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THERMODINAMICS

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Vaibhav Singh
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0% found this document useful (0 votes)
83 views47 pages

THERMODINAMICS

Uploaded by

Vaibhav Singh
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
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ke ki cce FREE zy’ that part of. 4 Enrall Page No: 7 Date: foe a mite 4 Thermo Surroundings ithe on Pe ee agstem) Lox pack__ yo ie mela iavertgatian , othex than aypiten——$§$_. ~ Baaadany 2 ke that - pact which seperater the. we System 4 £ rround eg L nn e Tt allows ux bo_contral ee ok tack —o] all mavens of matter” £ enere ¥ | ‘ech out of the aystern dd ~ 7 ! or —— 2} 4/ ¥ __ y = i dart _ eon == bounds. . Z™\ »—+—- — - ———_. €¢ —— Enroll KO oo ; Sy tH BE xs ep | @chan of ! exchangs ~~ -Meiller exchange shu _... | both “mater eal } A-line oneey c JA energy _ Pas - y . poaxi bbe - a ee oo. o ~ naa oe State. of the the pyplers — @ | I Batten | For er ene atate 4 — * ial | S-t sh { caleutationa. (ate mutt be desciibed. e_agder te__make. "4 tle need to. describe _ ———— becipy vy it before t after the S _.. a || fn. thermodynamics dea ais age ac | prop ertign. Pines om. . oa s _ L flake of thermodynamic. eythern _— a Lie adecibed ye at ore Etbulk) Hl rm) Enroll Page No 7 Date / | Stale Jonchona | Stoke sorscieg Thane sorta ax “ oe Tn order to. ~trepstel defines _ele of he of the we Hem it ix. not neces ~_ a cp the ery teens all the — Ce cerdain ine. of prmpertia chick en Cin be. sed i aoa ot agi afficient C a a on eA. mace - . ——pedper'e. bra petvtion -axe_fizad blest a cae . we hae efined cals —____ —_—- he a ate of. tha an. nar. __ emily Arced we se | Toeanal ‘cergy of the ok wv re: De. hall kind 0 a [py cami Se I pad ah Us Change He chaage the onltvnal : dy F + Heat dork Hatter — enbert ox leave yyy ——. —Enrell_ Paga No: Daa ff i | Ag C1 G og Tndernal ¢ ay a ; ee : - I te - a te cs _____ j k © [nictege ty meta oat oe ae pin. clofed Ayplter 7 | OG ht Ot 2U, | the = Osn = [Av = Orn | thermédlgnamécs ~ — . i Focigy ca can_neither he Created nox he_dushoryed | nae - - ~ a , s Hy Ye _ oo _ a 7 j vw Enrott Page No: Date.) f >, Slate unctions [Slale vatable axt...hote variable — those valuas defend only on the. habe a} Hu Agee but not_m how” it hos been achieved. - cy Pe Yalurne in_above diagrane. ___.... —.- reek kik cee ion ~ ~~ ~ ~ ~~ ~ ~ a v - eT . v7 ~ > 1B c - fs which axe oo dependent on | the. egdtern baa __. C idaken 4. achieve. a ~ Parca Ata! aaa heat C ce __ S an oa __ U -— — - - C _ — _ ~~ eg ~ i 1) isothermal process ligochow'c forocegs w)_Itgoharic t wv) lladiabatic. -brotesr » pes lic process = _| Trothermal Procege |. Game dernperature dermag hout.) iT remaing cott- a _ w " en «oe CGoe ‘ € | Sy 2 c ae f c eadgqec T Enroll. ~ - —_—_—. Page No: w st ~— Dae i ___ | Tsabari 6 oc | i ic Fron: _—______ Hl Sapme procese roughout tne pew) ee Wy CeCOCCHEOCOCCOECOOC CEE EE _— Enrail_ Page No. Date OCE COC H OOO — ee w . — S --—_____ g- — — eS A Aystem andergoes_. 