Material Safety Data Sheet: Product and Company Identification 1
Material Safety Data Sheet: Product and Company Identification 1
Material Safety Data Sheet: Product and Company Identification 1
ARADUR® 22962
E-Mail: [email protected]
2. Hazards identification
Physical state : Liquid.
Odor : Slight
Color : Colorless.
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Emergency overview : DANGER!
CAUSES EYE AND SKIN BURNS. CAUSES RESPIRATORY TRACT IRRITATION.
MAY CAUSE ALLERGIC SKIN REACTION. MAY BE HARMFUL IF SWALLOWED.
CAN ENTER LUNGS AND CAUSE DAMAGE.
Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not breathe
vapor or mist. Do not ingest. Do not get in eyes or on skin or clothing. Use only with
adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash
thoroughly after handling.
See toxicological information (Section 11)
GENERAL INFORMATION : Read the entire MSDS for a more thorough evaluation of the hazards.
3. Composition/information on ingredients
Name CAS number %
Isophorone diamine 2855-13-2 60 - 100
Notes to physician : Symptomatic and supportive therapy as needed. Following severe exposure medical
follow-up should be monitored for at least 48 hours.
5. Fire-fighting measures
Flash point : Closed cup: 110°C (230°F) [DIN 51758 EN 22719 (Pensky-Martens Closed Cup)]
Flammable limits : Lower: 1.2%
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
nitrogen oxides
Extinguishing media
Suitable : Use an extinguishing agent suitable for the surrounding fire.
Not suitable : None known.
Special exposure hazards : Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to avoid : No specific data.
Materials to avoid : strong acids, strong bases, strong oxidising agents
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.
11 . Toxicological information
Potential acute health effects
Inhalation : Severely irritating to the respiratory system.
Ingestion : Harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause
damage. May cause burns to mouth, throat and stomach.
Skin : Corrosive to the skin. Causes burns. May cause sensitization by skin contact.
Eyes : Corrosive to eyes. Causes burns.
11 . Toxicological information
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Isophorone diamine LD50 Oral Rat 1000 mg/kg -
Sensitizer
Product/ingredient name Route of Species Result
exposure
Isophorone diamine skin Guinea pig Sensitizing
12 . Ecological information
Environmental effects : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment. This product shows a low bioaccumulation potential.
Aquatic ecotoxicity
Product/ingredient name Test Result Species Exposure
Isophorone diamine DIN 38412 Acute EC50 42 Daphnia - 24 hours
(Lumistox test) mg/L Daphnia magna
Straus 1820
DIN 38412 Acute EC50 37 Algae - 72 hours
(Lumistox test) mg/L Scenedesmus
subspicatus
Not known Acute LC50 185 Fish - Golden 48 hours
mg/L orfe (Leuciscus
idus)
203 Fish, Acute Acute LC50 110 Fish - Zebra fish 96 hours
Toxicity Test mg/L (Brachydanio
rerio)
Biodegradability
Other ecological information
Not Determined
Not Determined
Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Isophorone diamine 0.99 - low
12 . Ecological information
Other adverse effects : No known significant effects or critical hazards.
PBT : Not applicable.
Other information
13 . Disposal considerations
Waste disposal : The generation of waste should be avoided or minimized wherever possible. Significant
quantities of waste product residues should not be disposed of via the foul sewer but
processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Disposal of this product, solutions
and any by-products should at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional local authority requirements.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
14 . Transport information
Proper shipping name
DOT : ISOPHORONEDIAMINE
TDG : ISOPHORONEDIAMINE
IMDG : ISOPHORONEDIAMINE
IATA : ISOPHORONEDIAMINE
14 . Transport information
PG* : Packing group
15 . Regulatory information
U.S. Federal regulations
HCS Classification : Corrosive material
Sensitizing material
U.S. Federal regulations : United States inventory (TSCA 8b): This material is listed or exempted.
TSCA 5(a)2 final significant : None.
new use rule (SNUR)
TSCA 5(e) substance : None.
consent order
TSCA 12(b) one-time : None.
export notification:
TSCA 12(b) annual export : None.
notification
SARA 302/304/311/312 : SARA 302/304/311/312 extremely hazardous substances: No Ingredient Listed
extremely hazardous
substances
SARA 311/312 hazard : SARA 311/312 MSDS distribution - chemical inventory - hazard identification:
identification Isophorone diamine: Immediate (acute) health hazard
Clean Air Act - Ozone : This product does not contain nor is it manufactured with ozone depleting substances.
Depleting Substances
(ODS)
15 . Regulatory information
International lists : Australia inventory (AICS): This material is listed or exempted.
China inventory (IECSC): This material is listed or exempted.
Japan inventory: This material is listed or exempted.
Korea inventory: This material is listed or exempted.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): This material is listed or exempted.
16 . Other information
Label requirements : CAUSES EYE AND SKIN BURNS. CAUSES RESPIRATORY TRACT IRRITATION.
MAY CAUSE ALLERGIC SKIN REACTION. MAY BE HARMFUL IF SWALLOWED.
CAN ENTER LUNGS AND CAUSE DAMAGE.
Hazardous Material :
Information System (U.S.A.)
Health 3
Flammability 1
Physical hazards 0
Personal protection
The customer is responsible for determining the PPE code for this material.
