Azza 2
Azza 2
Faculty of science
chemistry department
Graduation project on
Water pollution and treatment
Prepared by:
Azza El-Sayed Rabea
B.Sc. Student, 4th level, Department of biochemistry, Faculty of
Science, Mansoura
supervisor:
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1 water pollution
Fig(1)
Raw sewage and industrial waste in the New River as it passes from Mexicali (Mexico) to Calexico,
California[1]
water pollution, the release of substances into subsurface groundwater or into lakes,
streams, rivers, estuaries, and oceans to the point where the substances interfere with
beneficial use of the water or with the natural functioning of ecosystems.
Water pollution (or aquatic pollution) is the contamination of water bodies, usually
as a result of human activities, so that it negatively affects its uses. [1]: 6 Water bodies
include lakes, rivers, oceans, aquifers, reservoirs and groundwater.
Water pollution results when contaminants mix with these water bodies. Contaminants
can come from one of four main sources: sewage discharges, industrial activities,
agricultural activities, and urban runoff including stormwater.[2]
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This form of pollution can lead to many problems, such as the degradation of aquatic
ecosystems or spreading water-borne diseases when people use polluted water for
drinking or irrigation.[3]
Another problem is that water pollution reduces the ecosystem services (such as
providing drinking water) that the water resource would otherwise provide.
Sources of water pollution are either point sources or non-point sources. Point sources
have one identifiable cause, such as a storm drain, a wastewater treatment plant or an oil
spill. Non-point sources are more diffuse, such as agricultural runoff. [4] Pollution is the
result of the cumulative effect over time.
Pollution may take the form of toxic substances (e.g., oil, metals,
plastics, pesticides, persistent organic pollutants, industrial waste products), stressful
conditions (e.g., changes of pH, hypoxia or anoxia, increased temperatures,
excessive turbidity, changes of salinity), or the introduction of pathogenic organisms.
Contaminants may include organic and inorganic substances.
Definition
A practical definition of water pollution is: "Water pollution is the addition of
substances or energy forms that directly or indirectly alter the nature of the water body
in such a manner that negatively affects its legitimate uses".[1]: 6 Water is typically
referred to as polluted when it is impaired by anthropogenic contaminants. Due to these
contaminants, it either no longer supports a certain human use, such as drinking water,
or undergoes a marked shift in its ability to support its biotic communities, such as fish.
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Types and sources of water pollutants
Water bodies can be polluted by a wide variety of substances, including pathogenic
microorganisms, putrescible organic waste, fertilizers and plant nutrients, toxic
chemicals, sediments, heat, petroleum (oil), and radioactive substances.
A point source is a pipe or channel, such as those used for discharge from an industrial
facility or a city sewerage system.
A dispersed (or nonpoint) source is a very broad unconfined area from which a variety
of pollutants enter the water body, such as the runoff from an agricultural area.
Point sources of water pollution are easier to control than dispersed sources, because the
contaminated water has been collected and conveyed to one single point where it can be
treated.
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1.1.1 ORGANIC POLLUTANTS
Organic pollutants can be further divided into following categories
• Oil
• The dissolved oxygen available in the water body will be consumed for aerobic
oxidation of organic matter present in the wastewater.
• Hence, depletion of the DO will be a serious problem adversely affecting aquatic life,
if the DO falls below 4.0 mg/L. This decrease of DO is an index of pollution.
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• Most of these compounds are toxic and biorefractory organics i.e., they are resistant
to microbial degradation.
Example 1:
• Polychlorinated biphenyls (PCBs) (oily liquid or solid) are used in the industries since
which are complex mixtures of chlorobiphenyls used in electrical equipments like
capacitors[20].
• Being a fat soluble they move readily through the environment and within the tissues
or cells.
• these compounds are exceedingly persistent and their stability to chemical reagents is
also high.
1. Composition
•Soaps are salts of higher fatty acids, such as sodium stearate, C17H35COO-Na+
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•Soap’s cleaning action results largely from its emulsifying power and its ability to
lower the surface tension of water[19].
2. Disadvantages
•The primary disadvantage comes from its reaction with divalent cations to form
insoluble salts of fatty acids:
•These insoluble solids, usually salts of magnesium or calcium, are not at all effective
as cleaning agents.
•In addition, the insoluble salts form deposits on clothing and in washing machines.
Detergents
•10–30% surfactant.
•Ion exchangers.
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•Anticorrosive sodium silicates.
•Bleaches.
•Enzymes.