0. seth comes. 5, Tact ie that ae Hy ep ee Proce ¢ frreversible a oe ee ro + = = rocess during which.._Only at nial €. final yin, aemain in “egll” plage. on “ } z “ saith - surrounding at. be ine gil” ath ~ oS ach. feeb Surrounding ima for com pletion > Angianoneads ¥ | v. w ' Enroll _. Page No: Date: 7 7 fs f i i I Heat £ love _ wa These aie... - _.. hich appear _- an'y dung the” auhast cof Caney ‘ rt = — __ Heat x the _energ } which will trangfer acrope w—-—- --boundary ashi Hoare oo [4_demperature cli feren a tee plo Aptian 4. _ Rae i _ CEE RCC ex ‘ | —-The energy whith will tmngfer aeroye tha a boundary when them jp 00 temperature. differne __. i ble ( - (£y-—mechanital .elechicab. magnetic._grnidalional. || Sign Convention. (TupAc)_of Heat 4 bork. | Reat_abpgor hed — je aystemn_= ave _ ¢ ‘Hea by dhe gaatem = -ve Work dene on > Hh a fitlern = He Werk don. by the syteon, 2.2ve ee COCOCECOCEOCOCEOCCEOOEE ec OOG -— di — Area of Crone sections coe cee ELE Ed | = OWS exes dob Fett = | We feet Coli dad : | | = -Aldi-ds * ext (Adi Ad, ) + Pext (vi-Ve) ce Co coe ff Pex AY hor _pmall work a= tea dv ey Aye at | | ZZ gop « __ I. Wa equal &° area under Ha | RY cure ith volume I we ‘i eo oe > _—_—___— ne. S | ° UF OHS = Ue Mathematical equation for aus of. “conservation. Op --—#nergy for cloted__syslem. - ~ we ~— aa. - te fe AY? @th - oa ~~ (The _inkrnal. eneeyy of tha ppd —increasea by ——__4e kj .f heat absorbed by the xytern is rok} _ ——_lfind We work dons by tha. egatenr - | @tp tok} ¢ O- 20K a eet TF —— | ok done bj the tyabinn te to bp Cece oce ce Cc cece oe Enroll. Page No: oOOoG CACULAIEON. OF WORK FOR. Dites@enr “WORK FOR. Dipee@enr o TYPE of PRocers ON AN TDPFAL Mar = (@) | Irothermat Process. —— HE. a ~ _ i), Reverxible i). Treversi ble 2 { ~~ i) ! Reversible. Expangio n n Uretheenall <= Ne | I | 4 sh ee dee (atr-dy v iH als = flemt dr) ee mis fimtdy + ted _ bis. ~ (feetsdy TT vi [al - ner Ldwv],, i Enroll ~ w 4 v Page No- aa ji wt -— = = = pee et net in P, P. ~~ - == five tn Pe Pe = = Pi¥zin ‘ti - vy Pe = 2. o8nRt log Ve i Ve ” = -2.403x5 mofxt_i-atm x i008 x0 ax ge. A KE pr find ssothlem_by Ha TO Hl Suglerm. —— faa - =P. (nv 4 vt =~ hatmx sl x 7.303X0-3X Ah oe > IOS #teratm c. | _. - 7 wf For all processes 2 : COOL OCHEK Area ander the curve will jie the magnitude of work done oo _. | I ,O6¢ w= =f few. dv } @. iF Fran = = ork = ~ fot de = +f wlde = Pers. (VE -vi Dl in the above cow... ge - [ee brev > Liar. with .2i9n | uatloneal, hie? bbrever eceoee Oe eer eee ace e cee COC pelm.tm) 4g fp ef temaved | rE CCE EO ¢ COE OE > © Cart « ie a — Farol. Page Ne tek Cree KOE COCCHEEOCHKOCCOOCOOCEOCOOCOCEEETE LArlarsn) park daw singh fhe _| Ar (a oaese) Bak Ame_ive ale: Nt compression Ty Lier. <1Blm, <1oln fooler. = Single two eee n Aiee SD rleh TRO the wemad. iyothitenad —. ——fhe te anal — — a bi fae. | The above procets HF ocuring by a Cot eat. P ofA Pp’ + As Area of trary tection ceo [lee] vevercible ar (acig{a | : |p [rev. (rothermak compress ign —As(AcoeA | 1 fwWlive. tathermal