Assignment -

Chemical Equilibrium

SUBSCRIBE
 Level 1

SUBSCRIBE
 The standard Gibbs energy change at 300 K for the
reaction,
2A ⇌ B + C is 2494.2 J. At a given time, the composition of
the reaction mixture is [A] = ½ , [B] = 2 and [C] = ½ . The
reaction proceeds in the : [ R = 8.314 J K mol-1, e = 2.718 ]

A forward direction because Q > KC

B reverse direction because Q > KC

C forward direction because Q < KC

D reverse direction because Q < KC

SUBSCRIBE
 The standard Gibbs energy change at 300 K for the
reaction,
2A ⇌ B + C is 2494.2 J. At a given time, the composition of
the reaction mixture is [A] = ½ , [B] = 2 and [C] = ½ . The
reaction proceeds in the : [ R = 8.314 J K mol-1, e = 2.718 ]

A forward direction because Q > KC

B reverse direction because Q > KC

C forward direction because Q < KC

D reverse direction because Q < KC

SUBSCRIBE
 Solution:

SUBSCRIBE
 The ratio Kp / KC for the reaction,
CO(g) + ½ O2(g) ⇌ CO2(g) is :

A 1 / √(RT)

B (RT)½

C RT

D 1

SUBSCRIBE
 The ratio Kp / KC for the reaction,
CO(g) + ½ O2(g) ⇌ CO2(g) is :

A 1 / √(RT)

B (RT)½

C RT

D 1

SUBSCRIBE
 Solution:

SUBSCRIBE
 N2(g) + 3H2(g) ⇌ 2 NH3(g) , K1 … (i)
N2(g) + O2(g) ⇌ 2 NO(g) , K2 … (ii)
H2(g) + ½ O2(g) ⇌ H2O(g) , K3 …(iii)
The equation for the equilibrium constant of the reaction
2NH3(g) + 5/2 O2(g) ⇌ 2NO(g) + 3H2O(g) , K4 ; in terms of K1 , K2 and K3 is:

A K1K2 / K3

B K1K32 / K2

C K1K2K3

D K2K33 / K1

SUBSCRIBE
 N2(g) + 3H2(g) ⇌ 2 NH3(g) , K1 … (i)
N2(g) + O2(g) ⇌ 2 NO(g) , K2 … (ii)
H2(g) + ½ O2(g) ⇌ H2O(g) , K3 …(iii)
The equation for the equilibrium constant of the reaction
2NH3(g) + 5/2 O2(g) ⇌ 2NO(g) + 3H2O(g) , K4 ; in terms of K1 , K2 and K3 is:

A K1K2 / K3

B K1K32 / K2

C K1K2K3

D K2K33 / K1

SUBSCRIBE
 Solution:

SUBSCRIBE
 For the reaction, N2O4(g) ⇌ 2NO2(g) the degree of
dissociation at equilibrium is 0.2 at 1 atm pressure. The
equilibrium constant, Kp will be :

A 1/2

B 1/4

C 1/6

D 1/8

SUBSCRIBE
 For the reaction, N2O4(g) ⇌ 2NO2(g) the degree of
dissociation at equilibrium is 0.2 at 1 atm pressure. The
equilibrium constant, Kp will be :

A 1/2

B 1/4

C 1/6

D 1/8

SUBSCRIBE
 Solution:

SUBSCRIBE
 On increasing the pressure, in which direction will the gas phase
reaction proceed to re-establish equilibrium, is predicted by
applying the Le-Chatelier’s principle. Consider the reaction :
N2(g) + 3H2(g) ⇌ 2NH3(g)
Which of the following is correct, if the total pressure at which the
equilibrium is established, is increased without changing the
temperature?

A K will remain same B K will decrease

C K will increase D K will increase initially

and decrease when
pressure is very high

SUBSCRIBE
 On increasing the pressure, in which direction will the gas phase
reaction proceed to re-establish equilibrium, is predicted by
applying the Le-Chatelier’s principle. Consider the reaction :
N2(g) + 3H2(g) ⇌ 2NH3(g)
Which of the following is correct, if the total pressure at which the
equilibrium is established, is increased without changing the
temperature?

A K will remain same B K will decrease

C K will increase D K will increase initially

and decrease when
pressure is very high

SUBSCRIBE
 Solution:

In the reaction, N2(g) + 3H2(g) ⇌ 2NH3(g) If the total

pressure at which the equilibrium is established, is
increased without changing the temperature, K will
remain same. K changes only with change in
temperature.