•Optical brighteners.
Surfactant
• Example:
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ABS was replaced by a biodegradable surfactant known as linear
alkyl sulfonate LAS.
the alkyl portion of LAS is not branched and does not contain the tertiary carbon that
is so difficult to biodegradability so the levels of surfactant found in water have
decreased markedly.
Oil spills may be due to releases of crude oil from tankers, offshore platforms, drilling
rigs and wells, as well as spills of refined petroleum products (such as gasoline, diesel)
and their by-products, heavier fuels used by large ships such as bunker fuel, or the spill
of any oily refuse or waste oil.[citation needed]
Petroleum (oil) pollution occurs when oil from roads and parking lots is carried in
surface runoff into water bodies.
Accidental oil spills are also a source of oil pollution—as in the devastating spills from
the tanker Exxon Valdez (which released more than 260,000 barrels in Alaska’s Prince
William Sound in 1989) and from the Deepwater Horizon oil rig (which released more
than 4 million barrels of oil into the Gulf of Mexico in 2010).
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Oil slicks eventually move toward shore, harming aquatic life and damaging recreation
areas.
Oil pollution occurs when oil in its various forms is introduced to environments and
contaminates them[16].
1.1.2 ACIDITY
The most common sources of pollutant acid in water:
3. Sulfuric acid produced by the air oxidation of pollutant sulfur dioxide enters natural
waters as acidic rainfall.
ALKALINITY
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1. Excess alkalinity generally are not introduced directly into water from anthropogenic
sources.
2. In many geographic areas, the soil and mineral strata are alkaline and impart a high
alkalinity to water.
SALINITY
Examples of human activities which increase water salinity:
1. In the production of shale oil ا:high percentage of leachable Na2SO4.
1.1.3 SEDIMENTS
Sources
• The natural processes of soil erosion.
• Mining activities.
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•Thermal pollution may cause significant departures from normal activities of aquatic
communities[17].
•Industrial effluents.
•Domestic sewage.
•Hydro-electric power.
2. Increase toxicity
4. Interference in reproduction
5. Direct mortality
Eutrophication control:
•Eliminating phosphates from detergents.
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•Removing phosphate at the sewage treatment plant.
Hypochlorous acid, HOCl, is a weak acid that dissociates according to the reaction, The
two chemical species formed by chlorine in water, HOCl and OCl- , are known as free
available chlorine which is very effective in killing bacteria[5].
The chloramines are called combined available chlorine which, although a weaker
disinfectant than free available chlorine. Too much ammonia in water is considered
undesirable because it exerts excess demand for chlorine.
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Ozone
Ozone is sometimes used as a disinfectant in place of chlorine, particularly in Europe.
Advantages of ozonation over chlorination:
Disadvantage
The solubility of ozone in water is relatively low, which limits its disinfective power.
Wastewater is used water that needs to be treated before being discharged into another
body of water in order to prevent additional contamination of water sources. There are
many different sources of wastewater. Wastewater is everything that you flush down
the toilet or pour down the drain[19]. Runoff and rainwater from the streets, combined
with other contaminants, finally make their way to a wastewater treatment facility.
Industrial and agricultural sources of waste water are other potential sources. Certain
wastewaters are more challenging to treat than others; industrial wastewater, for
instance, might be challenging to treat, whereas domestic Whilst home waste is
relatively simple to handle, the number of pharmaceuticals and personal care items
contained in domestic wastewater is making it more challenging to do so.
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•Treatment of wastewater to make it acceptable for release or reuse.
c. Oxygen also aids iron removal by oxidizing soluble Fe(II) to insoluble Fe(III).
d. CaO or Ca(OH)2 after aeration raises the pH and can precipitates Ca2+ and Mg2+ .
b. Activated silica.
c. Synthetic polyelectrolytes.
The settling occurs in a secondary basin after the addition of carbon dioxide to lower
the pH.
Sludge from both the primary and secondary basins is pumped to a sludge lagoon. The
water is finally chlorinated, filtered, and pumped to the city water mains [16].
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( Municipal water Treatment )
1.3.2 TREATMENT OF WATER FOR INDUSTRIAL USE
Common treatment processes:
External treatment, usually uses processes such as:
•Aeration.
•Filtration.
•Clarification to remove material which cause problems from water, such substances:
•Hardness.
•Dissolved gases.
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•Addition of precipitants, such as phosphate used for calcium removal.
•Adjustment of pH.
•Disinfection for food processing uses or to prevent bacterial growth in cooling water.
