Crack - Test - Products - Black - Magnetic Ink - CTB3

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Section 1 - Identification of the Material and Supplier


Chemical nature: Magnetic ink aerosol
Trade Name: CrackTest CTB-3 Black Magnetic Ink
Product Use: Magnetic particle inspection.
Creation Date: December, 2016
This version issued: December, 2016 and is valid for 5 years from this date.
Poisons Information Centre: Phone 13 1126 from anywhere in Australia

Section 2 - Hazards Identification


Statement of Hazardous Nature
This product is classified as: Xn, Harmful. F+, Extremely Flammable. Not classified as hazardous according to the
criteria of SWA.
Dangerous according to Australian Dangerous Goods (ADG) Code, IATA and IMDG/IMSBC criteria.
SUSMP Classification: None allocated.
ADG Classification: Class 2.1: Flammable gases.
UN Number: 1950, AEROSOLS

GHS Signal word: DANGER


Flammable aerosols Category 2
Gases under pressure - Compressed gas
Specific Target Organ Toxicity - Single Exposure Category 3
HAZARD STATEMENT:
H223: Flammable aerosol
H280: Contains gas under pressure; may explode if heated.
H336: May cause drowsiness or dizziness.
PREVENTION
P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from heat, sparks, open flames and hot surfaces. - No smoking.
P211: Do not spray on an open flame or other ignition source.
P241: Use explosion-proof electrical ventilating, lighting and other equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P251: Pressurized container: Do not pierce or burn, even after use.
P261: Avoid breathing fumes, mists, vapours or spray.
P262: Do not get in eyes, on skin, or on clothing.
P271: Use only outdoors or in a well ventilated area.
P280: Wear protective gloves, protective clothing and eye or face protection.
RESPONSE
P312: Call a POISON CENTRE or doctor if you feel unwell.
P362: Take off contaminated clothing and wash before reuse.
P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353: IF ON SKIN (or hair): Remove immediately all contaminated clothing. Rinse skin with water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P308+P313: If exposed or concerned: Get medical advice.
P372: Explosion risk in case of fire.
P381: Eliminate all ignition sources if safe to do so.
P370+P378: In case of fire, use carbon dioxide, dry chemical, foam. Water fog or fine spray is the preferred
medium for large fires.

SAFETY DATA SHEET This version issued: December, 2016


Issued by: Russell Fraser Sales Pty Ltd Phone: 02 9545 4433 (any time)
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: CrackTest CTB-3 Black Magnetic Ink
Page: 2 of 6
This version issued: December, 2016
STORAGE
P403: Store in a well-ventilated place.
P405: Store locked up.
P402: Store in a dry place.
P410+P412: Store below 30°C, protect from direct sunlight and do not expose to temperatures exceeding
50°C.
DISPOSAL
P501: If they can not be recycled, dispose of contents to an approved waste disposal plant and containers to
landfill (see Section 13 of this SDS).
Emergency Overview
Physical Description & Colour: Aerosol, dispensed product is a black oily liquid
Odour: Mild oily odour.
Major Health Hazards: vapours may cause drowsiness and dizziness.

Section 3 - Composition/Information on Ingredients


Ingredients CAS No Conc, % TWA (mg/m3) STEL (mg/m3)
Naphtha (petroleum), hydrotreated heavy 64742-48-9 60-100 not set not set
Petroleum gases, liquefied, sweetened 68476-86-8 30 not set not set
Magnetic particles secret Very low not set not set
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non
hazardous ingredients are also possible.
The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day
for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no
longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures
at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.

