Physical Test - Q - 05.07.2021

Epsilon
Ramnagar Road 5 . Agartala .Tripura (west).
CLASS 12 - CHEMISTRY
Full physical test
Time Allowed: 1 hour and 30 minutes Maximum Marks: 50
1. Henry's law constant for CO2 in water is 1.67 × 108 Pa at 298 K. Calculate the quantity of CO2 [3]
in 500 mL of soda water when packed under 2.5 atm CO2 pressure at 298 K.
2. SnO2 forms a positively charged colloidal sol in acidic medium and a negatively charged sol in [3]
the basic medium. Explain.
3. Assertion: With an increase in temperature activation energy of the reaction decreases. [1]
Reason: For every 10º rise in the temperature, the rate of the reaction doubles for most of the
reactions.
a) Both assertion and reason are b) Both assertion and reason are
CORRECT and reason is the CORRECT CORRECT but, reason is NOT THE
explanation of the assertion. CORRECT explanation of the
assertion.
c) Assertion is CORRECT but, reason is d) Assertion is INCORRECT but, reason

INCORRECT. is CORRECT
4. Assertion: Activity of an enzyme is pH-dependent. [1]
Reason: Changes in pH affects the solubility of the enzyme in water.
a) Both assertion and reason are b) Both assertion and reason are
CORRECT and reason is the CORRECT CORRECT but, reason is NOT THE
explanation of the assertion. CORRECT explanation of the
assertion.
c) Assertion is CORRECT but, reason is d) Assertion is INCORRECT but, reason

INCORRECT. is CORRECT.
5. Match the graph given in column A with the order of reaction given in column B. More than [2]
one item in column A may link to the same item of column B:
Column A Column B
(a) . .(i) 1st order.
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(ii) zero order.
(b) .
(c) Positive catalyst alters the rate of reaction. (iii) by increasing the activation energy.
(d) Negative catalyst alters the rate of reaction. (iv) by lowering the activation energy.
6. Match the items of column I and column II [2]
Column I Column II
(a) Diamond (i) short interval of time
(b) instantaneous rate (ii) ordinarily rate of conversion is imperceptible
(c) Average rate (iii) long duration of time
7. Which point defect of its crystals decreases the density of a solid? [1]
8. What is meant by the term forbidden zone in reference to band theory of solids? [2]
9. Schottky defect lowers the density of a solid. Explain. [2]
10. With the help of a labelled diagram show that there are four octahedral voids per unit cell in a [3]
cubic close-packed structure.
11. Define the term azeotropes. [1]
12. On mixing equal volumes of water and ethanol what types of deviation would you expect [1]
from Raoult's law?
13. What do you expect to happen when Red Blood Corpuscles (RBC's) are placed in [1]
i. 1% NaCl solution
ii. 0.5% NaCl solution.
14. Define the term: Molality. [2]
15. What happens when pressure greater than osmotic pressure is applied on the solution [2]
separated by a semi permeable membrane from the solvent?
16. 100 g of liquid A (molar mass 140 g mol-1) was dissolved in 1000 g of liquid B (molar mass 180 [5]
g mol-1). The vapour pressure of pure liquid B was found to be 500 torr. Calculate the vapour
pressure of pure liquid A and its vapour pressure in the solution if the total vapour pressure
of the solution is 475 Torr.
17. A galvanic cell has electrical potential of 1.1V. If an opposing potential of 1.1V is applied to this [1]
cell, what will happen to the cell reaction and current flowing through the cell?
18. The following curve is obtained when molar conductivity λm (y-axis) is plotted against the [2]
square root of concentration C1/2 (x-axis) for two electrolytes A and B.
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a. What can you say about the nature of the two electrolytes A and B?
b. How do you account for the increase in molar conductivity λm for the electrolytes A and B
on dilution?
19. HCl does not give an acidic solution in benzene why? [2]
20. Calculate the potential for half cell containing [K2Cr2O7(aq)] = 0.10M, [Cr3+ (aq)] = 0.20M and [3]
[H
+
(aq)] = 1.0 × 10
−4
M . The half cell reaction is
C r2 O
2−
7
(aq) + 14 H
+
+ 6e
−
→ 2C r
3+
(aq) + 7 H2 O(l) Given that E Θ = 1.33V .
21. State a condition under which a bimolecular reaction is kinetically first-order reaction. [1]
22. The rate constant of a reactant is 2 × 10 −2
L mol
−1 −1
s . What is the order of the reaction. [1]
23. The decomposition reaction of ammonia gas on platinum surface has a rate constant k = 2.5 [1]
× 10-4 mol L-1 s-1. What is the order of the reaction?
24. a. The half life for the decomposition of nitramide is 2.1 hours at 15°C. [5]
N H2 N O2 (aq) → N2 O(g) + H2 O(l) . If 6.2 g of N H2 N O2 decomposes, calculate:
i. Time taken for 99% decomposition of N H2 N O2
ii. Volume of N2 O (dry) produced at STP
b. The conversion of X to Y follows second order kinetics. If concentration of 'X' is increased to
three times how will it affect the rate of formation of 'Y' and why?
25. Between NH3 and CO2, which gas will be adsorb more readily on the surface of charcoal? [1]
Explain with suitable reason.

x
26. In chemisorption, why m
initially increases and then decreases with rise in temperature? [1]
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Epsilon

Ramnagar Road 5 . Agartala .Tripura (west).

c) Assertion is CORRECT but, reason is d) Assertion is INCORRECT but, reason

c) Assertion is CORRECT but, reason is d) Assertion is INCORRECT but, reason

(a) . .(i) 1st order.

6. Match the items of column I and column II [2]

(a) Diamond (i) short interval of time

(b) instantaneous rate (ii) ordinarily rate of conversion is imperceptible

(c) Average rate (iii) long duration of time

Explain with suitable reason.

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