SUBSCRIBE
 For the following equilibrium, N2O4 ⇌ 2NO2 in gaseous
phase, NO2 is 50% of the total volume when equilibrium is
set up. Hence, percent of dissociation of N2O4 is :

A 50%

B 25%

C 66.66%

D 33.33%

SUBSCRIBE
 For the following equilibrium, N2O4 ⇌ 2NO2 in gaseous
phase, NO2 is 50% of the total volume when equilibrium is
set up. Hence, percent of dissociation of N2O4 is :

A 50%

B 25%

C 66.66%

D 33.33%

SUBSCRIBE
 Solution:

SUBSCRIBE
 XY2 dissociates as XY2(g) ⇌ XY(g) + Y(g) . When the initial
pressure of XY2 is 600 mm Hg, the total equilibrium
pressure is 800 mm Hg. Calculate K for the reaction
assuming that the volume of the system remains
unchanged

A 50

B 100

C 166.6

D 400.0

SUBSCRIBE
 XY2 dissociates as XY2(g) ⇌ XY(g) + Y(g) . When the initial
pressure of XY2 is 600 mm Hg, the total equilibrium
pressure is 800 mm Hg. Calculate K for the reaction
assuming that the volume of the system remains
unchanged

A 50

B 100

C 166.6

D 400.0

SUBSCRIBE
 Solution:

SUBSCRIBE
 In reaction A + 2B ⇌ 2C + D , initial concentration of B was 1.5 times
of [A], but at equilibrium the concentrations of A and B became
equal. The equilibrium constant for the reaction is :

A 8

B 4

C 12

D 6

SUBSCRIBE
 In reaction A + 2B ⇌ 2C + D , initial concentration of B was 1.5 times
of [A], but at equilibrium the concentrations of A and B became
equal. The equilibrium constant for the reaction is :

A 8

B 4

C 12

D 6

SUBSCRIBE
 Solution:

SUBSCRIBE
 At 600°C, Kp for the following reaction is 1 atm,
X(g) ⇌ Y(g) + Z(g)
at equilibrium, 50%, of X(g) is dissociated. The total
pressure of the equilibrium system is p atm. What is the
partial pressure (in atm) of X (g) at equilibrium?

A 1

B 4

C 2

D 0.5

SUBSCRIBE
 At 600°C, Kp for the following reaction is 1 atm,
X(g) ⇌ Y(g) + Z(g)
at equilibrium, 50%, of X(g) is dissociated. The total
pressure of the equilibrium system is p atm. What is the
partial pressure (in atm) of X (g) at equilibrium?

A 1

B 4

C 2

D 0.5

SUBSCRIBE
 Solution:

SUBSCRIBE
 Consider the reaction equilibrium,
2SO2(g) + O2(g) ⇌ 2SO3(g) ; ∆H° = –198 kJ

On the basis of Le-Chatelier’s principle, the condition favourable for

the forward reaction is :

A lowering of temperature as well as pressure

B increasing of temperature as well as pressure

C lowering the temperature and increasing the pressure

D any value of temperature and pressure

SUBSCRIBE
 Consider the reaction equilibrium,
2SO2(g) + O2(g) ⇌ 2SO3(g) ; ∆H° = –198 kJ

On the basis of Le-Chatelier’s principle, the condition favourable for

the forward reaction is :

A lowering of temperature as well as pressure

B increasing of temperature as well as pressure

C lowering the temperature and increasing the pressure

D any value of temperature and pressure

SUBSCRIBE
 Solution:

∆ng = – ve ; Reaction takes place with decrease in

number of moles or pressure; hence increase in
pressure shifts the equilibrium in forward side.
∆H°=– ve ; Reaction takes place with evolution of heat
or increase in temperature, hence decrease in
temperature shifts the equilibrium in forward side

SUBSCRIBE
 At 77°C and one atmospheric pressure, N2O4 is 70%
dissociated into NO2 . What will be the volume occupied by
the mixture under these conditions if we start with 10g of
N2O4?

A 6.32 L

B 5.32 L

C 6.38 L

D 5.38 L

SUBSCRIBE
 At 77°C and one atmospheric pressure, N2O4 is 70%
dissociated into NO2 . What will be the volume occupied by
the mixture under these conditions if we start with 10g of
N2O4?

