SDS: NPA994

SAFETY DATA SHEET Version: 1

Date of
11/11/2022
NORMAL PARAFFIN C10/13 revision:
Page: 1 to 11

1. IDENTIFICATION
Product name: NORMAL PARAFFIN C10/13
Product code: NPA994
Relavant uses: Cereal Protector; paraffination of fruits and cheeses; in the cosmetics industry (lipsticks,
pencils and creams); in the paper waxing industries; making packaging for food and frozen
foods; in the formulation of pharmaceutical products; preparation of orthodontic molds.
Supplier: REFINARIA DE MATARIPE S.A.
SÃO FRANCISCO DO CONDE, RODOVIA BA 523 KM 4 – CEP 43.900-000 - MATARIPE –
Address:
BA
Telephone number: 0800 117 2020
Emergency telephone 0800 117 2020
number:
2. HAZARDS IDENTIFICATION
Hazard classification according to Annex VI of Regulation (EC) No 1272/2008 - classification, labelling and packaging of
substances and mixtures (CLP), in accordance with GHS (Globally Harmonized System of Classification and Labelling of
Chemicals, UN).

2.1 Classification of the substance or mixture

Hazard classification Category

Flammable liquid 4

Skin corrosion/irritation 3

Serious eye damage/irritation 2B

Target Organ Systemic Toxicity – Single exposure 2

Aspiration toxicity 1
2.2 GHS label elements

Pictogram:
Signal word: DANGER
H224 – Extremely flammable liquid and vapour.
H316 – Causes mild skin irritation.
H341 – Suspected of causing genetic defects.
H350 – May cause cancer.
H361 – Suspected of damaging fertility or the unborn child.
Hazard statement:
H335 – May cause respiratory irritation.
H336 – May cause drowsiness or dizziness.
H372 – Causes damage to organs through prolonged or repeated exposure.
H304 – May be fatal if swallowed and enters airways.
H402 – Harmful to aquatic life.
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Prevention:
P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P210 - Keep away from heat, hot surface, sparks, open flames and other ignition sources. -
No smoking.
P233 - Keep container tightly closed.
P240 - Ground/bond container and receiving equipment.
P241 - Use explosion-proof [electrical/ventilating/lighting/.../] equipment.
P242 - Use only non-sparking tools.
P243 - Take precautionary measures against static discharge.
P260 – Do not breathe dust/fume/gas/mist/vapors/spray.
P264 – Wash thoroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P271 - Use only outdoors or in a well-ventilated area.
P273 - Avoid release to the environment.
P280 – Wear protective gloves/protective clothing/eye protection/face protection.
Response:
Precautionary P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER/doctor/...
statement: P303 + P361 + P353 - IF ON SKIN (or hair): Take off Immediately all contaminated clothing.
Rinse SKIN with water [or shower].
P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P308 + P311 - IF exposed or concerned: Call a POISON CENTER/doctor/...
P308 + P313 – If exposed or concerned: Get medical advice/attention.
P312 - Call a POISON CENTER or doctor/... if you feel unwell.
P314 – Get medical advice/attention if you feel unwell.
P321 – Specific treatment (see section 4).
P331 - Do NOT induce vomiting.
P332 + P313 – If skin irritation occurs: Get medical advice/attention.
P370 + P378 - In case of fire: Use dry chemical powder or carbon dioxide (CO2) to extinguish.
Storage:
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 - Store in a well-ventilated place. Keep cool.
P405 – Store locked up.
Disposal:
P501 – Dispose of contents/container in appropriate places for waste / final disposal
(appropriate landfill accredited by competent bodies and/or with specialized companies for
incineration or other destination in accordance with local/regional/national/international
regulations.
2.3 Hazards not otherwise classified
Explosion hazard with air contact.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance or mixture: SUBSTANCE.
Technical name: Marine fuel.
CAS number: 86290-81-5
Concentration range: ---
Synonyms: Benzine
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Impurities that Ingredient name Concentration (%) CAS number

contribute to the
Benzene < 1 (w/w)* 71-43-2
danger:
*According ANP Resolution, benzene content must be done in Gasoline A and Quality
Certificate must be reported considering the addition of anhydrous ethanol fuel to
Gasoline A, at a percentage point below the value in effect on the date of gasoline
manufacture.
Other ingredients There are no other ingredients in concentrations above the cut-off values.