1 Flammability
Health 3 0 Instability
Special
IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICABILITY OF SUCH
INFORMATION AND RECOMMENDATIONS AND THE SUITABILITY OF ANY PRODUCT FOR ITS OWN PARTICULAR
PURPOSE.
THE PRODUCT MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION. WHILE CERTAIN HAZARDS
ARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE IS MADE THAT THESE ARE THE ONLY HAZARDS THAT
EXIST.
Hazards, toxicity and behaviour of the products may differ when used with other materials and are dependent upon
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ARADUR® 22962
16 . Other information
the manufacturing circumstances or other processes. Such hazards, toxicity and behaviour should be determined
by the user and made known to handlers, processors and end users.
For further Product EHS related questions concerning this document or its contents, please
contact:
E-Mail: [email protected]
2. HAZARDS IDENTIFICATION
Irritating to eyes and skin.
May cause sensitization by skin contact.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature
Bisphenol A epoxy resin containing reactive diluent
preparation
Hazardous components
Chemical Name CAS-No. Symbol(s): R-phrase(s) Concentration [%]
butanedioldiglycidyl ether 2425-79-8 Xn R20/21 R36/38 R43 14.00 - 22.00
EC-No.: 219-371-7 R52/53
reaction product: bisphenol A- 25068-38- Xi, N R36/38 R43 R51/53 78.00 - 90.00
(epichlorhydrin); epoxy resin 6
(number average molecular
weight < 700)
Eye contact : Rinse immediately with plenty of water for at least 15 minutes.
If eye irritation persists, consult a specialist.
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SAFETY DATA SHEET
according to applicable EC directive
5. FIRE-FIGHTING MEASURES
Suitable extinguishing : Water spray.
media Carbon dioxide (CO2).
Foam.
Dry powder.
Methods for cleaning up : Soak up with inert absorbent material and dispose of as
hazardous waste.
Storage
Further information on : Keep away from food, drink and animal feeding stuffs.
storage conditions Keep container tightly closed.
Store at room temperature in the original container.
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SAFETY DATA SHEET
according to applicable EC directive
Huntsman Advanced
Materials
Hand protection : Material of gloves for long term application (BTT>480 min):
Butyl rubber
Ethyl Vinyl Alcohol Laminate (EVAL)
Material of gloves for short term/splash application (10
min<BTT<480 min):
Nitrile rubber
Neoprene rubber
Use gloves approved to relevant standards e.g. EN 374
(Europe), F739 (US).
Suitability and durability of a glove is dependent on usage, e.g.
frequency and duration of contact, chemical resistance of glove
material and dexterity. Always seek advice from glove
suppliers.
Additonal information can be found for instance at
www.gisbau.de
Colour : yellow
Odour : slight
pH : 7.7
at (20 °C)
1:1 in water
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SAFETY DATA SHEET
according to applicable EC directive
Water solubility : at 20 °C
Note: practically insoluble
Hazardous decomposition : Carbon oxides. Burning produces obnoxious and toxic fumes.
products
Ecotoxicity effects
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SAFETY DATA SHEET
according to applicable EC directive
ADR:
UN-No: 3082
Class: 9
Classification code: M6
Packaging group: III
Risk No.: 90
ADR/RID-Labels: 9
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
contains: BISPHENOL A EPOXY RESIN
RID:
UN-No: 3082
Class: 9
Packaging group: III
Risk No.: 90
ADR/RID-Labels: 9
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
contains: BISPHENOL A EPOXY RESIN
Sea transport
IMDG:
UN-No: 3082
Class: 9
Packaging group: III
ADR/RID-Labels: 9
MFAG:
EmS: F-A S-F
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
contains: (BISPHENOL A EPOXY RESIN)
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SAFETY DATA SHEET
according to applicable EC directive
Air transport
IATA-DGR:
UN/ID No.: UN 3082
Class: 9
Packaging group: III
Packing instruction (cargo 914
aircraft):
Max. Qty/Pack.: 450.00 L
( 999.00 = No limit )
Packing instruction 914
(passenger aircraft):
Max. Qty/Pack.: 450.00 L
( 999.00 = No limit )
ADR/RID-Labels: 9
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
contains: (BISPHENOL A EPOXY RESIN)
Symbol(s): : Xi Irritant
N Dangerous for the environment
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SAFETY DATA SHEET
according to applicable EC directive
National legislation
Notification status
: EINECS yes
: TSCA yes
The provision of Safety Data Sheets comes under Regulation 6 of CHIP (CHIP is the recognised
abbreviation for the Chemicals Hazard Information and Packaging Regulations). This is an addition
to the Health and Safety at Work Act 1974.Users of products supplied by Huntsman Advanced
Materials should take appropriate measures to ensure working practices are in accordance with the
Control of Substances Hazardous to Health Regulations (COSHH).
All information is based on results gained from experience and tests and is believed to be accurate
but is given without acceptance of liability for loss or damage attributable to reliance thereon as
conditions of use lie outside our control. Users should always carry out sufficient tests to establish
the suitability of any products for their intended applications. No statements shall be incorporated in
any contract unless expressly agreed in writing nor construed as recommending the use of any
product in conflict of any patent. All goods are supplied subject to Huntsman Advanced Materials
General Conditions of Sale.
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