Material Safety Data Sheet

Section 1. Chemical Product and Company Identification

Common Name TB1282B Code 1214-09-01
MSDS# 3-TB-20-0321
Supplier Three Bond International
6184 Shumacher Park Drive Validation Date 1/9/2003
West Chester, OH 45069
Print Date 1/9/2003
Synonym Not available.

Trade name TB1282B Responsible Name Company

Material Uses Industrial applications: One component silicone rubber compound.

In Case of Monday-Friday, 830-500pm,
Emergency 5 1 3 - 7 7 9 - 7 3 0 0 E S T . O R
Manufacturer ThreeBond Co., Ltd. 800-424-9300 - 24 hours

Section 2. Composition, Information on Ingredients

Name CAS # % by Weight Exposure Limits

1) Carbon Black 1333-86-4 10-20 TWA: 3.5 (mg/m3) from ACGIH (TLV) [United States]
TWA: 3.5 (mg/m3) from OSHA (PEL) [United States]
2) Toluene 108-88-3 1-4 TWA: 50 (ppm) from ACGIH (TLV) [United States]
TWA: 188 (mg/m3) from ACGIH (TLV) [United States]
TWA: 100 (ppm) from NIOSH
3) Acetone, a decomposition product. 67-64-1 TWA: 500 (ppm) from ACGIH (TLV) [United States]
TWA: 1188 (mg/m3) from ACGIH (TLV) [United States]

Section 3. Hazards Identification

Physical State and Solid. (Black Paste)
Appearance

Emergency Overview CAUTION!

Reacts with air, moisture or water; slowly generating acetone vapors. Acetone is flammable. Acetone is
formed upon contact with water or humid air. Overexposure to vapors may cause drowsiness, and harmful
to liver and blood. May irritate eyes, nose and throat.
After handling, always wash hands thoroughly with soap and water.
Routes of Entry Eye contact. Inhalation (acetone, toluene). Ingestion.

Potential Acute Health Effects

Eyes Eye contact with uncured product or its vapors may cause slight irritation.

Skin On direct skin contact, unhardened product may cause minor irritation. Repeated or prolonged contact may
cause skin senzitization.
Inhalation Overexposure to vapors may irritate eyes, nose and throat. It may cause headache and dizziness.

Ingestion Ingestion of large amount of uncured silicone compound may cause gastrointestinal irritation.

Potential Chronic Health Prolonged exposure to toluene vapors may lead to damage to many organ systems having effects on:
Effects central and peripheral nervous systems, vision, hearing, liver, kidneys, heart and blood.Prolonged exposure
to toluene has been associated with temporal changes in personality and memory. Animal studies with
toluene have shown: mild, reversible liver effects, cardiac sensitization, respiratory track damage (nose,
throat and airways), effects on hearing, and central nervous system damage.
Medical Conditions Preexisting eye and skin disorders may be aggravated by exposure to this product.
Aggravated by
Overexposure:

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Overexposure Headache, drowsiness, and general CNS (central nervous system) depression effects.
/Signs/Symptoms
See Toxicological Information (section 11)

Section 4. First Aid Measures

Eye Contact Flush with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.

Skin Contact In case of contact, immediately wash skin with plenty of water and mild soap. Remove any contaminated
clothing and shoes. Wash clothing before reuse.
Inhalation If exposed to concentrated vapors, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen and get medical attention.
Ingestion This material is for industrial use only. Ingestion is unlikely. However, if ingested, obtain emergency medical
attention.
Notes to Physician Treat according to person's condition and specifics of exposure.

Section 5. Fire Fighting Measures

Flammability of the Product May be combustible at high temperature.

Auto-Ignition Temperature Not available.

Flash Points Not applicable for solid.

Flammable Limits Not available.

Products of Combustion These products are carbon oxides (CO, CO2). Some metallic oxides, nitrogen oxides (NO, NO2, NOx...),
Silicon oxides, and Formaldehyde.