cambre trite Bites ae —prae Lepore Pow [rv tres sm] s ha block, | fC] Pr meg d Oo © oO « | © ¢ COGECGCOLE CE i] . ape ¢ ef oe wc a: AG on ighen lolock em, ¥ tx ka phe Le The bistro t+ . — ‘i : Pig kom Ee | co pb of P*e my comnbrease by cot: pt nl ix | w ad 7 oo ~ e --— > - e Ares of cress rection ¥ , Enroll, COCCOE CECE ECR KR EER KOO Cecaggreceoccnrer q¢ Winerarbl, > t i f - — = — [Meohige > belive. > Uli >> Mle, = fe vespibt | single furs wih rake oe Ath b, camp. | Hn cern p core cempreanien _ Temperature. _variaiion 3) Temp. will -vemain_cott.. a a Temp. will L" taco. than 4 wt dete then incre i iv) Tenp. jail leer _covttin aovly . jy) tem be anil inte continu ews __. Tony _ La @eyvp . Lu gid . . I Enroll_, “Page No! Dae 7 fF ALS Te £1 toa poR mua S—- 9-2 TWKTe< To dhe 2T9 OE Seo G@ © oo | 3 © € Foe 4 BPv= MrVrims* . . a -——Fox_maalnoie Gofal onllon tints trey Trees tb J Hrvems* — TIkE = _pxapy _ aa — Talerriat ener COCOCEHOELOECOCOCOCEOCOCHE COE EEOC EE KEKE Fm. ean. of. kr es U = ert + for menoatamic. qu hinernat lenergy of g™ © |Monoatomic gas has a on “Hhsco degree. ae Sof eack boa r. of. erg "y low ~h— —24uipartition > (O me | deus of nl > pe then ite pe energy —taill he equal will be o mel TPT O Ebr = feat acihy ee ¥ Ge ¥ -—— Enroll Page No: Date wn _.A_A _ Or = GAL + Gar a -—-. Tf O70, then Cr 7G. : — »” Sera err me a tgslemn depo on bulk of eres ear ee Oa woe | Q@en Qa a x nat mar Oscar ___ = mar ___ vivir feak “capacity a aie heat capocity EE ate ms] —-—heat __, _—___ capacity = C4T= Cmndt- MSOF CCC HK CRE OOOH COCKE >t Ge Pi There al ae re will be safe a) soalar. heal capacity. cS 4 ‘ pe O+W = AU on ei eal gine ou —4=f Peet dve _ ~{ tex feet we AY ee dv) * (aa uate — — Praceaa ik oben = Process ia itohorte tee Qe-Pesfdv=AU . poco Ortorlvivid= uu, —s fe Or: {lan ttexttv Jeli tot wR Ho tathalby of te fp bm Enroll Page Ne Dae: ff ~ SS SSsSsSsssssau—_«_aw907=1 war —— | (One eat oa yee 4 lam chang : Enthalpy= = (utev) en Fake parttion Hh = Ut Pe He = U+P.V2 woe _ i “Aue Ha-H. wa? (Ue Ue) ER Va“PLVn. - 7 Tfaws aut (etd)? por all zlabe of the —mabler C.ba) LT the epstem ip ideal gan. Lin _tahich : now of rig. oceing fie. a wail xemain coll) Au: aut (ner, - apt, ) _ — - _ , iene Bor aka] ee coe temp, (n caitt yang) tb) which i i Awe Aut (marnar) _ . w w he. ns ae - a we a ~ . we ee ‘et a ae te. -- ~~ ~ we | to. fuma_of Linlernal energy € “broduct of. ~ coon . a V connie ~~ ~ foes “ . : ~ . - ay u 5 - . - C noi . . . —oceuniag ak . L a i L F ; | 5 i e¢ a Enroll Page No = + Dae: ff He Heueey - i _._Au= Au t dfpv) ——-— __f} Ain ix ee — _- Ad Ad tAfney | _____ _faa=durnearl * “be iven deal a 7 na tplin u ‘Ae Aud nett - te) j—_AH= Aut nab. peli 04 (PVe- PV), aAlt bBR== cCl4aDh eer NT St stant 2 Ga) tel, t == eet tt ch h)_ LA) ine inl a) Fete} Witt LP SE 2HEp ot og We Cl)+ Ot = cot +10 2G Hot 4 130... §COe Tro, Hos tJ —-7 - ey o “Sn tha cage. of “zeachian invat npg ee _ | AH au it au if [aay 0] dQ, = Dam dT Oe = Nand AH Op- (toe “ford? Qu = [dev *fnemet abv ~ av = ddd | v ~ - --- Enroll — age Ne: w ae ue oo x j Heuer fox hole of matter oe wo | Antavialpy) se boo. Lidsal)-Lna reachionl: 2 ca. “ | AH* Av ralner) . — « 1 Cm OT > NevewAT + RAP “ el Ay meyer _epuah on tporath., he — we we roa we. fants? bats\ a } Hr —. , CrHe + 60. 