explanations or examples of each
type, I can provide further information¹².
In the context of heat exchange, the First Law can be expressed as:
$$ \Delta U = Q - W $$
where:
- \( \Delta U \) is the change in internal energy of the system,
- \( Q \) is the net heat transferred into the system, and
- \( W \) is the net work done by the system.
This equation tells us that the change in internal energy of a system is equal to
the heat added to the system minus the work done by the system. So, when heat
is exchanged, it either changes the internal energy of the system or does work, or
a combination of both¹².
Problem: A hot fluid enters a heat exchanger at 150°C and leaves at 100°C. A cold
fluid enters the heat exchanger at 30°C and needs to be heated to 80°C. The mass flow
rate of the hot fluid is 1 kg/s, and its specific heat capacity is 4.2 kJ/kg°C. The mass
flow rate of the cold fluid is 0.5 kg/s, and its specific heat capacity is 4.0 kJ/kg°C.
Assume no heat loss to the surroundings.
Solution: First, we calculate the heat lost by the hot fluid using the formula:
Since the heat lost by the hot fluid must equal the heat gained by the cold fluid
(assuming no heat loss to the surroundings),
However, there is a discrepancy here because the heat lost by the hot fluid is greater
than the heat gained by the cold fluid. This indicates that either the mass flow rate or
the temperature change of one of the fluids must be adjusted to achieve balance.
If we assume the mass flow rates are fixed, we can adjust the outlet temperature of the
cold fluid to balance the heat exchange. Let’s find the new outlet temperature
This result is not physically possible since the cold fluid cannot end up hotter than the
hot fluid after heat exchange. Therefore, we need to re-evaluate the initial conditions
or check for any possible errors in the problem setup.
For more solved problems and detailed explanations on heat exchange, you can refer
to resources like textbooks on heat transfer or online educational platforms1234. If you
have a specific problem or topic in mind, let me know, and I can assist you further!
Thermal equilibrium is a state in which two or more objects or systems that are in
contact with each other do not exchange heat, meaning they are at the same
temperature¹²³. This concept is based on the **Zeroth Law of Thermodynamics**,
which states that if two systems are in thermal equilibrium with a third system,
then they are also in thermal equilibrium with each other¹.
The gas cylinder becomes cold when you cook due to a phenomenon known as the
Joule-Thomson effect1. When you use the stove, the liquefied gas inside the cylinder
is released through a valve and evaporates to become a gas. This evaporation process
requires heat, which is absorbed from the surrounding environment, including the
cylinder itself. As a result, the temperature of the cylinder drops, making it feel cold to
the touch.
This cooling effect is more noticeable when the stove is running at maximum output
because the heat transfer from the outside air to the canister is not fast enough to
compensate for the heat absorbed during the evaporation of the fuel2. In certain
conditions, this can even cause frost to develop on the outside of the cylinder2.
It’s an interesting example of how energy transfer works and why proper handling and
insulation of gas cylinders are important, especially in colder environments. If you
have any more questions or need further explanation, feel free to ask!
If you have any more questions or need further clarification, feel free to ask!
where:
- \( \alpha_L \) is the linear coefficient of thermal expansion,
- \( L \) is the original length of the material,
- \( dL \) is the change in length,
- \( dT \) is the change in temperature.
Different materials have different CTE values. For example, metals typically have
higher CTE values than ceramics. Here are some examples of linear CTE values for
common materials¹:
- Aluminum: 21 - 24 x 10⁻⁶ °C⁻¹
- Copper: 16 - 16.7 x 10⁻⁶ °C⁻¹
- Glass: 5.9 - 9.0 x 10⁻⁶ °C⁻¹
- Concrete: 13 - 14 x 10⁻⁶ °C⁻¹