PRESI DENT’SOFFI CE

REGIONALADMI NISTRATOI NANDLOCALGOVERNMENT

FORM SI XPRE- MOCKJOI NTEXAMI NATI ONS
IRINGA, NJOMBEANDMBEYA
132/1 CHEMI STRY1
(ForBot hSchool andPr i
vateCandi dat es)
Time;
3Hour s Tuesday6thOct,2020
I
nst r
ucti
ons
1. Thi spaperconsi st sofsect ionsA, andBcompr isedofat otaloften(10)questi
ons.
2. Answerat otalofni ne(9)quest i
ons.Answeral lquestionsi nsectionAandchooset wo(2)
quest ionsf r
om sect i
onB.
3. Cel l
ul arphonesandanyunaut hor i
zedmat er
ial
sar enotal lowedint heexaminati
onroom.
4. Wr itey ourExami nat i
onNumberonev erypageofy ouranswersheet( s)/bookl
et(s)
5. Thi spaperconsi st sofsi x(6)pr i
ntedpages
6. Thef ol l
owingconst antmaybeused
-1 -
K1or8. -1 -
 Gasconst ant,R=0. 0821at mLmol 314JMol K1,
 Ry dber g’sconst ant,RH =1. 097x107m-1
 Vel oci t
yofl i
ght,c=3. 108m/ s
 Planck’ sconstant ,h=6. 63x10-34Js
R.M. M C=12, O=16, H=1

SECTI ONA( 70Mar ks)

Answersev
en( 7)questi
onsf r
om thi
ssecti
on
1. (
a) Nametheorbi
tal
sindiagramsrepresentedbylet
ter
sA,B,
C,D,
E,
F,
G,H,
Iand
Jbel
ow

(
04mar
ks)
(
b) ReferQn.1(E)above,
i
. Suggestt hree(3)dif
fer
enthybri
dizat
ioncanbeformed
ii
. Dr awandnamet hree(3)di
ff
erentgeometri
calst
ruct
urescor
respondi
ngi
n
1(
b)(
i)above
i
ii
. St atetheanglefor
medbet weenatomsin1(b)(
ii
)above.
Page1of1
 (
06mar
ks)
2. (
a) (
i) Def i
nehydrogenbond?
(
ii
) Tot hefoll
owingcompounds,giv
ingreason(s)t
oeachi dent
if
yandar range
-
them inorderofhydr
ogenbondingstrengt
h.Bif
luori
dei onHF2 ,Water(H2O)
,
-
Hy drogenfl
uori
de(HF),
Hydratedhydroxyl
ion(H3O2), and2nit
rophenol

(
3.5mar
ks)
(
b) Namet
het
ypesofbondsf
ormedi
nst
ruct
uresi
,i
i,
andi
ii
bel
ow;

i i
i

i
i
i
(
1.5mar
ks)

(
c) Drawdi
agr
amsofor
bit
alov
erl
apofthef
oll
owi
ngmolecul
es.
(i
)H2 (
ii
)HCl (i
i
i)Cl
2 (i
v)O2 (v)N2
(05marks)

3. (
a) Defi
net
hef ol
lowingterms
(i
) Tr ipl
epoi nt
(i
i
) Cr iti
caltemperature
(i
i
i) Criti
calpressure
(i
v) Criti
calvolume
(v
) Rel ativ
emol ecularmass
(
2.5mar
ks)
(
b) Stat
e
(i
) Boy l
e’slaw
(i
i
) Char l
e’slaw
(i
i
i) Dalt
on’slawstat
esthat
(i
v) Avogadro’sl
awstat
esthat
(
04mar ks)
(
c) Therel
ati
vev
apourdensi
tyofPCl
5at250is57.
6whatist
hepercent
ageof
di
ssoci
ati
onoft
hecompoundunderthesecondi
ti
ons.
Page2of2
 P=31g/
mol Cl
=35.
5g/
mol
(
3.5mar
ks)
4. (
a) (
i) Def i
necol ligativeproperties
(
ii
) Theosmot icpr essureofanaqueoussol uti
oncont ai
ns10gofBaCl 2perli
tr
e
is3. 2at m at15℃.Cal culatet hedegreeofdissoci
at i
onofBaCl
2.