A 6.32 L

B 5.32 L

C 6.38 L

D 5.38 L

SUBSCRIBE
 Solution:

SUBSCRIBE
 An aqueous solution contains 0.10 M H2S and 0.20 M
HCl. If the equilibrium constants for the formation of
HS- from H2S is 1.0 × 10-7 and that of S2- fromHS- ions is
1.2 × 10-13 , then the concentration of S2- ions in
aqueous solution is :

A 5 × 10-8

B 3 × 10-20

C 6 × 10-21

D 5 × 10-19

SUBSCRIBE
 An aqueous solution contains 0.10 M H2S and 0.20 M
HCl. If the equilibrium constants for the formation of
HS- from H2S is 1.0 × 10-7 and that of S2- fromHS- ions is
1.2 × 10-13 , then the concentration of S2- ions in
aqueous solution is :

A 5 × 10-8

B 3 × 10-20

C 6 × 10-21

D 5 × 10-19

SUBSCRIBE
 Solution:

SUBSCRIBE
 The equilibrium constant at 298 K for a reaction,
A + B ⇌ C + D is 100. If the initial concentrations of all the
four species were 1 M each, then equilibrium
concentration of D (in mol L -1 ) will be :

A 0.818

B 1.818

C 1.182

D 0.182

SUBSCRIBE
 The equilibrium constant at 298 K for a reaction,
A + B ⇌ C + D is 100. If the initial concentrations of all the
four species were 1 M each, then equilibrium
concentration of D (in mol L -1 ) will be :

A 0.818

B 1.818

C 1.182

D 0.182

SUBSCRIBE
 Solution:

SUBSCRIBE
 For the reaction, SO2(g) + ½ O2(g) ⇌ SO3 (g ),
if Kp = KC (RT)x , where, the symbols have usual
meaning, then the value of x is (assuming ideality)

A -1

B -½

C 1/2

D 1

SUBSCRIBE
 For the reaction, SO2(g) + ½ O2(g) ⇌ SO3 (g ),
if Kp = KC (RT)x , where, the symbols have usual
meaning, then the value of x is (assuming ideality)

A -1

B -½

C 1/2

D 1

SUBSCRIBE
 Solution:

SUBSCRIBE
 Consider the following equilibrium in a closed
container N2O4(g) ⇌ 2NO2(g) . At a fixed temperature,
the volume of the reaction container is halved. For
this change, which of the following statements hold
true regarding the equilibrium constant (KP) and
degree of dissociation (α) ?

A Neither Kp nor α changes

B Both Kp and α change

C Kp changes but α does not change

D Kp does not change but α change

SUBSCRIBE
 Consider the following equilibrium in a closed
container N2O4(g) ⇌ 2NO2(g) . At a fixed temperature,
the volume of the reaction container is halved. For
this change, which of the following statements hold
true regarding the equilibrium constant (KP) and
degree of dissociation (α) ?

A Neither Kp nor α changes

B Both Kp and α change

C Kp changes but α does not change

D Kp does not change but α change

SUBSCRIBE
 Solution:

SUBSCRIBE
 When two reactants, A and B are mixed to give
products, C and D, the reaction quotient, (Q ) at the
initial stages of the reaction :

A Is zero

B decreases with time

C is independent of time

D increases with time

SUBSCRIBE
 When two reactants, A and B are mixed to give
products, C and D, the reaction quotient, (Q ) at the
initial stages of the reaction :

A Is zero

B decreases with time

C is independent of time

D increases with time

SUBSCRIBE
 Solution:

SUBSCRIBE
 A reversible chemical reaction is having two reactants
in equilibrium. If the concentration of the reactants are
doubled then the equilibrium constant will :

A be doubled

B become one fourth

C be halved

D remain the same

SUBSCRIBE
 A reversible chemical reaction is having two reactants
in equilibrium. If the concentration of the reactants are
doubled then the equilibrium constant will :

A be doubled

B become one fourth

C be halved

D remain the same

SUBSCRIBE
 Solution:

Equilibrium constant depends only upon the

temperature, not upon the concentration of reactant.
Thus, on doubling concentration, equilibrium constant
remains the same

SUBSCRIBE
 At certain temperature and a total pressure of 10 Pa 5 ,
iodine vapours contains 40% by volume of iodine
atoms. Kp for the equilibrium I2 (g) ⇌ 2I (g) will be :

A 0.67

B 1.5

C 2.67 × 104

D 9.0 × 104

SUBSCRIBE
 At certain temperature and a total pressure of 10 Pa 5 ,
iodine vapours contains 40% by volume of iodine
atoms. Kp for the equilibrium I2 (g) ⇌ 2I (g) will be :

A 0.67

B 1.5

C 2.67 × 104

D 9.0 × 104

SUBSCRIBE
 Solution:

SUBSCRIBE
 A vessel at 1000 K contains CO2 with a pressure of 0.5
atm. Some of the CO2 is converted into CO on the
addition of graphite. If the total pressure at
equilibrium is 0.8 atm, the value of Kp is :

A 1.8 atm

B 3 atm

C 0.3 atm

D 0.18 atm

SUBSCRIBE
 A vessel at 1000 K contains CO2 with a pressure of 0.5
atm. Some of the CO2 is converted into CO on the
addition of graphite. If the total pressure at
equilibrium is 0.8 atm, the value of Kp is :

