Material Safety Data Sheet

Revision Number: 003.3 Issue date: 02/19/2013

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: Nordbak Brush Ceramic - Grey IDH number: 702265
Product type: Epoxy Hardener Item number: 98733_301000
Region: United States
Company address: Contact information:
Henkel Corporation Telephone: 860.571.5100
One Henkel Way MEDICAL EMERGENCY Phone: Poison Control Center
Rocky Hill, Connecticut 06067 1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887Emergency telephone:
860.571.5100
Internet: www.henkelna.com

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
HMIS:
Physical state: Liquid HEALTH: *3
Color: light yellow FLAMMABILITY: 1
Odor: ammoniacal PHYSICAL HAZARD: 0
Personal Protection: See MSDS Section 8
DANGER: CAUSES EYE AND SKIN BURNS.
MAY CAUSE ALLERGIC SKIN AND RESPIRATORY REACTION.
MAY BE HARMFUL IF SWALLOWED OR ABSORBED THROUGH SKIN.
MAY CAUSE RESPIRATORY TRACT IRRITATION.

Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion

Potential Health Effects

Inhalation: Allergic respiratory reaction. May cause respiratory tract irritation. May cause irritation to nose
and throat.
Skin contact: May cause skin burns. May cause allergic skin reaction. Rash. Redness. May be harmful if
absorbed through skin.
Eye contact: Severe eye irritation. Redness. Tissue damage. Tearing. Pain and discomfort. Corneal edema
may give appearance of "blue haze" or "fog" around lights.
Ingestion: May be harmful if swallowed. May cause burns of mouth and throat if swallowed.

Existing conditions aggravated by Eye, skin, and respiratory disorders. Skin allergies. Asthma.
exposure:

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR
1910.1200).

See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous components CAS NUMBER %
Benzyl alcohol 100-51-6 30 - 60
Formaldehyde, polymer with benzenamine, hydrogenated 135108-88-2 30 - 60
Diethylenetriamine 111-40-0 1-5
4,4'-Methylenebis(cyclohexylamine) 1761-71-3 1-5
Organic Acid Unknown 1-5
4,4'-Isopropylidenediphenol 80-05-7 1-5

IDH number: 702265 Product name: Nordbak Brush Ceramic - Grey

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 4. FIRST AID MEASURES
Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention.

Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove
contaminated clothing and footwear. Wash clothing before reuse. Thoroughly
clean shoes before reuse. If symptoms develop and persist, get medical
attention.

Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get
medical attention.

Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel. Keep

individual calm. Get medical attention.

5. FIRE FIGHTING MEASURES

Flash point: 93 °C (199.4 °F) Setaflash Closed Cup

Autoignition temperature: Not available.

Flammable/Explosive limits - lower: Not available.

Flammable/Explosive limits - upper: Not available.

Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide.

Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as
turn-out gear.

Unusual fire or explosion hazards: In case of fire, keep containers cool with water spray.

Hazardous combustion products: Oxides of carbon. Oxides of nitrogen. Ammonia. Phenolics. Nitric acid.
Aldehydes. Nitrosamines. Irritating organic fragments.

6. ACCIDENTAL RELEASE MEASURES

Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.

Environmental precautions: Do not allow product to enter sewer or waterways.

Clean-up methods: Remove all sources of ignition. Immediately contact emergency personnel.
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder,
universal binder, sawdust). Store in a closed container until ready for disposal.

7. HANDLING AND STORAGE

Handling: Do not taste or swallow. Avoid contact with eyes, skin and clothing. Do not
breathe gas/fumes/vapor/spray. Use only with adequate ventilation. Keep
container closed. Wash thoroughly after handling.

Storage: Store in original container until ready to use. Keep in a cool, well ventilated
area away from heat, sparks and open flame. Keep container tightly closed
until ready for use.

For information on product shelf life contact Henkel Customer Service at (800) 243-4874.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.

IDH number: 702265 Product name: Nordbak Brush Ceramic - Grey

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Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER
10 ppm (44.20
Benzyl alcohol None None None
mg/m3) TWA
Formaldehyde, polymer with benzenamine,
None None None None
hydrogenated
(SKIN)
Diethylenetriamine None None None
1 ppm TWA
4,4'-Methylenebis(cyclohexylamine) None None None None
Organic Acid None None None None
4,4'-Isopropylidenediphenol None None None None

Engineering controls: Use local exhaust ventilation if the potential for airborne exposure exists.

Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure
limit(s).

Eye/face protection: Safety goggles or safety glasses with side shields.

Skin protection: Chemical resistant, impermeable gloves.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Liquid
Color: light yellow
Odor: ammoniacal
Odor threshold: Not available.
pH: Alkaline
Vapor pressure: Not available.
Boiling point/range: 400 °C (752°F)
Melting point/ range: Not available.
Specific gravity: 1.0616
Vapor density: Not available.
Flash point: 93 °C (199.4 °F) Setaflash Closed Cup
Flammable/Explosive limits - lower: Not available.
Flammable/Explosive limits - upper: Not available.
Autoignition temperature: Not available.
Evaporation rate: Not available.
Solubility in water: Partially soluble
Partition coefficient (n-octanol/water): Not available.
VOC content: < 0.1 %; < 1 g/l (value for resin and hardener together)

10. STABILITY AND REACTIVITY

Stability: Stable

Hazardous reactions: Will not occur.

Hazardous decomposition products: None

Incompatible materials: Strong oxidizing agents. Strong reducing agents. Metals. Acids. Strong
mineral acids. Strong bases. Peroxides.

Conditions to avoid: Store away from incompatible materials. Excessive heat.

IDH number: 702265 Product name: Nordbak Brush Ceramic - Grey

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 11. TOXICOLOGICAL INFORMATION
OSHA Carcinogen
Hazardous components NTP Carcinogen IARC Carcinogen
(Specifically Regulated)
Benzyl alcohol No No No
Formaldehyde, polymer with
No No No
benzenamine, hydrogenated
Diethylenetriamine No No No
4,4'-Methylenebis(cyclohexylamine) No No No
Organic Acid No No No
4,4'-Isopropylidenediphenol No No No

Hazardous components Health Effects/Target Organs

Benzyl alcohol Allergen, Central nervous system, Corrosive, Irritant
Formaldehyde, polymer with benzenamine, hydrogenated No Records
Diethylenetriamine Allergen, Irritant, Eyes
4,4'-Methylenebis(cyclohexylamine) Irritant, Allergen
Organic Acid No Data
4,4'-Isopropylidenediphenol Allergen, Blood, Irritant, Kidney, Reproductive, Spleen

12. ECOLOGICAL INFORMATION

Ecological information: Not available.

13. DISPOSAL CONSIDERATIONS

Information provided is for unused product only.

Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal.

Hazardous waste number: Not a RCRA hazardous waste.

14. TRANSPORT INFORMATION

U.S. Department of Transportation Ground (49 CFR)
Proper shipping name: Amines, liquid, corrosive, n.o.s. (Diethylenetriamine, 4,4-methylenebis-
cyclohexylamine)
Hazard class or division: 8
Identification number: UN 2735
Packing group: III

International Air Transportation (ICAO/IATA)

Proper shipping name: Amines, liquid, corrosive, n.o.s. (Diethylenetriamine, 4,4-methylenebis-
cyclohexylamine)
Hazard class or division: 8
Identification number: UN 2735
Packing group: III

Water Transportation (IMO/IMDG)

Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. (Diethylenetriamine, 4,4-methylenebis-
cyclohexylamine)
Hazard class or division: 8
Identification number: UN 2735
Packing group: III

15. REGULATORY INFORMATION

United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
TSCA 12(b) Export Notification: None above reporting de minimus

IDH number: 702265 Product name: Nordbak Brush Ceramic - Grey

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 CERCLA/SARA Section 302 EHS: None above reporting de minimis
CERCLA/SARA Section 311/312: Immediate Health, Delayed Health
CERCLA/SARA 313: This product contains the following toxic chemicals subject to the reporting requirements of
section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40
CFR 372). 4,4'-Isopropylidenediphenol (CAS# 80-05-7).

California Proposition 65: No California Proposition 65 listed chemicals are known to be present.

Canada Regulatory Information

CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.
WHMIS hazard class: D.2.A, D.2.B, E

16. OTHER INFORMATION

This material safety data sheet contains changes from the previous version in sections: 1

Prepared by: Gary Pierson, Manager, Regulatory Affairs

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.

IDH number: 702265 Product name: Nordbak Brush Ceramic - Grey

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