Quantum Mechanics
Quantum Mechanics
PHY-109
Unit IV :Quantum Mechanics
ELECTROMAGNETIC THEORY
LASER WAVES
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@Dr. Subhojyoti Sinha Ref: Engineering Physics : HK Malik and AK Singh
Failures of the classical concepts
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@Dr. Subhojyoti Sinha
What is Compton effect ?
The Compton effect is the term used for an unusual result observed when X-rays are scattered on some
materials. By
classical theory, when an electromagnetic wave is scattered off atoms, the wavelength of the scattered radiation is
expected to be the same as the wavelength of the incident radiation. Contrary to this prediction of classical
physics, observations show that when X-rays are scattered off some materials, such as graphite, the scattered X-
rays have different wavelengths from the wavelength of the incident X-rays. This classically unexplainable
phenomenon was studied experimentally by Arthur H. Compton and his collaborators, and Compton gave its
explanation in 1923.
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@Dr. Subhojyoti Sinha Ref: Engineering Physics : HK Malik and AK Singh
Development of Quantum mechanics
The development of quantum mechanics took place in two stages :-
The first stage: It began (in the year 1900) with Max Planck’s hypothesis according to which the radiation is
emitted or absorbed by matter in discrete packets or quanta of energy. This energy is equal to ℎʋ, where h is Planck’s
constant and ʋ is the frequency of radiation. This hypothesis led to a theory which was not completely satisfactory
being a mixture of classical and non-classical concepts.
The second stage: It began in 1925 along with two points of views. For example, (i) matrix mechanics was
introduced by Heisenberg, in which only observed quantities like frequencies and intensities of spectral lines are
taken into account and unobserved quantities like positions, velocities, etc. in electronic orbits are omitted.
(ii) Another form of quantum mechanics is called wave mechanics, whose theory was developed by Schroedinger in
1926. In this mechanics, concepts of classical wave theory and deBroglie’s wave particle relationship are combined
with each other.
With the application of quantum mechanics, several problems of atomic physics have been solved. However, this
mechanics also has certain limitations. Therefore, a more complete theory of particles called quantum field theory
has been accepted since 1947.
In order to understand the development of wave mechanics, we begin with the blackbody radiation.
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@Dr. Subhojyoti Sinha Ref: Engineering Physics : HK Malik and AK Singh
Emission of Radiation
❖ All bodies emit electromagnetic radiation over a range of wavelengths.
A cooler body radiates less energy than a warmer body.
➢ We also know by observation that when a body is heated and its
temperature rises, the perceived wavelength of its emitted radiation
changes from infrared to red, and then from red to orange, and so forth.
As its temperature rises, the body glows with the colors corresponding
to ever-smaller wavelengths of the electromagnetic spectrum.
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@Dr. Subhojyoti Sinha
Two important laws summarize the experimental findings of blackbody
radiation: Wien’s displacement law and Stefan’s law.
Wien’s displacement law: The peak in the blackbody spectrum shifts to progressively
shorter wavelength (higher frequencies) as the temperature is increased.
where λmax is the position of the maximum in the radiation curve. In other
words, λmax is the wavelength at which a blackbody radiates most strongly at a
given temperature T. Note that in this equation the temperature is in kelvins.
Note that Wien’s displacement law tells us that the higher the temperature of
an emitting body, the shorter the wavelength of the radiation it emits.
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@Dr. Subhojyoti Sinha Ref: Concept of Modern Physics by Aurther Beiser.
Check Your Understanding
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@Dr. Subhojyoti Sinha
Q. Which of the following cannot be explained by the laws
of classical Physics
(A)Blackbody radiation
(B)Photoelectric effect
(C)Stability of the atoms
(D)All of these
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Q. The peak in the blackbody spectrum shifts to
progressively _____________ as the temperature is
increased.
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Online simulation: https://phet.colorado.edu/sims/html/blackbody-spectrum/latest/blackbody-spectrum_en.html
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Stefan’s Law
Stefan’s law is associated with the total power of blackbody radiation emitted across
the entire spectrum of wavelengths at a given temperature. This total power is
represented by the area under the blackbody radiation curve for a given T. As the
temperature of a blackbody increases, the total emitted power also increases.
Quantitatively, Stefan’s law expresses this relation as-
𝑷(𝑻) = σA𝑻𝟒
where A is the surface area of a blackbody, T is its temperature (in kelvins), and σ is the Stefan–Boltzmann
constant, σ = 5.670 ×10-8 W/(m2.K4).
Stefan’s law enables us to estimate how much energy a star is radiating by remotely
measuring its temperature.
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@Dr. Subhojyoti Sinha
Check Your Understanding
Q. Suppose that two stars, α and β, radiate exactly the same
total power. If the radius of star α is three times that of star β,
Which one is hotter?