A 1.8 atm

B 3 atm

C 0.3 atm

D 0.18 atm

SUBSCRIBE
 Solution:

SUBSCRIBE
 The equilibrium constant for the reaction,
H2(g) + I2 (g) ⇌ 2HI(g) is 64. If the volume of the
container is reduced to half of the original volume, the
value of the equilibrium constant will be :

A 16

B 32

C 64

D 128

SUBSCRIBE
 The equilibrium constant for the reaction,
H2(g) + I2 (g) ⇌ 2HI(g) is 64. If the volume of the
container is reduced to half of the original volume, the
value of the equilibrium constant will be :

A 16

B 32

C 64

D 128

SUBSCRIBE
 Solution:

SUBSCRIBE
 Assertion (A) : The equilibrium constant for a reaction having positive
ΔH° increases with increase of temperature.
Reason (R) : The temperature dependence of the equilibrium constant
is related to ΔS° and ΔH° for the reaction.

A Both A and R are true and R is the true explanation of A

B Both A and R are true but R is not the true explanation of A

C A is true but R is true

D Both A and R are false

SUBSCRIBE
 Assertion (A) : The equilibrium constant for a reaction having positive
ΔH° increases with increase of temperature.
Reason (R) : The temperature dependence of the equilibrium constant
is related to ΔS° and ΔH° for the reaction.

A Both A and R are true and R is the true explanation of A

B Both A and R are true but R is not the true explanation of A

C A is true but R is true

D Both A and R are false

SUBSCRIBE
 Solution:

Increased temperature always shifts the equilibrium

towards endothermic reaction.

SUBSCRIBE
 56 g of N2 and 6 g of H2 were kept at 400°C in 1 L vessel.
The equilibrium mixture contained 27.54 g of NH3 . The
approximate value of KC for the above reaction in
mol-2 L2 is :

A 0.128

B 0.118

C 0.148

D 0.008

SUBSCRIBE
 56 g of N2 and 6 g of H2 were kept at 400°C in 1 L vessel.
The equilibrium mixture contained 27.54 g of NH3 . The
approximate value of KC for the above reaction in
mol-2 L2 is :

A 0.128

B 0.118

C 0.148

D 0.008

SUBSCRIBE
 Solution:

SUBSCRIBE
 For the reaction, 2NO2 (g) ⇌ 2NO(g) + O2 (g)
[KC = 1.8 ×10−6 at 184°C, R = 0.00831 kJ/(mol K)]
when Kp and KC are compared at 184°C it is found that :

A whether Kp is greater than, less than or equal to KC

depends upon the total gas pressure

B Kp = K C

C Kp is less than KC

D Kp is greater than KC

SUBSCRIBE
 For the reaction, 2NO2 (g) ⇌ 2NO(g) + O2 (g)
[KC = 1.8 ×10−6 at 184°C, R = 0.00831 kJ/(mol K)]
when Kp and KC are compared at 184°C it is found that :

A whether Kp is greater than, less than or equal to KC

depends upon the total gas pressure

B Kp = K C

C Kp is less than KC

D Kp is greater than KC

SUBSCRIBE
 Solution:

SUBSCRIBE
 1.1 moles of A are mixed with 2.2 moles of B and the mixture is
kept in a 1 L flask till the equilibrium, A + 2B ⇌ 2C + D is reached. At
equilibrium, 0.2 mole of C is formed. The equilibrium constant of
the above reaction is :

A 0.0002

B 0.004

C 0.001

D 0.003

SUBSCRIBE
 1.1 moles of A are mixed with 2.2 moles of B and the mixture is
kept in a 1 L flask till the equilibrium, A + 2B ⇌ 2C + D is reached. At
equilibrium, 0.2 mole of C is formed. The equilibrium constant of
the above reaction is :

A 0.0002

B 0.004

C 0.001

D 0.003

SUBSCRIBE
 Solution:

SUBSCRIBE
 A flask containing 0.5 atm pressure of A2(g), some
solid AB added into flask which undergoes
dissociation according to 2AB(s) ⇌ A2(g) + B2(g)
Kp = 0.06 atm2
The total pressure (in atm) at equilibrium is :

A 0.70

B 0.6

C 0.10

D None of these

SUBSCRIBE
 A flask containing 0.5 atm pressure of A2(g), some
solid AB added into flask which undergoes
dissociation according to 2AB(s) ⇌ A2(g) + B2(g)
Kp = 0.06 atm2
The total pressure (in atm) at equilibrium is :

A 0.70

B 0.6

C 0.10

D None of these

SUBSCRIBE
 Solution:

SUBSCRIBE
 Level 2

SUBSCRIBE
 For N2O4 ⇌ 2NO2 KP = 476 find KC at 288 K

SUBSCRIBE
 For N2O4 ⇌ 2NO2 KP = 476 find KC at 288 K

Ans : 2

SUBSCRIBE
 Solution:

SUBSCRIBE
 PCl5 ⇌ PCl3 + Cl2, KC = 1.844

If 3 moles of PCl5 are taken in 1 L vessel. Find

equilibrium concentration of PCl5 (in M).