7 400, HHO ! | Ari? He- cue _ e(txHeg, + 4XAno) -(% Heys t XH) (D> tN $50, ——> B2NLOs a | AME Hes ite, oe [Atma de (22 Hast Ha) LG ta 4502: — eco tg _ 4x = SXHa) © OCCEC CME CECH OCEOCEEEE < — Th in dapined ox - ecabhalpy chonge—duriag arn oe leaker all the shetie, invilved ih the ag” re prerent in Hoeix slandacd slate > cleat. “do_we man bj standard hale « atu bilan 1 The Mat d. c_substanct af Apecifed. ein 4 1 bar prenpure.. te. ww © > CHa $20. 7 COL + PHO _- Act = (1X Heat 2H) C1 x Hes 2X How) _ ~ | | \ | H a |. CHateq, —— cotemo PR Qe @ Mm & + Ptagyt Y= {hx Honig #2 Xbb yt >». i int L eV Act = Bayt a «ay ey a ta cnol_soli & converted iat 1 mel af itguid. An. their. SL atoke ¥ | [atl phase tronaforma tion one trotharmad J ; | _ ¥ Enroll Page Ne: 4 Date ik eothatps change whan fmol gue | comple Hy comaried ith tml. cf —eshaur LS L | ' elandard. flat ___ = - |Slandand enthalfy of. Sub -Sublienetan een z et | [Tt i4 enthalpy chany- “whin_} sala} solid ia - | Smpledely comrarted — inh 1 mal eaf $ar in there | , indard etaeee Cc | Apion ean Add _ froma poo! is_cavered wee with mil fp fa abs ch heat must be ‘nal. iby tale ab 298k? Caleulak “the i edna nur weapourtxation. ooh Ayap Viggo 292K = 44-F/ me! | ae H He PY | aus aut (ov) Vol no lsIT | Lane mur A(ney) __. Ag = At + (anjer ne ite _Avap Ut EXP! Ereira eo x 298 : kK. rrel Enroll_, Page No: it — | te enthalpy chan. “ehen Lt mel..of subedana he - -|-Joomed from. theiy constituent elumunts i the Adandard ~tak - ee . _ | in they most stabi state 4 -agyeyete acer sta <. a Hibs) + Sent Sy,d,.20019) ——> nso oY Orne Apt DL Crdget THLE) > GrelO : : : oe a Art? ApH Cette try ao _~ |p Toned ; ‘ Y — co a _ te eacosts) Colt) t Cau) dots ayer, ~ aa pC O09) _. _ Acth = ApH co colt) ++a.tr) — On Lt $200 => C04 Hd Enroll _ Page Ne: 7] Date: 13 (01 2023] 12023] et Cee fe a iB), - CCCOCEL EEE ECE OEEEEEL |S [ee Note: Ths gtd snthlfy of Jamabion Jose wt ~AMiealantn 10 ihe—afersneesiale—i¢—iaken oat Au we ALL) 0 . _ Ot _ Balt) _ ° - als) Aste grag ~~ Codgraphite __O i ets. ee | _— chy 0 : . —.. Ds a _ a _. Fatg) Pld 0 0 Phi Oo. Hy) oO uu} 0 0 ° Oulg) De a Pip whit —_ kis Oo —- .. S¥ is)... 0 . Ayo) oO. - Nab} o ——Ati.thambic @ an Sau. Qhite _ Oo | | — |] Catyt 60, torte | a Meats) ph0et8) > HOU Ars aeitwe Dl 4Ctagr +44 i. GH) pelt? A Hg) we i) Qouge £Ox tt) ———> Couly) Aras dp aut g) et 4. Catsty) => May, MALE) an Aol ay sg _ Ce ye t0et#), CON) xe ¥ a er Aitentr) a v ah) tot) > hom xe, — far: ARH ae 14) GS 7 Gist CO, —— 400. HAH - 5 ArH? 2c0.