CHM 111 Lab 1 Fun With Dimensional Analysis Last Version
CHM 111 Lab 1 Fun With Dimensional Analysis Last Version
Objectives
Convert numbers from regular notation to scientific notation.
Perform calculations to the correct number of significant figures.
Perform calculations using numbers with SI units.
Convert between base units and units containing prefixes.
Perform calculations using dimensional analysis.
Become acclimated with common laboratory equipment
Introduction
Scientific Notation
Scientific notation is a way to express numbers. It is especially useful for numbers that are very large or
very small. In addition, it uses only significant figures, which is helpful for understanding error (see
below). In scientific notation, a number is presented containing two components: a coefficient and the
number 10 raised to a power. The coefficient contains a single nonzero number to the left of the decimal
space.1
As an example, consider the speed of light: 299,000,000 m/s. We would write this as 2.99 x 108 m/s in
scientific notation. The coefficient is 2.99 and must be a number greater than or equal to 1 and less than
10 (one non-zero number will be to the left of the decimal space). The power of 10 is raised to the
exponent 8 because you would have to multiply 2.99 by 108 to get the correct number. You can also think
about the 8 being from the number of spaces you moved the decimal space. There is an understood
decimal at the end of 299,000,000 that we need to move to the right of the number 2 (to allow only a
single digit to the left of the decimal). The seven is a positive integer because the number is very large.
2 9 9, 0 0 0, 0 0 0
0.000003
Alternatively 0.000003 m is also difficult to express without scientific notation. In order to convert this
number to we move the decimal to behind the 3 (the first nonzero number) and add the power of 10 (here
we moved the decimal 6 times so the exponent is -6) 3 x 10-6. Here the exponent is negative because
the number is very small (less than 1). Scientific notation is sometimes referred to as exponential
notation. 1
The following summary can be used as a guide for doing DA. While not all steps listed below will be
necessary to solve all problems, any problem can be solved using the following. Do not memorize the
sequence of steps, but rather complete practice until you understand how to solve these problems.
Dimensional analysis is a fundamental part of chemistry and will be applied all semester. It is imperative
you gain an understanding of how to perform calculations using dimensional analysis.
1. Determine what you want to know. Read the problem and identify what you're being asked to
figure out, e.g. "how many milliliters are in 1 liter of solution."
a. Find starting and ending units:
We are looking for mg in L which means we begin with L and end with mL. You may
want to draw out the step(s) you will need for this conversion.
L mL
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2. Determine what you already know.
a. What are you given by the problem, if anything? Example we know we have 1 liter of
solution.
b. Determine conversion factors that may be needed and write them in a form you can use,
such as "60 min/1 hour."
Here we would need 1 L = 1000 mL Which we can write as a fraction
1L or 1000 mL
1000 mL 1L
4. Solve: Make sure all the units other than the answer units cancel out, and then do the math.
a. Simplify the numbers by cancellation.
b. Multiply all the top numbers together, then divide into that number all the bottom numbers.
c. Double check to make sure you didn't press a wrong calculator key by dividing the first top
number by the first bottom number, alternating until finished, then comparing the answer to
the first one. Miskeying is a significant source of error, so always double check.
d. Round off the calculated answer. Make sure you use the appropriate number of significant
figures.
e. Add labels (the answer unit) to the appropriately rounded number to get your answer.
Compare units in answer to answer units recorded from first step.
1L 1000 mL 1000 mL
1L
5. Take a few seconds and ask yourself if the answer you came up with makes sense. If it
doesn't, start over. 3
A helpful way to check rules 3 & 4 is to write the number in scientific notation. If you can/must get
rid of the zeros, then they are NOT significant.
Examples: How many significant figures are present in the following numbers?
