GTM 5 Srichaitanya 2023

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Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI


A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60_Elite, Target & LIIT‐BTs JEE-MAIN Date: 29-12-2023
Time: 03.00Pm to 06.00Pm GTM-05 Max. Marks: 300
IMPORTANT INSTRUCTION:
1. Immediately fill in the Admission number on this page of the Test Booklet with Blue/Black Ball Point Pen
only.
2. The candidates should not write their Admission Number anywhere (except in the specified space) on the
Test Booklet/ Answer Sheet.
3. The test is of 3 hours duration.
4. The Test Booklet consists of 90 questions. The maximum marks are 300.
5. There are three parts in the question paper 1,2,3 consisting of Physics, Chemistry and Mathematics having
30 questions in each subject and subject having two sections.
(I) Section –I contains 20 multiple choice questions with only one correct option.
Marking scheme: +4 for correct answer, 0 if not attempt and ‐1 in all other cases.
(II) Section‐II contains 10 Numerical Value Type questions. Attempt any 5 questions only, if more than 5
questions attempted, First 5 attempted questions will be considered.
∎ The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer
value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and
less than 11 round off is 11).
To cancel any attempted question bubble on the question number box.
For example: To cancel attempted question 21. Bubble on 21 as shown below

.
Question Answered for Marking Question Cancelled for Marking
Marking scheme: +4 for correct answer, 0 if not attempt and ‐1 in all other cases.
SRI CHAITANYA IIT ACADEMY, INDIA 29‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐05_Q.P
6. Use Blue / Black Point Pen only for writing particulars / marking responses on the Answer Sheet. Use of pencil is
strictly prohibited.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, mobile phone any electron
device etc, except the Identity Card inside the examination hall.
8. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
9. On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in the Hall.
However, the candidate are allowed to take away this Test Booklet with them.
10. Do not fold of make any stray marks on the Answer Sheet

Name of the Candidate (in Capital): ________________________________________________

Admission Number:
Candidate’s Signature:________________ Invigilator’s Signature: ________________

29‐12‐23_Sr.Super60_Elite, Target & LIIT‐BTs_Jee‐Main_GTM‐05_Test Syllabus


PHYSICS : Theory Based
CHEMISTRY : Theory Based
MATHEMATICS : Theory Based

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SRI CHAITANYA IIT ACADEMY, INDIA 29‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐05_Q.P
PHYSICS Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. A rod is supported horizontally by means of two strings of equal length as shown in figure.
If one of the string is cut. Then tension in other string at the same instant will:

Mg

1) remain unaffected 2) increase


3) decreases 4) become equal to weight of the rod
2. Curie temperature is the temperature above which:
1) a ferromagnetic material becomes paramagnetic.
2) a paramagnetic material becomes diamagnetic.
3) a ferromagnetic material becomes diamagnetic.
4) a paramagnetic material becomes ferromagnetic.

3.  2 2

Potential is varying with x and y as V  2 x  y . The corresponding field pattern is:
y y

x x

1) 2)
y y

x x

3) 4)
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4. Two electrons are moving with the same speed V. One electron enters a region of uniform
electric field while the other enters a region of uniform magnetic field. After sometime if the
de Broglie wavelength of the two are 1 and 2 , then (select the best alternative)

1) 1  2 2) 1  2
3) 1  2 or 1  2 4) 1  2 or 1  2 or 1  2
5. A rod PQ is connected to the capacitor plates. The rod is placed in a magnetic field (B)
directed downward perpendicular to the plane of the paper. If the rod is pulled out of
magnetic field with velocity v as shown in figure.

 B   
   

P
M
    
V
N

 Q    
1) plate M will be positively charged
2) plate N will be positively charged
3) both plates will be similarly charged
4) no charge will be collected on plates
6. In hydrogen like atoms the ratio of difference of energies E4 n  E2 n and E2 n  En varies with
atomic number z and principle quantum number n as
z2 z4 z
1) 2 2) 4 3) 4) none of these
n n n
7. Consider two identical iron spheres A and B, A lies on a thermally insulating plate, whilst B
hangs from an insulating thread as shown. Equal amounts of heat are given to the two
spheres. Then

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SRI CHAITANYA IIT ACADEMY, INDIA 29‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐05_Q.P

1) Temperature of A is greater than that of B


2) Temperature of B is greater than that of A
3) A and B will have equal temperature
4) None of the above
8. A stream of particles   particles encounters a stationary unknown nucleus in a cloud
chamber. After a collision, the two nuclei are scattered in mutually perpendicular directions.
If some kinetic energy is lost in the collision, the unknown nucleus must be
1) A proton 2) a nucleus lighter than an   particle
3) an   particle 4) a nucleus heavier than an   particle
9. Assertion(A): A capacitor is connected to an ideal battery. A dielectric slab is slowly
inserted into the gap between the plates of capacitor. Work required in the process is
positive.
Reason (R): Force due to capacitor will try to pull dielectric into the capacitor. To slowly
insert external force needs to be outward i.e. opposite to displacement.
1) Assertion is false but Reason is true.
2) Both Assertion and Reason are true but Reason is NOT the correct explanation of
Assertion
3) Both Assertion and Reason are true and Reason is the correct explanation of Assertion
4) Assertion is true but Reason is false.
10. Two concentric conducting shells can be connected by a switch ‘s’ as shown. Inner shell has
charge Q.
Statement-1: Charge on inner sphere flows from inner shell to outer shell when switch is
closed.
Statement-2: Charge will not flow if Q is negative as charge can not flow from low to high
potential.
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'S'

1) Statement-1 is incorrect and statement-II is correct


2) Statement-1 is correct and Statement-II is incorrect
3) Both Statement-1 Statement-II are incorrect
4) Both Statement-1 and Statement-II are correct
11. Two concentric conducting spheres are as shown. A point charge (Q) is at common center.
Inner sphere is a hollow shell having charge 2Q and outer sphere is a grounded thick hollow
sphere. Which of the following is correct graph of potential as a function of distance from
centre?