(r1 + snow 13 ¢#kI J rol “| Explanation of “cnil_for Aah Peto) Olt) ——4codel? Cmel —. ; ee “ptt -2138 KI] a enact CHK t€molecul. Oy 2 gs molerule Os, + gmoleculsdo. VOT — i reatlien © fe ee _ i nla 2eaction xa tl - ef - __ oe 1 Na x 43 - | mol ~ é hat tll be Henle of nrg evcerd, pean 2 xn 2 rémse ko x fo _. rool ja. action roa! A143 x mol _ a (eta popes tral ip tattion edge kg ee Ala reaction Herr’: law of constant heat summation... nachfied jee dias of Conservation of energy) _ 3 cL Oo | Tj a reaction. tate plain several ep then Loh. Atandard enthalpies "the intermediate 1 he divided at th sar..dempercdure. moe OE _ TAH? 44 + By, + DH . _ — poe FO Ea ~ a te. Atandard sotholby of eachon is Hy tum cachont Into ashich the owrall reacton maj >, -.-— Enroll = ——Enthalpise of different tybex. of eaction = e. aathalhy a antl enbaaie ia a we (6). Bond enthalpy (Ay) ee we (4) :Lottice enthalpy 0 Ow) 2b Eathatpy Sie ey ae ~ . Giandard enthal p bustin ae a he hy hay Th a ne we —jLcombletly. undergo ¢ combustion_in. Heir standard \- state. oe i Cay Outt) —— ey L. : _Aché cael _ vo AcH: Hon ye a _@ The cumbusion : oon mel_o} “benzene fakes —_ , Plax at 23% k_and } “alm. Alter combustion C0, (s/ Stand #0 Lam. prduted and 3207. Ok1 of | heat ie Ubernied. Calculate Hu _rlandard_« t and _- tel mol! epettiely cel — GHelt) + t80.t1) —— gco.(t) 4 3Hofl) _ | a AzH! = -32C7 k1f most. _. ArH = Ebi k Ot ~ Fgik Sj Hp 2 (ex Ay Hea, (14 3X DpH oe ecece dene rc een cane a» Enroll, Page No: Cas 7? TE is de elined ax sass, ¢ _ —-Eathal py ot femiaation Laat satel ing ang lh x into their_afome in - gakea fhale » eal) ———> cA Pye geen . tae Ona conviried _: COUCHCLOGLOG COGe o ff dal t 4Hly) c - ~tNals] <> nal. AW? De® Down 02 —— HYP n+ el) . ~ . YY —_ a AH Atty gig) Aca t — = ot) ——> WareHae ely ~ yo ce Dy Oral a . ; — oo i; : Bre} | Bend clispaciaten iat_endacthermie prom > lr. I; Bonel formation tf an exe tharamls—fanta s —. ww _—__ (ede) Co He _ 16d Ff = aN oe — + Alle dtkg so 9 mt a - ~ v v lt I | = Encoll | 1 i Page Ne: Date: if LO chatg) = aig cll) at-ct Opts Qe Ay Hone ee NEN = Neh eNQ) a Are Attn tg) = AgHaeN | Oly) + Of9) a a LBA bytligegs = AgHlioeg nn _ Teg t aly) _ Ace Batheng typ > 16651. Gl + Hly) © 4427k) _ w—c~H(y) Hla)? +459kI WoC-HG) —— Wee HEy) = +452 kJ wee ly) eye iy) = teeta = etT RI IL | Aya ges “ns —_< bf? rs oe pe bend ental | avy. bend enthalpy ~ ant — veh oT — _ _o- Art = ArH AHG AH ~ Zed eer + Beer) Ceo | yoy pe Dyt = Bde) TL -Eepeied)}__ ee md BHC HC= CH, 1902 ——> 800, 8H, 0 Ara fizrbecw # 2% e-6 t2Ece scot IxEo=04 we nto en i ~ | ese + axfoso) —~+ 2fomc=o) + ak (p14) We hi “ we Br Ede, a Emdee we oe ao - | Arte fee PL Eee E 3x E020} - Ft Sig t Heya } we | -—__— a a ~ “ a a — fioxécra t 12% Emo [2k 400+ 2% 350 $2x6o0+9x suo} Pianta ti2x2204 = peoo-tFlee L¥ 22360 kI/ mot __ 2 CoH $802 —— $60, to ArH = fex teow + 20% bey £15 XEoro J PtEceg + (OL wc5 “16600 — 16¢00 = —4000 ki/md — Enroll, Page No: Date: chan 1g, where i -noal._of. .umic folid will be formed. from. | theit comyHuank jana in press . we ‘Natl + Aa oy Nat ts) AH’ = “Tek feno) biieo calculation AW una? powsible Sof we use. Born Habers pth —meatad $$ 5 - _. Nate) + ae Nact dr) OT : | ptotes-ay — — . = Enrott Page No: - | a at ee = amet wt. itfewnce & we 4h _ ee ee Nal eL the ely) “lroly __Imol Natt ip ee eo Arts ApH toe ty _ om | nets. wv a = Imol Mac) _ ce. i AH Beal a H! oe — = ae. || Brae the Bonebn Halas k—tele— fon —Mg Cle te | I | Mgt tcl Dima iy - ~ sar] | gbdec C a8: . we Mg) eet ly) wep 2X Dey HCI “LA wis ApH ned + Bde # _—Enrall i Paga No: ate: 27/023 7 cee AH Hout tao => Hel sy —— Sal’ 4) 64-01 k Y/mst nelly) + Soro 2h 28a —— dal” 2). __-72.03 ka moi VHC a) + + Oho THU tong > ah “808 feat —jHel gt. Wo ACL es gat -FA-ES RA J mned —. 