NUMBER # SIGNIFICANT FIGURES RULE(S)
48,923 5 1
3,967 4 1
900.06 5 1, 2, 4
0.0004 (=4 E-4) 1 1, 4
8.1000 5 1, 3
501.040 6 1, 2, 3, 4
3,000,000 (=3 E+6) 1 1
10.0 (=1.00 E+1) 3 1, 3, 4
Mega
kilo
hecto Base Unit = meter, liter, or gram
deka
BASE UNIT
deci
centi
mili
SIZE OF UNIT
micro
nano
DIRECTION OF DECIMAL
Factors of ten 6 3 2 1 0 -1 -2 -3 -6 -9
(no. of decimal
places)
Conversion Examples:
1 kilometer = 1000 meters (decimal moved 3 places to the right)
10 liters = 10 000 mililiters (decimal moved 3 places to the right)
2.5 centimeters = 0.025 meters (decimal moved 2 places to the left)
1 microgram = 1000 nanograms (decimal moved 3 places to the right)
5 meters = 5 000 000 000 nanometers (decimal moved 9 places to the right)
hecto h 1 00 102
deka da 10 101
meter m 1 100
The Basic
liter L 1 Metric 100
Units
gram g 1 100
deci d 0.1 10 -1
centi c 0.01 10 -2
milli m 0.001 10 -3
Wear safety goggles at any time any group is performing the experiment.
Inspect all equipment for damage. Broken or chipped glassware should be reported and placed into
glass container.
The balance should be in the lock position during transport. When ready to use unlock the balance
by turning it over and finding the switch. Use the balance in the unlocked position when weighing.
At the end of the lab switch it back to the lock position and return to the cart.
Waste water for today’s lab can be disposed of down the drain at your station.
Return all trays with in order with clean, dry glassware and items and place on cart.
Please, please return all # materials to the proper # drawers and # trays.
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Name ____________________________________________ Date ________________
Lab Partner Name___________________________________ Bin #________________
Pre-lab Assignment/Questions
N o t e – this pre-lab must be finished before you come to lab.
1. Length Meter
2. Mass kg
3. Volume L
4. Temperature Kelvin
5. Second s
Fill in the blanks on the following table giving commonly used conversion factors:
1. Obtain a thermometer and record the temperature of the room to the correct number of
significant figures.
____________________________________
Use a ruler from your drawer to determine the dimensions of a 250 mL beaker. Make sure you
use the appropriate number of significant figures. You must show all calculations and units for
full credit.
5. Why does the beaker capacity exceed the volume printed on the side?
6. Compare the graduated cylinder to the beaker. Which will make the more accurate
measurement? Why?
7. Obtain a 50 mL beaker and fill to the 30.0 mL mark using DI water. Make sure you remember
to read from the bottom of your meniscus line. Pour this entire amount into your 50 mL
graduated cylinder. Read the volume again (using your meniscus). Do not pour out.
8. Using the balance, place a weight boat on the balance and tare or zero. Add the paperclip and
record the weight in grams.
__________________________.
9. Again place the weight boat on the balance and tare. Obtain a pipet bulb from your drawer.
Using the DI water from your graduated cylinder and a pipet, draw 1mL of DI water by rolling
the wheel allowing the water to fill to the mark. Transfer the entire contents of the pipet to the
weight boat to determine the mass.
9. Convert 25 cm to mm.
PostLab Questions
13. Convert 2.5 yards to inches. (Remember, there are 3 feet in 1 yard.)
14. Convert 1.2 years into hours. (Remember, there are 365 days in 1 year.)
18. An average human lives to be 70 years old. How many seconds would have elapsed during
this person’s lifetime?
19. The usual aspirin tablet contains 5.00 grains of aspirin. How many mg of aspirin are in one
tablet? (Remember 1 grain = 1.43x10-4 lb, 1 lb = 454 g.)
20. How many 3 oz oranges would you need to eat to meet the U.S. recommended daily
allowance of 60.0 mg of vitamin C, if there are 70 mg of vitamin C for every 100 g of orange?
(Remember, 16 oz = 454 g.)*