4. FIRST AID MEASURES

Move affected person to fresh air. If not breathing, if breathing is irregular or if
Inhalation: respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Get medical assistance and present this SDS.
Brush off loose particles from skin. Wash with plenty water, for at least 15 minutes.
Skin contact: Remove contaminated clothing and wash it before reuse. Get medical assistance and
present this SDS.
Flush with plenty of water for at least 15 minutes, occasionally lifting the upper and
Eye contact: lower eyelids. Remove contact lenses, if present and easy to do. Get medical assistance
and present this SDS.
Wash the mouth with plenty of water. DO NOT INDUCE VOMITING. Whether vomiting
Ingestion: occurs spontaneously, lay the patient on her side to prevent her from aspirating the
residue. Get medical assistance and present this SDS.
Actions that should be
Never give anything by mouth to an unconscious person.
avoided:
Protection of frist-aiders: Avoid contact with the product when helping the victim.
4.1 Most important symptoms and effects, both acute and delayed
Headaches, nausea, dizziness and mental confusion. Cough. Rednes and dryness of the skin and eye.
4.2 Notes to physician
Avoid contact with the product when helping the victim. Keep the victim at rest and warm. Do not give anything
by mouth to an unconscious person. Symptomatic treatment should understand, above all, supportive measures
such as correction of hydroelectrolytic and metabolic disorders, in addition to respiratory assistance.
5. FIRE-FIGHTING MEASURES
Measures that must be taken in the firefighting, caused by the substance, or that occurs around.

5.1 Extinguishing media

Suitable Use dry chemical powder, alcohol resistant foam and carbon dioxide (CO2).
extinguishing media:
Unsuitable Don’t use direct water jets over the burning liquid. Water spray only in packaging.
extinguishing media:
5.2 Specific hazards arising from the chemical
Evacuate the area. Fight fire from a safe distance. Wear full PPE and self-contained
Specials procedures: respiratory protection. Use dikes to contain water used in combat. Position yourself with
your back to the wind. Use water fog/spray to cool exposed equipment close to the fire.
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Vapors can travel great distances causing the flame to retreat or new fires in both open
Dangers from
and confined environments. Containers can explode if heated. When heated it can release
combustion:
hydrogen sulfide.
5.3 Special protective actions for fire-fighters
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action
shall be taken involving any personal risk or without suitable training. Fire-fighters should wear appropriate
protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive
pressure mode.

6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1 – For non- No action shall be taken involving any personal risk or without suitable training. Put on
emergency appropriate personal protective equipment (see Section 8). Keep unnecessary
personnel: personnel Away.
If specialized clothing is required to deal with the spillage, take note of any information
in Section 8 on suitable and unsuitable materials. See also the information in "For
6.1.2 – For nonemergency personnel".
emergency Removal of sources of ignition: Interrupt electrical power and turn off sources that
responders: generate sparks. Remove from the site all material that could cause the beginning of fire
(ex.: spilled diesel oil).
Dust control: Not applicable as it is a liquid.
6.2 Environmental precautions
Special Procedures: Inform the relevant authorities if the product has caused environmental pollution
(sewers, waterways, soil or air). Do not allow any potentially contaminated water,
including rainwater, runoff from firefighting or spills, to enter any waterway, sewer or
drain.

6.3 Methods and materials for containment and cleaning up

Paved Floor: Use natural or spill containment barriers. Collect spilled product and place in
appropriate containers. Adsorb remaining product with dry sand, earth, vermiculite, or
any other inert material. Place the adsorbed material in appropriate containers and
remove them to a safe place. For final disposal, proceed according to Section 13 of this
SDS. Soil: Remove layers of contaminated soil until it reaches uncontaminated soil, collect
Cleaning methods:
this material and place in a sealed and properly identified container. Bodies of water:
Immediately interrupt the abstraction for human or animal consumption and contact the
nearest environmental agency and the company's emergency center, since the measures
to be adopted depend on the proportions of the accident, the characteristics of the water
body in question and the quantity of the product involved.
Difference between
There is no distinction between large and small leak actions for this product.
small and large leak:
Prevention of Prevent the product from contaminating streams, lakes, water sources, wells, sewers,
secondary hazards: storm sewers and effluents.
Isolate the area. Use PPE. Remove sources of ignition. Contain spillage. Collect in
Procedures:
containers for disposal. Avoid contamination of water courses.
Methods: Do not use the empty packaging.
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7. HANDLING AND STORAGE

