TEST#25

Topic: Analytical Chemistry

Time allowed: 90 min

Marks: 100

1. Which of the following aqua regia is

(a) 1 part conc. HCl (b) 3 part conc. HCl (c) 2 part conc. HCl (d) 1 part conc.
and 3 parts conc. and 1 parts conc. and 1 parts conc. HCl and 2
HNO3 HNO3 HNO3 parts conc.
HNO3
2. In a qualitative inorganic analysis of basic radicals, HCl is preferred to
HNO3, for preparing a solution of given substance. This is because
(a) Nitrates are not (b) Nitric acid (c) Hydrochloric (d) none
decomposed to contains nitrogen acid is not a strong
sulphides oxidizing agent
3. Mark the compound which turn black with Ammonium Hydroxide
(a) lead chloride (b) mercurous (c) mercuric chloride (d) silver
chloride chloride
4. Silver Halide which is least soluble in Ammonium Hydroxide is.
(a) AgBr (b) AgCl (c) AgF (d) AgI
5. Which of the following sulphides is not soluble in hot dil Nitric acid?
(a) CuS (b) ZnS (c) HgS (d) CdS
6. Nitric acid is added…..the precipitation of Group III ?
(a) after (b) before (c) it is not added (d) both a and
b
7. II-B sub-group of basic radicals consists of
(a) As, Cd and Hg (b) Zn, Cd and Hg (c) Cu, Hg, Au (d) As, Sb, Sn
8. In which mode of expression the concentration of a solution remains
independent of temperature
(a) Molality (b) Formality (c) Normality (d)Molarity
9. What is the colour of the Phenolsulfonphthalein indicator at pH 7.0?
(a) red (b) violet (c) green (d) yellow
10. Why does the colour of [Fe(SCN)]2+ solution appear red?
(a) Complex add (b) Absorbs in the (c) absorbs in red (d) none
red radiation to green region region
solvent.
www.aoperho.com Lecturer preparation with Qasim mahi (03086403836)
11. What type of indicator is Chlorophenol Red
(a) redox indicator (b) acid-base (c) adsorption (d) none
indicator indicator
12. When do we use Buffer Solution?
(a) to make the (b) ) to make the (c) to prevent (d) none
solution basic solution acidic solution’s pH change
13. What type of method is the spectroscopic technique?
(a) instrumental (b) radioactive (c) gravimetric (d)titrimetric
methods methods method method
14. Na2CO3 cannot be used in place of (NH4)2CO3 for the precipitation
of V group because:
(a) Na+ interferes in (b) concentration of (c) sodium will react (d) Mg will be
the detection of carbonate anion is with acid radicals precipitated
group 5 very low
15. Which of the following is not a type of Spectroscopy
(a) gamma ray (b) X-ray (c) nuclear magnetic (d) sound
resonance
16. Hypsochromic shift is also called as
(a) blue shift (b) yellow shift (c) red shift (d) Violet shift
17. unit of wavelength is
(a) cm-1 (b) L-1 (c) mm-1 (d) none of
these
18. Bathochromic shift is also called as
(a) yellow shift (b) blue shift (c) Violet shift (d) none of
these
19. 10 angstrom is equal to
(a) 10-9 cm (b) 10-7 cm (c) 10-10cm (d) none of
these
20. which of the following are the detector of gas chromatography
(a) thermal (b) flame ionization (c) electron capture (d) all of these
conductivity detector detector detector
21. which one is not used in gas chromatography
(a) packed column (b) open tubular (c) capillary column (d) all of these
column
22. if analytical work has to be carried out in UV region cuvette must be made-
up of
(a) gelatin (b) glass (c) plastic (d) quartz
23. premix burner is also known as
(a) total (b) mecker burner (c) laminar flow (d) bunsen
www.aoperho.com Lecturer preparation with Qasim mahi (03086403836)
consumption burner burner burner
24. which one is the application of flame photometry
(a) to determine (b) to study (c) to estimate (d) all of these
functional group chemical structure metallic ions like
sodium potassium
magnesium
25. chopper is used in which instrument
(a) HPTLC (b) HPLC (c) single beam (d) none of
photometer these
26. which one is not used as carrier gas in gas chromatography
(a) carbon dioxide (b) hydrogen (c) helium (d) nitrogen
27. the source of radiation used in infrared spectroscopy
(a) Nernst glower (b) sodium lamp (c) deuterium (d) tungsten
discharge lamp lamp
28. in NMR which solvent is used as reference solvent
(a) water (b) ethanol (c) CMC (d) none of
these
29. Fermi resonance is often observed in
(a) polyatomic (b) monoatomic (c) halogenerated (d) none of
molecules molecules compounds these
30. Nernst equation is generally practiced in
(a) complexometric (b) polarimetry (c) potentiometry (d) none of