Section 4 - First Aid Measures


General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by
this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all
times. Have this SDS with you when you call.
Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
Skin Contact: Gently blot away excess liquid. Wash gently and thoroughly with water (use non-abrasive soap if
necessary) for 5 minutes or until chemical is removed.
Eye Contact: Quickly and gently blot material from eyes. No effects expected. If irritation does occur, flush
contaminated eye(s) with lukewarm, gently flowing water for 5 minutes or until the product is removed. Obtain medical
advice if irritation becomes painful or lasts more than a few minutes. Take special care if exposed person is wearing
contact lenses.
Ingestion: If product is swallowed or gets in mouth, do NOT induce vomiting; wash mouth with water and give some
water to drink. If symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor.
Section 5 - Fire Fighting Measures
Fire and Explosion Hazards: The major hazard in fires is usually inhalation of heated and toxic or oxygen
deficient (or both), fire gases. There is a moderate risk of an explosion from this product if commercial quantities are
involved in a fire. Firefighters should take care and appropriate precautions. Violent steam generation or eruption may
occur upon application of direct water stream on hot liquids.
Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.
Extinguishing Media: In case of fire, use carbon dioxide, dry chemical, foam. Water fog or fine spray is the
preferred medium for large fires. Try to contain spills, minimise spillage entering drains or water courses.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade. There is a danger of a
violent reaction or explosion if significant quantities of this product are involved in a fire. Recommended personal
protective equipment is full fire kit and breathing apparatus.
Flash point: Extremely flammable aerosol.
Upper Flammability Limit: 6%
Lower Flammability Limit: 1%
Autoignition temperature: No data.
Flammability Class: Extremely Flammable aerosol

SAFETY DATA SHEET


Issued by: Russell Fraser Sales Pty Ltd Phone: 02 9545 4433 (any time)
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: CrackTest CTB-3 Black Magnetic Ink
Page: 3 of 6
This version issued: December, 2016
Section 6 - Accidental Release Measures
Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Evacuate
the spill area and deny entry to unnecessary and unprotected personnel. As a minimum, wear overalls, goggles and
gloves. Suitable materials for protective clothing include Nitrile. Eye/face protective equipment should comprise, as a
minimum, protective glasses and, preferably, goggles. If there is a significant chance that vapours or mists are likely
to build up in the cleanup area, we recommend that you use a respirator. Usually, no respirator is necessary when
using this product. However, if you have any doubts consult the Australian Standard mentioned below (section 8).
Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill
is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains
or waterways. Take suitable precautions e.g. use of non-sparking equipment to avoid creating sparks or flames which
may ignite the spilled material. Leaking gases may form an explosion hazard. Any equipment capable of building an
electrostatic charge should be electrically grounded. Sweep up and shovel or collect recoverable product into labelled
containers for recycling or salvage, and dispose of promptly. Recycle containers wherever possible after careful
cleaning. After spills, wash area preventing runoff from entering drains. If a significant quantity of material enters
drains, advise emergency services. This material may be suitable for approved landfill. Ensure legality of disposal by
consulting regulations prior to disposal. Thoroughly launder protective clothing before storage or re-use. Advise
laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible
materials listed in Section 10.
Storage: Store in a cool (below 30°C), well ventilated area. Protect from direct sunlight. Make sure that surrounding
electrical devices and switches are suitable. Check containers and valves periodically for leaks. If you keep more than
25kg of flammable gases, you are probably required to license the premises or notify your Dangerous Goods
authority. If you have any doubts, we suggest you contact your Dangerous Goods authority in order to clarify your
obligations. Check packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection
The following Australian Standards will provide general advice regarding safety clothing and equipment:
Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501
set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
Exposure limits have not been established by SWA for any of the significant ingredients in this product.
No special equipment is usually needed when occasionally handling small quantities. The following instructions are
for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.
Ventilation: This product should only be used in a well ventilated area. If natural ventilation is inadequate, use of a
fan is suggested.
Eye Protection: Eye protection such as protective glasses or goggles is recommended when this product is being
used.
Skin Protection: You should avoid contact even with mild skin irritants. Therefore you should wear suitable
impervious elbow-length gloves and facial protection when handling this product. See below for suitable material
types.
Protective Material Types: We suggest that protective clothing be made from the following materials: nitrile.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned above.
Safety deluge showers should, if practical, be provided near to where this product is being handled commercially.
Section 9 - Physical and Chemical Properties:
Physical Description & colour: Aerosol, dispensed product is a black oily liquid
Odour: Mild oily odour.
Boiling Point: 235°C at 100kPa (dispensed product)
Freezing/Melting Point: No specific data. Liquid at normal temperatures.
Volatiles: Not available.
Vapour Pressure: 447 kPa (aerosol) at 24°C
Vapour Density: 2
Specific Gravity: 0.82
Water Solubility: Insoluble.