•Primary treatment.
•Secondary treatment.
•Tertiary treatment.
Primary Treatment
Consists of the removal of insoluble matter such as (grit and grease) from water.
•Screening removes or reduces the size of trash and large solids that get into the sewage
system.
•These solids are collected on screens and scraped off for subsequent disposal.
•Grit in wastewater consists of materials that do not biodegrade well and generally have
a high settling velocity.
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2. To protect moving parts from abrasion and wear.
1. The material that floats in the primary settling basin is known as grease.
2. The grease consists of (oils, waxes, free fatty acids, and insoluble soaps containing
Ca and Mg).
3. Normally, some of the grease settles with the sludge and some floats to the surface,
where it can be removed by a skimming device.
4. Flocculent particles can aggregate, a process that may be aided by the addition of
chemicals.
• The standard method for indirect measurement of the amount of pollution (that
cannot be oxidized biologically) in a sample of water .
• The chemical oxygen demand test procedure is based on the chemical decomposition
of organic and inorganic contaminants , dissolved or suspended in water.
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• The result of a chemical oxygen demand test indicates the amount of the water –
dissolved oxygen (expressed as parts per million or milligrams per liter of water)
consumed by the contaminants , during two hours of decomposition from a solution
of boiling potassium dichromate .
• The higher the chemical oxygen demand ,the higher the amount of pollution in the
test sample.
Wastewater first passes through primary and secondary treatment at this treatment
facility. The BNR procedure takes place in the bioreactors for the tertiary treatment. To
break down the pollutants in the water[11], the BNR process uses bacteria growing in a
variety of environments across a number of tanks. The three tanks each have a distinct
environment with varying levels of oxygen. Other bacterial activities cannot break down
ammonia into nitrate and nitrogen gas when the water moves through the three tanks to
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remove phosphorus. Whereas conventional methods remove significantly less than 90%
of the phosphates, the BNR technique can remove over 90% of them. Before the water
enters the secondary clarifier, a settling tank, where the bacteria-filled sludge settles, it
spends around nine hours in the bioreactors to the bottom of the tank[17].
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Table S2: Comparison between the advantages and disadvantages of the main
techniques for heavy metal removal from wastewater.
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2 Diseases Caused by Water Pollution
We need to drink water. We also need clean water with which to wash viruses, bacteria
and chemicals from our food and from our skin. And yet, around over 1 billion people
do not have access to improved drinking water sources and around 2.4 billion
people lack adequate sanitation. Four-fifths of all illnesses in developing countries are
from waterborne diseases [1].
The World Health Organization estimates waterborne diseases cause two million deaths
annually, mostly of young children [2].
And these diseases, manifesting in diarrhea and infections are only the more obvious
illnesses caused by water pollution. Cancers from chemicals, like mercury falling in
acid rain, or neurological problems from pesticides in agricultural runoff or lead
leaching through the soil into the groundwater from a smelter, chemicals that poison
marine life and make their way up the food chain are less easy to pinpoint as caused by
polluted water.
Water can become polluted by deliberate direct dumping of garbage or animal carcasses,
accidents like oil spills, or indirectly from storm drainage, runoff from polluted soils,
pollution leaching through the soil and into the groundwater [1] or even by rain bringing
down the particulate matter in the atmosphere from industrial processes and the burning
of fossil fuels.
3 Waterborne diseases
Waterborne diseases are caused by drinking water or eating food washed in water
containing protozoa that can cause infections like toxoplasmosis or giardiasis,
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containing viruses like polio or Hepatitis A, water with bacteria like E.coli, cholera or
typhoid fever or water with parasites like hookworm and ringworm.
Waterborne diseases are generally from human or animal waste in the water. The most
common waterborne diseases in North America are from one of two microscopic
parasites found in human feces that then contaminate
water: Cryptosporidium and Giardia. They each can cause severe abdominal cramps,
nausea, headaches, gas and fever, chills and vomiting [3].
Legionnaires disease, swimmer’s ear, SARS (Sever acute respiratory syndrome), polio,
botulism – these are all diseases we are familiar with and they are all waterborne
diseases. [4]
4 Dysentery
Dysentery causes inflammation of the intestines, severe abdominal pains and diarrhea,
often with blood.
Typhoid fever is a life-threatening illness one can contract by eating food handled by a
person shedding the Salmonella Typhi bacteria or by eating food washed with water
contaminated by sewage with the Salmonella Typhi bacteria. Once ingested, the
bacteria multiply in the bloodstream.