SUBSCRIBE
 PCl5 ⇌ PCl3 + Cl2, KC = 1.844

If 3 moles of PCl5 are taken in 1 L vessel. Find

equilibrium concentration of PCl5 (in M).

Ans : 1.4

SUBSCRIBE
 Solution:

SUBSCRIBE
 The dissociation of solid NH4HS in a closed container
produces a pressure of 1.12 atm at 105oC. Calculate Kp for
the equilibrium, NH4HS(s) ⇌ NH3 (g ) + H2S (g)

SUBSCRIBE
 The dissociation of solid NH4HS in a closed container
produces a pressure of 1.12 atm at 105oC. Calculate Kp for
the equilibrium, NH4HS(s) ⇌ NH3 (g ) + H2S (g)

Ans : 0.3136

SUBSCRIBE
 Solution:

SUBSCRIBE
 The equilibrium 2 CuI ⇌ Cu0 + CuII in aqueous medium
at 25°C shifts towards the left in the presence of :

(One or more than one correct option)

A NO3-

B Cl-

C SCN-

D CN-

SUBSCRIBE
 The equilibrium 2 CuI ⇌ Cu0 + CuII in aqueous medium
at 25°C shifts towards the left in the presence of :

(One or more than one correct option)

A NO3-

B Cl-

C SCN-

D CN-

SUBSCRIBE
 Solution:

Cl- , CN- and SCN- forms precipitate with Cu (I), remove

Cu (I) ion from equilibrium and reaction shifts in
backward direction according to Le-Chatelier's
principle.

SUBSCRIBE
 For the reaction, PCl5(g) ⇌ PCl3(g) + Cl2 (g) the forward
reaction at constant temperature is favoured by :

(One or more than one correct option)

A introducing an inert gas at constant volume

B introducing chlorine gas at constant volume

C introducing an inert gas at constant pressure

D increasing the volume of the container

E introducing PCl5 at constant volume

SUBSCRIBE
 For the reaction, PCl5(g) ⇌ PCl3(g) + Cl2 (g) the forward
reaction at constant temperature is favoured by :

(One or more than one correct option)

A introducing an inert gas at constant volume

B introducing chlorine gas at constant volume

C introducing an inert gas at constant pressure

D increasing the volume of the container

E introducing PCl5 at constant volume

SUBSCRIBE
 Solution:

If inert gas is introduced at constant pressure, volume

of container will have to be increased and this will
favour the forward reaction. Also adding PCl5 (g) at
constant volume will favour forward reaction because
PCl5 (g) is a reactant.

SUBSCRIBE
 The degree of dissociation is 0.4 at 400 K and 1.0 atm
for the gaseous reaction PCl5 ⇌ PCl3 + Cl2 .
Assuming ideal behaviour of all the gases, calculate
the density of equilibrium mixture(g/L) at 400 K and
1.0 atm (relative atomic mass of P = 31.0 and Cl =
35.5)

SUBSCRIBE
 The degree of dissociation is 0.4 at 400 K and 1.0 atm
for the gaseous reaction PCl5 ⇌ PCl3 + Cl2 .
Assuming ideal behaviour of all the gases, calculate
the density of equilibrium mixture(g/L) at 400 K and
1.0 atm (relative atomic mass of P = 31.0 and Cl =
35.5)

Ans : 4.54

SUBSCRIBE
 Solution:

SUBSCRIBE
 The progress of reaction, A ⇌ nB with time, is
represented in fig. use given below.

Determine the equilibrium constant, K.

SUBSCRIBE
 The progress of reaction, A ⇌ nB with time, is
represented in fig. use given below.

Determine the equilibrium constant, K.

Ans : 1.2

SUBSCRIBE
 Solution:

SUBSCRIBE
 The equilibrium constant of the reaction
A2 (g )+ B2 (g ) ⇌ 2AB (g) at 100°C is 50. If a one litre
flask containing one mole of A2 is connected to a two
litre flask containing two moles of B2 , how many
moles of AB will be formed at 373 K?

