Safety Data Sheet
Acylics polyurethane finish
Conforms to Regulation (EC) No. HQ-SDS-012, Annex II, as amended by Regulation No. 7th Sep. 2008
SECTION 1 : Identification of the substance/ mixture and of the company/ undertaking
1.1 Product identifier
Product name: Acylicpolyrerthane finish
Company name: Wuhan hongqiao coating.Co,.Ltd.
1.2 Relevant identified uses of the substance or mixture and uses advised against
Field of application : used only as part of two- or multi component products.
Ready-for-use mixture : (see base component)
Identified uses : Industrial applications, Professional applications, Used by spraying.
1.3 Details of the supplier of the safety data sheet 1.4 Emergency telephone number
Company details : Panwan Chemical Emergency telephone number (with hours of operation)
industrial estate Jiayu
HUBEI province +86 0715-6067456 (08.00 - 17.00)
SECTION 2 : Hazards identification
2.1 Classification of the substance or mixture
Product definition : Mixture
Classification according to Regulation (EC) No. HQ-SDS-012
2.2 Label elements
Hazard pictograms :
Signal word : Warning
Precautionary statements : Wear protective gloves. Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
Prevention : hexamethylene diisocyanate, oligomerisation product (biuret type)
hexamethylene-di-isocyanate
Hazardous ingredients : Contains isocyanates. May produce an allergic reaction.
Supplemental label elements :
Not applicable.
Special packaging requirements
Containers to be fitted with child-
resistant fastenings : Not applicable.
Tactile warning of danger :
Version: 0.09 Page: 1/12
Safety Data Sheet
Acylics polyurethane finish
SECTION 3 : Composition/ information on ingredients
3.2 Mixtures
Product/ ingredient name % CAS
hydrocy acrylic resin ≥50 - ≤75 79-10-7
xylene ≥5 - <10 1330-20-7
Ethlene glycol ether acetate
≥5- ≤10 95-47-6
pigment
≥10 - ≤20
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
SECTION 4: First aid measures
4.1 Description of first aid measures
General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth
to an unconscious person.
If breathing is irregular, drowsiness, loss of consciousness or cramps: Call 119 and give immediate
treatment (first aid).
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15
minutes, occasionally lifting the upper and lower eyelids. In all cases of doubt, or when symptoms
persist, seek medical attention.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Give nothing by
mouth. If unconscious, place in recovery position and get medical attention immediately.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use
recognized skin cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show this container or label. Keep person warm
and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so
that vomit will not re-enter the mouth and throat.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that
fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing
apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
4.2 Most important symptoms and effects, both acute and delayed
Safety Data Sheet
Acylics polyurethane finish
SECTION 4: First aid measures
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No specific data.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : If gasses have been inhaled, from the decomposition of the product, symptoms may be delayed. Treat
symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested
or inhaled.
Specific treatments : No specific treatment.
SECTION 5 : Firefighting measures
5.1 Extinguishing media
Extinguishing media : Recommended: alcohol resistant foam, CO2 , powders, water spray.
Not to be used: waterjet.
5.2 Special hazards arising from the substance or mixture
Hazards from the substance or Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated,
mixture : a pressure increase will occur and the container may burst, with the risk of a subsequent explosion.
Hazardous combustion products : Decomposition products may include the following materials: carbon oxides nitrogen oxides
5.3 Advice for firefighters
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any
personal risk or without suitable training. Fire will produce dense black smoke. Exposure to decomposition products may cause a health
hazard. Cool closed containers exposed to fire with water. Do not release runoff from fire to drains or watercourses. Fire-fighters should
wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a
basic level of protection for chemical incidents.
SECTION 6 : Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Avoid all direct contact with the spilled material. Exclude sources of ignition and be aware of explosion hazard. Ventilate the area. Avoid
breathing vapor or mist. Refer to protective measures listed in sections 7 and 8. No action shall be taken involving any personal risk or
without suitable training. If the product contaminates lakes, rivers, or sewers, inform the appropriate authorities in accordance with local
regulations.
6.2 Environmental precautions
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air).
6.3 Methods and materials for containment and cleaning up
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Use spark-proof tools and explosion-proof equipment.
Safety Data Sheet
Acylics polyurethane finish
SECTION 6 : Accidental release measures
See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.
SECTION 7 : Handling and storage
7.1 Precautions for safe handling
Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Prevent the creation of flammable or
explosive concentrations of vapors in air and avoid vapor concentrations higher than the occupational exposure limits. In addition, the
product should be used only in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment
should be protected to the appropriate standard. To dissipate static electricity during transfer, ground drum and connect to receiving
container with bonding strap. No sparking tools should be used. Contains isocyanates. Exposure to isocyanate may result in acute irritation
and/or sensitisation when breathing.
Care should be taken when re-opening partly-used containers.
Avoid inhalation of vapour, dust and spray mist. Avoid contact with skin and eyes. Eating, drinking and smoking should be prohibited in area
where this material is handled, stored and processed. Appropriate personal protective equipment: see Section 8. Always keep in containers
made from the same material as the original one.
