SAFETY DATA SHEET

Version 1.4 SDS Number 300000000004

Revision Date 03.08.2016 Print Date 11.01.2021

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND THE COMPANY/UNDERTAKING

Identification of the : Argon
substance/preparation

Chemical formula : Ar

Other means of identification : Argon, Argon gas, Gaseous Argon, GAR

Use of the Substance/Mixture : General Industrial

Restrictions on Use : No data available.

Manufacturer/Importer/Distribu : UNITED INDUSTRIAL GASES COMPANY LLC

tor P.O. BOX 11, Rusayl
Postal Code 124, Sultanate of Oman
C.R. No.: 1297190 Fin. Code 13077201
Tel: +968 2444 6030 / +968 2444 6031

Email Address – Technical : [email protected]

Information

Telephone : +968 911 20697

Emergency telephone number : +968 911 20697

(24h)

2. HAZARDS IDENTIFICATION
GHS classification
Gases under pressure - Compressed gas.

GHS label elements

Hazard pictograms/symbols

Signal Word: Warning

Hazard Statements:
H280:Contains gas under pressure; may explode if heated.

Precautionary Statements:

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Storage : P403:Store in a well-ventilated place.

Other hazards which do not result in classification

High pressure gas.
Can cause rapid suffocation.

Environmental Effects
Not harmful.

3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/Mixture : Substance

Components Chemical formula CAS Number Concentration

(Volume)
Argon Ar 7440-37-1 100 %

Concentration is nominal. For the exact product composition, please refer to technical specifications.

4. FIRST AID MEASURES

General advice : Remove victim to uncontaminated area wearing self contained breathing
apparatus. Keep victim warm and rested. Call a doctor. Apply artificial respiration
if breathing stopped.

Eye contact : In case of direct contact with eyes, seek medical advice.

Skin contact : Adverse effects not expected from this product.

Ingestion : Ingestion is not considered a potential route of exposure.

Inhalation : Remove to fresh air. If breathing has stopped or is labored, give assisted
respirations. Supplemental oxygen may be indicated. If the heart has stopped,
trained personnel should begin cardiopulmonary resuscitation immediately. In
case of shortness of breath, give oxygen.

Symptoms : Exposure to oxygen deficient atmosphere may cause the following symptoms:
Dizziness. Salivation. Nausea. Vomiting. Loss of mobility/consciousness.

Notes to physician
Treatment : If exposed or concerned: Get medical attention/advice.

5. FIRE-FIGHTING MEASURES
Suitable extinguishing media : All known extinguishing media can be used.

Specific hazards : Upon exposure to intense heat or flame, cylinder will vent rapidly and or rupture
violently. Product is nonflammable and does not support combustion. Move away
from container and cool with water from a protected position. Keep containers
and surroundings cool with water spray.

Special protective equipment : Wear self contained breathing apparatus for fire fighting if necessary. Standard
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for fire-fighters protective clothing and equipment (Self Contained Breathing Apparatus) for fire
fighters. Standard EN 137 - Self-contained open-circuit compressed air breathing
apparatus with full face mask. Standard EN 469 - Protective clothing for
firefighters. Standard - EN 659: Protective gloves for firefighters.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Gas/vapor heavier than air. May accumulate in confined spaces, particularly at or
below ground level. Evacuate personnel to safe areas. Wear self-contained
breathing apparatus when entering area unless atmosphere is proved to be safe.
Monitor oxygen level. Ventilate the area.

Environmental precautions : Do not discharge into any place where its accumulation could be dangerous.
Prevent further leakage or spillage if safe to do so.

Methods for cleaning up : Ventilate the area.

Additional advice : If possible, stop flow of product. Increase ventilation to the release area and
monitor oxygen level. If leak is from cylinder or cylinder valve, call the emergency
telephone number. If the leak is in the user's system, close the cylinder valve and
safely vent the pressure before attempting repairs.