SUBSCRIBE
 The equilibrium constant of the reaction
A2 (g )+ B2 (g ) ⇌ 2AB (g) at 100°C is 50. If a one litre
flask containing one mole of A2 is connected to a two
litre flask containing two moles of B2 , how many
moles of AB will be formed at 373 K?

Ans : 1.86

SUBSCRIBE
 Solution:

SUBSCRIBE
 One mole of N2 and 3 moles of PCl5 are placed in a 100
L vessel heated to 227°C. The equilibrium pressure is
2.05 atm. Assuming ideal behaviour, calculate the
degree of dissociation for PCl5 in the reaction,
PCl5 (g) ⇌ PCl3 (g) + Cl2 (g)

SUBSCRIBE
 One mole of N2 and 3 moles of PCl5 are placed in a 100
L vessel heated to 227°C. The equilibrium pressure is
2.05 atm. Assuming ideal behaviour, calculate the
degree of dissociation for PCl5 in the reaction,
PCl5 (g) ⇌ PCl3 (g) + Cl2 (g)

Ans : 0.33

SUBSCRIBE
 Solution:

SUBSCRIBE
 Assume that the decomposition of HNO3 can be
represented by the following equation
4HNO3(g) ⇌ 4NO2(g) + 2H2O(g) + O2(g)
and the reaction approaches equilibrium at 400 K
temperature and 30 atm pressure. At equilibrium
partial pressure of HNO3 is 2 atm. Calculate Kc in
(mol/L)3 at 400 K:
(Use : R = 0.08 atm-L/mol-K)

SUBSCRIBE
 Assume that the decomposition of HNO3 can be
represented by the following equation
4HNO3(g) ⇌ 4NO2(g) + 2H2O(g) + O2(g)
and the reaction approaches equilibrium at 400 K
temperature and 30 atm pressure. At equilibrium
partial pressure of HNO3 is 2 atm. Calculate Kc in
(mol/L)3 at 400 K:
(Use : R = 0.08 atm-L/mol-K)

Ans : 32

SUBSCRIBE
 Solution:

SUBSCRIBE
 Determine the degree of association (polymerization)
for the reaction in aqueous solution
6HCHO ⇌ C6H12O6
If observed (mean) molar mass of HCHO and C6H12O6
is 150 :

SUBSCRIBE
 Determine the degree of association (polymerization)
for the reaction in aqueous solution
6HCHO ⇌ C6H12O6
If observed (mean) molar mass of HCHO and C6H12O6
is 150 :

Ans : 0.96

SUBSCRIBE
 Solution:

SUBSCRIBE
 One mole of nitrogen is mixed with three moles of
hydrogen in a four litre container. If 0.25 percent of
nitrogen is converted to ammonia by the following
reaction N2(g) + 3H2(g) ⇌ NH3(g ) , then calculate the
equilibrium constant, Kc in concentration units.

SUBSCRIBE
 One mole of nitrogen is mixed with three moles of
hydrogen in a four litre container. If 0.25 percent of
nitrogen is converted to ammonia by the following
reaction N2(g) + 3H2(g) ⇌ NH3(g ) , then calculate the
equilibrium constant, Kc in concentration units.

Ans : 0.468

SUBSCRIBE
 Solution:

SUBSCRIBE
 The thermal dissociation equilibrium of CaCO3(s) is
studied under different conditions
CaCO3 (s) ⇌ CaO(s) + CO2 (g)
For this equilibrium, the correct statement(s) is (are)

(One or more than one correct option)

A ΔH is dependent on T

B K is independent of the initial amount of CaCO3.

C K is dependent on the pressure of CO2 at a given T.

D ΔH is independent of catalyst, if any

SUBSCRIBE
 The thermal dissociation equilibrium of CaCO3(s) is
studied under different conditions
CaCO3 (s) ⇌ CaO(s) + CO2 (g)
For this equilibrium, the correct statement(s) is (are)

(One or more than one correct option)

A ΔH is dependent on T

B K is independent of the initial amount of CaCO3.

C K is dependent on the pressure of CO2 at a given T.

D ΔH is independent of catalyst, if any

SUBSCRIBE
 Solution:

SUBSCRIBE
 A vessel of 250 litre was filled with 0.01 mole of Sb2S3
and 0.01 mole of H2 to attain the equilibrium at 440°C
as Sb2S3(s) + 3H2(g) ⇌ 2Sb(s) + 3H2S(g )
After equilibrium, the H2S formed was analysed by
dissolved it in water and treating with excess of Pb2+
to give 1.19 g of PbS as precipitate. What is the value of
Kc at 440°C?