7.2 Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations for flammable liquids. Store in a cool, well-ventilated area away from incompatible materials and
ignition sources. Keep out of the reach of children. Keep away from: Oxidizing agents, strong alkalis, strong acids as well as of amines,
alcohols and water. No smoking. Prevent unauthorized access. Containers that are opened must be carefully resealed and kept upright to
prevent leakage.
7.3 Specific end use(s)
See separate Product Data Sheet for recommendations or industrial sector specific solutions.
SECTION 8 : Exposure controls/ personal protection
8.1 Control parameters
Recommended monitoring procedures
If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment.
Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres -
Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy)
European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure
to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of
procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
8.2 Exposure controls
Appropriate engineering controls
Arrange sufficient ventilation by local exhaust ventilation and good general ventilation to keep the airborne concentrations of vapors or dust
lowest possible and below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-
station location.
Individual protection measures
General : Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be
worn when soiling is so great that regular work clothes do not adequately protect skin against contact
with the product. Safety eyewear should be used when there is a likelihood of exposure.
Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,
using lavatory, and at the end of day.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the assessment indicates a higher degree of
protection: chemical splash goggles.
Hand protection : Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. The
quality of the chemical-resistant protective gloves must be chosen as a function of the specific
workplace concentrations and quantity of hazardous substances.
Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the
appropriate type. Below listed glove(s) should be regarded as generic advice:
Recommended: Silver Shield / Barrier / 4H gloves, polyvinyl alcohol (PVA), Viton®
May be used: nitrile rubber, butyl rubber
Short term exposure: neoprene rubber, natural rubber (latex), polyvinyl chloride (PVC)
Body protection : Personal protective equipment for the body should be selected based on the task being performed and
the risks involved handling this product.
Wear suitable protective clothing. Always wear protective clothing when spraying.
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator. If
working areas have insufficient ventilation: When the product is applied by means that will not generate
an aerosol such as, brush or roller wear half or totally covering mask equipped with gas filter of type A,
when grinding use particle filter of type P. Be sure to use an approved/certified respirator or equivalent.
Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous
fumes. Wet sanding/flatting should be used wherever possible. If exposure cannot be avoided by the
SECTION 9:Physical and Chemical proprties
Physical state : Liquid
Color: Transparent
Odor: Solvent-like
PH: Testing not relevant or not possible due to nature of the produt
Melting point: -25.5℃
Flash point: Closed cup:40℃ (104F)
Specific gravity: 1.0-1.3g/cm3
Viscosity: Aspiration hazard Not classified ,Testing not relevant due to nature of the product
Explosive properties: Testing not relevant or not possible due to nature of the product
Oxidizing properties: Testing not relevant or not possible due to nature of the product
SECTIONG 10: Stability and reactivity
Higly reactive or incompatible with the following materials :oxidizing materials
Reactive or incompatible with the following materials:reducing materials
When exposed to high temperatures(i.e. in case of fire) harmful decomposition products may be formed:
Decomposition products may include the following materials:carbon oxides nitrogen oxides.
SECTION 11:Toxicological information
Xylene:
LD50:4300mg/kg (By mouse mouth)
LDLo:50mg/kg ( By people mouth)
LDLo:50mg/kg (By mouse mouth)
LD50:1700mg/kg (Guinea rabbit skin)
Ethyl acetate
LD50:5620mg/kg (By mouse mouth)
LD50:4940mg/kg (By mouse mouth)
LC50:1600mg/m3,8 hour(By mouse )
Pigment:No known significant effects
Hydrocy acrylic resin
LD50:5000mg/kg ( By people mouse mouth)
Acute toxicity:dizzy,headache etc uncomfortable reactions
Carcinogenicity :No known data avaliable in our database
Thrill:for skin and eye
Reproductive toxicity :No known data avaliable in our database
Respiratory or skin allergy:May cause skin allergy to susceptible
SECTION 12:Ecological information
Ecotoicity:No known data avaliable in our database
Biological concentration:No known data avaliable in our database
Biodegradability:No known data avaliable in our database
Non-biodegradability:No known data avaliable in our database
SECTION 13:Disposal considerations
Waste treatment methods
The generation of waste should be avoided or minimized wherever possible. Residuce of the product is listed as
hazardous waste.Dispose of according to all state and local applicable regulatons, Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of all authoritier with jurisdiction. Spillage
remains,discarded clothes and similar should be discarded in a fireproof container.
SECTION 14:Transport information
Dangerous goods No:32198
Dangerous goods(UN)No:1139
Hazard Classification(UN):3
Packaging category:Ⅲ
Packing mark:
SECTION 15;Regulatory information
GB1503-1995 Regulations on Safety Management of Hazardous Chemicals
TJ136-79 National Standard for Occupational Hygiene of the People”s Republic of China
GB7691-87 Safety code for painting -Safety .ventilation and air-clean-up for painting process
GB12463-1990 General specification for transport packages of dangerous goods
SECTION 16:Other information
Procedure used to derive the classification accordings to Regulation No.5th Sep. 2018
Department :Technology Wuhan hongqiao coating Co,.LTD.
Modification description:25th. Apr. 2016 Modify according to GB/T1648-2008 Chemical product MSDS