2Q

R Q

3R
2R

V V

r r
R 3R R 3R
1) 2)

V
V

r r
R 2R R 2R 3R
3) 4)
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12. Consider the following four statements.
A. A paramagnetic substance displays greater magnetization when cooled.
B. Diamagnetism is independent of temperature.
C. If a solenoid uses Iron for its core instead of air then field will be greater.
D. Magnetic field lines are closed loops
Which statements are true?
1) Only A and B 2) A, B and C 3) A, B and D 4) All four
13. ‘Parsec’ is the unit of-
1) Time 2) Distance 3) Frequency 4) Angular acceleration
14. Fusion reaction takes place at high temperature because
1) atoms get ionized at high temperature
2) kinetic energy is high enough to overcome the coulomb repulsion between nuclei
3) molecules break up at high temperature
4) nuclei break up at high temperature
15. The equation has Statement-I and Statement-2. Of the four choices given after the
statements, choose the one that best describes the two statements.
Statement-1: Very large size telescopes are reflecting telescopes.
Statement-2: It is easier to provide mechanical support to large size mirrors than large size
lenses
1) Statement-1 is true and Statement-2 is false
2) Statement-1 is false and Statement-2 is true
3) Statement-1 and Statement-2 are true and Statement-2 is correct explanation for
Statement-1
4) Statement-1 and Statement-2 are true and Statement-2 is not the correct explanation for
Statement-1

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SRI CHAITANYA IIT ACADEMY, INDIA 29‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐05_Q.P
16. Assertion: Earth has an atmosphere but the moon does not.
Reason: Moon is small in comparison to earth
1) Assertion and Reason are true but Reason is not correct explanation for Assertion
2) Assertion and Reason are false
3) Assertion is true and Reason is false
4) Assertion and reason are true but Reason is correct explanation for Assertion
17. Assertion: Two conducting rods of same material and same lengths are joined end to end as
shown in figure. Heat current H is flowing through them as shown. Temperature difference
across rod-1 is more than the temperature difference across rod-2.
H

1 2

Reason: Thermal resistance of rod-1 is less compared to rod-2.


1) If both Assertion and Reason are true and Reason is the correct explanation of Assertion.
2) If both Assertion and Reason are true but Reason is not the correct explanation of
Assertion
3) If Assertion is true but Reason is false
4) If both Assertion and Reason are false
18. Assertion: If a wire is stretched, only half of the work done in stretching the wire remains
stored as elastic potential energy.
1
Reason: Potential energy stored in the wire is  stress    strain 
2
1) If both Assertion and Reason are true and Reason is the correct explanation of Assertion.
2) If both Assertion and Reason are true but Reason is not the correct explanation of
Assertion.
3) If Assertion is true but Reason is false.
4) If Assertion is false but Reason is true.
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19. Two soap bubbles coalesce to form a single large drop.
Match the following columns.
Column I Column II
A. Surface energy in the process will p. Increase
B. Temperature of the drop will q. Decrease
C. Pressure inside the soap bubble will r. Remain same
1) Aq, B  p, C q 2) Aq, B r, C  p
3) A p, B r, C q 4) Aq, B  p, C r
20. Assertion: In the circuit shown in figure, battery is ideal. If a resistance R0 is connected in
parallel with R, power across R will increase.
Reason: Current drawn from the battery will increase.

E
1) If both Assertion and Reason are true and Reason is the correct explanation of Assertion
2) If both Assertion and Reason are true but Reason is not correct explanation of Assertion
3) If Assertion is true but Reason is false
4) If Assertion is false but Reason is true
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5 questions attempted. The
Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is
10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

Note:
From: Question number’s 21 to 30 rules for Answer marking
If your answer is options 2,4 Then you have to fill the OMR sheet
as ‘24’
If your answer is options 1,3,4 Then you have to fill the OMR sheet
as ‘134’
And if your answer is options 1,2,3,4 then you have to fill the OMR sheet as
‘1234’

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SRI CHAITANYA IIT ACADEMY, INDIA 29‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐05_Q.P
21. A block of mass 1 kg moves under the influence of external forces on a rough horizontal
surface. At some instant, it has a speed of 1 m/s due east and an acceleration of 1 m/s2 due
north. The force of friction acting on it is F
1) F acts due west
2) F acts due south
3) F acts in the south west direction
4) The magnitude of F cannot be found the given data
22. A particle is taken from point A to point B under the influence of a force field. Now it is
taken back from B to A and it is observed that the work done in taking the particle from A to
B is not equal to the work done in taking it from B to A. If Wnc and Wc is the work done by
non conservative forces and conservative forces present in the system respectively, U is
the change in potential energy,  k is the change is kinetic energy, then
1) Wnc U  k 2) Wc U 3) Wnc Wc  k 4) Wnc U  k
23. If electron of the hydrogen atom is replaced by another particle of same charge but of double
the mass, then:
1) Bohr radius will increase
2) Ionisation energy of the atom will be doubled
3) Speed of the new particle in a given state will be lesser than the electron’s speed in same
orbit
4) Gap between energy levels will now be doubled
24. An object is floating in a liquid, kept in a container. The container is placed in a lift. Choose
the correct option(s)
1) Buoyant force increases as lift accelerates up
2) Buoyant force decreases as lift accelerates up
3) Buoyant force remains constant as lift accelerates
4) The fraction of solid submerged into liquid does not change
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25. Charges Q1 and Q2 lie inside and outside respectively of a closed Gaussian surface S. Let E

be the field at any point on S and  be the flux of E over S:


1) If Q1 changes, both E and  will change 2) If Q 2 changes E will change
3) If Q1  0 and Q2  0 then E  0 but   0 4) If Q1  0 and Q2  0 then E  0 but   0
26. The reactance of a circuit is zero. It is possible that the circuit contains:
1) An inductor and a capacitor 2) An inductor but no capacitor
3) A capacitor but no inductor 4) Neither an inductor nor a capacitor
27. For a body executing SHM with amplitude A, time period T, maximum velocity vmax and
T
phase constant zero. Which of the following statements are correct for 0  t  (y is
4
displacement from mean position particle is at mean position at t = 0)?
1) At y   A 2  , v   v max 2  2) For v   v max 2  , y   A 2 

3) For t  T 8 , y   A 2  4) For y   A 2  , t  T 8

28. An astronaut leaves his spaceship for some experiment and floats freely in space at rest
relative to his spaceship. His friend in the spaceship ignites a rocket installed on the
spaceship for a very short duration. Which of the following observations can you make
relative to a reference frame moving together with the astronaut outside the spaceship?
1) The spaceship has lesser kinetic energy than ejected gases
2) The spaceship and the ejected gases have equal kinetic energies
3) The spaceship has greater kinetic energy than the ejected gases
4) Magnitudes of momenta of spaceship and ejected gases are equal
29. In an X-ray tube, electrons emitted from a filament (cathode) carrying current I hit a target
(anode) at a distance d from the cathode. The target is kept at a potential V higher than the
cathode resulting in emission of continuous and characteristic X-rays. If the filament current

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SRI CHAITANYA IIT ACADEMY, INDIA 29‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐05_Q.P
I
I is decreased to , the potential difference V is increased to 2V, and the separation
2
d
distance d is reduced to , then
2
1) the cut-off wavelength will reduce to half, and the wavelengths of the characteristic X-
rays will remain the same
2) the cut-off wavelength as well as the wavelengths of the characteristic X-rays will remain
the same
3) the cut-off wavelength will reduce to half, and the intensities of all the X-rays will
decrease
4) the cut-off wavelength will become two times lager, and the intensity of all the X-rays
will decrease
30. The breakdown in a reverse biased p-n junction is more likely to occur due to
1) large velocity of the minority charge carriers if the doping concentration is small
2) large velocity of the minority charge carriers if the doping concentration is large
3) strong electric field in a depletion region if the doping concentration is small
4) strong electric field in the depletion region if the doping concentration is large

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SRI CHAITANYA IIT ACADEMY, INDIA 29‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐05_Q.P
CHEMISTRY Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.

31. For the process : H2O l  (1 atm, 373.15K) H2O  g  (1 atm, 373.15K), the correct set of
thermodynamic parameter is
1)  G  0;  S   ve 2)  G  0;  S   ve
3)  G   ve;  S  0 4)  G   ve ;  S   ve
32. Assertion:- When aniline is subjected to nitration by conc. HNO3 &H2SO4 meta nitro aniline
is formed in considerable amount.
Reason: - NH2 is o/p directing but ring deactivating group.
1) Assertion is True, Reason is true: Reason is the correct explanation for Assertion.
2) Assertion is true Reason is true: Reason is not the correct explanation for Assertion.
3) Assertion is True, Reason is False.
4) Assertion is False, Reason is true.
+
NH 2 OH H LiAlH 4
O (A) (B) (C) ; The product 'C' is
33.
OH

N N N O N OH
1) H 2) 3) H 4) H H
34. The equilibrium constant for ionization constant of acetic acid in an aqueous solution of
concentration ‘C’ is given by
c  c2 c  c2 c  c2 c  c2
1) K  2) K  3) K  4) K 
 c   (    c )   c   (    c )
35. Which one of the following is correct (Major product)
NMe2 NMe2 OCH 3 OCH 3

Na / liq NH 3 Na / liq NH 3

1) 2)
COOH COOH NMe2 NMe2

Na / liq NH 3 Na / liq NH 3

3) 4)
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36. Which of the following is/are aromatic in character?

(I) (II) (III) (IV)


1) II only 2) I, III and IV 3) II ,III and IV 4) I, II, III and IV
37. About CH 2 F2 the correct statement is.
1) The order of bond angles is HCH  HCF  FCF
2) The shape of the molecule is tetrahedral
3) All bond angles are equal.
4) The order of bond angles is HCH  HCF  FCF
38. The major product formed in the reaction given below is
O

1.NaOH,Br2
NH
2.H3O+

O
NH2 Br

COOH CONH 2
1) 2)
O

COOH
O

CONH 2
3) 4) O
39. Assertion (A): Components of a mixture of red and blue inks can be separated by
distributing the components between stationary and mobile phases in paper chromatography.
Reason (R): The coloured components of inks migrate at different rates because paper
selectively retains different components according to the difference in their partition
between the two phases.
1) Both A and R are correct and R is the correct explanation of A.
2) Both A and R are correct but R is not the correct explanation of A.
3) Both A and R are not correct.
4) A is not correct but R is correct
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40. A metal ‘M’ shows the following observable changes in the sequence of reactions. Identify
the metal. M
M 
dil . H 2 SO4
 colourless solution 
aq NaOH

White ppt 
excess NaOH
colourless solution 
H2S
 White ppt
1) Bi 2) Pb 3) As 4) Zn
41. The rate of hydrolysis of boron halides will be in the order of
1) BF3  BCl3  BBr3  BI3 2) BCl3  BF3  BBr3  BI3
3) BI3  BBr3  BCl3  BF3 4) BI3  BCl3  BF3  BBr3
42. The equilibrium:
P4  g   6Cl2  4PCl3  g  is obtained by mixing equal moles of P4 and Cl2 in an evacuated
vessel. Then at equilibrium:
1)  Cl2    PCl3  2)  Cl2    P4  3)  P4    Cl2  4)  PCl3    P4 
43. Biuret test is not given by :
1) proteins 2) urea
3) polypeptide 4) carbohydrates
44. Which of the following complex has highest C  O bond energy?
1) Ni  CO  
 4
2)  Co  CO  
 6
3
3) Mn  CO  
 6

4)  Fe  CO 5 
45. Which of the following diazonium coupling reactions is not feasible?

