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    Volumetric Analysis 1

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    ferdosbanu667
    This document describes a volumetric analysis experiment to determine the molarity and strength of a potassium permanganate (KMnO4) solution using Mohr's salt (ammonium iron(II) sulfate) as the standard solution. Potassium permanganate acts as the oxidizing agent and oxidizes the iron(II) in Mohr's salt to iron(III). The document provides the reaction equations, experimental procedure which involves titrating 10 mL of 0.05 M Mohr's salt with KMnO4 until a pale pink endpoint is reached, observations recorded, calculations performed, and results - the molarity of KMnO4 was determined to be 0.01 M and its strength was calculated to

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    Volumetric Analysis 1

    Uploaded by

    ferdosbanu667
    10 views2 pages
    This document describes a volumetric analysis experiment to determine the molarity and strength of a potassium permanganate (KMnO4) solution using Mohr's salt (ammonium iron(II) sulfate) as the standard solution. Potassium permanganate acts as the oxidizing agent and oxidizes the iron(II) in Mohr's salt to iron(III). The document provides the reaction equations, experimental procedure which involves titrating 10 mL of 0.05 M Mohr's salt with KMnO4 until a pale pink endpoint is reached, observations recorded, calculations performed, and results - the molarity of KMnO4 was determined to be 0.01 M and its strength was calculated to

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    Class 12 volumetric analysis

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    volumetric analysis 1

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    This document describes a volumetric analysis experiment to determine the molarity and strength of a potassium permanganate (KMnO4) solution using Mohr's salt (ammonium iron(II) sulfate) as the standard solution. Potassium permanganate acts as the oxidizing agent and oxidizes the iron(II) in Mohr's salt to iron(III). The document provides the reaction equations, experimental procedure which involves titrating 10 mL of 0.05 M Mohr's salt with KMnO4 until a pale pink endpoint is reached, observations recorded, calculations performed, and results - the molarity of KMnO4 was determined to be 0.01 M and its strength was calculated to

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    10 views2 pages

    Volumetric Analysis 1

    Uploaded by

    ferdosbanu667
    This document describes a volumetric analysis experiment to determine the molarity and strength of a potassium permanganate (KMnO4) solution using Mohr's salt (ammonium iron(II) sulfate) as the standard solution. Potassium permanganate acts as the oxidizing agent and oxidizes the iron(II) in Mohr's salt to iron(III). The document provides the reaction equations, experimental procedure which involves titrating 10 mL of 0.05 M Mohr's salt with KMnO4 until a pale pink endpoint is reached, observations recorded, calculations performed, and results - the molarity of KMnO4 was determined to be 0.01 M and its strength was calculated to

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 2

    Volumetric Analysis – 1

    AIM : To estimate the molarity and strength of the given KMnO4 solution using
    M
    (0.05)
    20
    Mohr’s salt as standard solution

    Principle : Acidified KMnO4 can oxidise FeSO4 of FAs into Fe3(SO4)3. Hence known
    volume of FAS is titrated against KMnO4. Here KMnO4 act as oxidizing agent and
    FeSO4 as reducing agent

    Chemical Reaction :
    2 KMnO4  10 FeSO4 ( NH 4 )2 SO4 .6 H 2O  8H 2 SO4  K 2 SO4
     2MnSO4  5Fe2 ( SO4 )2  10( NH 4 )2 SO4  68H 2O
    Ionic equation :
    MnO4  8H   5e  Mn2  4 H 2O(Re du )

    [ Fe2  Fe3  1e ]  5.....(oxidation)


    MnO4  8H   5Fe2  Mn2  5Fe3  4 H 2O
    Procedure : (i) Exactly 10 ml of 0.05M FAS is pipetted out into a clean conical flask and
    about 1 test tube of full dil. H2SO4 is added
    (ii) The solution of the conical flask is titrated against KMnO4 taken in the burette until a
    permanent pale pink colour is obtained this is the end point of titration
    (iii) The burette readings are recorded & repeated the titration for agreeing values

    Observation : Burette : KMnO4 soln


    Conical flask : 10 ml of 0.05 FAS + 1 test of dil. H2 SO4
    Indicator : KMnO4 is self indicator
    End point : Colour less to pale pink
    Tabulation :

    S No Volume of Burette Readings Concordant


    FAS solution Initial Final Value
    1 10 ml 0 9.8 9.9
    2 10 ml 0 9.9
    3 10 ml 0 9.9
    Titrate value = 9.9
    Calculation : we know that

    a1(M1  V1) KMnO4  a2 (M 2  V2 ) FAS


    a1 = No of electrons gained per formula unit of KMnO4 = 5
    a2 = No of electrons lost per formula unit of FAS = 1
    M1 = molarity of KMnO4 = ? M2 = molarity of FAS = 0.05
    V1 = Volume of KMnO4 = 9.9 V2 = volume of FAS = 10
    Then
    1 M V 1 0.05  10
    M1   2 2  
    5 V1 5 10
    0.5
      0.01M
    49.5
    Result : Molarity of given KMnO4 = 0.01 M
    Strength of KMnO4 = M x GMW
    0.01 x 158 = 1.58 g/L

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