7. HANDLING AND STORAGE

Handling
Protect cylinders from physical damage; do not drag, roll, slide or drop. Do not allow storage area temperature to
exceed 50°C (122°F). Only experienced and properly instructed persons should handle compressed
gases/cryogenic liquids. Before using the product, determine its identity by reading the label. Know and
understand the properties and hazards of the product before use. When doubt exists as to the correct handling
procedure for a particular gas, contact the supplier. Do not remove or deface labels provided by the supplier for the
identification of the cylinder contents. When moving cylinders, even for short distances, use a cart (trolley, hand
truck, etc.) designed to transport cylinders. Leave valve protection caps in place until the container has been
secured against either a wall or bench or placed in a container stand and is ready for use. Use an adjustable strap
wrench to remove over-tight or rusted caps. Before connecting the container, check the complete gas system for
suitability, particularly for pressure rating and materials. Before connecting the container for use, ensure that back
feed from the system into the container is prevented. Ensure the complete gas system is compatible for pressure
rating and materials of construction. Ensure the complete gas system has been checked for leaks before use.
Employ suitable pressure regulating devices on all containers when the gas is being emitted to systems with lower
pressure rating than that of the container. Never insert an object (e.g. wrench, screwdriver, pry bar, etc.) into valve
cap openings. Doing so may damage valve, causing a leak to occur. Open valve slowly. If user experiences any
difficulty operating cylinder valve discontinue use and contact supplier. Close container valve after each use and
when empty, even if still connected to equipment. Never attempt to repair or modify container valves or safety
relief devices. Damaged valves should be reported immediately to the supplier. Close valve after each use and
when empty. Replace outlet caps or plugs and container caps as soon as container is disconnected from
equipment. Do not subject containers to abnormal mechanical shock. Never attempt to lift a cylinder by its valve
protection cap or guard. Do not use containers as rollers or supports or for any other purpose than to contain the
gas as supplied. Never strike an arc on a compressed gas cylinder or make a cylinder a part of an electrical circuit.
Do not smoke while handling product or cylinders. Never re-compress a gas or a gas mixture without first
consulting the supplier. Never attempt to transfer gases from one cylinder/container to another. Always use
backflow protective device in piping. When returning cylinder install valve outlet cap or plug leak tight. Never use
direct flame or electrical heating devices to raise the pressure of a container. Containers should not be subjected
to temperatures above 50°C (122°F).

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Storage
Full containers should be stored so that oldest stock is used first. Containers should be stored in a purpose build
compound which should be well ventilated, preferably in the open air. Stored containers should be periodically
checked for general condition and leakage. Observe all regulations and local requirements regarding storage of
containers. Protect containers stored in the open against rusting and extremes of weather. Containers should not
be stored in conditions likely to encourage corrosion. Containers should be stored in the vertical position and
properly secured to prevent toppling. The container valves should be tightly closed and where appropriate valve
outlets should be capped or plugged. Container valve guards or caps should be in place. Keep containers tightly
closed in a cool, well-ventilated place. Store containers in location free from fire risk and away from sources of
heat and ignition. Full and empty cylinders should be segregated. Do not allow storage temperature to exceed
50°C (122°F). Return empty containers in a timely manner.

Technical measures/Precautions
Containers should be segregated in the storage area according to the various categories (e.g. flammable, toxic,
etc.) and in accordance whit local regulations. Keep away from combustible material.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering measures
Provide natural or mechanical ventilation to prevent oxygen deficient atmospheres below 19.5% oxygen.

Personal protective equipment

Respiratory protection : Self contained breathing apparatus (SCBA) or positive pressure airline with mask
are to be used in oxygen-deficient atmosphere.
Air purifying respirators will not provide protection. Users of breathing apparatus
must be trained.

Hand protection : Wear working gloves when handling gas containers.

Standard EN 388 - Protective gloves against mechanical risk.

Eye protection : Safety glasses recommended when handling cylinders.

Standard EN 166 - Personal eye-protection.

Skin and body protection : Safety shoes are recommended when handling cylinders.
Standard EN ISO 20345 - Personal protective equipment - Safety footwear.

Special instructions for : Ensure adequate ventilation, especially in confined areas.

protection and hygiene

Remarks : Simple asphyxiant.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Compressed gas. Colorless gas

Odor : No odor warning properties.

Odor threshold : No data available.

pH : Not applicable.
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Melting point/range : -309 °F (-189.3 °C)

Boiling point/range : -302 °F (-185.8 °C)

Flash point : Not applicable.

Evaporation rate : Not applicable.

Flammability (solid, gas) : Refer to product classification in Section 2

Upper/lower : No data available.

explosion/flammability limit

Vapor pressure : Not applicable.

Water solubility : 0.061 g/l

Relative vapor density : 1.379 (air = 1) Heavier than air.

Relative density : No data available.

Partition coefficient : Not applicable.