N2Cl + OH N N OH

1)

H3C N2Cl + OCH3 H3C N N OCH3

2)

O 2N N 2 Cl + OCH 3 O 2N N N OCH 3

NO 2
3) NO 2

NO 2 H 3C NO 2 H 3C

O 2N N 2 Cl + CH3 O 2N N N CH3

NO 2 H 3C
4) NO 2 H 3C

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46. Select the law that corresponds to data shown for the following reaction
A  B  Products
Exp [A] [B] Initial rate
1 0.012 0.035 0.1
2 0.024 0.070 0.8
3 0.024 0.035 0.1
4 0.012 0.070 0.8
1) Rate  k  B  2) Rate  k  B  3) Rate  k  A B  4)Rate  k  A  B 
3 4 3 2 2

47. In the following


NO3  As2 S3  H 2O  AsO43  NO  SO42  H 
Equivalent weight of As2S3 (Molecular weight M) is
3M M M M
1) 2) 3) 4)
28 4 24 28
48. Which of the following is incorrect?

1) PCl5 exists as PCl4 


PCl6  in solid state
 

2) PBr5 exists as  PBr4   in solid state


 
 PBr6

3) Liquid IF5 selfionises to give IF4  and IF6 


 

4) ICl can undergo ionization as I  and ICl2 


 

49. In the given reaction, the structure of X is:


H

N

Br2
 X 

H
Br
N
Br
N

1) Br 2)
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H N
N

Br

3) Br 4) Br
50. Which failed to form Osazone with excess of C6H5NHNH2 in strongly alkaline medium

1) D-glucose 2) D-Mannose 3) 4) All of these


(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
  
51. In the reaction: CN  H  NO3  CO2  NO  H2O (unbalanced ), if the stoichiometry of

, H  & NO3 are x, y & z respectively,. Find  y  z /x ?



CN 

52. How many of the following reactions give haloform as one of the products?
Cl  3
i H O
 i  H 2O /  
 ii  I 2 / NaOH 
(i) 
 ii  I 2 / NaOH 
(ii)

Cl

O
O O

(iii) 
I 2 / NaOH
 (iv)
OCH 3 
I 2 / NaOH

O

O
 i  Hg  OAC 
 
2 2 4 / H O, NaBH
(v)   2
ii I / NaOH , 

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53. CH3  CH  CH  O  CH2  CH3 
dil acid
 X  Y (Y gives positive haloform test)

The number of possible isomers for X excluding stereo isomers and including X.
0 0 0
54. If E1 , E2 and E3 are standard oxidation potentials for Fe Fe 2 , Fe 2 Fe3 and Fe Fe3 , then

E 20  2 E10
E 
0
3 . The value of n is……….
n
55. Among the following, the total number of reactions/ processes in which the entropy
increases are:
a. 2NaHCO3  Na2CO3  s  CO2  g   H 2O  g 
b. A liquid cyrstallises into a solid.
c. Temperature of crystalline solid is raised from zero K to 100 K.
d. Hard boiling of an egg.
e. Intermixing of gases at constant temperature.
f. Boiling of water
g. Desalination of water.
h. NH3  g ,10atm  NH3  g ,1atm
56.

CH 2

KMnO4
H 2C CH 2 A  gas   B

1 mole  LiAlH 4

H C
D

If X is no of moles of CO2 and Y is no. of hydrogens that can participate in hyperconjugation

in D ,then (X + Y) is……

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SRI CHAITANYA IIT ACADEMY, INDIA 29‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐05_Q.P
57. Xenon trioxide in strongly alkaline solution forms a product A which slowly

disproportionate into B and xenon gas. The oxidation number of xenon in A is

58. Total number of moles of P-H bonds is in the product(s) formed when one mole of white

phosphorous completely react with NaOH solution.

59. How many of the following undergo decarboxylation on heating


O O
HOOC
O

HOOC O
COOH
COOH

COOH
COOH
COOH
COOH
COOH  H 2C  2
COOH

60. How many of the following compounds are more reactive than chlorobenzene towards
nitration?
CH 3

F NO2 O O O CH 3 OH NMe2

CN CHO OMe
Br

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MATHEMATICS Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.

61. S1 : function  : 5, 81  R defined by   x    x  5 2  x  812  x , takes the value 43 for
some x  5, 81
S2 : If a function y  g  x is defined on 5, 81 , then for any k   g  5  , g  81  there is some
point c  5, 81 such that g  c   k
1) S1 is true and S2 is true for every function g
2) S1 is true and S2 is not true for every function g
3) S1 is not true and S2 is true for very function g
4) S1 is not true and S2 is not true for every function g
62. Which of the following is always true
1) One root of the equation ax  bx  c  0,  a, b  R & c  R  Q & a  0 in the form of
2

p  q then other root is p  q  p  z, q  z  

2) Exactly one of the root of the equation ax 2  bx  c  0,  a  0  lies in the given interval
 k1 , k2  if   k1 .  k2   0
3) If a,b,c, d,e,  are positive real numbers and d   e2  0. The equations
d e 
ax 2  2bx  c  0,  a  0  and dx 2  2ex    0  d  0  have a common root, then  
a b c
4) a,b,c are in A.P and G.P then (a, b, c) can be (0, 0, 0)
63. In a parallelogram as shown in the figure  a  b 

D u1  bx  ay  ab
C
u3  ax  by  ab
u4  ax  by  2ab

A u2  bx  ay  2ab B
Equation of the diagonal AC is
1 4  u2u3  0
1) uu 2) u1  u2  u3  u4  0
1 2  u3u4  0
3) uu 1 3  u2u4  0
4) uu
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  01, then
n
64. If 9  80  I   where I, n are integers and
1) I is an odd integer 2) I is an even integer
3)  I    I     2  
n
4) 12   2  9  80