Fire Hazards in Presence of Slightly flammable to flammable in presence of open flames and sparks.
Various Substances

Explosion Hazards in None known.

Presence of Various
Substances
Fire Fighting Media SMALL FIRE: Use DRY chemical powder.
and Instructions LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Protective Clothing (Fire)
Vapor respirator or a self contained breathing apparatus.

Special Remarks on Fire When burned, hazardous products of combustion include carbon monoxide/dioxide, silicon compounds and
Hazards formaldehyde.

Special Remarks on Container explosion may occur under fire conditions. (Toluene)
Explosion Hazards

Section 6. Accidental Release Measures

Small Spill and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal container.
Disposal of collected material, residues, and cleanup materials may be governmentally regulated. Observe
all applicable local, state, and federal waste management regulations.
Large Spill and Leak Use a shovel to put the material into a convenient waste disposal container. Dispose per regulatory
requirements. See Section 8 for personal protective equipment for spills.

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Section 7. Handling and Storage

Handling Use with adequate ventilation. In case of insufficient ventilation, wear suitable respiratory equipment.
Product will produce acetone once package is opened in open air.
Storage Keep container tightly closed. Keep in a cool, dry, well-ventilated location. Store away from extreme heat.

Section 8. Exposure Controls, Personal Protection

Engineering Controls Use only in well ventilated areas. Local exhaust is recommended for bulk repackaging or continous large
quantity use.
Personal Protection
Eyes Safety glasses.

Body Clothing coveralls recommended.

Respiratory Wear appropriate respirator when ventilation is inadequate.

Hands Gloves (impervious).

Feet Chemical resistant shoes.

Protective Clothing
(Pictograms)

Personal Protection in Case Goggles. Organic vapor respirator. Boots. Gloves. Clothing coverall recommended.
of a Large Spill

Product Name Exposure Limits

1) Carbon Black TWA: 3.5 (mg/m 3) from ACGIH (TLV) [United States]
TWA: 3.5 (mg/m 3) from OSHA (PEL) [United States]
2) Toluene TWA: 50 (ppm) from ACGIH (TLV) [United States]
TWA: 188 (mg/m 3) from ACGIH (TLV) [United States]
TWA: 100 (ppm) from NIOSH
3) Acetone TWA: 500 (ppm) from ACGIH (TLV) [United States]
TWA: 1188 (mg/m 3) from ACGIH (TLV) [United States]
Consult local authorities for acceptable exposure limits.

Section 9. Physical and Chemical Properties

Physical State and Solid. (Black Paste) Odor Acetone odor.
Appearance

Molecular Weight Not applicable. Taste Not available.

Color Black
Molecular Formula Not applicable.

pH (1% Soln/Water) Not applicable.

Boiling/Condensation Point Not available.

Melting/Freezing Point Not available.

Critical Temperature Not available.

Specific Gravity 1.07 (Water = 1)

Vapor Pressure Not applicable.

Vapor Density >1 (Air = 1)

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Volatility Not available.

Odor Threshold Not available.

Evaporation Rate <1

VOC Not available.

Viscosity Not available.

LogKow Not available.

Ionicity (in Water) Not available.

Dispersion Properties Is not dispersed in water.

Solubility Insoluble in water.

Physical Chemical Comments Not available.

Section 10. Stability and Reactivity

Stability and Reactivity The product is stable.

Conditions of Instability Reacts with water or moisture to create acetone.

Incompatibility with Various Reactive or incompatible with moisture or water.

Substances Reactive with oxidizing agents.

Hazardous Decomposition When burned, hazardous products of combustion include carbon monoxide/dioxide, silicon compounds and
Products formaldehyde.

Hazardous Polymerization Will not occur.

Section 11. Toxicological Information

Toxicity to Animals Acute oral toxicity (LD50): 50 mg/kg [Human/30 min]. (Toluene).