SUBSCRIBE
 A vessel of 250 litre was filled with 0.01 mole of Sb2S3
and 0.01 mole of H2 to attain the equilibrium at 440°C
as Sb2S3(s) + 3H2(g) ⇌ 2Sb(s) + 3H2S(g )
After equilibrium, the H2S formed was analysed by
dissolved it in water and treating with excess of Pb2+
to give 1.19 g of PbS as precipitate. What is the value of
Kc at 440°C?

Ans : 1

SUBSCRIBE
 Solution:

SUBSCRIBE
 In a chemical reaction ,
the initial concentration of B was 1.5 times of the
concentration of A, but the equilibrium
concentrations of A and B were found to be equal.
The equilibrium constant (K) for the aforesaid
chemical reaction is :

SUBSCRIBE
 In a chemical reaction ,
the initial concentration of B was 1.5 times of the
concentration of A, but the equilibrium
concentrations of A and B were found to be equal.
The equilibrium constant (K) for the aforesaid
chemical reaction is :

Ans : 4

SUBSCRIBE
 Solution:

SUBSCRIBE
 Match standard free energy of the reaction with the
corresponding equilibrium constant.

Column I Column II

A. ΔGo > 0 I. K > 0

B. ΔGo < 0 II. K = 1

C. ΔGo = 0 III. K = 0

IV. K < 1

SUBSCRIBE
 Match standard free energy of the reaction with the
corresponding equilibrium constant.

Column I Column II

A. ΔGo > 0 I. K > 0

B. ΔGo < 0 II. K = 1

C. ΔGo = 0 III. K = 0

IV. K < 1

Ans : A - 4 ; B - 1 ; C - 2

SUBSCRIBE
 Solution:

SUBSCRIBE
 For a reaction, A ⇌ P, the plots of [A] and [P] with
time at temperatures T1 and T2 are given on the side.

If T2 > T1 , the correct statement(s) is are (Assume

ΔHӨ and ΔSӨ are independent of temperature and
ratio of ln K at T1 to ln K at T2 is greater than T2 /T1 .
Here H , S , G and K are enthalpy, entropy, Gibbs
energy and equilibrium constant, respectively.)

(One or more than one correct option)

A ΔHӨ < 0 ; ΔSӨ < 0 B ΔGӨ < 0 ; ΔHӨ > 0

C ΔGӨ < 0 ; ΔSӨ < 0 D ΔGӨ < 0 ; ΔSӨ > 0

SUBSCRIBE
 For a reaction, A ⇌ P, the plots of [A] and [P] with
time at temperatures T1 and T2 are given on the side.

If T2 > T1 , the correct statement(s) is are (Assume

ΔHӨ and ΔSӨ are independent of temperature and
ratio of ln K at T1 to ln K at T2 is greater than T2 /T1 .
Here H , S , G and K are enthalpy, entropy, Gibbs
energy and equilibrium constant, respectively.)

(One or more than one correct option)

A ΔHӨ < 0 ; ΔSӨ < 0 B ΔGӨ < 0 ; ΔHӨ > 0

C ΔGӨ < 0 ; ΔSӨ < 0 D ΔGӨ < 0 ; ΔSӨ > 0

SUBSCRIBE
 Solution:

SUBSCRIBE
 The equilibrium SO2Cl2 (g) ⇌ SO2 (g) + Cl2 (g) is
attained at 25°C in a closed container and an inert
gas, helium is introduced. Which of the following
statements are correct?

(One or more than one correct option)

A Concentration of SO2 ,Cl2 and SO2Cl2 change.

B More chlorine is formed

C Concentration of SO2 is reduced

D None of the above

SUBSCRIBE
 The equilibrium SO2Cl2 (g) ⇌ SO2 (g) + Cl2 (g) is
attained at 25°C in a closed container and an inert
gas, helium is introduced. Which of the following
statements are correct?

(One or more than one correct option)

A Concentration of SO2 ,Cl2 and SO2Cl2 change.

B More chlorine is formed

C Concentration of SO2 is reduced

D None of the above

SUBSCRIBE
 Solution:

SO2Cl2 (g) ⇌ SO2 (g) + Cl2 (g)

Adding inert gas at constant volume will not affect

partial pressure of reactant or products, hence will not
affect equilibrium amount of either reactant or
products.