65. Let S1 : A function f always has a local maximum between any two local minima. Then f
must be differentiable
S2 : If a function is defined on  a , b  and continuous on  a, b , then it takes its extreme
values on  a, b.
S3 : Every continuous and bounded function on  ,   takes its extreme values.
The number of statements among the S1, S2 , S3 which are always true for every function
1) 0 2) 1 3) 2 4) 3
66. Graph of y    x  is given below

 0, 3
2 x
1 3
1

1
Then graph of y  is best represented by
  x
y y

12 2 13 2
0 x x
1 3 0 1 3
1 1

1) 2)

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SRI CHAITANYA IIT ACADEMY, INDIA 29‐12‐23_ Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐05_Q.P
y y

2 x y 1
0 1 3
1 13
0 x
1 2 3
3) 4)
67. Which of the following is true
1) If   x  is continuous at x  a then at x  a limit need not exist for ƒ 𝑥
2) For every continuous functions   x  , g  x  on  0,  satisfying   x   g  x  for all x  0
and both lim x and limg  x exist finitely
x x

3) If both functions   x  and g  x  have limits at x  a, then Lt    g  x      Lt   g  x   


x a  x a 
[ ] denotes G.I.F
4) for every continuous monotonic functions f  x  , g  x on  , Then their sum
  x   g  x  is monotonic on 
68. Let   x   x 2  2ax  b, g  x   cx 2  2dx  1 be quadratic expressions whose graph is as
shown in the figure  a  0, cd  0 
y

y  g  x
y    x
A

B
A' O
B'
Here it is given that AA'  BB ' and OA '  OB .
Absolute values of sum of roots of equations   x   0 and g  x   0 are p and q respectively
then p  q 
2d 2d
1) 2 a  2) 2  a  d  3) 1  b 4) 2 a 
c c
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69. f(x) and g(x) both defined R  R are two non-constant continuous functions then
Statement – 1: If g (x) is periodic then f(g(x)) is also periodic
Statement – 2: If g(x) and f(x) are both aperiodic then f(g (x)) is aperiodic.
Statement – 3: If g(x) is periodic with fundamental period T then f(g(x)) is not periodic
Statement – 4: If g(x) is periodic with fundamental period T then f(g(x)) is also periodic with
period T
Which of the following must be truth value of above statements in that order.
1) TFFT 2) TFTT 3) FFTT 4) TTTT
1
Let function y    x  satisfies the differential equation x 2
dy
70.  y e  x  0  and
2 x

dx
lim f  x   1 . Identify the incorrect statement?
x 0 

1) Range of   x is  0, 1   1  2)   x is bounded
2

3) lim   x 1
e 1
x
4) 0 f  x  dx  0 f  x dx
1
dx 1
71. STATEMENT–1: The inequality 0 1  x n  1 
n
is true for n  N .

1
x n1  x n  x 2n1
STATEMENT–2:  dx  0,  n  N .
0
1  x n

1) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for


Statement-1
2) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for
Statement-1
3) Statement-1 is True, Statement-2 is False
4) Statement-1 is False, Statement-2 is False

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72. f(x) and g(x) are functions defined on R  R
Statement 1: If f(x) is continuous and g(x) is discontinuous at x = a then their product is
continuous at x = a if f(a) = 0
Statement 2: If f(x) is continuous and g(x) is discontinuous at x = a and if g(a) = 0 then their
product is continuous at x = a
Statement 3: If f(x) is differentiable and g(x) is not derivable at x = a then their product is
derivable at x = a if g(x) is continuous and f(a) = 0
Statement 4: If f(x) is differentiable and g(x) is not derivable at x = a then their product is
derivable at x = a if g(x) is continuous and g(a) = 0
Which of the following must be truth value of above statements in that order.
1) FFFF 2) FFTF 3) TFFF 4) TFTF
73. Which of the following is true?
1) Number of equivalence relations on vowels in English language is 50.
2) Brother among humans is symmetric relation
3) RoS and SoR are symmetric only when R  S (for relations R & S)
4) RoS and SoR are symmetric if RoS  SoR (for relations R & S)
74. Statement – 1 : If  : 1,2,3,4,5  1,2,3,4,5 then the number of onto functions such that
  i   i and  1  2 is 11
Statement – 2 : If n(n >1) things are arranged in row, the number of ways in which they can
be de- arranged so that no one of them occupies its original place is
 1 1 n 1 
n ! 1    ......   1 
 1! 2! n! 
Statement–3:Number of ways of distribution of 12 identical balls into 3 identical boxes is 19
Statement–4: Number of ways of distribution of n identical objects among r persons, each
nr 1
one of whom can receive any number of objects is Cr 1
Which of the following must be truth value of above statements in that order.
1) FTFT 2) FFTF 3) TTTT 4) TFTF
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75. A bag contains four tickets having numbers 112, 121, 211, 222 written on them. Denote by
Ai  i  1,2,3 the event that the ith digit from left of the number on a randomly drawn ticket is
1.
1) A1, A2, A3 are independent events
2) P  Ai A j   P  Ai  P ( A j ) for all i j
3) P  Ai  Aj   P  Ai  P( Aj ) for all 1  i  j  3
4) P  Ai  Aj   P  Ai  P( Aj ) for all 1  i  j  3