Chronic Effects on Humans The chronic toxicity of this substance is not fully known. Possible chronic effects based on raw materials
contained in this product:
Carbon Black as an inhalable airborne dust or powder particle is classified as a proven carcinogen by
NIOSH. By IARC, Carbon Black an inhalable dust or powder particle is classified 2A (Probable carcinogen
for humans). By ACGIH, Carbon Black an inhalable dust or powder particle is classified A4 (Not classified
carcinogen for humans or animals).

Toluene is not classified as a carcinogen, by EPA (D), ACGIH (A4), and IARC (3). Toluene is classified an
an experimental teratogen, meaning that some data suggests it is a human reproductive mutagen.
Other Toxic Effects on None.
Humans

Special Remarks on Toxicity

to Animals

Special Remarks on Chronic Carbon Black: as an airborne inhalation dust or powder is listed as both possibly carcinogenic to
Effects on Humans carcinogenic in humans.
Exposure to Carbon Black as aiborne dust is unlikely in the TB1282B because the carbon black particle is
suspended as a wetted out, solid filler in the uncured product, and it is fully contained within the polymer
matrix
Special Remarks on Other No additional remark.
Toxic Effects on Humans

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Section 12. Ecological Information

Ecotoxicity Not available.

BOD5 and COD Not available.

Biodegradable/OECD Not available.

Mobility Not available.

Products of Degradation Not available.

Toxicity of the Products of None known.

Biodegradation

Special Remarks on the Not available.

Products of Biodegradation

Section 13. Disposal Considerations

Waste Information Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Waste Stream Not available.

Consult your local or regional authorities.

Section 14. Transport Information

DOT Classification Not a DOT controlled material (United States).

Not regulated.

Marine Pollutant Not available.

Special Provisions for Not applicable.

Transport
ADR/RID Classification Not controlled under ADR (Europe).

IMO/IMDG Classification Not controlled under IMDG.

ICAO/IATA Classification Not controlled under IATA.

Section 15. Regulatory Information

HCS Classification Class: Contains material which can cause cancer.
Class: Target organ effects.
U.S. Federal Regulations TSCA 8(b) inventory: All ingredients are on TSCA.
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: Toluene
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: Toluene: fire, immediate health
hazard, delayed health hazard
SARA 313 toxic chemical notification and release reporting: Toluene 2.2%
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean air act (CAA) 112 accidental release prevention: No products were found.
Clean air act (CAA) 112 regulated flammable substances: Toluene; Acetone

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Clean air act (CAA) 112 regulated toxic substances: No products were found.

International Regulations
EINECS Not available.

DSCL (EEC) R41- Risk of serious damage to eyes.

R45- May cause cancer.

International Lists Australia: Acetone

Japan (MITI): Acetone

State Regulations No products were found.
California prop. 65: This product contains the following ingredients for which the State of California has found
to cause birth defects which would require a warning under the statute: Toluene

Section 16. Other Information

Label Requirements Reacts with air, moisture or water; slowly generating acetone vapors. Acetone is flammable. Acetone is
formed upon contact with water or humid air. Overexposure to vapors may cause drowsiness, and harmful
to liver and blood. May irritate eyes, nose and throat.

Hazardous Material Health * 2 National Fire Fire Hazard

Information System Fire Hazard 1 Protection 1
(U.S.A.) Association (U.S.A.) Health
2 2 Reactivity
Reactivity 2
Specific Hazard
Personal Protection C

References Today's revision is No.1.3.It supercedes Rev 1.2 on 6/25/02. Rev. 1.2 superceded Rev.1.1 of 09/14/2001. Section
14 & 11 revised.

Other Special Exposure to air or moisture causes curing and acetone vapors are formed gradually.
Considerations

Validated by Company on 1/9/2003. Verified by Company.

Printed 1/9/2003.

Monday-Friday, 830-500pm, 513-779-7300 EST. OR 800-424-9300 - 24 hours

Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its
subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be
used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.