(A) Star β is hotter
(B) Star α is hotter
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@Dr. Subhojyoti Sinha
Theoretical explanation of the Blackbody radiation spectra
The physical model of a blackbody at temperature T is that of the
electromagnetic waves enclosed in a cavity (see Figure) and at
thermodynamic equilibrium with the cavity walls. The waves can exchange
energy with the walls. The objective here is to find the energy density
distribution among various modes of vibration at various wavelengths (or
frequencies). In other words, we want to know how much energy is carried
by a single wavelength or a band of wavelengths. Once we know the energy
distribution, we can use standard statistical methods (similar to those
studied in a previous chapter) to obtain the blackbody radiation curve,
Stefan’s law, and Wien’s displacement law.
However, as shown in the Figure , the Rayleigh–Jeans law fails to correctly reproduce experimental results.
In the limit of short wavelengths, the Rayleigh–Jeans law predicts infinite radiation intensity, which is inconsistent with the
experimental results in which radiation intensity has finite values in the ultraviolet region of the spectrum.
This divergence between the results of classical theory and experiments, which came to be called the ultraviolet
catastrophe, shows how classical physics fails to explain the mechanism of blackbody radiation.
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Planck’s Quantum Hypothesis
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@Dr. Subhojyoti Sinha
Planck’s Quantum Hypothesis ( continued)
Each discrete energy value corresponds to a quantum state of a Planck oscillator.
Quantum states are enumerated by quantum numbers.
For example, when Planck’s oscillator is in its first n = 1 quantum state, its energy is
E1 = h f ; when it is in the n = 2 quantum state, its energy is E2 = 2h f ; when it is in the
n = 3 quantum state, E3 = 3h f ; and so on.
Note that the equation : En= nhf shows that there are infinitely many quantum states,
which can be represented as a sequence {hf,2hf, 3hf,…, (n – 1)hf, nhf, (n + 1) hf,…}.
Each two consecutive quantum states in this sequence are separated by an energy
jump, ΔE = h f .
An oscillator in the wall can receive energy from the radiation in the cavity (absorption), or it can give away
energy to the radiation in the cavity (emission). The absorption process sends the oscillator to a higher
quantum state, and the emission process sends the oscillator to a lower quantum state. Whichever way this
exchange of energy goes, the smallest amount of energy that can be exchanged is hf. There is no upper limit to
how much energy can be exchanged, but whatever is exchanged must be an integer multiple of hf. If the energy
packet does not have this exact amount, it is neither absorbed nor emitted at the wall of the blackbody.
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Planck’s blackbody radiation law
Planck’s hypothesis gives the following theoretical expression for the
power intensity of emitted radiation per unit wavelength:
where c is the speed of light in vacuum and kB is Boltzmann’s constant, Planck’s theoretical result (continuous curve) and
kB = 1.380 × 10−23 J/K. the experimental blackbody radiation curve (dots).
Photoelectric effect
ELECTROMAGNETIC THEORY
FIBER OPTICS
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What is photoelectric effect?
When light of suitable frequency is incident onto a clean metal surface
it will cause electrons to leave that surface ( the light will eject the
electrons from the surface). This is called photoelectric effect and the
electrons are called photoelectrons.
Experimental setup:
The experimental setup to study the photoelectric effect is shown
schematically in this Figure . The target material serves as the cathode,
which becomes the emitter of photoelectrons when it is illuminated by
monochromatic radiation. We call this electrode the photoelectrode.
Photoelectrons are collected at the anode. The potential difference
between the electrodes can be increased or decreased, or its polarity
can be reversed. The electrodes are enclosed in an evacuated glass
tube so that photoelectrons do not lose their kinetic energy on
collisions with air molecules in the space between electrodes.
Fig. An experimental setup to study the photoelectric effect. The
anode and cathode are enclosed in an evacuated glass tube. The
Materials: Alkali metals like lithium, sodium, potassium etc. are found to be very voltmeter measures the electric potential difference between the
photo-sensitive. They emit electrons even when ordinary visible light falls on them. electrodes, and the ammeter measures the photocurrent. The
Experiments show that with light of suitable frequencies(ultraviolet rays, X-rays and ɣ- incident radiation is monochromatic.
rays) almost all metals exhibit photoelectric effect.
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@Dr. Subhojyoti Sinha Ref: Concept of Modern Physics by Arthur Beiser
Check out this Simulation: Virtual Lab
https://phet.colorado.edu/sims/cheerpj/photoelectric/latest/photoelectric.html?simulation=photoelectric
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Experimental observations
(1) If the frequency of the incident radiation is greater than the
threshold frequency (ʋ0) (certain minimum frequency), only A
then the emission of electrons takes place.
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Dr. Subhojyoti Sinha Ref: Engineering Physics : HK Malik and AK Singh
Q. In case of Photoelectric effect if the intensity of the
incident light increases ( frequency above the
threshold frequency) then the photocurrent
(A)Increases
(B)Decreases
(C)Remains the same
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The photoelectric effect has three important characteristics
that cannot be explained by classical physics:
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Ref: Concept of Modern Physics by Arthur Beiser @Dr. Subhojyoti Sinha
(3) The independence of the kinetic energy of photoelectrons
on the intensity of incident radiation : Typical experimental
curves are shown in Figure, in which the photocurrent is plotted
versus the applied potential difference between the electrodes. For
the positive potential difference, the current steadily grows until it
reaches a plateau. Furthering the potential increase beyond this
point does not increase the photocurrent at all. A higher intensity of
radiation produces a higher value of photocurrent. For the
negative potential difference, as the absolute value of the
potential difference increases, the value of the photocurrent
decreases and becomes zero at the stopping potential. For any
intensity of incident radiation, whether the intensity is high or low,
the value of the stopping potential always stays at one value.