4d. Orpiaaely dilted cal” ae | | = & g| i | Oo GO ow ods ~ 2 | 2nthatp Piaf tai. af a subslane _ i2—2._Cntha' py w- ee ‘ nani When _{ mt of © the .zubrlands ix s . disco ed in a Gail amount 4 Solven}. gy i Enthalpy._of-. of Topi ty Piluteol Substance... 2 _ His entha 'by change sheaf HS 46. a a —_______.. ye ~ a a Foie: AotKoL.- -o _AB[s) ————-— A “oul B (oq) = “Aguannlt Cet (otathermic) o |89. the cliseolution of Tanue_ solid “yy -everall_an .. endothermic races bf value of. Aut’ Be Ange HY ome —. — |comparoble then there ionic fulidy ore dittalved in abbveciable amount. a _ 7 ~ —> v Enroll = > Page Ne: Dee ff - w w eters == > <== = a _. _ (6 if =" Solution | . Aue ye ae Tp LI. the nT a more we MA velution. with aceur. | Pf temp. will incweare the —salublily af tonic. i wali will ineweare _ En Haalpy of dilubion re EOC E EERE k “| ti shodian Jancaur ee. — all thane proce sen which brace sen which iGither accux, by ilfall} ov ee ocour by staelh —afer_a_proper tartation but thes can be mats 4 help of exter nat agcnt _ tame Criteria afer Sponlonily Sh. disorder in the _ayatn ee soa ba entepypt—— COCCkL OK CCH OK COKE E | System. + surrounding * univerte _ Toa t © Averers = tv] ee ——--prce_uiill_atuat, be shor tansous Avram s 2 ove} wae racers ail be. non -Aponfaniaw ta : Ge. divsction but sail!be spontaneous in oppeaik - -. || Aiee tiom — —____. . >| [Arar S = 0 oe ee Paseo) vill be ia_.eguill thaum FL AS xO and Asal Y [AS< One + r Dry s + Assur S$ > An S Ags + Quan 5 Ante « Tr Ags = Og = A _ _. v. — =a ~ Gubbr = are pat - ” meres OU ETS an — tig ps — Page j Date:1 102/93 _— Enroll Keech ee cee + cu, = AtttS— — T ot Oys + Asst, = Asctat $ a a Asys - Mri Ss ~— a Apt a a we 4 7 ~ ee - a jf ee AH = AG + + dlrs) ee w foncens metering at co . - vi ane nat TAs TAS + sah . — a pe - , fas S@+t TAS w , EAS — sO aos aw Tas} av-7as].. - “ ir ~ re | a _ _ - T For ry: ; _ _.! - Aga? Oyn-Thys] -ii) w ~ Ass G = -TAmat S| ee “ | For Lf __. ee ~ i ; so Gi > i _ . wo JAG = Gy _ “ | =e | ~~ 4 ~ a — GOO? " $0.4 > -Vve il ae AtoalS = 7ve | | —So.fdsp a * te | foc mon =2panlancaus. frocene re oo | | ! | | | | CoO” > | | | COE ? ¢€ PO) ass tre AG~ AH-14S Here AG qift alusays. be SPONTANEOUS _f} as = -ve AG > AH-TAS alway —he_-ve. 4 the process -. tai _ broter sill bef laul= [fa é pu _ [Addl > Iras}] = ~ve i Spon taneous —.mpilavl ctaasi = tve 4 Msp in given divechon but (CER PR ROKR OE AG = AH-TAS ~~ | ~ te if a 7 w tT} process te endothermic voce ee Lan ve, _ _ ota) : ya AS tre & _ ~ “ve & Ce - ME = AH-Tads , AS*0 . 7 4¥e,. process will be 'NSp. procegz wil) be in._egh —_ : Nan ghonianeous Shontartaa

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