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Symptoms include a very high fever, stomach pains, headache, extreme fatigue, joint
pain and loss of appetite [6].
Sometimes, too, a rash will spread across the abdomen known as rose spots [7].
4.2 Cholera
Cholera is an acute, diarrheal illness caused by infection of the intestine with the
bacterium Vibrio. Cholera is rare in the United States but globally, cholera cases have
increase steadily since 2005.
Epidemics are generally related to fecal contamination of water supplies or street vended
foods.
Severe cases may cause profuse watery diarrhea, vomiting, and leg cramps. The rapid
loss of body fluids can lead to dehydration and shock and without treatment, death can
occur within hours [8].
4.3 Hepatitis A
Hepatitis A is a liver disease caused by the hepatitis A virus. The virus enters the water
via the feces of an infected person. This can happen through broken pipes or by sewage
overflows.
Accordingly, the virus can spread through water used to wash food. Too, a person living
in the same household where personal hygiene is poor can contract Hepatitis A by
putting something in her mouth that has been contaminated with the feces of the ill
person.
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4.4 Water-washed diseases
When there is not an adequate supply of clean water for washing, eye and skin infections
can easily occur and be very difficult to clear.
4.5 Trachoma
Trachoma is responsible for the visual impairment or blindness of nearly two million
people in the poorest, most rural areas of Africa, Central and South America, Asia,
Australia and the Middle East. Women and children are the most vulnerable
populations[19].
It is an infectious disease, spreading through personal contact and by flies that have been
in contact with the discharge form the eyes or nose of the infected person [10].
4.6 Yaws
Yaws is a poverty-related bacterial skin infection that can severely disfigure children as
well as affect their bones and cartilage.
4.7 Scabies
It is contagious and spreads quickly through close physical contact [12]. It can be difficult
if not impossible to get rid of scabies without washing bed linens and towels in hot,
clean soapy water.
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4.8 Shigellas
Shigellas is another infectious disease that can spread from an infected person to
contaminate water or food.
Shigellas and the E.coli bacteria are the most common cause of traveler’s diarrhea,
often from eating salad or sandwiches that have involved hand contact by someone who
has picked up the bacteria from feces or feces-contaminated water and not washed their
hands properly [18].
4.10 Schistosomiasis
The most common is schistosomiasis, or blood flukes, a parasite that hatches from eggs
in the feces or urine of infected persons who defecate or urinate in freshwater in the
tropics.
About two hundred million people are infected with this parasite.
When the eggs hatch, the blood fluke parasite grows and multiplies inside snails. When
they leave the snails, the parasites can penetrate the skin of persons who are wading,
swimming, bathing, or washing in contaminated water.
The wormy parasite lives within the blood vessels of the human host, where the female
produces eggs.
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It is the body’s reaction to the eggs, not the worms themselves that cost a host of
problems, including anemia, malnutrition, learning problems and over time, damage to
the intestines, liver, bladder and even to the lungs.
Eggs have also been found in the spinal cord or brain where they can cause
inflammation, seizures or even paralysis [14].
Polluted water can be a factor for water-related vector-borne diseases, that is, diseases
carried by mosquitoes or other insects who find favorable breeding grounds in polluted
waters and multiply more rapidly. These insects then act as hosts for parasites and cause
many serious diseases[20].
• Malaria
• Japanese encephalitis
• Yellow fever
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REFFERENCES
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4. SE.Manahan,Environmental, Chemistry,LewisPublisher,
USA,6th Edn.(1994).
5. W.Hagemann,W.BishofsbergerandE.Engelmem(Eds),
Upgrading Waste.Water.Treatment.Plants,Pergamon
.Press,Ehnsford,N.Y. (1990).
International,N.Delhi,2nd Edn.(2005)
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8. Younos, T.; Tulou, K. E. Overview of desalination
techniques. Journal of Contemporary Water Research &
Education 2005, 132 (1), 3-10.
9. Al-Karaghouli, A.; Renne, D.; Kazmerski, L. L. Solar and
wind opportunities for water desalination in the Arab
regions. Renewable and Sustainable Energy Reviews 2009,
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(GO) for removing lead ions from aqueous solutions.
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13. Gaikwad, M. S.; Balomajumder, C. Simultaneous
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by CFSK and CFSD models. Journal of Molecular Liquids
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15. "Water Pollution". Environmental Health Education
Program. Cambridge, MA: Harvard T.H. Chan School of
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