Sicherheitsdatenblatt

Safety data sheet

000924 Anti-Spatter / Antihaft - spray bottle / Sprühflasche 1 l

BERND SIEGMUND GMBH · LANDSBERGER STRASSE 180 · 86507 OBEROTTMARSHAUSEN · GERMANY

Page: 1

Compilation date: 29.11.2017

Revision date: 19.10.2018

Revision No: 1.1

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name: SIEGMUND ANTIHAFT

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of substance / mixture: PC35: Washing and cleaning products (including solvent based products). Silicone-free product.

1.3. Details of the supplier of the safety data sheet

Company name: Bernd Siegmund GmbH

Landsberger Straße 180

86507 Oberottmarshausen

Tel: (08203) 9607/0

Fax: (08203) 9607/33

Email: [email protected]

1.4. Emergency telephone number

Emergency tel: 089 / 19240

Section 2: Hazards identification

2.1. Classification of the substance or mixture

Classification under CLP: Eye Dam. 1: H318; -: EUH208

Most important adverse effects: Contains d-limonene. May produce an allergic reaction. Causes serious eye damage.

2.2. Label elements

Label elements:

Hazard statements: EUH208: Contains d-limonene. May produce an allergic reaction.

H318: Causes serious eye damage.

Hazard pictograms: GHS05: Corrosion

Signal words: Danger

Precautionary statements: P102: Keep out of reach of children.

P280: Wear protective gloves/protective clothing/eye protection/face protection.

P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present

and easy to do. Continue rinsing.

P310: Immediately call a POISON CENTER/doctor.

2.3. Other hazards

PBT: This product is not identified as a PBT/vPvB substance.

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Section 3: Composition/information on ingredients

3.2. Mixtures

Hazardous ingredients:

FETTALKOHOLALKOXYLAT (C10)

EINECS CAS PBT / WEL CLP Classification Percent

GELISTET 166736-08-9 - Acute Tox. 4: H302; Eye Dam. 1: H318 1-10%

2-(2-BUTOXYETHOXY)ETHANOL - REACH registered number(s): 01-2119475104-44-XXXX

203-961-6 112-34-5 - Eye Irrit. 2: H319 1-10%

D-LIMONENE

227-813-5 5989-27-5 - Flam. Liq. 3: H226; Skin Irrit. 2: H315; Skin Sens. <1%
1: H317; Aquatic Acute 1: H400; Aquatic Chronic
1: H410

Section 4: First aid measures

4.1. Description of first aid measures

Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Wash immediately with plenty of

soap and water.

Eye contact: Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist examination.

Ingestion: Wash out mouth with water. Do not induce vomiting. If conscious, give half a litre of water to drink immediately.

Consult a doctor.

Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so.

4.2. Most important symptoms and effects, both acute and delayed

Skin contact: There may be irritation and redness at the site of contact.

Eye contact: There may be pain and redness. The eyes may water profusely. There may be severe pain. The vision may

become blurred. May cause permanent damage.

Ingestion: There may be soreness and redness of the mouth and throat. Nausea and stomach pain may occur.

Inhalation: There may be irritation of the throat with a feeling of tightness in the chest.

Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

4.3. Indication of any immediate medical attention and special treatment needed

Immediate / special treatment: Eye bathing equipment should be available on the premises.

Section 5: Fire-fighting measures

5.1. Extinguishing media

Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers.

5.2. Special hazards arising from the substance or mixture

Exposure hazards: In combustion emits toxic fumes.

5.3. Advice for fire-fighters

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.

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Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions: Mark out the contaminated area with signs and prevent access to unauthorised personnel. Do not attempt to take

action without suitable protective clothing - see section 8 of SDS. Turn leaking containers leak-side up to prevent

the escape of liquid.

6.2. Environmental precautions

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.

6.3. Methods and material for containment and cleaning up

Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate

method.

6.4. Reference to other sections

Reference to other sections: Refer to section 8 of SDS.

Section 7: Handling and storage

7.1. Precautions for safe handling

Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Avoid the formation or

spread of mists in the air.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions: Store in a cool, well ventilated area. Keep container tightly closed.

Suitable packaging: Must only be kept in original packaging.

7.3. Specific end use(s)

Specific end use(s): No data available.