STATEMENT – 1 : If the circles x  y  2gx  2 fy  0 and x  y  2g x  2 f y  0 are


2 2 2 2 1 1
76.
concentric g 1   g1 and they represent same circle
STATEMENT- 2: Let C be any circle with centre (0, 2) . There can be atmost 2 points with
rational coordinates on C.
STATEMENT- 3: Circle x 2  y 2 – 6 x – 4 y  9  0 bisects the circumference of the circle

x 2  y 2  8 x  6 y  23  0
STATEMENT- 4: If centre of first circle lie on the second circle then it bisects
circumference of second circle
Which of the following must be truth value of above statements in that order.
1) TTTT 2) FTTF 3) TFTF 4) TTTF
77. STATEMENT -1: Through the vertex ‘O’ of the parabola y2  4x chords OP & OQ are
drawn at right angles to one another. For all positions of the line through P and Q cuts the
axis of parabola at a fixed point
STATEMENT-2: The focus of the parabola y2  4ax is of the form  x1, 0

1) Both Statements are true and Statement-2 is the correct explanation of Statement-1
2) Both Statements are true but Statement-2 is not the correct explanation of Statement-1
3) Statement-1 is true, Statement-2 is false
4) Statement-1 is false, Statement-2 is true

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78. For square matrices A and B of same order which of the following is not true. (with real
entries)
(O is null matrix and I is Identity matrix of same order as A and B)
1) If AB = O and A is not null matrix then B is singular matrix
2) If A is skew symmetric then adjoint of A can be skew symmetric.
3) If AB = O then  det A 2   det B 2  0

4) If AB = I then BA =I
79. Identify the correct statement.
1) If system of n simultaneous linear equations has a unique solution, then coefficient matrix
is singular
2) If system of n simultaneous linear equations has a unique solution, then coefficient matrix
is non singular
3) If A1 exists,  adj . A 1 may not exist
cos x  sin x 0
 
4) If F  x    sin x cos x 0 , then F  x  .F  y   F  x  y 
 0 0 0

80. Which of the following conclusion(s) hold(s) true for a non-zero vector a ?
         
1) .
ab  .
ac  b  c 2)  b  a  c  b  c
a
       
3) a.b  a.c and a  b  a  c  b  c 4) a  b  a  b  a .b  0

(NUMERICAL VALUE TYPE)


Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

81. Let V1 be the variances of 2024 observations which are in A.P with first term 2024 and
common difference is 2024 and Let V2 be the variances of 2024 observations which are in
A.P with first term 2023 and common difference 2024 then V1 :V2  m: n where the greatest
2 digit value of m  n is m, nN

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82. Area of mid point triangle of a triangle whose vertices are complex numbers z1, z2, z3 is
z1 z1 1
i
z2 z2 1 then k 
k
z3 z3 1
     
83. Given a, b and c are three vectors such that b and c are unit like parallel vectors and a  4.
  
If  c  2b then the sum of all possible values of  is equal to ______
a
84. The points P and Q are 1, 1, 1 and  2,1,1 The point of intersection of lines containing the
 
D.r.s of PR 1, 2,1 and QS 1, 4, 2  is A, if AB is perpendicular to PR and QS and
 AB 
2
 32, and possible position of B are B1, B2 then  B1 B 2 2 
2x
85. For x  1, sin 1  k  2 tan 1 x then 3  k 
1 x 2

3
d 2x 2  d y  dx 
2
86. l 2  k  2    0 Then number of possible ordered pair  l, k  is (for twice
dy  dx   dy 
dx d 2 x
differentiable invertible function y    x  , & are finite values.)  l , k  Z and l  3 .
dy dy2
2
87. If I   x  sin 2  sin x   cos 2  cos x   dx , then  I   ___ , where . denotes the greatest integer
0

function
1 ac
88. sin12 0.sin 48 0.sin 54 0  ,  b  tan18 tan 78, c  tan54 tan 48  then the value of is
a b
89. A point P(x, y) moves in such a way that [x + y + 1] = [x] (where [.] greatest integer
function) and x  (0, 4). Then the area representing all the possible positions of P equals
90. A triangle is formed by the points A  0, 0  , B  3, 0  and C  3, 4  . A and C are foci of ellipse

7
and B lies on the ellipse. If area of ellipse is p  p  N  . then the value of p is
2

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Sri Chaitanya IIT Academy.,India.


 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60_Elite, Target & LIIT‐BTs JEE-MAIN Date: 29-12-2023
Time: 03.00Pm to 06.00Pm GTM-05 Max. Marks: 300
KEY SHEET
PHYSICS
1) 3 2) 1 3) 4 4) 4 5) 1
6) 4 7) 2 8) 4 9) 1 10) 2
11) 3 12) 4 13) 2 14) 2 15) 3
16) 1 17) 3 18) 3 19) 1 20) 4
21) 14 22) 123 23) 24 24) 14 25) 123
26) 14 27) 1234 28) 14 29) 13 30) 14

CHEMISTRY
31) 1 32) 3 33) 2 34) 4 35) 4
36) 2 37) 1 38) 1 39) 1 40) 4
41) 3 42) 3 43) 4 44) 2 45) 2
46) 1 47) 4 48) 2 49) 4 50) 4
51) 1 52) 3 53) 9 54) 3 55) 6
56) 8 57) 6 58) 9 59) 3 60) 6

MATHEMATICS
61) 2 62) 3 63) 4 64) 1 65) 3
66) 4 67) 1 68) 4 69) 1 70) 3
71) 1 72) 2 73) 4 74) 3 75) 4
76) 4 77) 2 78) 3 79) 2 80) 3
81) 98 82) 16 83) 4 84) 128 85) 2
86) 3 87) 19 88) 8 89) 4 90) 6

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SOLUTIONS
PHYSICS
Mg L ML2
1. Before string is cut T  , Just after string is cut Mg  
2 2 3
3g L   3g  Mg
 Mg  T  M    M  T
2L 2   4  4
2. Factual based
3. V  2  x2  y 2 

Equipotential surfaces will be hyperbolic and E everywhere will be  to them.
4. For electron in electric field, magnitude of its momentum may increase, decrease or may
aquire same speed as initial value.
5.   BV develops across rod PQ.
By Lenz’s law, plate M get positively charged.
E1 E
 12
E4 n  E2 n 16n 4n 2 1
6.    constant.
E2 n  En E1 E1
 2 4
2
4n n
7. As a result of thermal expansion, the size of both spheres increases. The centre of mass of the sphere
lying on the plate rises, whilst that of the sphere hanging on the thread sinks. Thus, the potential energy
of the first sphere increases, whilst that of the second one decreases as shown in the figure.