In classical theory, the photoelectron absorbs electromagnetic energy in a continuous way; this means that when
the incident radiation has a high intensity, the kinetic energy is expected to be high. Similarly, when the radiation has a low
intensity, the kinetic energy is expected to be low. But the experiment shows that the maximum kinetic energy of
photoelectrons is independent of the light intensity.
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@Dr. Subhojyoti Sinha
More discussion on the failure of the classical wave theory…..
The classical wave theory of light fails to account for the characteristics of the photo electric effect.
According to the wave theory, the energy of light is equally distributed uniformly over the entire
wavefront. So it is difficult to understand how such uniformly distributed energy could suddenly
concentrate on extremely small cross-section of the electron. Calculations on the basis of wave theory
shows that the time required for an atom to gather sufficient energy from such wavefront, so that the
electron may escape the surface, may in some cases run into several days. But experiment shows that
the effect is instantaneous. Further application of wave theory to photo electric effect compels us to
conclude that the initial velocity of electron emission should depend on the intensity of the incident
light which is contrary to experimental findings. The existence of threshold frequency in each case, is
also, contrary to the conditions of wave theory, for it seems quite without reason why a sufficiently
intense beam of low frequency fails to liberate an electron while a feeble beam of high frequency
succeeds in doing so.
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@Dr. Subhojyoti Sinha
❑ In Einstein’s interpretation, interactions take place between individual electrons and individual photons. The absence
of a lag time means that these one-on-one interactions occur instantaneously. This interaction time cannot be
increased by lowering the light intensity. The light intensity corresponds to the number of photons arriving at the
metal surface per unit time. Even at very low light intensities, the photoelectric effect still occurs because the
interaction is between one electron and one photon. As long as there is at least one photon with enough energy to
transfer it to a bound electron, a photoelectron will appear on the surface of the photoelectrode.
❑ The existence of the cut-off frequency ʋ0 for the photoelectric effect follows from the previous because the kinetic
energy KEmax of the photoelectron can take only positive values. This means that there must be some threshold
frequency for which the kinetic energy is zero. In this way, we obtain the explicit formula for cut-off frequency:
𝝓 𝒉𝒄
ʋ0= in term of wavelength 𝝀𝟎 = this is known as cutoff wavelength or threshold wavelength .
𝒉 𝝓
𝟏𝟐𝟒𝟎 𝒆𝑽.𝒏𝒎
The value of hc=1240 eV.nm so the threshold wavelength can also be written as 𝝀𝟎 =
𝝓 𝒆𝑽
❑ Cut-off frequency depends only on the work function of the metal and is in direct proportion to it. When the work
function is large (when electrons are bound fast to the metal surface), the energy of the threshold photon must be
large to produce a photoelectron, and then the corresponding threshold frequency is large. Photons with frequencies
larger than the threshold frequency ʋc always produce photoelectrons because they have KEmax > 0. Photons with
frequencies smaller than ʋ0 do not have enough energy to produce photoelectrons. Therefore, when incident radiation
has a frequency below the cutoff frequency, the photoelectric effect is not observed.
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@Dr. Subhojyoti Sinha
Threshold frequency, Work function, Stopping potential and Kinetic energy of the emitted electrons
eV0= (KE)max
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Fig ref: Concept of modern physics by Arthur Beiser
Go through the text books and the reference books, as mentioned in your syllabus (PHY109), thoroughly.
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Fig ref: Concept of Modern Physics by Arthur Beiser
Q. It is possible to liberate an electron from a metal
surface having work function 4.8 eV with an incident
radiation of wavelength - h=Planck's constant = 6.63 x10 J s
c= speed of light =3x 10 m/s
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(A)5000 Å
(B) 2000 Å
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Q. If ʋ represents the frequency of the incident light
and ʋ0 represents the threshold frequency for a
particular metal. Then the maximum velocity of the
electrons (having mass m) can be represented as
𝟐𝒉
(A) ℎ ʋ − ʋ𝟎 (B) ʋ𝟎 − ʋ
𝒎
𝟐𝒎 𝟐𝒉
(C) ʋ − ʋ𝟎 (D) ʋ − ʋ𝟎
𝒉 𝒎
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Q. The threshold frequency for photoelectric
emission in copper is 1.10×1015 Hz. Find the
maximum kinetic energy in eV when light of
frequency 1.20×1015 Hz is directed on the copper
surface. h=Planck's constant = 6.63 x10 J s
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(A)0.41 eV
(B)0.66 eV
(C) 0 eV
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