titration these
31. solo Chrome black indicator is used in which type of titration
(a) acid base (b) argentometric (c) gravimetric (d) none of
titration titration analysis these
32.which of the following is protogenic solvent
(a) sulfuric acid (b) acetic acid (c) both of these (d) none of
these
33. which of the following is amphiprotic solvent
(a) acetic acid (b) alcohol (c) both of these (d) none of
these
34.which of the following is protophilic solvent
(a) ammonia (b) pyridine (c) both (d) none
35.which of the following is polar aprotic solvent
(a) HF (b) Acetic acid (c) water (d)none of
these
36.which of the following is a polar protic solvent
(a) DCM (b) THF (c) acetonitrile (d) none of
www.aoperho.com Lecturer preparation with Qasim mahi (03086403836)
 these
37. in gas chromatography which detector is preferred for analysis of drug
containing halogens
(a) flame ionization (b) thermal (c) electron capture (d) none of
detector conductometric detector these
detector
38. normally graph plotted in IR spectroscopy
(a) %T vs frequency (b) absorbance (c) %T vs wave (d) none of
versus wavelength number these
39. IR spectroscopy is generally used to determine
(a) molecular (b) functional group (c) number of proton (d) all of these
structure
40. the most intense peak in mass spectrum is called
(a) mass peak (b) metastable peak (c) base peak (d) M + 1 peak
41. Nitrogen estimation is done by which of the following methods
(a) Kjeldahl method (b) gasometry (c) Karl Fisher (d) none of
these
42. analytical chemistry is based on
(a) identification (b) quantitative (c) separation (d) all of these
determination
43. to find out cation and anion present in salt is an example of
(a) qualitative (b) quantitative (c) volumetric (d) none of
analysis analysis analysis these
44. numerical difference between measured value and the true value is called
(a) error (b) accuracy (c) rounding off (d) none of
these
45. how many general types of sampling are there
(a) 2 (b) 3 (c) 4 (d) 5
46. if every 100th bottle is selected as sample, it is an example of
(a) random (b) non-random (c) symmetric (d) both b and
sampling sampling sampling c
47. the degree of agreement between measured value and the true value is
(a) precision (b) error (c) accuracy (d) none of
these
48. analytical chemistry plays vital role in……… branch of science
(a) chemistry (b) biochemistry (c) biology (d) all of these
49. Measurement which is close to the true value is called
(a) accurate (b) precise (c) average (d) error
50. if most probable reading of a titration is 10 ml and observed values are9.8,
www.aoperho.com Lecturer preparation with Qasim mahi (03086403836)
 9.9 and 9.8 ml, then accuracy and precision are……….. respectively
(a) low, low (b low, high (c) High, low (d) high, high
51. value of 9.834 should be round off to
(a) 9.83 (b) 9.835 (c) 9.8 (d) 9.834
52. titration is an example of……….. analysis
(a) volumetric (b) increment (c) subsample (d) none of
these
53. false statement regarding indeterminate error is
(a) these are (b) cause of error (c) cannot be (d) their
accidental errors cannot be avoided or corrected magnitude can
discovered be determined
exactly
54. which of the following is caused by poor calibration of the instrument
(a) random (b) gross (c) systematic (d) precision
55. which of the following error is caused by careless handling
(a) random (b) gross (c) systematic (d) none of
these
56. indeterminate errors are called
(a) random error (b) accidental error (c) personal error (d) both a and
b
57. if a pipette is not calibrated then it is example of
(a) accidental error (b) instrumental (c) random error (d) none of
error these
58. usually how many types of errors are present in scientific measurement
(a) 2 (b) 3 (c) 5 (d) none of
these
59. determinate error can be
(a) avoided (b) corrected (c) both of these (d) none of
these
60. which of the following is not operational error
(a) compound is not (b) unable to predict (c) solutions are not (d)incomplete
dissolved completely color change of transferred properly drying of
in solvent indicator sample
61. systematic error is due to
(a) overuse of (b) careless use of (c) both of these (d) none of
instrument instrument these
62. small portions taken from the bulk is known as
(a) gross (b) increment (c) sample (d) none of
these