7.1 Precautions for safe handling:

Handle the product only in well-ventilated areas or with adequate general/place

Safe handling ventilation systems. Avoid formation of vapors or mists. Avoid exposure to the product.
guidelines: Avoid contact with incompatible materials. Wear protective gloves, protective clothing,
eye protection, face protection as indicated in Section 8.
Eating, drinking and smoking should be prohibited in areas where this material is handled,
stored and processed. Workers should wash hands and face before eating, drinking and
Hygiene measures:
smoking. Remove contaminated clothing and protective equipment before entering
eating areas. See also Section 8 for additional information on hygiene measures.
Suitable: Wash contaminated clothing separately before reuse, avoiding contact with
other items for personal use. Wash hands and face during breaks and at the end of work
Technical measures
hours.
appropriate to the
Unsuitable: Do not wash contaminated clothing together with other clothing or utensils
workers:
for personal use.

7.2 Conditions for safe storage, including any incompatibilities

Keep the product in a cool, dry and well-ventilated place, away from sources of heat and
ignition. The storage place must contain a containment basin to retain the product in case
of leakage. Keep containers tightly closed and properly labeled. The storage place must
Suitable conditions:
have an impermeable floor, free of combustible materials and with a containment dike to
retain in case of leakage. No need to add stabilizers and antioxidants to ensure product
durability.
Conditions to avoid: Moist locations, heat sources and direct sunlight.
Keep away from heat, sparks, open flame and hot surfaces. Do not smoke. Keep the
Fire and explosion container tightly closed. Ground the container vessel and product receiver during
prevention: transfers. Only use non-sparking tools. Avoid the accumulation of electrostatic charges.
Use explosion-proof electrical, ventilation and lighting equipment.
Incompatible product Do not store together with food, feed, medicines, beverages, intended for human and
and materials / other animal consumption. Adopt good personal hygiene practices. Do not save or consume
information: food in the workplace. Wash hands before eating or smoking.
Safe materials for
Not specified.
packaging:
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

Occupational exposure Ingredient name Exposure limits Type References
limits: 300 ppm TLV-TWA
Gasoline ACGIH
500 ppm TLV-STEL
0.5 ppm TLV-TWA
Benzene ACGIH
2.5 ppm TLV-STEL
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Biological indicators:
Substance Indicator(s) Collection Value of IBE/EE* Notation
time
Benzene S-Phenylmercapturic acid (S- PMA) End of shift 25 µg/g.creat. B(1)

Trans, trans-Muconic acid (TTMA) in End of shift 500 µg/g.creat. B(1)

urine Comments:
for the Steelworks,
the rule currently in
force will be
maintained
*IBE/EE - Biological Indicators of Excessive Exposure
(1)
B - Background

8.2 Engineering controls

Appropriate: If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local
exhaust ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. It is recommended to make
emergency showers and eyewash stations available in the work area.
8.3 Individual protection measures

Use of a filter respirator for organic vapors is recommended for average exposures
above half the TLV-TWA. In cases where exposure exceeds 3 times the TLV-TWA value,
Respiratory
use a self-contained, full facepiece, air-supplied respirator (SCBA) operated in positive
protection:
pressure mode. Follow guidance from the Respiratory Prevention Program (PPR), 4th
ed. São Paulo: Fundacentro, 2016.
Hand protection: For handling use PVC protective gloves.
Eye/face protection: Safety glasses or face protection (splash shield).
Other skin Waterproof clothing and protective PVC gloves, closed safety footwear and Sudden
protection: Fire (FR) protective clothing.
Thermal hazards: Not expected under normal use. Not relevant/applicable due to nature of the product.
Keep the PPE properly clean and in proper conditions of use, periodically carrying out
Special Precautions:
inspections and possible maintenance and/or replacement of damaged equipment.
Hygiene measures: Wash contaminated clothing separately, avoiding contact with other personal items.
Collective emergency
Emergency shower and eyewash.
means:

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance (physical state and color): Yellowish liquid.
Odor and odor threshold: Characteristic.
pH: Not applicable.
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Melting point: Not available.