(
04marks)
(
b) (i
) Ment ionthr ee( 3)conditionsf oraccuratemolecul
armassofasol ute
obtai nedusi ngt hecolli
gat i
v eproper
ties.
(i
i) Det ermi net hef reezi
ngpoi ntdepressionofmet hy
lalcoholi
nasoluti
onmade
bydi ssol ving18. 5gmet hyl al
cohol(CH3OH)in850gofwat er(
Kfforwater=
-
1
1.86℃kgmol )
(
06marks)
5. (
a) Withone( 01)v ividexampl e,definet hefoll
owingterms.
(i
) Anoxi de
(i
i) Met al oxide
(i
ii
) Basi coxi des
(i
v) Aci dicoxi des
(vi
) Amphot ericoxi des
(
06marks)
(
b) Usingequat ions, giveone( 01)exampl eofanoxidethatisprepar
edusingeachof
thefol
lowingmet hods.
(i
) Di rectmet hod.
(i
i) I ndirectmet hod.
(
01marks)
(
c) Completeandbal ancet hefoll
owi ngchemi calequati
ons
Heat
(
i) Na2CO3(
s)→
Heat
(
ii
) CaCO3(
s)→
Heat
(
ii
i) MgCO3(
s)→
Heat
(
iv) ZnCO3(
s)→
Heat
(
v) PbCO3(
s)→
Heat
(
vi) CuCO3(
s)→
(
03mar
ks)
6. (
a) Defi
net
hefol
lowingterms
(i
) Ent hal
py(heat)ofsolut
ion
(i
i
) Ent hal
py(heat)ofdi
luti
on
(i
i
i) Heatoftransi
ti
on
(i
v) Heatoffusion
(02marks)
(
b) Calcul
atetheenthalpyofr
eacti
onint
heproduct
ionofmet al
l
icironi
nthebl
ast
fur
nace;thefol
lowingareequati
onsf
orsever
alreact
ions.
g)→ 3Fe(
Fe3O4+4CO( s)+4CO2(
g) ∆Hθ=?
Page3of3
 i
) 3Fe(
s)+2O2(
g)→ Fe3O4(
s) ∆Hθ=-117.
13kJ/
mol
i
i
) s)+1O2(
C( g) ∆Hθ=-110.
g)→ CO( 65kJ/
mol
2
i
i
i) C(
s)+O2(
g)→ CO2(
g) ∆Hθ=-393.
50kJ/
mol
(
04mar
ks)
(
c) Dr
awbor n-
Habercycl
eusingthef
oll
owi
nginf
ormat
ion.
θ
∆Hf =-601.7kJ/mol
θ
∆HA.E,Mg =146kJ/mol
θ
∆H1 I.E=736kJ/
st mol
θ
∆H2 I.E=1448kJ/
nd mol
∆Hθ
A.E,O 2
=1D.E= 498.4 =249.
2kJ/mol
2 2
∆Hθ A=-
st
1 E. 141.
8kJ/mol
θ
∆H2 E.A
nd =+790.8kJ/mol
θ
∆HL.E =-3830.3kJ/mol
(
04mar
ks)
7. (
a) Defi
nethef ollowingt er ms;
(i
) Het er ogeneousequi li
brium
(i
i
) Homogeneousequi l
i
brium
(i
i
i) Dy nami cequi libri
um
(i
v) React ionquot i
ent
(
b) (i
) St atet wo( 2)appl i
cati
onsoft heequi
li
bri
um constant
(i
i
) Consi dert her eaction:N2O4 2NO2
Showt hatKp = Kc.RT
(05mar ks)
(
c) 0.
035mol esofSO2, 0. 500mol esofSO2Cl2,
and0.080mol esofCl2arecombi nedin
o
anevacuated5. 00Lf l
askandheat edto100C.Whati sQbef or
et hereact
ion
begi
ns?Whi chdi rectionwi llt
her eacti
onpr
oceedinordertoestabli
shequil
ibrium
gi
venthat,fort her eact i
on:
SO2Cl
2(g) SO2(g)+Cl 2(g), Kc=0.078at100oC
(03mar ks)

SECTIONB( 30Mar ks)

Answertwo(2)questi
onsfrom t
hissect
ion
8. (
a) Givingone(1)exampledefi
nethefoll
owing.
(i
) El ectrophi
les
(i
i) Nucl eophi
les
(i
ii) Fr eeradi
cal
(06mar
ks)
(
b) Listfi
ve(5)Pecul
iarpr
opert
iesofcar
bonat om t
hatenabl
eittofor
m suchan
extensi
verangeofcompounds:
(04mar
ks)

Page4of4
 (
c) Apr i
maryhaloalkaneAC4H9Brr eact
edwi t
hal cohol
i
cKOHt ogivecompoundB, B
reactedwit
hHy drogenBr omidetoform anisomerofA, (
C) .WhenAisr eact
edwith
sodium i
ndryetheritgaveacompoundpr oducedwhenBr omobutanewasr eact
ed
withsodium.Drawt hestructur
eofAandwr it
eequationsforall
react
ions.
(04marks)
9. (
a) (i
) Def i
neAromat i
cit
y
(i
i) Expl ainwhyi sBenzeneSoSt able?
(03marks)
(
b) GivetheIUPACnamesoft hefol
lowi
ngcompounds;

(
i) (
ii
)

(
ii
i) (
iv) (
v)

(
10mar
ks)

(
c) Compl
etet
hef
oll
owi
ngr
eact
ions

H2O
(
i) 2→
+Br

[O]
(
ii
) →

(
02mar
ks)

10. (
a) Defi
net
hefol
lowi
ng.
(i
) Wat erpoll
uti
on
(i
i
) Heav ymetals
(i
i
i) PCB
(i
v) DDT
(
04mar
ks)
(
b) (
i) Whati
saci
drai
n?
Page5of5
 (
ii
) Descr
ibet
wo( 2)rol
esofacidrai
ninenv i
ronmental
pollut
ion.
(
03mar ks)
(
c) (
i) Howi sozoneformedintheatmosphere?
(i
i) Gi
ving equat
ions, expl
ain how Chl orofl
uor
ocarbonsCFCs present
s i
n
at
mospherecausethedeplet
ionofozone.
(
08mar ks)

Page6of6