According to the first law of thermodynamics, the heat transferred to the spheres produces not only an
increase in internal energy and the small amount of work done in expanding against the atmospheric
pressure (this is the same for both spheres), but also a change in gravitational potential energy. The
potential energy of the sphere lying on the insulating plate increases a little, therefore its internal energy
increases by less than the residual heat transferred. Conversely, the decrease in potential energy of the
hanging sphere contributes positively to the increase in its internal energy. In summary, the temperature
of the sphere suspended from the thread will be higher.
8.
P  P'  P ,   900  P2   P'   P 2
2

 P'   P 2
2
P2
Dividing with 2m   
2m 2m 2m
P2 p2
should be sum of and lost kinetic energy
2m 2m
Where m is mass of unknown nucleus  m  m
9. Conceptual
10. Charge will always flow from inner shell to outer irrespective of magnitude or sign of
charge.
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11. kQ k  2 Q  k   3Q  kQ kQ
V R  r      
r R 2R r 2R
k  3Q  k  3Q  V  2R  r   0
v R  r  2R   
r 2R
12. Conceptual
13. 1 Parsec  3.26 y  3.08  1016 m
14. Fusion reaction takes place at high temperature because kinetic energy is high enough to
overcome the coulomb repulsion between nuclei.
15. S-1 true as reflecting telescopes are easier to construct due to handling of spherical
mirrors. As only one side of mirror is used so on other side the mirror can be mounted
where in case of lenses mounting can only be done at thin edges which is partially
difficult. That’s why very large size telescopes are made by using mirrors instead of
lenses  S  2 : It is true and explaining S-1.
16. Escape velocity on moon is less than that on earth.

17. R
KA
18. Conceptual
19. Surface Energy  Surface area
20. Conceptual
21. Property of friction.
22. Work energy theorem.
1
23. E  m and r 
m
24. Buoyancy force when lift accelerates upwards  Vs  g  a  
V  g  Vs g .........1 Vs'   g  a   V  g  V  a
Vs'  g  Vs'  a  V  g  V  a Vs'  g  Vs'  a  Vs  g  Vs  a  Using equation 1 
Vs'  g  a   Vs  a  g  Vs'  Vs
25. Flux depends upon charges inside Gaussian surface and field on all charges.
26. Circuit might be pure resistive (OR)
It might have inductor and capacitor but oscillating in resonance
27. Use V   A2  x 2 And x  Asin t
28. Fext  0  Psys  constant
p2
k since mspaceship  mgas So kspaceship  k gas
2m
hc 1  dN hc dN
29. min   min   min new  2 I    decreases
eV V 2 dt  dt
Hence I decreases
30. Conceptual

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CHEMISTRY
31. (2) Refer NCERT
32. Refer NCERT volume II 12th page 395
33. Beckmann rearrangement reaction.
34. We have
CH3COOH  CH3COO  H 
c 1    c c
CH 3COO  H    c 2
 
K 
CH 3COOH  1   
c  c /  
2
c  c2
since    c /   , we get K  
1   c /       c 
35. BIRCH REDUCTION
36. II is non aromatic
37. The order of bond angles is HCH  HCF  FCF
38. ANS:A, HOFFMANN BROMIDE REARRANGEMENT
39. Both A and R are correct and R is the correct explanation of A.
40. Zinc Metal
41. From BF3 to BI 3 back bonding decreases. Hence B –X bond strength decreases. So, rate
of hydrolysis increases.
42. Ans: C  P4    Cl2 
43. Biuret test is given by amide (proteins, urea, polypeptide)
44. More the electron density in central atom more will be the tendency for back bonding
then less will be the C – O bond energy
45. Presence of EWG- on diazonium ions at o & p-positions favour coupling reactions.
Diazonium ion without electron withdrawing groups does not couple with anisole.
46. From experiments (3) and (2), [A] is constant and [B] is double and rates becomes 8
times, so order w.r.t [B] = 3.
From experiments (1) and (3), [B] is constant and [A] is doubled, but rate does not
change, so order w.r.t [A] = 0. Thus, rate  k  B 
3

47. 2 As3  2 As5  4e1 3s 2  3s6  24e1


M
2 As3  352  2 As5  3s6  2Be1 E As S  2 3
28
48. PBr5 exists as  PBr4   PBr6  in solid state
49. Step I: Attack of bromine atom as electrophile and formation of cyclic bromonium ion.
Step II: Attack of lone pair on electron-deficient carbon.
Step III: Removal of hydrogen as H+.
H H H Br 

N N N N

Br  Br
Br  Br Br

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SRI CHAITANYA IIT ACADEMY, INDIA 29‐12‐23_Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐05_KEY &SOL’S
50. Slightly acidic medium favours osazone formation for  -Hydroxy carbonyls
51. 1, Hint: 3CN  10H  7NO3  3CO2  10NO  5H2O
52.
Cl O
H 2O /  (can give Iodoform)
(i)  
Cl

 (does not give iodoform)


(ii) 
H 3O

OH
O O

O
(iii) 
I 2 / NaOH
  CHI3
O
O
O

(iv)   keto ester does not give Iodoform


O O O
Hg  OAC  / H O  NaBH (can give iodoform)
(v) 
2 2

4

O

CH 3  C  CH 2
53. CH3  CH  CH  OH , , HO  CH2  CH  CH 2 , CH3  CH 2  CHO
O
O
O
CH 3  C  CH 3 OH , CH  O  CH  CH
, , , 3 2