SAFETY DATA SHEET


Issued by: Russell Fraser Sales Pty Ltd Phone: 02 9545 4433 (any time)
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: CrackTest CTB-3 Black Magnetic Ink
Page: 4 of 6
This version issued: December, 2016
pH: Neutral.
Volatility: No data.
Odour Threshold: No data.
Evaporation Rate: No data.
Coeff Oil/water Distribution: No data
Autoignition temp: No data.
Section 10 - Stability and Reactivity
Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have
any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: Store below 30°C, protect from direct sunlight and do not expose to temperatures exceeding
50°C. Keep containers tightly closed. Containers should be kept dry. Keep containers and surrounding areas well
ventilated. Keep away from sources of sparks or ignition. Any electrical equipment in the area of this product should
be flame proofed. Protect this product from light.
Incompatibilities: No particular Incompatibilities.
Fire Decomposition: Combustion forms carbon dioxide, and if incomplete, carbon monoxide and possibly smoke.
Water is also formed. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion,
dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death.
Polymerisation: Polymerisation reactions are unlikely; they are not expected to occur.

Section 11 - Toxicological Information


Toxicity: A summary of white spirit type hydrocarbons can be found at
http://www.inchem.org/documents/ehc/ehc/ehc187.htm
Ingestion of white spirit has been reported to produce gastrointestinal irritation with pain, vomiting and diarrhoea.
Lesions of the mucous membranes in the oesophagus and the gastrointestinal tract followed the oral exposure.
Owing to its low viscosity and low surface tension, white spirit poses a risk of aspiration into the lungs following oral
exposure. A few mL of solvent aspirated into the lungs are able to produce serious bronchopneumonia and 10-30mL
may be fatal.
Prolonged dermal exposure to white spirit, e.g., resulting from wearing clothes that have been soaked or moistened
by white spirit for hours, may produce irritation and dermatitis.
Single cases of acute toxicity to the kidney, liver and bone marrow have been reported following exposure to white
spirit at high levels. However, owing to lack of details and the sporadic nature of the reports, the relevance of these
findings is unclear.
Inhalation of aliphatic hydrocarbon vapours seems to show little toxicity, but the vapours are CNS depressants and
have a disinhibiting euphoric effect.
Potential Health Effects
Inhalation:
Short Term Exposure: High vapour pressures may cause drowsiness and dizziness. In addition product is unlikely
to cause any discomfort or irritation. Intentional misuse by deliberately concentrating and inhaling contents of aerosol
containers can be harmful or fatal.
Long Term Exposure: Vapours may cause drowsiness and dizziness.
Skin Contact:
Short Term Exposure: Major health effect from this product is misuse of the aerosol function. If sprayed
continuously on skin or in eyes, it can cause frostbite.
Long Term Exposure: No data for health effects associated with long term skin exposure.
Eye Contact:
Short Term Exposure: If sprayed directly in the eye, this product will irritate. If spraying is prolonged, it may cause
damage through frostbite.
Long Term Exposure: No data for health effects associated with long term eye exposure.
Ingestion:
Short Term Exposure: Significant oral exposure is considered to be unlikely. This product is unlikely to cause any
irritation problems in the short or long term.
Long Term Exposure: No data for health effects associated with long term ingestion.
Carcinogen Status:
SWA: No significant ingredient is classified as carcinogenic by SWA.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: No significant ingredient is classified as carcinogenic by IARC.
SAFETY DATA SHEET
Issued by: Russell Fraser Sales Pty Ltd Phone: 02 9545 4433 (any time)
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: CrackTest CTB-3 Black Magnetic Ink
Page: 5 of 6
This version issued: December, 2016
Section 12 - Ecological Information
Insufficient data to be sure of status.
Biodegradation is expected to be the primary fate process for aliphatic hydrocarbons in soil and water. The rate and
extent of biodegradation are dependent on the ambient temperature, the presence of a sufficient number of
microorganisms capable of metabolizing the hydrocarbons and the concentration of white spirit in or on the soil or
water.
Biodegradation of C7 to C12 hydrocarbons is expected to be significant under environmental conditions favourable to
microbial oxidation. Naturally occurring hydrocarbon-degrading microorganisms have been isolated from polluted soil
and, to a lesser extent, non-polluted soil.
The low water solubility and moderate vapour pressure of white spirit (Stoddard solvent) suggest that volatilization
and subsequent photo-oxidation are important processes for abiotic degradation in the atmosphere.
The octanol/water partition coefficient (log Pow) of white spirit (17% v/v aromatics) has been found to be 3.5 to 6.4.
This indicates a moderate potential for bioaccumulation by organisms from water and a likelihood of partitioning to fat
within organisms.