www.aoperho.com Lecturer preparation with Qasim mahi (03086403836)

63. solvent extraction is a…….. analytical technique
(a) qualitative (b) quantitative (c) separating (d)identificatio
n
64.when the component has a small value of K, it is supposed to have an affinity
for
(a) mobile phase (b) stationary phase (c) both of these (d) none of
these
65. solvent extraction is based on the relative…..of two liquids.
(a) solubilities (b) texture (c) color (d) odour
66. Solvent extraction is more efficient when the extraction is repeated with
(a) extra solvent (b) large solvent (c) small solvent (d) no solvent
67. What is the color post extraction of iodine?
(a) blue (b) indigo (c) purple (d) red
68. what is the use of ether layer in solvent extraction
(a) to separate (b) inorganic (c) separate solvent (d) separate
organic impurities impurity separation fiber
69. which of the following technique is used when distribution ratio of the
solvent is large
(a) countercurrent (b) continuous (c) batch extraction (d) both A and
extraction extraction C
70. which of the following is universal solvent
(a) ether (b) alcohol (c) ammonia (d) none of
these
71. a mobile phase cannot be
(a) liquid (b) gas (c) solid (d) none of
these
72. which of the following are the types of solvent extraction techniques
(a) batch extraction (b) continuous (c) countercurrent (d) all of these
extraction extraction
73. column extraction method is used when distribution ratio is
(a) high (b) moderate (c) small (d) one
74. the process of removal of solute after extraction is called
(a) stripping (b) sampling (c) decantation (d) none of
these
75. usually one of the solvents used in solvent extraction is
(a) glue (b) inorganic solvent (c) organic solvent (d) viscous
solvent
76. the solvent is selected for the solvent extraction by considering
(a) solvent must be (b) solute must be (c) solvent must have (d) none of
www.aoperho.com Lecturer preparation with Qasim mahi (03086403836)
miscible in water readily recoverable a higher boiling these
from the solvent point
77. which of the following technique is used for the separation of insoluble
particles from liquid
(a) filtration (b) crystallization (c) chromatography (d) solvent
extraction
78. indicate the separation technique used to separate a mixture of two
immiscible liquids like oil and water
(a) filtration (b) decantation (c) hand sorting (d)centrifugati
on
79. branch of chemistry where the properties of materials are studied as
function of temperature is called
(a) spectroscopy (b) chromatography (c) thermal analysis (d) none of
these
80. in TGA graph straight line means
(a) compound is (b) compound get (c) compound is (d) none of
stable hydrolyzed unstable these
81. in TGA graphs steeper line mean
(a) compound is (b) compound is (c) both of these (d) none of
stable unstable these
82. which of the following is a type of planar chromatography
(a) paper (b) TLC (c) both of these (d) none of
chromatography these
83. which force is involved in chromatography
(a) hydrogen (b) electrostatic (c) London force (d) all of these
bonding force
84. chromatography is the process for identification purification and separation
of components of a mixture on the basis of
(a) difference in (b) difference in (c) difference in their (d) none of
their solubility their affinity for concentration of these
mobile and solution
stationary phase
85. which of the following is not a type of column chromatography
(a) liquid (b) gas (c) TLC (d)
chromatography chromatography supercritical
fluid
chromatograph
y
86. in which of the following type of paper chromatography does the mobile
phase move horizontally over a circular sheet of paper
www.aoperho.com Lecturer preparation with Qasim mahi (03086403836)
(a) radial paper (b) ascending paper (c) descending paper (d) none of
chromatography chromatography chromatography these
87. Gooch Crucible is made-up of
(a) porcelain (b) quartz (c) plastic (d) brass
88. estimation of sodium in seawater is an example of
(a) qualitative (b) quantitative (c) both of these (d) none of
analysis analysis these
89. the solid remained on filter paper during filtration is called
(a) substance (b) solute (c) filtrate (d) residue
90. the liquid obtained after passing the mixture through filter paper is termed
as
(a) extract (b) residue (c) filtrate (d) sample
91. Sintered crucible is made up of
(a) glass (b) plastic (c) bronze (d) porcelain
92. the solution left after the formation of crystals is called
(a) filtrate (b) residue (c) mother liquor (d) none of
these
93. which of the following cannot be used as adsorbent in column adsorption
chromatography
(a) magnesium (b) silica gel (c) activated alumina (d) potassium
oxide permanganate
94.which of the following type of chromatography involves the separation of
substance in a mixture over 0.2 millimeter thick layer of an adsorbent
(a) column (b) paper (c) TLC (d) none of
chromatography chromatography these
95. systematic error maybe
(a) additive (b) multiplicative (c) both of these (d) none of
these
96. UV spectroscopy can be used to distinguish
(a) conjugated and (b) carbonyl and (c) cis and trans (d) all of these
isolated diene alpha,beta isomer
unsaturated
carbonyl
compounds
97. an isolated functional group capable of absorbing UV radiation is called
(a) auxochrome (b) chromophore (c) oxidant (d) none of
these
98. Which of the following is not chromophore?
(a) -NO2 (b) -N=N- (c) -OH (d) -C=O

www.aoperho.com Lecturer preparation with Qasim mahi (03086403836)

99. which compound absorbs light with the longest wavelength
(a) 1,3,5,7 (b) 1,3,5 octatriene (c) 1,3-butadiene (d) 1,3,5-
octatetraene hexatriene
100. which compound shows the longest 𝝀𝒎𝒂𝒙 in the UV spectrum
(a) toluene (b) benzoic acid (c) styrene (d) p-vinyl
benzoic acid

www.aoperho.com Lecturer preparation with Qasim mahi (03086403836)