54. Fe  Fe2  2e ; E10 Fe2  Fe3  e ; E10


Adding (1) and (2), we have Fe  Fe3  3e ; E10 G10  2FE10
E20  2 E10
G20  1FE20 G30  G10  G20 3FE30  2FE10 1FE20 E30 
3
55. Ans:6, Sol: Entropy increases in (a), (c), (d),(e), (f) and (h).
CH 2
O
KMnO4
H 2C CH 2 HOOC COOH

OH O

H LiAlH 4
CH 2
H 3C
 H 3C CH 3 H 3C CH 3

56. Solution : D C B

57. 𝑋𝑒𝑂 𝑂𝐻 ⇇ 𝐻𝑋𝑒𝑂


2HXeO4  2OH  
 XeO64  Xe  O2  2H 2O
58. P4  3 NaOH  3H 2O  3NaH 2 PO4  PH3
3 2  3  9
59. I, iv, v
60.
CH 3

F O O OH NMe 2 OMe

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MATHEMATICS
61. Apply M.V.T
62. a, b can be irrational
63. Subtract P.S.L
64.
9  4 5   I  
n

Let  9  4 5    '
n

I     '  9  4 5   9  4 5 
n n
 even integer
0    '  2    ' 1
 I is an odd integer.
65. Draw graphs
66. Draw graphs
67. Draw graphs
68. Draw graphs of periodic functions
69. Draw graphs of periodic functions
70.
1
1
dy dy e x
x2  y 2e x  2  2 dx, integrating both sides, is
dx y x
1
1 ex
1 1
  2 dx  C Putting  t  2 dx  dt
y x x x
1
1 1 1
   et dt  C    et  C   e x  C
y y y
1 n 1
x  x n  x 2 n1  1 n1 
71. 0 1  x n dx  0  1  xn  1  x  dx  0  
1 1
  1  x n1  dx
dx

0
1 x n
0
1
dx 1 1 2 1 2 a a
  1  ;  n  N . and   1   1   p 2  q 2  2 pq
0
1 x n
n n n n n p q
2 2
2 pq
72. Apply first principle
RoS is symmetric if  RoS   RoS
1
73.
But  RoS   S 1oR 1  SoR
1

 RoS is symmetric if RoS  SoR.


Similarly SoR is symmetric if SoR  RoS
74. Apply dearrangement formula
P A  B
75. P A B 
P B
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SRI CHAITANYA IIT ACADEMY, INDIA 29‐12‐23_Sr.Super60_Elite, Target & LIIT‐BTs _Jee‐Main_GTM‐05_KEY &SOL’S
76. Apply basic properties of circle
77. Write equation of chord joining t1 & t2 where t1t2  4 It will come in form of family of
lines.
78. AB  0 B  0 AB  0  A  0
79. B
A. If system of n simultaneous linear equations have a unique solution, then coefficient
matrix must be non-singular.
 Option A is incorrect.
B. If system of n simultaneous linear equations has a unique solution, then coefficient
matrix must be non-singular
 Option B is correct.
adj.A
C. since, A1   suppose A nn 
A
n 1
1 adj. A A 1
&A   n

A A A
If A1 exists, then adj. A is a non-singular matrix.
  adj. A must exist.
1

 Option C is incorrect.
D. We have
cos x  sin x 0   cos y  sin y 0 
F  x  F  y    sin x cos x 0   sin y cos y 0 
  
 0 0 0   0 0 0 
cos  x  y   sin  x  y  0 
 
  sin  x  y  cos  x  y  0   F  x  y 
 0 0 0 
80. C, D        
A. a.b  a.c  either b  c or a  b  c
        
B. a  b  a  c  either b  c or a  b  c
81. Variance is independent of theft of origin
1
82. Area of M.P A  area o  
4   
83. A,B,C, Given, a  4, b  1  c
 
Also, angle between b and c  0

84. 
L : r  i  j  k   i  2 j  k
1 


L2 : r  2i  j  k   i  4 j  2k 
Point of intersection 1    2  
1  2  1  4  1    1  2    1,   2
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Point of intersection A   3,5,3 . Let coordinate of B be  x, y, z 


Dr’s of AB  x  3, y  5, z  3
i j k
 
PR  QS  1 2 1 B  x, y, z    1,5,7  or  7,5, 1
1 4 2
 
85. sin 1  sin         ,  
  2
86. Use inverse function derivative

 
2
87. I     x   sin 2  sin x    cos 2  cos x  dx  2 I  2   sin 2  sin x   cos 2  cos x   dx
0 0
 
2 2
 I     sin 2  sin x    cos 2  cos x  dx     sin 2  cos x   cos 2  sin x   dx
0 0

2
2
2
 2 I    2dx  I  I1     x   2I  
2

0
2 0
1
88. Let   120 L.H.S  0
sin120 sin 480 sin 720 sin 540
sin 72
1 sin 3 12  sin 54
0 0
sin 360 sin 540 cos 360 1
   
4 sin 720 8sin 360 cos 360 8cos 360 8

tan A tan  60  A  tan  60  A   tan 3 A A  n 
6
89. If x   0,1 Then 1  x  y  0 , And if x  [1, 2) 0  x  y 1
1 
Required area  8  .1. 2 sin   4 sq. units
2 4

1
1 2 3
0
–1
–1

x+y=1
x+y=0
x + y = –1

90. 6 AC  5  2a  2ae  5 Also AB  BC  2a


 3, 4  C

A  0, 0  B  3, 4 

7 5 b 2 25
 2a  7  a  e  1 2  b 6
2 7 a 49
7
Area   ab     6  P  6
2

Sec: Sr.Super60_Elite, Target & LIIT‐BTs Page 8

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