SUBSCRIBE
 An amount of solid NH4SH is placed in a fask already
containing ammonia gas at a certain temperature
and 0.50 atm pressure. Ammonium hydrogen
sulphide decomposes to yield NH3 and H2S gases in
the fask. When the decomposition reaction reaches
equilibrium, the total pressure in the flask rises to
0.84 atm. The equilibrium constant for NH4SH
decomposition at this temperature is :

SUBSCRIBE
 An amount of solid NH4SH is placed in a fask already
containing ammonia gas at a certain temperature
and 0.50 atm pressure. Ammonium hydrogen
sulphide decomposes to yield NH3 and H2S gases in
the fask. When the decomposition reaction reaches
equilibrium, the total pressure in the flask rises to
0.84 atm. The equilibrium constant for NH4SH
decomposition at this temperature is :

Ans : 0.11

SUBSCRIBE
 Solution:

SUBSCRIBE
 Match the reactions with the relations of equilibrium constants :

Column I Column II

(A) H2(g) + I2 (g) ⇌ 2HI(g) (p) Kp = KC (RT)

(B) N2(g) + 3H2 (g) ⇌ NH3(g) (q) Kp = KC (RT)2

(C) PCl5(g) ⇌ PCl3(g) + Cl2 (g) (r) Kp = KC (RT)-2

(D) NH4SH ⇌ NH3(g) + H2S (g) (s) Kp = KC

(t) Kp = KC (RT)-1

SUBSCRIBE
 Match the reactions with the relations of equilibrium constants :

Column I Column II

(A) H2(g) + I2 (g) ⇌ 2HI(g) (p) Kp = KC (RT)

(B) N2(g) + 3H2 (g) ⇌ NH3(g) (q) Kp = KC (RT)2

(C) PCl5(g) ⇌ PCl3(g) + Cl2 (g) (r) Kp = KC (RT)-2

(D) NH4SH ⇌ NH3(g) + H2S (g) (s) Kp = KC

(t) Kp = KC (RT)-1

Ans : A → (s); B → (r); C → (p); D → (q)

SUBSCRIBE
 Solution:

SUBSCRIBE
 The % yield of ammonia as a function of time in the reaction,
N2(g) + 3H2(g) ⇌ NH3(g) ; ΔH < 0 at ( p , T1 ) is given on the side :

If this reaction is conducted at ( p , T1 ) , with T2 > T1 the % yield by

of ammonia as a function of time is represented by

(One or more than one correct option)

A B

C D

SUBSCRIBE
 The % yield of ammonia as a function of time in the reaction,
N2(g) + 3H2(g) ⇌ NH3(g) ; ΔH < 0 at ( p , T1 ) is given on the side :

If this reaction is conducted at ( p , T1 ) , with T2 > T1 the % yield by

of ammonia as a function of time is represented by

(One or more than one correct option)

A B

C D

SUBSCRIBE
 Solution:

Since, the reaction is exothermic, there will be less

ammonia at equilibrium and higher temperature.
However, rate of reaction increases with rise in
temperature, NH3 will be formed at faster rate in the
initial stage when the temperature is high.

SUBSCRIBE
 Kc for PCl5(g) ⇌ PCl3(g) + Cl2 (g) is 0.04 at 250oC. How
many mole of PCl5 must be added to a 3-litre flask to
obtain a Cl2 concentration of 0.15 M?

SUBSCRIBE
 Kc for PCl5(g) ⇌ PCl3(g) + Cl2 (g) is 0.04 at 250oC. How
many mole of PCl5 must be added to a 3-litre flask to
obtain a Cl2 concentration of 0.15 M?

Ans : 2.1

SUBSCRIBE
 Solution:

SUBSCRIBE
 The density of an equilibrium mixture of N2O4 and NO2
at 1 atm and 348 K is 184 g/L. Calculate Kc for the
equilibrium
N2O4(g) ⇌ 2NO2(g)

SUBSCRIBE
 The density of an equilibrium mixture of N2O4 and NO2
at 1 atm and 348 K is 184 g/L. Calculate Kc for the
equilibrium
N2O4(g) ⇌ 2NO2(g)

Ans : 9

SUBSCRIBE
 Solution:

SUBSCRIBE
 For the reaction A(g) ⇌ B(g) at 495 K , ΔrGo = –9.478 kJ mol–1.
If we start the reaction in a closed container at 495 K with 22
millimoles of A, the amount of B in the equilibrium mixture is
_______ millimoles. (Round off to the Nearest Integer).
[R = 8.314 J mol–1 K–1 ; ln 10 = 2.303]

SUBSCRIBE
 For the reaction A(g) ⇌ B(g) at 495 K , ΔrGo = –9.478 kJ mol–1.
If we start the reaction in a closed container at 495 K with 22
millimoles of A, the amount of B in the equilibrium mixture is
_______ millimoles. (Round off to the Nearest Integer).
[R = 8.314 J mol–1 K–1 ; ln 10 = 2.303]

Ans : 20

SUBSCRIBE
 Solution:

SUBSCRIBE
Join Vedantu JEE
Telegram channel
NOW!
Assignments
Notes
Daily Update

https://vdnt.in/JEEVedantu