Section 13 - Disposal Considerations


Disposal: This product may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for
its intended use. If it has been contaminated, it may be possible to reclaim the product by filtration, distillation or some
other means. If neither of these options is suitable in-house, consider controlled incineration, or contact a specialist
waste disposal company. Do not puncture or incinerate aerosol cans, even when empty.

Section 14 - Transport Information


Dangerous according to Australian Dangerous Goods (ADG) Code, IATA and IMDG/IMSBC criteria.
UN Number: 1950, AEROSOLS
Hazchem Code: 2Y
Special Provisions: 63, 190, 277
Limited quantities: ADG 7 specifies a Limited Quantity value of 1000mL for this class of product.
Dangerous Goods Class: Class 2.1: Flammable gases.
Packing Group: Not set
Packing Instruction: P003
Class 2.1 Flammable gases shall not be loaded in the same vehicle or packed in the same freight container with
Classes 1 (Explosives), 3 (Flammable Liquids) (where both flammable liquids and flammable gases are in bulk), 4.1
(Flammable Solids), 4.2 (Spontaneously Combustible Substances), 4.3 (Dangerous When Wet Substances), 5.1
(Oxidising Agents), 5.2 (Organic Peroxides), and 7 (Radioactive Substances). They may however be loaded in the
same vehicle or packed in the same freight container with Classes 2.2 (Non-flammable Non-Toxic gases), 3
(Flammable liquids except where both flammable liquids and flammable gases are in bulk), 6 (Toxic Substances), 8
(Corrosive Substances) 9 (Miscellaneous dangerous goods), Foodstuffs and foodstuff empties.

Section 15 - Regulatory Information


AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
Section 16 - Other Information
This SDS contains only safety-related information. For other data see product literature.
Acronyms:
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail (7th edition)
AICS Australian Inventory of Chemical Substances
SWA Safe Work Australia, formerly ASCC and NOHSC
CAS number Chemical Abstracts Service Registry Number
Hazchem Code Emergency action code of numbers and letters that provide information to emergency
services especially firefighters
IARC International Agency for Research on Cancer
NOS Not otherwise specified
NTP National Toxicology Program (USA)
R-Phrase Risk Phrase
SUSMP Standard for the Uniform Scheduling of Medicines & Poisons

SAFETY DATA SHEET


Issued by: Russell Fraser Sales Pty Ltd Phone: 02 9545 4433 (any time)
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: CrackTest CTB-3 Black Magnetic Ink
Page: 6 of 6
This version issued: December, 2016
UN Number United Nations Number
THIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW
TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW
THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE.
IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE,
THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS
OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT
TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.

Please read all labels carefully before using product.


This SDS is prepared in accord with the SWA document “Preparation of Safety Data Sheets for Hazardous
Chemicals - Code of Practice” (December 2011)
Copyright © Kilford & Kilford Pty Ltd, December, 2016.
http://www.kilford.com.au/ Phone (02)9251 4532

SAFETY DATA SHEET


Issued by: Russell Fraser Sales Pty Ltd Phone: 02 9545 4433 (any time)
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

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