Boiling point: -20 – 215°C
Flash point: < -43°C (closed cup).
Evaporation rate: > 1 (butyl acetate = 1)
Flammability (solid, gas): Not applicable.
Explosive (flammable) limits:
Lower 1.3%
Upper 7.1%
Vapor density: 3 - 4 (air = 1)
Relative density: 0.72 – 0.76 at 20°C.
Vapor pressure: 69 kPa at 37.8°C.
Solubility: Insoluble in water. Soluble in organic solvents.
Partition coefficient - n-octanol/water: Log know: 2 – 7.
Auto-ignition temperature: 257°C.
Decomposition temperature: Not available.
Viscosity: 0.41 mPa.
Other information: Distillation range: 27 – 220°C at 760 mmHg.
Volatile part: 100%.
10. STABILITY AND REACTIVITY

10.1 Reativity
Under normal conditions of storage and use, this product is non-reactive.
10.2 Chemical stability
Under normal conditions of storage and use, this product is stable. It does not undergo polymerization.
10.3 Possibility of hazardous reactions
Vapors can form explosive mixtures with air.
10.4 Conditions to avoid
High temperatures. Ignition sources and contact with incompatible materials.
10.5 Incompatible materials
Strong oxidizing agents and concentrate oxygen.
10.6 Hazardous decomposition products
In combustion it releases toxic and irritating gases. When heated it can release hydrogen sulfide.
11.TOXICOLOGICAL INFORMATION
The product is not expected to be acutely toxic.
Acute toxicity: LD50 Oral (rat): Not available.
LD50 Dermal (rat): Not available.
Skin corrosion/irritation: It causes skin irritation with redness and pain.
Eye damage/eye irritation: It causes eye irritation with redness.
Sensibilization: The product is not expected to cause respiratory or skin sensitization.
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Carcinogenicity: May cause cancer.

Gasoline: Carcinogenic in animals of unknown relevance to humans (Group A3 –
ACGIH).
Benzene: Carcinogenic to humans (Group 1 – IARC).
Chronic toxicity: Mutagenicity: Suspect to cause genetic defects.
Benzene: Positive results in in vivo and in vitro tests with human somatic cells
(Chromosome Aberration Assay).
Reproductive toxicity: Suspected to damaging fertility or the unborn child.
Benzene: Exposure is related to changes in menstruation, miscarriage and stillbirth.

Single Exposure: May cause respiratory tract irritation with coughing. May cause
gastrointestinal tract irritation with nausea and vomiting. Inhalation of the product
may cause mental confusion, drowsiness, dizziness and drowsiness.
Specific target organ toxicity: Repeated Exposure: Prolonged and repeated skin contact may cause dermatitis.
Repeated eye contact can cause irritation and chronic conjunctivitis. May cause
damage to the central nervous system and liver through prolonged and repeated
exposure.

Aspiration hazard: Aspiration into the lungs can result in chemical pneumonia.

12. ECOLOGICAL INFORMATION

12.1 Toxicity
Toxicity to aquatic Harmful to aquatic life.
organisms: LC50 Fish, 96h: 82 mg/L.
LC50 Algae: Not available.
LC50 Microcrustaceans: Not available.

12.2 Persistence and degradability

Low degradation and high persistence are expected.
12.3 Bioaccumulative potencial
Bioaccumulative potential in aquatic organisms is expected.
BCF: 273 (estimated value).
Log kow: 2 - 7 (estimated value).
12.4 Mobility in soil
Not determined.
12.5 Other adverse effects
Not available.
13. DISPOSAL CONSIDERATIONS

13.1 Disposal methods

Product Waste: Disposal of this product, solutions and any by-products should at all times comply with
the requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor.
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Used packaging: Empty containers or liners may retain some product residues. Empty containers retain
product residue and can be hazardous. Care should be taken when handling emptied
containers that have not been cleaned or rinsed out.

14. TRANSPORT INFORMATION

National and international regulations:

Land IMDG IATA

UN number ONU1203 UN1203 ONU1203
UN proper shipping name GASOLINA GASOLINE GASOLINA
Transport hazard class(es) 3 3 3

Packing group II II II
Environmental hazards Sim Yes Sim

Land transportation (United Nations, Orange Book):

o Risk number: 33
o Special Provision: 243
o Limited quantity:
Vehicle: 333 kg
Inner packing: 1 L

IMDG Classification, according International Maritime Dangerous Goods Code by International Maritime
Organization (IMO):
o EmS: F-E, S-E
o Special Provision: 243, 944
o Limited quantity: 1 L
o Marine Pollutant: Yes

IATA Classification, according Internacional Aviation Organization – Technical Instructions (ICAO – TI):
o Limited quantity:
Limited quantity max.: 10 L Packing instruction: Y341
Passenger Air: 5L Packing instruction: 353
Cargo Air: NA Packing instruction: NA
o Special Provision: A100

NOTE - The regulations mentioned above are those in force on the day this SDS is updated. Considering the
continuous evolution of regulations for the transport of dangerous goods, it is advisable to ensure their validity
with the responsible Competent Bodies.