(n-octanol/water)

Auto-ignition temperature : No data available.

Decomposition temperature : No data available.

Viscosity : Not applicable.

Molecular Weight : 39.95 g/mol

Density : 0.106 lb/ft3 (0.0017 g/cm3) at 70 °F (21 °C) Note: (as vapor)

Specific Volume : 9.68 ft3/lb (0.6043 m3/kg) at 70 °F (21 °C)

10. STABILITY AND REACTIVITY

Chemical Stability : Stable under normal conditions.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products
products should not be produced.

11. TOXICOLOGICAL INFORMATION

Likely routes of exposure

Effects on Eye : In case of direct contact with eyes, seek medical advice.

Effects on Skin : Adverse effects not expected from this product.

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Inhalation Effects : In high concentrations may cause asphyxiation. Asphyxiation may bring
about unconsciousness without warning and so rapidly that victim may be
unable to protect themselves.

Ingestion Effects : Ingestion is not considered a potential route of exposure.

Symptoms : Exposure to oxygen deficient atmosphere may cause the following

symptoms: Dizziness. Salivation. Nausea. Vomiting. Loss of
mobility/consciousness.

Acute toxicity

Acute Oral Toxicity : No data is available on the product itself.

Inhalation : No data is available on the product itself.

Acute Dermal Toxicity : No data is available on the product itself.

Serious eye damage/eye : No data available.

irritation

Sensitization. : No data available.

Chronic toxicity or effects from long term exposures

Carcinogenicity : No data available.

Reproductive toxicity : No data is available on the product itself.

Germ cell mutagenicity : No data is available on the product itself.

Specific target organ systemic : No data available.

toxicity (single exposure)

Specific target organ systemic : No data available.

toxicity (repeated exposure)

Aspiration hazard : No data available.

12. ECOLOGICAL INFORMATION

Ecotoxicity effects
Aquatic toxicity : No data is available on the product itself.

Toxicity to other organisms : No data available.

Persistence and degradability

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Biodegradability : No data is available on the product itself.

Mobility : Because of its high volatility, the product is unlikely to cause ground pollution.
Bioaccumulation : Refer to Section 9 "Partition Coefficient (n-octanol/water)".

Further information
This product has no known eco-toxicological effects.

13. DISPOSAL CONSIDERATIONS

Waste from residues / unused : Contact supplier if guidance is required. Return unused product in original
products cylinder to supplier. Refer to the EIGA code of practice Doc. 30 "Disposal of
Gases", downloadable at http://www.eiga.org for more guidance on suitable
disposal methods. List of hazardous waste codes: 16 05 05: Gases in pressure
containers other than those mentioned in 16 05 04.

Contaminated packaging : Return cylinder to supplier.

14. TRANSPORT INFORMATION

ADR
UN/ID No. : UN1006
Proper shipping name : ARGON, COMPRESSED
Class or Division : 2
Tunnel Code : (E)
Label(s) : 2.2
ADR/RID Hazard ID no. : 20
Marine Pollutant : No

IATA
UN/ID No. : UN1006
Proper shipping name : Argon, compressed
Class or Division : 2.2
Label(s) : 2.2
Marine Pollutant : No

IMDG
UN/ID No. : UN1006
Proper shipping name : ARGON, COMPRESSED
Class or Division : 2.2
Label(s) : 2.2
Marine Pollutant : No
Segregation Group: : None

RID
UN/ID No. : UN1006
Proper shipping name : ARGON, COMPRESSED
Class or Division : 2
Label(s) : 2.2

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Marine Pollutant : No

Further Information
Avoid transport on vehicles where the load space is not separated from the driver's compartment. Ensure vehicle
driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an
emergency. The transportation information is not intended to convey all specific regulatory data relating to this
material. For complete transportation information, contact customer service.

15. REGULATORY INFORMATION

Country Regulatory list Notification

USA TSCA Included on Inventory.
EU EINECS Included on Inventory.
Canada DSL Included on Inventory.
Australia AICS Included on Inventory.
Japan ENCS Included on Inventory.
South Korea ECL Included on Inventory.
China SEPA Included on Inventory.
Philippines PICCS Included on Inventory.

16. OTHER INFORMATION

Ensure all national/local regulations are observed.

Prepared by : Air Products and Chemicals, Inc. Global EH&S Product Safety Department

For additional information, please visit our Product Stewardship web site at
http://www.airproducts.com/productstewardship/

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