Topic 1
Topic 1
Topic 1
Solids
Solids have a fixed volume and shape and they have a high density
The particles are packed very closely together in a fixed and regular pattern
Liquids
Liquids also have a fixed volume but adopt the shape of the container
They are generally less dense than solids (an exception is water), but much denser than gases
The particles move and slide past each other which is why liquids adopt the shape of the
container and also why they are able to flow freely
Gases
Since there is a lot of space between the particles, gases can be compressed into a much smaller
volume
The particles are far apart and move randomly and quickly (around 500 m/s) in all directions
They collide with each other and with the sides of the container (this is how pressure is created
inside a can of gas)
2D diagram
Diffusion
This is the process by which different gases or different liquids mix and is due to the random
motion of their particles
Diffusing particles move from an area of high concentration to an area of low concentration
Eventually the concentration of particles is even as they spread out to occupy all of the available
space
Diffusion happens on its own and no energy input is required although it occurs faster at higher
temperatures
Diffusion of potassium manganate(VII), KMnO4 , in water. After a few hours the concentration of
KMnO4 is the same throughout the solution
Diffusion occurs much faster in gases than in liquids as gaseous particles move much quicker
than liquid particles
At the same temperature, different gases do not diffuse at the same rate.
Lighter gas particles can travel faster and hence further, therefore the lower its relative mass the
faster a gas will diffuse
This can be demonstrated in the reaction between ammonia, NH3, and hydrogen chloride gas,
HCl, inside a long glass tube
Where the two gases meet a white smoke of ammonium chloride, NH4Cl, is formed
This does not occur in the middle of the tube as you might expect, but much closer to the end
with the hydrogen chloride (Mr = 36.5) and the ammonia (Mr = 17) molecules are smaller and
lighter
NH3 molecules have less mass than the HCl molecule, so diffuse faster, hence the product (a white
smoke of NH4Cl) forms closer to the end where the HCl is