15. REGULATORY INFORMATION

National and international regulations
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ACGIH 2020 - “American Conference of Governmental Industrial Hygienists“; TLVs and BEIs based on the
documentation of the Threshold Limit Values for Chemical Substances and Physical Agents and Biological
Exposure Indices.
ECHA – “European Chemicals Agency”; Substance Information; disponível em:
<https://echa.europa.eu/pt/home>.
IATA - “International Air Transport Association” (Associação Internacional de Transporte Aéreo) Dangerous Goods
Regulation (DGR).
IMO – “International Maritime Organization” (Organização Marítima Internacional) International Maritime
Dangerous Goods Code (IMDG Code).
International Maritime Dangerous Goods Code, International Maritime Organization (IMO).
NIOSH – “National Institute for Occupational Safety and Health”; Immediately Dangerous to Life and Health
(IDLH) Values.
Orange Book - Transport of Dangerous Goods, Vol1 and Vol2, United Nations (UN).
Purple Book, Globally Harmonized System of Classification and Labeling of Chemicals (GHS), United Nations (UN).
Regulation (EC) No 1272/2008 - classification, labelling and packaging of substances and mixtures (CLP).
Technical Instructions (ICAO – TI), Internacional Aviation Organization.

16. OTHER INFORMATION

Version: 1

Authored by: Acelen Product Stewardship

References: Safety data sheets of raw materials, global regulatory body information, scientific literature, and testing
data.

Recommended Use - Follow all recommendations for use, storage and disposal indicated by the manufacturer /
registrant and described on the packaging, product package insert and mentioned in section 1 of this SDS.

Notice to reader - This product's safety information is provided to assist our customers in assessing compliance with
safety/health/ environmental regulations. The information contained herein is based on data available to us and is
correct to the best of our knowledge, information and belief at the date of its publication. However, no warranty
of merchantability, fitness for any use, or any other warranty is expressed or implied regarding the accuracy of this
data, the results to be obtained from the use thereof, or the hazards connected with the use of the product. Since
the use of this product is within the exclusive control of the user, it is the user's obligation to determine the
conditions for safe use of the product. Such conditions should comply with all regulations concerning the product.
The company referenced in this Safety Data Sheet assumes no liability for any injury or damage, direct or
consequential, resulting from the use of this product unless such injury or damage is attributable to the gross
negligence of such company.

Key to abbreviations:
ABNT - Agência Brasileira de Normas Técnicas;
ACGIH - American Conference of Governmental Industrial Higyenists;
ATE - Acute Toxicity Estimate;
BCF - Bioconcentration Factor;
BEI – Biological Exposure Indices;
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CAS - Chemical Abstracts Service;

EC50 - Effective concentration;
EPA - Environmental Protection Agency;
GHS - Globally Harmonized System of Classification and Labelling of Chemicals;
IATA - International Air Transport Association;
IBC - Intermediate Bulk Container;
IDLH - Immediately Dangerous To Life or Health;
IMDG - International Maritime Dangerous Goods;
LC50 - Lethal concentration 50%;
LD50 - Lethal dose 50%;
LEL - Lower explosive limit;
LogPow - logarithm of the octanol/water partition coeficiente;
MARPOL - International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol
of 1978. ("Marpol" = marine pollution);
NA - Not applicable;
NBR - Norma Brasileira;
ND - Not available;
NFPA - National Fire Protection Association;
NIOSH – National Institute for Occupational Safety and Health;
OSHA - Occupational Safety and Health Administration;
PEL - Permissible Exposure Limits;
PPE - Personal protective equipment;
REL - Recommended Exposure Limits;
SCBA – Self-contained breathing apparatus;
SGG - Segregation Group;
TLV - Threshold limit value;
TWA - Time Weighted Average;
UEL – Upper explosive limit;
UN - United Nations;
VOC - Volatile Organic Compound.