Section 8: Exposure controls/personal protection

8.1. Control parameters

Hazardous ingredients:

2-(2-BUTOXYETHOXY)ETHANOL

Workplace exposure limits: Respirable dust

State 8 hour TWA 15 min. STEL 8 hour TWA 15 min. STEL

UK 67.5 mg/m3 101.2 mg/m3 - -

DNEL/PNEC Values

DNEL / PNEC No data available.

8.2. Exposure controls

Engineering measures: Ensure there is sufficient ventilation of the area.

Respiratory protection: Self-contained breathing apparatus must be available in case of emergency.

Hand protection: Nitrile gloves.

Eye protection: Tightly fitting safety goggles. Ensure eye bath is to hand.

Skin protection: Protective clothing.

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Environmental: Refer to specific Member State legislation for requirements under Community environmental legislation.

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

State: Liquid

Colour: Blue

Odour: Characteristic odour

Evaporation rate: No data available.

Oxidising: No data available.

Solubility in water: No data available.

Viscosity: No data available.

Boiling point/range°C: >35 Melting point/range°C: No data available.

Flammability limits %: lower: No data available. upper: No data available.

Flash point°C: 60 - 93 Part.coeff. n-octanol/water: No data available.

Autoflammability°C: No data available. Vapour pressure: No data available.

Relative density: No data available. pH: 10-11

VOC g/l: No data available.

9.2. Other information

Other information: No data available.

Section 10: Stability and reactivity

10.1. Reactivity

Reactivity: Stable under recommended transport or storage conditions.

10.2. Chemical stability

Chemical stability: Stable under normal conditions.

10.3. Possibility of hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions. Decomposition may occur on

exposure to conditions or materials listed below.

10.4. Conditions to avoid

Conditions to avoid: Heat.

10.5. Incompatible materials

Materials to avoid: Strong oxidising agents. Strong acids.

10.6. Hazardous decomposition products

Haz. decomp. products: In combustion emits toxic fumes.

Section 11: Toxicological information

11.1. Information on toxicological effects

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Hazardous ingredients:

FETTALKOHOLALKOXYLAT (C10)

ORAL RAT LD50 300-2000 mg/kg

2-(2-BUTOXYETHOXY)ETHANOL

ORL MUS LD50 6050 mg/kg

ORL RAT LD50 4500 mg/kg

D-LIMONENE

ORL MUS LD50 5600 mg/kg

ORL RAT LD50 4400 mg/kg

SCU MUS LD50 3170 mg/kg

Toxicity values: No data available.

Symptoms / routes of exposure

Skin contact: There may be irritation and redness at the site of contact.

Eye contact: There may be pain and redness. The eyes may water profusely. There may be severe pain. The vision may

become blurred. May cause permanent damage.

Ingestion: There may be soreness and redness of the mouth and throat. Nausea and stomach pain may occur.

Inhalation: There may be irritation of the throat with a feeling of tightness in the chest.

Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

Other information: Not applicable.

Section 12: Ecological information

12.1. Toxicity

Hazardous ingredients:

FETTALKOHOLALKOXYLAT (C10)

Brachydanio rerio 96H LC50 >10-100 mg/l

Daphnia magna 48H EC50 >10-100 mg/l

12.2. Persistence and degradability

Persistence and degradability: The surfactants contained in the preparation comply with the legal regulations regarding biodegradability.

12.3. Bioaccumulative potential

Bioaccumulative potential: No data available.

12.4. Mobility in soil

Mobility: Soluble in water.

12.5. Results of PBT and vPvB assessment

PBT identification: This product is not identified as a PBT/vPvB substance.

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12.6. Other adverse effects

Other adverse effects: No data available.

Section 13: Disposal considerations

13.1. Waste treatment methods

Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company.

Recovery operations: Not applicable.

Disposal of packaging: Dispose of as normal industrial waste.

NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.

Section 14: Transport information

Transport class: This product does not require a classification for transport.

Section 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.2. Chemical Safety Assessment

Chemical safety assessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.

Section 16: Other information

Other information

Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 2015/830.

* indicates text in the SDS which has changed since the last revision.

Phrases used in s.2 and s.3: EUH208: Contains <name of sensitising substance>. May produce an allergic reaction.

H226: Flammable liquid and vapour.

H302: Harmful if swallowed.

H315: Causes skin irritation.

H317: May cause an allergic skin reaction.

H318: Causes serious eye damage.

H319: Causes serious eye irritation.

H400: Very toxic to aquatic life.

H410: Very toxic to aquatic life with long lasting effects.

Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a

guide. This company shall not be held liable for any damage resulting from handling or from contact with the above

product.

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